ACS Environmental Au最新文献

Pretreatment of lignocellulosic biomass is crucial yet challenging for sustainable energy production. This study focuses on enhancing enzymatic accessibility of cellulose in oil palm empty fruit bunches by optimizing pretreatment parameters to improve glucose and ethanol yields while reducing fermentation inhibitors. It evaluates the impact of maleic acid concentrations on biorefinery processes. High maleic acid concentrations (>25% w/w) may allow reuse and offer benefits over lower concentrations, such as enhanced delignification and increased sugar yield under milder conditions. Biomass undergoes pretreatment, enzymatic saccharification, and fermentation using Saccharomyces cerevisiae F118. Pretreatment with 75% maleic acid (w/w) for 60 min at 180 °C effectively removes lignin and hemicellulose, increasing cellulose accessibility but results in 74.8% crystallinity, hindering saccharification. A 50% maleic acid pretreatment yielded higher glucose (77.1%). Optimal ethanol production is achieved with 1% maleic acid pretreatment. However, the ethanol yield is negatively impacted by residual maleic acid on the solid matrix.

Pretreatment of lignocellulosic biomass is crucial yet challenging for sustainable energy production. This study focuses on enhancing enzymatic accessibility of cellulose in oil palm empty fruit bunches by optimizing pretreatment parameters to improve glucose and ethanol yields while reducing fermentation inhibitors. It evaluates the impact of maleic acid concentrations on biorefinery processes. High maleic acid concentrations (>25% w/w) may allow reuse and offer benefits over lower concentrations, such as enhanced delignification and increased sugar yield under milder conditions. Biomass undergoes pretreatment, enzymatic saccharification, and fermentation using Saccharomyces cerevisiae F118. Pretreatment with 75% maleic acid (w/w) for 60 min at 180 °C effectively removes lignin and hemicellulose, increasing cellulose accessibility but results in 74.8% crystallinity, hindering saccharification. A 50% maleic acid pretreatment yielded higher glucose (77.1%). Optimal ethanol production is achieved with 1% maleic acid pretreatment. However, the ethanol yield is negatively impacted by residual maleic acid on the solid matrix.

The global transition to clean energy technologies has escalated the demand for lithium (Li), a critical component in rechargeable Li-ion batteries, highlighting the urgent need for efficient and sustainable Li⁺ extraction methods. Nanofiltration (NF)-based separations have emerged as a promising solution, offering selective separation capabilities that could advance resource extraction and recovery. However, an NF-based lithium extraction process differs significantly from conventional water treatment, necessitating a paradigm shift in membrane materials design, performance evaluation metrics, and process optimization. In this review, we first explore the state-of-the-art strategies for NF membrane modifications. Machine learning was employed to identify key parameters influencing Li⁺ extraction efficiency, enabling the rational design of high-performance membranes. We then delve into the evolution of performance evaluation metrics, transitioning from the traditional permeance-selectivity trade-off to a more relevant focus on Li⁺ purity and recovery balance. A system-scale analysis considering specific energy consumption, flux distribution uniformity, and system-scale Li⁺ recovery and purity is presented. The review also examines process integration and synergistic combinations of NF with emerging technologies, such as capacitive deionization. Techno-economic and lifecycle assessments are also discussed to provide insights into the economic viability and environmental sustainability of NF-based Li⁺ extraction. Finally, we highlight future research directions to bridge the gap between fundamental research and practical applications, aiming to accelerate the development of sustainable and cost-effective Li⁺ extraction methods.

The global transition to clean energy technologies has escalated the demand for lithium (Li), a critical component in rechargeable Li-ion batteries, highlighting the urgent need for efficient and sustainable Li⁺ extraction methods. Nanofiltration (NF)-based separations have emerged as a promising solution, offering selective separation capabilities that could advance resource extraction and recovery. However, an NF-based lithium extraction process differs significantly from conventional water treatment, necessitating a paradigm shift in membrane materials design, performance evaluation metrics, and process optimization. In this review, we first explore the state-of-the-art strategies for NF membrane modifications. Machine learning was employed to identify key parameters influencing Li⁺ extraction efficiency, enabling the rational design of high-performance membranes. We then delve into the evolution of performance evaluation metrics, transitioning from the traditional permeance-selectivity trade-off to a more relevant focus on Li⁺ purity and recovery balance. A system-scale analysis considering specific energy consumption, flux distribution uniformity, and system-scale Li⁺ recovery and purity is presented. The review also examines process integration and synergistic combinations of NF with emerging technologies, such as capacitive deionization. Techno-economic and lifecycle assessments are also discussed to provide insights into the economic viability and environmental sustainability of NF-based Li⁺ extraction. Finally, we highlight future research directions to bridge the gap between fundamental research and practical applications, aiming to accelerate the development of sustainable and cost-effective Li⁺ extraction methods.

Brown carbon (BrC) has been recognized as an important light-absorbing carbonaceous aerosol, yet understanding of its influence on regional climate and air quality has been lacking, mainly due to the ignorance of regional coupled meteorology-chemistry models. Besides, assumptions about its emissions in previous explorations might cause large uncertainties in estimates. Here, we implemented a BrC module into the WRF-Chem model that considers source-dependent absorption and avoids uncertainties caused by assumptions about emission intensities. To our best knowledge, we made the first effort to consider BrC in a regional coupled model. We then applied the developed model to explore the impacts of BrC absorption on radiative forcing, regional climate, and air quality in East Asia. We found notable increases in aerosol absorption optical depth (AAOD) in areas with high OC concentrations. The most intense forcing of BrC absorption occurs in autumn over Southeast Asia, and values could reach around 4 W m^–2. The intensified atmospheric absorption modified surface energy balance, resulting in subsequent declines in surface temperature, heat flux, boundary layer height, and turbulence exchanging rates. These changes in meteorological variables additionally modified near-surface dispersion and photochemical conditions, leading to changes of PM_2.5 and O₃ concentrations. These findings indicate that BrC could exert important influence in specific regions and time periods. A more in-depth understanding could be achieved later with the developed model.

Brown carbon (BrC) has been recognized as an important light-absorbing carbonaceous aerosol, yet understanding of its influence on regional climate and air quality has been lacking, mainly due to the ignorance of regional coupled meteorology-chemistry models. Besides, assumptions about its emissions in previous explorations might cause large uncertainties in estimates. Here, we implemented a BrC module into the WRF-Chem model that considers source-dependent absorption and avoids uncertainties caused by assumptions about emission intensities. To our best knowledge, we made the first effort to consider BrC in a regional coupled model. We then applied the developed model to explore the impacts of BrC absorption on radiative forcing, regional climate, and air quality in East Asia. We found notable increases in aerosol absorption optical depth (AAOD) in areas with high OC concentrations. The most intense forcing of BrC absorption occurs in autumn over Southeast Asia, and values could reach around 4 W m^-2. The intensified atmospheric absorption modified surface energy balance, resulting in subsequent declines in surface temperature, heat flux, boundary layer height, and turbulence exchanging rates. These changes in meteorological variables additionally modified near-surface dispersion and photochemical conditions, leading to changes of PM_2.5 and O₃ concentrations. These findings indicate that BrC could exert important influence in specific regions and time periods. A more in-depth understanding could be achieved later with the developed model.

Actinides are elements that are often feared because of their radioactive nature and potentially devastating consequences to humans and the environment if not managed properly. As such, their chemical interactions with the biosphere and geochemical environment, i.e., their “biogeochemistry,” must be studied and understood in detail. In this Review, a summary of the past discoveries and recent advances in the field of actinide biogeochemistry is provided with a particular emphasis on actinides other than thorium and uranium (i.e., actinium, neptunium, plutonium, americium, curium, berkelium, and californium) as they originate from anthropogenic activities and can be mobile in the environment. The nuclear properties of actinide isotopes found in the environment and used in research are reviewed with historical context. Then, the coordination chemistry properties of actinide ions are contrasted with those of common metal ions naturally present in the environment. The typical chelators that can impact the biogeochemistry of actinides are then reviewed. Then, the role of metalloproteins in the biogeochemistry of actinides is put into perspective since recent advances in the field may have ramifications in radiochemistry and for the long-term management of nuclear waste. Metalloproteins are ubiquitous ligands in nature but, as discussed in this Review, they have largely been overlooked for actinide chemistry, especially when compared to traditional environmental chelators. Without discounting the importance of abundant and natural actinide ions (i.e., Th⁴⁺ and UO₂²⁺), the main focus of this review is on trivalent actinides because of their prevalence in the fields of nuclear fuel cycles, radioactive waste management, heavy element research, and, more recently, nuclear medicine. Additionally, trivalent actinides share chemical similarities with the rare earth elements, and recent breakthroughs in the field of lanthanide-binding chelators may spill into the field of actinide biogeochemistry, as discussed hereafter.

Actinides are elements that are often feared because of their radioactive nature and potentially devastating consequences to humans and the environment if not managed properly. As such, their chemical interactions with the biosphere and geochemical environment, i.e., their "biogeochemistry," must be studied and understood in detail. In this Review, a summary of the past discoveries and recent advances in the field of actinide biogeochemistry is provided with a particular emphasis on actinides other than thorium and uranium (i.e., actinium, neptunium, plutonium, americium, curium, berkelium, and californium) as they originate from anthropogenic activities and can be mobile in the environment. The nuclear properties of actinide isotopes found in the environment and used in research are reviewed with historical context. Then, the coordination chemistry properties of actinide ions are contrasted with those of common metal ions naturally present in the environment. The typical chelators that can impact the biogeochemistry of actinides are then reviewed. Then, the role of metalloproteins in the biogeochemistry of actinides is put into perspective since recent advances in the field may have ramifications in radiochemistry and for the long-term management of nuclear waste. Metalloproteins are ubiquitous ligands in nature but, as discussed in this Review, they have largely been overlooked for actinide chemistry, especially when compared to traditional environmental chelators. Without discounting the importance of abundant and natural actinide ions (i.e., Th⁴⁺ and UO₂ ²⁺), the main focus of this review is on trivalent actinides because of their prevalence in the fields of nuclear fuel cycles, radioactive waste management, heavy element research, and, more recently, nuclear medicine. Additionally, trivalent actinides share chemical similarities with the rare earth elements, and recent breakthroughs in the field of lanthanide-binding chelators may spill into the field of actinide biogeochemistry, as discussed hereafter.

This study reviews the literature on mercury (Hg) pollution in the Tapajós River basin from 1992 to 2022, focusing on the bioaccumulation in fish and the associated health risks to humans via ingesting contaminated species. Variability in Hg bioaccumulation was analyzed from both spatial (sub-basins) and ecological (trophic levels) perspectives. Mercury concentrations in fish muscle tissue and spatial differences in Hg levels were analyzed using nonparametric Kruskal-Wallis ANOVA and mapped with Inverse Distance Weighting. Additionally, a risk assessment of mercury contamination was conducted using the Target Hazard Quotient (THQ) and Maximum Safe Consuming Quantity (MSCQ) indices. Results indicate that Hg contamination is pervasive across the basin, with piscivorous fish showing the highest Hg levels, particularly in the middle Tapajós, upper Tapajs óand Teles Pires sub-basins, identified as contamination hotspots. Piscivorous species exhibited high Target Hazard Quotients (THQ), suggesting health risks for local consumers. The MSCQ values indicated that 75% of the fish species analyzed should be consumed in quantities lower than the current consumption daily average to avoid health risks.

This study reviews the literature on mercury (Hg) pollution in the Tapajós River basin from 1992 to 2022, focusing on the bioaccumulation in fish and the associated health risks to humans via ingesting contaminated species. Variability in Hg bioaccumulation was analyzed from both spatial (sub-basins) and ecological (trophic levels) perspectives. Mercury concentrations in fish muscle tissue and spatial differences in Hg levels were analyzed using nonparametric Kruskal–Wallis ANOVA and mapped with Inverse Distance Weighting. Additionally, a risk assessment of mercury contamination was conducted using the Target Hazard Quotient (THQ) and Maximum Safe Consuming Quantity (MSCQ) indices. Results indicate that Hg contamination is pervasive across the basin, with piscivorous fish showing the highest Hg levels, particularly in the middle Tapajós, upper Tapajs óand Teles Pires sub-basins, identified as contamination hotspots. Piscivorous species exhibited high Target Hazard Quotients (THQ), suggesting health risks for local consumers. The MSCQ values indicated that 75% of the fish species analyzed should be consumed in quantities lower than the current consumption daily average to avoid health risks.