This study presents the fabrication of LiFePO4 (LFP)-coated carbon fibers (CFs) as a positive electrode component for structural batteries, utilizing a spray coating technique. The successful coating of CFs through this method demonstrated their usefulness as efficient current collectors. The electrodes obtained using this method underwent electrochemical evaluations. Throughout the extended cycling tests at C/7, the maximum specific discharge capacity reached 146 mAh/g, maintaining a 77% capacity retention after 100 cycles. In rate performance assessments at the faster C-rate of 1.5C, the capacity measured 123 mAh/g, with a retention of 96%. The application of spray coating emerges as a promising technique for electrode production in structural batteries, showcasing its potential for optimizing performance in multifunctional energy storage systems.
本研究介绍了利用喷涂技术制造包覆碳纤维(CF)的磷酸铁锂(LFP),作为结构电池的正极元件。通过这种方法成功涂覆的碳纤维证明了其作为高效电流收集器的实用性。利用这种方法获得的电极进行了电化学评估。在 C/7 条件下进行的长时间循环测试中,最大比放电容量达到 146 mAh g-1,100 次循环后容量保持率为 77%。在以 1.5C 的较快 C 速率进行的速率性能评估中,容量测量值为 123 mAh g-1,容量保持率为 96%。喷涂技术是结构电池电极生产中一项前景广阔的技术,展示了其在优化多功能储能系统性能方面的潜力。
{"title":"LiFePO4-coated carbon fibers as positive electrodes in structural batteries: Insights from spray coating technique","authors":"Yasemin Duygu Yücel , Dan Zenkert , Rakel Wreland Lindström , Göran Lindbergh","doi":"10.1016/j.elecom.2024.107670","DOIUrl":"10.1016/j.elecom.2024.107670","url":null,"abstract":"<div><p>This study presents the fabrication of LiFePO<sub>4</sub> (LFP)-coated carbon fibers (CFs) as a positive electrode component for structural batteries, utilizing a spray coating technique. The successful coating of CFs through this method demonstrated their usefulness as efficient current collectors. The electrodes obtained using this method underwent electrochemical evaluations. Throughout the extended cycling tests at C/7, the maximum specific discharge capacity reached 146 mAh/g, maintaining a 77% capacity retention after 100 cycles. In rate performance assessments at the faster C-rate of 1.5C, the capacity measured 123 mAh/g, with a retention of 96%. The application of spray coating emerges as a promising technique for electrode production in structural batteries, showcasing its potential for optimizing performance in multifunctional energy storage systems.</p></div>","PeriodicalId":304,"journal":{"name":"Electrochemistry Communications","volume":null,"pages":null},"PeriodicalIF":5.4,"publicationDate":"2024-01-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1388248124000134/pdfft?md5=46b5efbf4bd9a0f73559cfa6d9bddacf&pid=1-s2.0-S1388248124000134-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139552159","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-01-24DOI: 10.1016/j.elecom.2024.107669
Linyue Li, Yang Wang, Binbin Dan, Shixuan Li, Zhoulu Wang, Di Wang, Xiang Liu
In conventional Li-CO2 batteries, Li2CO3 is an intractable discharge product due to its wide bandgap. To this end, researchers have focused more attention on the decomposition of Li2CO3 in order to reduce the high charge potential. However, even the kinetics of CO2 evolution process can be accelerated, Li2CO3 will still passivate the cathodes, which in turn affects the cycle life of Li-CO2 batteries. Here, we designed a CO2 partly-absent Li-CO2 battery, the concentration of CO2 involved during the discharge process is reduced, then the discharge potential of this battery can be moved to 2.1 V. Furthermore, the discharge product of this CO2 partly-absent Li-CO2 battery is proved to be LiOH instead of Li2CO3, it can be recharged at a low potential of 3.5 V benefit from the readily degradable product (LiOH). In this Li-CO2 battery, the effect of gas concentration on discharge process is studied firstly, and totally different results are discussed, offering new insights into the material design and the development of reliable rechargeable Li-CO2 batteries in the future.
{"title":"Gas concentration-driven LiOH chemistry in Li-CO2 batteries","authors":"Linyue Li, Yang Wang, Binbin Dan, Shixuan Li, Zhoulu Wang, Di Wang, Xiang Liu","doi":"10.1016/j.elecom.2024.107669","DOIUrl":"10.1016/j.elecom.2024.107669","url":null,"abstract":"<div><p>In conventional Li-CO<sub>2</sub> batteries, Li<sub>2</sub>CO<sub>3</sub> is an intractable discharge product due to its wide bandgap. To this end, researchers have focused more attention on the decomposition of Li<sub>2</sub>CO<sub>3</sub> in order to reduce the high charge potential. However, even the kinetics of CO<sub>2</sub> evolution process can be accelerated, Li<sub>2</sub>CO<sub>3</sub> will still passivate the cathodes, which in turn affects the cycle life of Li-CO<sub>2</sub> batteries. Here, we designed a CO<sub>2</sub> partly-absent Li-CO<sub>2</sub> battery, the concentration of CO<sub>2</sub> involved during the discharge process is reduced, then the discharge potential of this battery can be moved to 2.1 V. Furthermore, the discharge product of this CO<sub>2</sub> partly-absent Li-CO<sub>2</sub> battery is proved to be LiOH instead of Li<sub>2</sub>CO<sub>3</sub>, it can be recharged at a low potential of 3.5 V benefit from the readily degradable product (LiOH). In this Li-CO<sub>2</sub> battery, the effect of gas concentration on discharge process is studied firstly, and totally different results are discussed, offering new insights into the material design and the development of reliable rechargeable Li-CO<sub>2</sub> batteries in the future.</p></div>","PeriodicalId":304,"journal":{"name":"Electrochemistry Communications","volume":null,"pages":null},"PeriodicalIF":5.4,"publicationDate":"2024-01-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1388248124000122/pdfft?md5=27501bc6171fcb783c9503b0a6e60413&pid=1-s2.0-S1388248124000122-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139552778","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-01-24DOI: 10.1016/j.elecom.2024.107666
Seong Cheol Kim, Hiroaki Tsuchiya, Shinji Fujimoto
A numerical simulation of photocurrent transient was proposed to estimate properties of passive films and anodic films formed on pure Ti. To simulate photocurrent transient, partial differential equations describing the change in the concentration and positions of photoexcited charge carriers with time were developed based on the generation, recombination, and transports of the carriers. Simulations were performed by screening several parameters. The electron mobility, donor density, recombination coefficient and interfacial reaction rate coefficient were estimated by fitting simulated photocurrent transients to experimentally obtained transients.
{"title":"Numerical simulation of photocurrent transients generated from passive films and anodic films on pure Ti","authors":"Seong Cheol Kim, Hiroaki Tsuchiya, Shinji Fujimoto","doi":"10.1016/j.elecom.2024.107666","DOIUrl":"10.1016/j.elecom.2024.107666","url":null,"abstract":"<div><p>A numerical simulation of photocurrent transient was proposed to estimate properties of passive films and anodic films formed on pure Ti. To simulate photocurrent transient, partial differential equations describing the change in the concentration and positions of photoexcited charge carriers with time were developed based on the generation, recombination, and transports of the carriers. Simulations were performed by screening several parameters. The electron mobility, donor density, recombination coefficient and interfacial reaction rate coefficient were estimated by fitting simulated photocurrent transients to experimentally obtained transients.</p></div>","PeriodicalId":304,"journal":{"name":"Electrochemistry Communications","volume":null,"pages":null},"PeriodicalIF":5.4,"publicationDate":"2024-01-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1388248124000092/pdfft?md5=85cae9073afdff6173ec096f8dae262c&pid=1-s2.0-S1388248124000092-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139552651","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-01-19DOI: 10.1016/j.elecom.2024.107668
Jae-Hee Jeon , Ji-Eun Kim , Tae-Hyun Kim , Chu-Sik Park , Kwangjin Jung , Jaekyung Yoon , Joonho Kim , Young-Ho Kim , Kyoung-Soo Kang
This study fabricated an OER electrocatalyst with a hierarchical structure by electrodepositing Ni-Fe on NiO. The prepared electrocatalyst exhibited high activity and stability. Furthermore, the OER characteristics of the NiFe/NiO electrode were investigated by changing the metal (Ni and Fe) concentration and Ni:Fe ratio in the plating bath. As the plating bath concentration decreased, NiFe-layered double hydroxide was prominently formed due to an increase in local pH. The electrode obtained using a relatively low plating bath concentration of 130 mM demonstrated high activity with an overpotential of 245 mV and Tafel slope of 27.6 mV dec-1 at a current density of 10 mA/cm2. When the Ni:Fe ratio in the plating bath was adjusted, OER activity increased as the Fe content of the electrode increased to approximately 20.9 at.%, and as the Fe content increased beyond that, the activity gradually decreased. Fe inhibits Ni oxidation and acts as an active site owing to Fe3+ substitution in the γ-NiOOH structure, resulting in increased OER activity. However, when the Fe content was > 29 at.%, the inactive phase γ-FeOOH predominantly grew and the OER activity decreased.
本研究通过在 NiO 上电沉积 Ni-Fe 制备了一种具有分层结构的 OER 电催化剂。所制备的电催化剂具有高活性和稳定性。此外,还通过改变镀液中金属(镍和铁)的浓度以及镍铁比,研究了镍铁/氧化镍电极的 OER 特性。随着电镀液浓度的降低,由于局部 pH 值的升高,镍铁层双氢氧化物显著形成。在电流密度为 10 mA/cm2 时,过电位为 245 mV,Tafel 斜坡为 27.6 mV dec-1。调整镀液中的镍铁合金比例后,当电极中的铁含量增加到约 20.9 at.% 时,OER 活性增加;当铁含量超过这一比例时,活性逐渐降低。由于γ-NiOOH 结构中的 Fe3+ 取代作用,Fe 可抑制 Ni 氧化并充当活性位点,从而提高了 OER 活性。然而,当 Fe 含量为 >29 at.% 时,非活性相 γ-FeOOH 显著增加,OER 活性降低。
{"title":"Enhanced oxygen evolution reaction in hierarchical NiFe/NiO electrocatalysts: Effects of electrodeposition condition on electrode","authors":"Jae-Hee Jeon , Ji-Eun Kim , Tae-Hyun Kim , Chu-Sik Park , Kwangjin Jung , Jaekyung Yoon , Joonho Kim , Young-Ho Kim , Kyoung-Soo Kang","doi":"10.1016/j.elecom.2024.107668","DOIUrl":"10.1016/j.elecom.2024.107668","url":null,"abstract":"<div><p>This study fabricated an OER electrocatalyst with a hierarchical structure by electrodepositing Ni-Fe on NiO. The prepared electrocatalyst exhibited high activity and stability. Furthermore, the OER characteristics of the NiFe/NiO electrode were investigated by changing the metal (Ni and Fe) concentration and Ni:Fe ratio in the plating bath. As the plating bath concentration decreased, NiFe-layered double hydroxide was prominently formed due to an increase in local pH. The electrode obtained using a relatively low plating bath concentration of 130 mM demonstrated high activity with an overpotential of 245 mV and Tafel slope of 27.6 mV dec<sup>-1</sup> at a current density of 10 mA/cm<sup>2</sup>. When the Ni:Fe ratio in the plating bath was adjusted, OER activity increased as the Fe content of the electrode increased to approximately 20.9 at.%, and as the Fe content increased beyond that, the activity gradually decreased. Fe inhibits Ni oxidation and acts as an active site owing to Fe<sup>3+</sup> substitution in the γ-NiOOH structure, resulting in increased OER activity. However, when the Fe content was > 29 at.%, the inactive phase γ-FeOOH predominantly grew and the OER activity decreased.</p></div>","PeriodicalId":304,"journal":{"name":"Electrochemistry Communications","volume":null,"pages":null},"PeriodicalIF":5.4,"publicationDate":"2024-01-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1388248124000110/pdfft?md5=3b42b0327cb53c7ecb6e6e405e15bb82&pid=1-s2.0-S1388248124000110-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139509903","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-01-19DOI: 10.1016/j.elecom.2024.107667
Shun-Yi Jian , Yu-Cheng Liu , Chin-Jou Chang
Mg is the lightest structural metal on earth; hence, applications of its alloys have attracted attention from researchers. However, these alloys have poor corrosion resistance, which impedes their use in practice. Many researchers have investigated protective coatings for Mg alloys, but current methods consume much energy, use hazardous substances, or are complex (such as anodizing and micro-arc oxidation). This paper proposes a novel method of creating a durable and protective coating on Mg alloy substrates. The AZ91D Mg alloy was selected for investigation, and a Mn-V-P conversion coating treatment in which voltage of only 5 V was applied for 1 min to enhance the alloy’s corrosion resistance. A compact, single-layer film with uniform thickness was created; the average thickness was 1750 nm. The corrosion resistance of alloys treated with the method and through anodizing treatment was compared. For the novel coating, the corroded area fraction after a 168-h salt spray test was less than 5 %, superior to that for the coating produced through anodizing treatment. The feasibility and potential applications of the novel process are discussed.
{"title":"Novel green and ecofriendly route for fabricating a robust corrosion protection coating on AZ91D magnesium alloy","authors":"Shun-Yi Jian , Yu-Cheng Liu , Chin-Jou Chang","doi":"10.1016/j.elecom.2024.107667","DOIUrl":"10.1016/j.elecom.2024.107667","url":null,"abstract":"<div><p>Mg is the lightest structural metal on earth; hence, applications of its alloys have attracted attention from researchers. However, these alloys have poor corrosion resistance, which impedes their use in practice. Many researchers have investigated protective coatings for Mg alloys, but current methods consume much energy, use hazardous substances, or are complex (such as anodizing and micro-arc oxidation). This paper proposes a novel method of creating a durable and protective coating on Mg alloy substrates. The AZ91D Mg alloy was selected for investigation, and a Mn-V-P conversion coating treatment in which voltage of only 5 V was applied for 1 min to enhance the alloy’s corrosion resistance. A compact, single-layer film with uniform thickness was created; the average thickness was 1750 nm. The corrosion resistance of alloys treated with the method and through anodizing treatment was compared. For the novel coating, the corroded area fraction after a 168-h salt spray test was less than 5 %, superior to that for the coating produced through anodizing treatment. The feasibility and potential applications of the novel process are discussed.</p></div>","PeriodicalId":304,"journal":{"name":"Electrochemistry Communications","volume":null,"pages":null},"PeriodicalIF":5.4,"publicationDate":"2024-01-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1388248124000109/pdfft?md5=7718b4ea380458d60a02e0683c4958c2&pid=1-s2.0-S1388248124000109-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139552253","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-01-10DOI: 10.1016/j.elecom.2024.107665
Yurika Taniguchi , Shinya Kokuryo , Ryuji Takada , Xinran Yang , Koji Miyake , Yoshiaki Uchida , Norikazu Nishiyama
Heteroatom-doped carbons have attracted increasing attention in recent years as inexpensive high-performance electrocatalytic materials owing to their electrical properties. A precisely controlled synthesis method for heteroatom-doped carbons is important to improve their performance and expand their applications. In this study, we developed a fluoropyridine-medicated zeolite templating method for Nitrogen/Fluorine (N/F) co-doped carbons. The N/F co-doped carbons showed better catalytic performances for oxygen reduction reaction (ORR) than N-doped carbon prepared using pyridine. In particular, the optimized N/F co-doped carbon exhibited a higher half-wave potential (0.87 V vs. RHE) than commercial Pt-loaded carbon black and N/F co-doped carbons reported in the literature. The comparative studies using various N/F co-doped carbons revealed that semi-ionic bonded C-F might improve ORR activity. In contrast, the contribution from covalent or ionic C-F to improving ORR activity would be negligible.
近年来,掺杂杂原子的碳因其电性能而成为廉价的高性能电催化材料,受到越来越多的关注。精确控制掺杂杂原子碳的合成方法对于提高其性能和扩大其应用范围非常重要。在本研究中,我们开发了一种氟吡啶药用沸石模板法,用于氮/氟(N/F)共掺杂碳。与使用吡啶制备的氮掺杂碳相比,氮/氟共掺杂碳在氧还原反应(ORR)中表现出更好的催化性能。特别是,与文献报道的商用铂载碳黑和 N/F 共掺碳相比,优化的 N/F 共掺碳显示出更高的半波电位(0.87 V vs. RHE)。使用各种 N/F 共掺杂碳进行的比较研究表明,半离子键 C-F 可能会提高 ORR 活性。相反,共价或离子 C-F 对提高 ORR 活性的贡献微乎其微。
{"title":"Fluoropyridine-medicated zeolite templating method for N/F co-doped carbon with high electrocatalytic performance on oxygen reduction reaction","authors":"Yurika Taniguchi , Shinya Kokuryo , Ryuji Takada , Xinran Yang , Koji Miyake , Yoshiaki Uchida , Norikazu Nishiyama","doi":"10.1016/j.elecom.2024.107665","DOIUrl":"10.1016/j.elecom.2024.107665","url":null,"abstract":"<div><p>Heteroatom-doped carbons have attracted increasing attention in recent years as inexpensive high-performance electrocatalytic materials owing to their electrical properties. A precisely controlled synthesis method for heteroatom-doped carbons is important to improve their performance and expand their applications. In this study, we developed a fluoropyridine-medicated zeolite templating method for Nitrogen/Fluorine (N/F) co-doped carbons. The N/F co-doped carbons showed better catalytic performances for oxygen reduction reaction (ORR) than N-doped carbon prepared using pyridine. In particular, the optimized N/F co-doped carbon exhibited a higher half-wave potential (0.87 V vs. RHE) than commercial Pt-loaded carbon black and N/F co-doped carbons reported in the literature. The comparative studies using various N/F co-doped carbons revealed that semi-ionic bonded C-F might improve ORR activity. In contrast, the contribution from covalent or ionic C-F to improving ORR activity would be negligible.</p></div>","PeriodicalId":304,"journal":{"name":"Electrochemistry Communications","volume":null,"pages":null},"PeriodicalIF":5.4,"publicationDate":"2024-01-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1388248124000080/pdfft?md5=07333cee4d218595ce141a4b9970bc24&pid=1-s2.0-S1388248124000080-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139412180","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-12-29DOI: 10.1016/j.elecom.2023.107656
Nischal Oli , Wilber Ortiz Lago , Balram Tripathi , Mohan Bhattarai , Brad R. Weiner , Gerardo Morell , Ram S. Katiyar
The urgent demand for stable electrode materials, especially for the anode, arises in the pursuit of high-energy Li-ion batteries. This research focuses on bismuth oxide (Bi2O3) and uncovers its performance through a straightforward, commercially viable synthesis route, along with the optimization of binders and electrolytes. By employing a sodium carboxymethyl cellulose binder and fluoroethylene carbonate additives, the Bi2O3 anode demonstrates significantly enhanced performance compared to prior studies. It attains an impressive initial capacity of approximately 750 mA h g−1, exhibits excellent rate capability at 1000 mA g−1 and maintains stable cycling performance over 6000 cycles.
在开发高能锂离子电池的过程中,对稳定的电极材料,尤其是阳极材料的需求十分迫切。本研究以氧化铋(Bi2O3)为重点,通过直接、商业上可行的合成路线以及粘合剂和电解质的优化,揭示了其性能。通过采用羧甲基纤维素钠粘合剂和氟碳酸乙烯添加剂,Bi2O3 阳极的性能较之前的研究有了显著提高。它达到了令人印象深刻的初始容量(约 750 mA h g-1),在 1000 mA g-1 时表现出卓越的速率能力,并在 6000 个循环周期内保持稳定的循环性能。
{"title":"Enhanced electrochemical performance of Bi2O3 via facile synthesis as anode material for ultra-long cycle lifespan lithium-ion batteries","authors":"Nischal Oli , Wilber Ortiz Lago , Balram Tripathi , Mohan Bhattarai , Brad R. Weiner , Gerardo Morell , Ram S. Katiyar","doi":"10.1016/j.elecom.2023.107656","DOIUrl":"10.1016/j.elecom.2023.107656","url":null,"abstract":"<div><p>The urgent demand for stable electrode materials, especially for the anode, arises in the pursuit of high-energy Li-ion batteries. This research focuses on bismuth oxide (Bi<sub>2</sub>O<sub>3</sub>) and uncovers its performance through a straightforward, commercially viable synthesis route, along with the optimization of binders and electrolytes. By employing a sodium carboxymethyl cellulose binder and fluoroethylene carbonate additives, the Bi<sub>2</sub>O<sub>3</sub> anode demonstrates significantly enhanced performance compared to prior studies. It attains an impressive initial capacity of approximately 750 mA h g<sup>−1</sup>, exhibits excellent rate capability at 1000 mA g<sup>−1</sup> and maintains stable cycling performance over 6000 cycles.</p></div>","PeriodicalId":304,"journal":{"name":"Electrochemistry Communications","volume":null,"pages":null},"PeriodicalIF":5.4,"publicationDate":"2023-12-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S138824812300231X/pdfft?md5=26b5e808534bea4c3727b52714993fbe&pid=1-s2.0-S138824812300231X-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139071402","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-12-29DOI: 10.1016/j.elecom.2023.107652
Shaista Nouseen , Kalyan Ghosh , Martin Pumera
Two-dimensional (2D) MXenes are promising materials for a variety of sustainable energy-related applications such as photoelectrochemical water splitting and energy storage devices. Among the MXene family, the Ti3C2Tx is mostly prepared by selective etching of Al from the Ti3AlC2 MAX phase using hydrofluoric acid (HF) or in-situ produced HF as an etchant. However, the severe toxicity, handling of HF acid as well as the oxidation and degradation of freshly synthesized MXenes when stored as aqueous suspensions obstruct the large-scale production of MXenes. 3D printing is an innovative and versatile technology utilized for a plethora of applications in the field of energy applications. Thus, integration of 3D printing technology with the synthesis procedure of MXene will provide a new outlook for large-scale production and the long-storing capability of MXene. Herein, we fabricated a novel MAX (Ti3AlC2)/polylactic acid (PLA) filament for fused deposition modeling (FDM) 3D printing followed by etching of the 3D-printed MAX/PLA electrode into 3DP-etched-MAX employing chronoamperometry technique consecutively in 9 M HCl and 4 M NaOH as electrolytes. The 3D printed electrochemically etched MAX (3DP-etched-MAX) electrode shows promising behaviour for the photoelectrochemical hydrogen evolution reaction (HER) and capacitive performance. In general, this work demonstrates a path of production of large-scale manufacturing of MAX/PLA filament and 3DP-etched-MAX electrodes without using toxic HF for energy conversion and energy storage applications. This work paves the way to fabricate other novel MAX filaments and electrodes for several applications beyond energy conversion and storage.
二维(2D)MXene 是一种很有前途的材料,可用于各种可持续能源相关应用,如光电化学水分离和储能装置。在 MXene 家族中,Ti3C2Tx 大多是使用氢氟酸(HF)或原位生产的 HF 作为蚀刻剂,通过选择性蚀刻 Ti3AlC2 MAX 相中的 Al 制备而成。然而,氢氟酸的剧毒、处理以及新鲜合成的 MXenes 以水悬浮液形式储存时的氧化和降解都阻碍了 MXenes 的大规模生产。三维打印是一种创新的多功能技术,在能源应用领域有大量的应用。将三维打印技术与 MXene 的合成过程相结合,将为 MXene 的大规模生产和长期储存能力提供新的前景。在本报告中,我们制作了一种新型 MAX(Ti3AlC2)/聚乳酸(PLA)长丝,用于熔融沉积建模(FDM)3D 打印,然后在 9 M HCl 和 4 M NaOH 作为电解质的条件下,连续采用计时朋度技术将 3D 打印的 MAX/PLA 电极蚀刻为 3DP 蚀刻-MAX。三维打印的电化学蚀刻 MAX(3DP-蚀刻-MAX)电极在光电化学氢演化反应(HER)和电容性能方面表现出良好的性能。总之,这项工作为大规模制造 MAX/PLA 长丝和 3DP 蚀刻 MAX 电极而不使用有毒 HF 进行能量转换和储能应用展示了一条生产路径。这项工作为制造其他新型 MAX 长丝和电极铺平了道路,这些长丝和电极可用于能量转换和储存以外的多种应用。
{"title":"3D printing of MAX/PLA filament: Electrochemical in-situ etching for enhanced energy conversion and storage","authors":"Shaista Nouseen , Kalyan Ghosh , Martin Pumera","doi":"10.1016/j.elecom.2023.107652","DOIUrl":"10.1016/j.elecom.2023.107652","url":null,"abstract":"<div><p>Two-dimensional (2D) MXenes are promising materials for a variety of sustainable energy-related applications such as photoelectrochemical water splitting and energy storage devices. Among the MXene family, the Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub> is mostly prepared by selective etching of Al from the Ti<sub>3</sub>AlC<sub>2</sub> MAX phase using hydrofluoric acid (HF) or in-situ produced HF as an etchant. However, the severe toxicity, handling of HF acid as well as the oxidation and degradation of freshly synthesized MXenes when stored as aqueous suspensions obstruct the large-scale production of MXenes. 3D printing is an innovative and versatile technology utilized for a plethora of applications in the field of energy applications. Thus, integration of 3D printing technology with the synthesis procedure of MXene will provide a new outlook for large-scale production and the long-storing capability of MXene. Herein, we fabricated a novel MAX (Ti<sub>3</sub>AlC<sub>2</sub>)/polylactic acid (PLA) filament for fused deposition modeling (FDM) 3D printing followed by etching of the 3D-printed MAX/PLA electrode into 3DP-etched-MAX employing chronoamperometry technique consecutively in 9 M HCl and 4 M NaOH as electrolytes. The 3D printed electrochemically etched MAX (3DP-etched-MAX) electrode shows promising behaviour for the photoelectrochemical hydrogen evolution reaction (HER) and capacitive performance. In general, this work demonstrates a path of production of large-scale manufacturing of MAX/PLA filament and 3DP-etched-MAX electrodes without using toxic HF for energy conversion and energy storage applications. This work paves the way to fabricate other novel MAX filaments and electrodes for several applications beyond energy conversion and storage.</p></div>","PeriodicalId":304,"journal":{"name":"Electrochemistry Communications","volume":null,"pages":null},"PeriodicalIF":5.4,"publicationDate":"2023-12-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1388248123002278/pdfft?md5=2d11ba28a16829d5d2aea692bac18f37&pid=1-s2.0-S1388248123002278-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139062315","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-12-28DOI: 10.1016/j.elecom.2023.107655
Andrei Kulikovsky
A model for impedance of a PEM fuel cell cathode catalyst layer under simultaneous application of potential and oxygen concentration harmonic perturbations is solved. The solution demonstrates strong lowering of the layer impedance under increase in the amplitude of oxygen concentration perturbation. Small in–phase oscillations of the overpotential and oxygen concentration lead to formation of a sub–layer with negligible oxygen transport loss. Working as an ideal non–polarizable electrode, this sub–layer dramatically reduces the system impedance.
{"title":"Performance of a PEM fuel cell cathode catalyst layer under oscillating potential and oxygen supply","authors":"Andrei Kulikovsky","doi":"10.1016/j.elecom.2023.107655","DOIUrl":"10.1016/j.elecom.2023.107655","url":null,"abstract":"<div><p>A model for impedance of a PEM fuel cell cathode catalyst layer under simultaneous application of potential and oxygen concentration harmonic perturbations is solved. The solution demonstrates strong lowering of the layer impedance under increase in the amplitude of oxygen concentration perturbation. Small in–phase oscillations of the overpotential and oxygen concentration lead to formation of a sub–layer with negligible oxygen transport loss. Working as an ideal non–polarizable electrode, this sub–layer dramatically reduces the system impedance.</p></div>","PeriodicalId":304,"journal":{"name":"Electrochemistry Communications","volume":null,"pages":null},"PeriodicalIF":5.4,"publicationDate":"2023-12-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1388248123002308/pdfft?md5=238f7db55bf70cf2b8f34ff3e8833db4&pid=1-s2.0-S1388248123002308-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139061782","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
In this work, we study the oxygen reduction reaction (ORR) properties of Pt-containing 3d transition-metal high-entropy alloy (Pt-HEA) surfaces, focusing on the constituent alloying elements. The surface Pt and underlying Cr-Mn-Co-Ni(1 1 1) (Pt/Cr-Mn-Co-Ni(1 1 1)) stacked lattice layers, which are synthesized through the vacuum deposition of the underlying alloy and surface Pt stacking layers on Pt(1 1 1) substrate, exhibit high pristine ORR activity and structural stability under potential-cycle loading, compared to Pt/Cr-Co-Ni, Pt/Mn-Co-Ni, and Pt/Co-Ni(1 1 1) surfaces. The outperformed ORR properties are attributed to the effective suppression of the surface segregation of Cr. This study demonstrates that not only the “high-entropy” effect induced by increasing the numbers of constituent elements but also the “chemical affinity” of Pt and the individual HEA constituent elements determine the ORR performances of Pt-HEA.
{"title":"Pt-surface stabilization by high-entropy alloys for enhancing oxygen reduction reaction property: Single-crystal model catalyst study","authors":"Yoshihiro Chida , Takeru Tomimori , Naoto Todoroki , Toshimasa Wadayama","doi":"10.1016/j.elecom.2023.107657","DOIUrl":"10.1016/j.elecom.2023.107657","url":null,"abstract":"<div><p>In this work, we study the oxygen reduction reaction (ORR) properties of Pt-containing 3<em>d</em> transition-metal high-entropy alloy (Pt-HEA) surfaces, focusing on the constituent alloying elements. The surface Pt and underlying Cr-Mn-Co-Ni(1<!--> <!-->1<!--> <!-->1) (Pt/Cr-Mn-Co-Ni(1<!--> <!-->1<!--> <!-->1)) stacked lattice layers, which are synthesized through the vacuum deposition of the underlying alloy and surface Pt stacking layers on Pt(1<!--> <!-->1<!--> <!-->1) substrate, exhibit high pristine ORR activity and structural stability under potential-cycle loading, compared to Pt/Cr-Co-Ni, Pt/Mn-Co-Ni, and Pt/Co-Ni(1<!--> <!-->1<!--> <!-->1) surfaces. The outperformed ORR properties are attributed to the effective suppression of the surface segregation of Cr. This study demonstrates that not only the “high-entropy” effect induced by increasing the numbers of constituent elements but also the “chemical affinity” of Pt and the individual HEA constituent elements determine the ORR performances of Pt-HEA.</p></div>","PeriodicalId":304,"journal":{"name":"Electrochemistry Communications","volume":null,"pages":null},"PeriodicalIF":5.4,"publicationDate":"2023-12-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1388248123002321/pdfft?md5=271f257cd95f6013aac964a33c319fc9&pid=1-s2.0-S1388248123002321-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139057053","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}