Pub Date : 2026-02-01DOI: 10.1016/j.electacta.2026.148353
Martin Šefčík, Ghazaleh Kholafazadehastamal, Thomas Peeters, Jan Fischer, Anna Kubíčková, Clive E. Hall, Josephus G. Buijnsters, Simona Baluchová
Venlafaxine (VF) and its active metabolite desvenlafaxine (DVF) are widely prescribed antidepressants that are only partially metabolized and excreted in significant amounts, making them clinically important analytes and environmentally relevant contaminants. In this study, a free-standing boron-doped diamond (BDD) electrode is exploited in a dual role for the electrochemical detection and degradation of VF and DVF, integrated into a custom 3D-printed dual-function electrochemical cell. The nucleation (BDDNS) and growth (BDDGS) sides of the BDD plate were systematically compared under different surface terminations. Oxidized BDDNS (O-BDDNS) provided three well-resolved oxidation peaks for VF, whereas hydrogen-terminated BDDNS (H-BDDNS) yielded a single distinct peak for DVF in 0.1 M H2SO4. Differential pulse voltammetric (DPV) methods were developed with limits of detection of 0.35 µM for VF (peak 1) and 0.34 µM for DVF and wide linear ranges in the low-to-high micromolar region. By exploiting the different surface-termination preferences and multi-peak behaviour of VF, simultaneous determination of VF and DVF was achieved. The methods showed good selectivity toward common interferents and were successfully applied to spiked river water and pharmaceutical capsules using the standard addition approach, giving recoveries close to 100%. In the 3D-printed cell, BDDGS was used for electrochemical advanced oxidation, achieving ∼97% degradation of 1 mM VF and DVF in 0.1 M H2SO4 within 20 min under galvanostatic conditions, following pseudo-first-order kinetics. In situ DPV on BDDNS enabled real-time monitoring of VF decay, demonstrating an integrated detect-and-degrade platform based on BDD and additive manufacturing.
文拉法辛（VF）及其活性代谢物去文拉法辛（DVF）是广泛使用的抗抑郁药，仅部分代谢并大量排出，使其成为临床重要分析物和环境相关污染物。在这项研究中，一个独立的掺硼金刚石（BDD）电极被用于VF和DVF的电化学检测和降解的双重作用，集成到一个定制的3d打印双功能电化学电池中。系统比较了不同表面末端条件下BDD板的成核（BDDNS）面和生长（BDDGS）面。氧化BDDNS （O-BDDNS）在0.1 M H2SO4中产生了三个清晰的VF氧化峰，而端氢BDDNS （H-BDDNS）在0.1 M H2SO4中产生了一个清晰的DVF氧化峰。差分脉冲伏安法（DPV）的检测限分别为VF（峰1）0.35µM和DVF（峰1）0.34µM，在低至高微摩尔区域线性范围宽。利用VF的不同表面终止偏好和多峰行为，实现了VF和DVF的同时测定。该方法对常见干扰物具有良好的选择性，并成功地应用于加样河水和药物胶囊中，加样回收率接近100%。在3d打印电池中，BDDGS被用于电化学高级氧化，在0.1 M H2SO4中，在恒流条件下，按照准一级动力学，在20分钟内实现了1 mM VF和DVF的~ 97%降解。BDDNS上的原位DPV能够实时监测VF衰减，展示了基于BDD和增材制造的集成检测和降解平台。
{"title":"3D-printed electrochemical cell for both detection and degradation of venlafaxine and desvenlafaxine with boron-doped diamond electrode","authors":"Martin Šefčík, Ghazaleh Kholafazadehastamal, Thomas Peeters, Jan Fischer, Anna Kubíčková, Clive E. Hall, Josephus G. Buijnsters, Simona Baluchová","doi":"10.1016/j.electacta.2026.148353","DOIUrl":"https://doi.org/10.1016/j.electacta.2026.148353","url":null,"abstract":"Venlafaxine (VF) and its active metabolite desvenlafaxine (DVF) are widely prescribed antidepressants that are only partially metabolized and excreted in significant amounts, making them clinically important analytes and environmentally relevant contaminants. In this study, a free-standing boron-doped diamond (BDD) electrode is exploited in a dual role for the electrochemical detection and degradation of VF and DVF, integrated into a custom 3D-printed dual-function electrochemical cell. The nucleation (BDD<sub>NS</sub>) and growth (BDD<sub>GS</sub>) sides of the BDD plate were systematically compared under different surface terminations. Oxidized BDD<sub>NS</sub> (O-BDD<sub>NS</sub>) provided three well-resolved oxidation peaks for VF, whereas hydrogen-terminated BDD<sub>NS</sub> (H-BDD<sub>NS</sub>) yielded a single distinct peak for DVF in 0.1 M H<sub>2</sub>SO<sub>4</sub>. Differential pulse voltammetric (DPV) methods were developed with limits of detection of 0.35 µM for VF (peak 1) and 0.34 µM for DVF and wide linear ranges in the low-to-high micromolar region. By exploiting the different surface-termination preferences and multi-peak behaviour of VF, simultaneous determination of VF and DVF was achieved. The methods showed good selectivity toward common interferents and were successfully applied to spiked river water and pharmaceutical capsules using the standard addition approach, giving recoveries close to 100%. In the 3D-printed cell, BDD<sub>GS</sub> was used for electrochemical advanced oxidation, achieving ∼97% degradation of 1 mM VF and DVF in 0.1 M H<sub>2</sub>SO<sub>4</sub> within 20 min under galvanostatic conditions, following pseudo-first-order kinetics. <em>In situ</em> DPV on BDD<sub>NS</sub> enabled real-time monitoring of VF decay, demonstrating an integrated detect-and-degrade platform based on BDD and additive manufacturing.","PeriodicalId":305,"journal":{"name":"Electrochimica Acta","volume":"1 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146101902","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-02-01DOI: 10.1016/j.electacta.2026.148351
Ana C.M. Oliveira, Raquel G. Rocha, Mariana C. Marra, Agata Rodak, Mateusz Cieślik, Robert D. Crapnell, Craig E. Banks, Jacek Ryl, Rodrigo A.A. Muñoz
This work investigates the influence of diamondized nanocarbon (DNC) surface charge on the performance of 3D-printed CB/PLA electrodes for paracetamol detection. Three filaments were prepared by the thermal method, incorporating DNCs with different zeta potentials, one positive (+20 mV) and two negative (-30 mV and -45 mV). Surface characterization by XPS and Raman spectroscopy revealed that DNC charge affects dispersion, polymer coverage, and the exposure of carbon black domains, whereas SEM images showed that positively charged DNCs tend to aggregate, whereas negatively charged DNCs remain well-dispersed. Contact angle measurements indicated increased hydrophilicity for electrodes containing negatively charged DNCs. Electrochemical analysis demonstrated lower charge-transfer resistance and superior current response for these electrodes, with an extended linear range and improved detection limits for paracetamol (∼1.5 times higher than positively charged DNCs). Overall, the results highlight that the DNC zeta potential is a key parameter for optimizing 3D-printed electrodes, providing a simple, low-cost strategy for the fabrication of portable and high-performance electrochemical sensors. Importantly, this is the first report demonstrating that DNC zeta potential significantly influences filament synthesis for electrochemical applications, opening new opportunities for the incorporation of various nanoparticles into filament composite.
{"title":"Tuning electrochemical properties of 3D-printed PLA/carbon black electrodes via diamondized nanocarbon functionalization","authors":"Ana C.M. Oliveira, Raquel G. Rocha, Mariana C. Marra, Agata Rodak, Mateusz Cieślik, Robert D. Crapnell, Craig E. Banks, Jacek Ryl, Rodrigo A.A. Muñoz","doi":"10.1016/j.electacta.2026.148351","DOIUrl":"https://doi.org/10.1016/j.electacta.2026.148351","url":null,"abstract":"This work investigates the influence of diamondized nanocarbon (DNC) surface charge on the performance of 3D-printed CB/PLA electrodes for paracetamol detection. Three filaments were prepared by the thermal method, incorporating DNCs with different zeta potentials, one positive (+20 mV) and two negative (-30 mV and -45 mV). Surface characterization by XPS and Raman spectroscopy revealed that DNC charge affects dispersion, polymer coverage, and the exposure of carbon black domains, whereas SEM images showed that positively charged DNCs tend to aggregate, whereas negatively charged DNCs remain well-dispersed. Contact angle measurements indicated increased hydrophilicity for electrodes containing negatively charged DNCs. Electrochemical analysis demonstrated lower charge-transfer resistance and superior current response for these electrodes, with an extended linear range and improved detection limits for paracetamol (∼1.5 times higher than positively charged DNCs). Overall, the results highlight that the DNC zeta potential is a key parameter for optimizing 3D-printed electrodes, providing a simple, low-cost strategy for the fabrication of portable and high-performance electrochemical sensors. Importantly, this is the first report demonstrating that DNC zeta potential significantly influences filament synthesis for electrochemical applications, opening new opportunities for the incorporation of various nanoparticles into filament composite.","PeriodicalId":305,"journal":{"name":"Electrochimica Acta","volume":"5 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146101900","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-02-01DOI: 10.1016/j.electacta.2026.148356
Xin Liu, Yuhang Ding, Meichao Li, Zhenlu Shen
The synthetic routes for constructing CF2Cl-containing compounds is being developed due to their increasingly utility in drug modification and organic synthesis. Herein, we report a convenient electrochemical protocol for chlorodifluoromethylation reactions of 2H-indazoles and quinoxalinones using ClCF2SO2Na as the efficient chlorodifluoromethylating reagent via C(sp2)−H functionalization without any transition-metal catalysts and stoichiometric oxidants. Cyclic voltammetry and control experiments indicate that a radical pathway is involved during the reaction. Under this mild and operationally simple process, a variety of desired CF2Cl-substituted products were synthesized in an undivided cell, achieving isolated yields of up to 88%. Other sodium sulfinates functionalized with fluorinated groups, such as −CF2CH3, −CF2Et, −CF2Pr, −CF2COOEt and −CFH2, also emerge as suitable substrates for the developed method, highlighting its broad potential applicability. In addition, the value of the developed method is further demonstrated by gram-scale experiments and downstream transformation reactions.
{"title":"Investigation of the Electrochemical Chlorodifluoromethylation Reactions of 2H-Indazoles and Quinoxalinones with ClCF2SO2Na","authors":"Xin Liu, Yuhang Ding, Meichao Li, Zhenlu Shen","doi":"10.1016/j.electacta.2026.148356","DOIUrl":"https://doi.org/10.1016/j.electacta.2026.148356","url":null,"abstract":"The synthetic routes for constructing CF<sub>2</sub>Cl-containing compounds is being developed due to their increasingly utility in drug modification and organic synthesis. Herein, we report a convenient electrochemical protocol for chlorodifluoromethylation reactions of 2<em>H</em>-indazoles and quinoxalinones using ClCF<sub>2</sub>SO<sub>2</sub>Na as the efficient chlorodifluoromethylating reagent via C(<em>sp<sup>2</sup></em>)−H functionalization without any transition-metal catalysts and stoichiometric oxidants. Cyclic voltammetry and control experiments indicate that a radical pathway is involved during the reaction. Under this mild and operationally simple process, a variety of desired CF<sub>2</sub>Cl-substituted products were synthesized in an undivided cell, achieving isolated yields of up to 88%. Other sodium sulfinates functionalized with fluorinated groups, such as −CF<sub>2</sub>CH<sub>3</sub>, −CF<sub>2</sub>Et, −CF<sub>2</sub>Pr, −CF<sub>2</sub>COOEt and −CFH<sub>2</sub>, also emerge as suitable substrates for the developed method, highlighting its broad potential applicability. In addition, the value of the developed method is further demonstrated by gram-scale experiments and downstream transformation reactions.","PeriodicalId":305,"journal":{"name":"Electrochimica Acta","volume":"36 2 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146098422","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-02-01DOI: 10.1016/j.electacta.2026.148352
Gabriel C. da Silva, Xianxian Xie, Michael Vorochta, Ivan Khalakhan, Serhiy Cherevko
Platinum-coated titanium porous transport layers (PTLs) are commonly used in proton exchange membrane water electrolyzers (PEMWE) to ensure electrical contact and corrosion resistance on the anode side. While the impact of platinum on interfacial performance has been extensively studied, the effect of Pt coating thickness on dissolution stability is still not well understood. In this study, model Pt/Ti thin films with tuned Pt thicknesses ranging from 1 to 100 nm are fabricated using magnetron sputtering. The films are examined using operando scanning flow cell inductively coupled plasma mass spectrometry (SFC-ICP-MS). Our findings reveal that thin Pt coatings do not block Ti dissolution under the tested conditions, while coatings of 20 nm or thicker substantially suppress Ti dissolution under specific dynamic operating protocols. In fluoride-containing electrolytes, the most robust and consistent suppression of Ti dissolution across all investigated conditions is achieved with 100 nm Pt coating. These results highlight critical Pt thickness thresholds necessary to suppress Ti corrosion under the operating conditions investigated here and provide a mechanistic foundation for the rational design of PTL coatings prior to validation at the device level.
{"title":"How much platinum is enough? Stability of Pt-coated titanium films for porous transport layers (PTLs) in acidic and fluoride-containing electrolyte","authors":"Gabriel C. da Silva, Xianxian Xie, Michael Vorochta, Ivan Khalakhan, Serhiy Cherevko","doi":"10.1016/j.electacta.2026.148352","DOIUrl":"https://doi.org/10.1016/j.electacta.2026.148352","url":null,"abstract":"Platinum-coated titanium porous transport layers (PTLs) are commonly used in proton exchange membrane water electrolyzers (PEMWE) to ensure electrical contact and corrosion resistance on the anode side. While the impact of platinum on interfacial performance has been extensively studied, the effect of Pt coating thickness on dissolution stability is still not well understood. In this study, model Pt/Ti thin films with tuned Pt thicknesses ranging from 1 to 100 nm are fabricated using magnetron sputtering. The films are examined using operando scanning flow cell inductively coupled plasma mass spectrometry (SFC-ICP-MS). Our findings reveal that thin Pt coatings do not block Ti dissolution under the tested conditions, while coatings of 20 nm or thicker substantially suppress Ti dissolution under specific dynamic operating protocols. In fluoride-containing electrolytes, the most robust and consistent suppression of Ti dissolution across all investigated conditions is achieved with 100 nm Pt coating. These results highlight critical Pt thickness thresholds necessary to suppress Ti corrosion under the operating conditions investigated here and provide a mechanistic foundation for the rational design of PTL coatings prior to validation at the device level.","PeriodicalId":305,"journal":{"name":"Electrochimica Acta","volume":"87 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146101901","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-02-01DOI: 10.1016/j.electacta.2026.148354
Chiara Iannace, Simone Ciampi
Electrochemical processes at gas–liquid interfaces remain largely unexplored, despite the ubiquity and functional importance of bubbles in both natural systems as well as in analytical, separation, and purification technologies. Impedance measurements of electrode–bubble junctions demonstrate that a stable nanoscale liquid film persists between a nitrogen bubble and a platinum ultramicroelectrode. This aqueous disjoining film has an unexpectedly high ionic conductivity, which further increases with increasing bubble deformation. The efficiency of ionic transport within this confined liquid pocket is ion-specific and linked to the ability of electrolyte ions, principally anions, to accumulate at the air–water interface. The presence of surface ions and mechanical stiffening of the bubble, as it deforms under the pressure of the electrode, modulate the junction’s resistance, while its capacitance is influenced by the electrostatics of overlapping anionic clouds on the bubble with the positive charge of the electrode. Electrochemiluminescence imaging data confirm sustained charge transfer across the junction, which indicate effective solution bulk-to-confined film mass transport. Our findings establish gas bubble–metal junctions as a new electrochemical platform, and help advance the understanding of bubbles as chemically active entities rather than passive insulating voids.
{"title":"Pressure and Electrolyte-Modulated Ionic Conductivity of Bubble–Electrode Junctions","authors":"Chiara Iannace, Simone Ciampi","doi":"10.1016/j.electacta.2026.148354","DOIUrl":"https://doi.org/10.1016/j.electacta.2026.148354","url":null,"abstract":"Electrochemical processes at gas–liquid interfaces remain largely unexplored, despite the ubiquity and functional importance of bubbles in both natural systems as well as in analytical, separation, and purification technologies. Impedance measurements of electrode–bubble junctions demonstrate that a stable nanoscale liquid film persists between a nitrogen bubble and a platinum ultramicroelectrode. This aqueous disjoining film has an unexpectedly high ionic conductivity, which further increases with increasing bubble deformation. The efficiency of ionic transport within this confined liquid pocket is ion-specific and linked to the ability of electrolyte ions, principally anions, to accumulate at the air–water interface. The presence of surface ions and mechanical stiffening of the bubble, as it deforms under the pressure of the electrode, modulate the junction’s resistance, while its capacitance is influenced by the electrostatics of overlapping anionic clouds on the bubble with the positive charge of the electrode. Electrochemiluminescence imaging data confirm sustained charge transfer across the junction, which indicate effective solution bulk-to-confined film mass transport. Our findings establish gas bubble–metal junctions as a new electrochemical platform, and help advance the understanding of bubbles as chemically active entities rather than passive insulating voids.","PeriodicalId":305,"journal":{"name":"Electrochimica Acta","volume":"26 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146101904","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-02-01DOI: 10.1016/j.electacta.2026.148350
Alenzo Murray, Giovanni Valenti, Priscilla Baker
The design of a sensitive and accurate electrochemiluminescence (ECL) immunosensor for the early detection of cardiac biomarkers at low concentrations is essential to improve patient outcomes. In this study, a conductive metal-organic framework (c-MOF), Cu3(HHTP)2, was drop-coated onto a screen-printed carbon electrode (SPCE) to produce an ultra-efficient electrochemical sensing platform which was subsequently functionalized with cTnI antibodies (Ab) and bovine serum albumin (BSA) for selective detection of the cardiac Troponin I. Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) confirmed the successful stepwise fabrication of the immunosensor. We investigated the ECL behaviour of the Cu3(HHTP)2-modified SPCE using [Ru(bpy)3]2+ as the luminophore and found that a significant increase in ECL intensity was achieved compared to that of the unmodified SPCE. This enhancement was attributed to the high conductivity, porous structure, the increased surface area of the c-MOF and crucially the HHTP ligand plays a critical role in enabling ECL generation in this system. The analytical performance of the immunosensor was evaluated by monitoring the ECL responses at varying cTnI concentrations. The immunosensor achieved a detection limit of 10.23 ± 1.06 pg/mL in vitro, well below the clinically relevant cTnI thresholds, highlighting its potential for rapid and early-stage cardiac biomarker detection. These findings suggest the Cu3(HHTP)2-based ECL immunosensor represents a viable sensing platform that significantly increases conductivity and ECL efficiency without the need of additional co-reactant species.
{"title":"A Conductive Metal-Organic Framework-Modified Electrode for Sensitive Electrochemiluminescent Detection of Cardiac Troponin I","authors":"Alenzo Murray, Giovanni Valenti, Priscilla Baker","doi":"10.1016/j.electacta.2026.148350","DOIUrl":"https://doi.org/10.1016/j.electacta.2026.148350","url":null,"abstract":"The design of a sensitive and accurate electrochemiluminescence (ECL) immunosensor for the early detection of cardiac biomarkers at low concentrations is essential to improve patient outcomes. In this study, a conductive metal-organic framework (c-MOF), Cu<sub>3</sub>(HHTP)<sub>2</sub>, was drop-coated onto a screen-printed carbon electrode (SPCE) to produce an ultra-efficient electrochemical sensing platform which was subsequently functionalized with cTnI antibodies (Ab) and bovine serum albumin (BSA) for selective detection of the cardiac Troponin I. Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) confirmed the successful stepwise fabrication of the immunosensor. We investigated the ECL behaviour of the Cu<sub>3</sub>(HHTP)<sub>2</sub>-modified SPCE using [Ru(bpy)<sub>3</sub>]<sup>2+</sup> as the luminophore and found that a significant increase in ECL intensity was achieved compared to that of the unmodified SPCE. This enhancement was attributed to the high conductivity, porous structure, the increased surface area of the c-MOF and crucially the HHTP ligand plays a critical role in enabling ECL generation in this system. The analytical performance of the immunosensor was evaluated by monitoring the ECL responses at varying cTnI concentrations. The immunosensor achieved a detection limit of 10.23 ± 1.06 pg/mL in vitro, well below the clinically relevant cTnI thresholds, highlighting its potential for rapid and early-stage cardiac biomarker detection. These findings suggest the Cu<sub>3</sub>(HHTP)<sub>2</sub>-based ECL immunosensor represents a viable sensing platform that significantly increases conductivity and ECL efficiency without the need of additional co-reactant species.","PeriodicalId":305,"journal":{"name":"Electrochimica Acta","volume":"17 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146098423","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-01-31DOI: 10.1016/j.electacta.2026.148345
Hao Luo, Hu He
{"title":"Fully Coupled Multi-Physics Modeling and Synergistic Structural Optimization for High Uniformity 8-inch Wafer Electroplating","authors":"Hao Luo, Hu He","doi":"10.1016/j.electacta.2026.148345","DOIUrl":"https://doi.org/10.1016/j.electacta.2026.148345","url":null,"abstract":"","PeriodicalId":305,"journal":{"name":"Electrochimica Acta","volume":"48 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2026-01-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146095530","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-01-31DOI: 10.1016/j.electacta.2026.148346
Justin M. Holland, Darren M. Driscoll, Ethan C. Thomas, Richard L. Fitzhugh
{"title":"Preparation of a Uranium Monocarbide Anode and Electrochemical Characterization in Molten LiCl-KCl-UCl3","authors":"Justin M. Holland, Darren M. Driscoll, Ethan C. Thomas, Richard L. Fitzhugh","doi":"10.1016/j.electacta.2026.148346","DOIUrl":"https://doi.org/10.1016/j.electacta.2026.148346","url":null,"abstract":"","PeriodicalId":305,"journal":{"name":"Electrochimica Acta","volume":"52 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2026-01-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146095531","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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