EnergyChem最新文献

Inspired by enzymatic catalysis, a variety of covalent organic frameworks (COFs), which have precisely engineered microenvironments enabled by the well-defined porous channels and cavities with catalytically active sites built in, have been developed to mimic the catalytic process of enzymes. The structure diversity and customizability of COFs make them an ideal platform for studying the catalyst structure-activity relationship in heterogeneous catalysis and obtaining a thorough understanding of the catalytic mechanisms. In this review, we summarize the recent progress in the development of COF materials for catalysis applications, with a particular focus on their microenvironment effects. Representative examples of organocatalysis, asymmetric organocatalysis, and metal-supported catalysis utilizing the microenvironment effect enabled by diversified COF materials are discussed. Finally, we outline the key fundamental issues to be addressed and provide our perspectives on the future of COF-based catalysis.

Using solar energy to couple the photoinduced reductive half-reaction with a matched oxidative half-reaction has received increasing attention in recent years. Such a process represents an alternative artificial photosynthetic route for energy storage and chemical synthesis, like killing two birds with one stone. This review article concisely summarizes and highlights the state-of-the-art progresses of semiconductor-based dual-functional photoredox catalysis that couples the reductive half-reaction such as the proton (H⁺) reduction into H₂, CO₂ reduction, and O₂ reduction to H₂O₂ with a matched oxidative organic transformation reaction including alcohol oxidation, C-C/-C-O coupling, -C-N coupling, biomass or plastics photoreforming, and other reactions, which can make full use of the electrons and holes generated from the semiconductors to realize the solar fuel conversion and selective organic transformation into valuable chemicals simultaneously. The challenges and prospects for future development of semiconductor-based dual-functional photoredox catalysis are also presented.

CO₂ electrolysis technology powered by renewable electricity is a sustainable strategy to reduce anthropogenic carbon emissions while producing valuable chemicals. Unfortunately, compared with CO₂ reduction reaction (CO₂RR) in cathode, the sluggish-kinetics and low value-added product (i.e., O₂) of anodic oxygen evolution reaction (OER) during CO₂ electrolysis will seriously drag down the whole efficiency and economic benefits. Alternatively, replacing OER with some thermodynamically more favorable oxidation reactions is promising to reduce energy input while producing high value-added products. Therefore, coupling CO₂RR with these oxidation reactions to construct paired electrosynthesis systems is more meaningful for future applications, which has gained some far-reaching achievements in recent years. In this review, we summarize recent progress in construction of paired electrosynthesis systems involving CO₂RR and propose possible future research directions. We start with fundamentals about traditional CO₂ electrolysis. Then we propose the definition and classification of paired electrolysis, especially those involving CO₂RR. Subsequently, we emphatically discuss the selection of various oxidation reactions coupled with CO₂RR in the proposed paired electrolysis systems. Finally, from our point of view, the current challenges and corresponding perspectives on the development of paired electrolysis involving CO₂RR are presented to inspire possible future research directions.

Health care is one of the most promising applications for triboelectric nanogenerators (TENGs). In this review, we summarize recent advances in the three most popular health care-related applications of TENGs: microbial disinfection, interventional therapy and implantable microsystems. Furthermore, we discuss the evolution of important common technologies of TENGs in these three applications, which covers energy harvesting, energy storage and energy-efficient functional design. For these three promising applications, this paper explores their future technical roadmap and reveals a trend towards smaller, stronger, more effective and more controllable triboelectric devices and systems.

Transmission electron microscopy (TEM) is widely used in the materials science community because of its high spatial, temporal and energy resolution. However, for electron beam-sensitive halide perovskites (HPs), the achievements offered by TEM are still in their infancy due to the nonnegligible structural damage caused by the incident electron beams to the fragile structure. Despite these challenges, the potential for TEM to provide unique insights into the microstructure and phase evolution of HPs at the atomic scale, to track the dynamic ion migration behaviors, and to explore the effects of lattice defects on physicochemical properties is still fascinating. In this review, we summarize recent achievements in HPs through advanced analytical methods embedded in the TEM, including high-resolution/scanning TEM (HRTEM/STEM) imaging, electron diffraction (ED) analysis, X-ray energy dispersive spectroscopy (EDS), and electron energy-loss spectroscopy (EELS) measurement, and in-situ TEM observation, with the aim of providing a multi-dimensional and multi-scale understanding of the intrinsic properties of HPs that have not yet been discovered. In addition, we delve into the inherent beam-damage mechanisms affecting the delicate HPs crystal, thereby emphasizing the significant hurdles associated with employing TEM in HPs research. Finally, we present a number of effective strategies that may be beneficial in reducing the damage caused by beams. In particular, the introduction of a direct-detection electron-counting (DDEC) camera has contributed significantly to the advancement of low-dose imaging and the suppression of beam damage to the intrinsic structure of HPs. With the improvement of low-dose imaging technology, TEM characterization is expected to promote a comprehensive understanding of the intrinsic properties of HPs in terms of structure-property-performance and to expand the wide range of applications of HPs in optoelectronic devices.

Ni-rich layered transition metal oxides possess remarkably high capacity and thus are very competitive cathode materials in high-energy lithium-ion batteries (LIBs) for electric vehicles, but encounter the critical problems of fast degradation caused by the highly reactive nickel component. Here in this review we intensively summarize thedegradation mechanism of Ni-rich cathode materials including e.g., residual lithium species, cation mixing, gas generation, surface structure reconstruction, crack, thermal instability, and transition metal dissolution. Furthermore, the state-of-art strategies e.g., new preparation methods, single-crystal, doping, structure design, coating and new binders, to tackle these degradation problem are accounted. This review might be inspiring for better understanding the degradation mechanism and relevant coping approaches of high-energy cathode materials for lithium ion batteries.

The ongoing surge in demand for energy conversion and storage spurs the development of high-efficiency batteries. In recent decades, aqueous alkaline batteries (AABs) have been the focus point owing to the high safety, low cost, environmental benefits, impressive output voltage and theoretical energy density. However, the large-scale application of AABs is hindered by the poor cyclability and insufficient capacity utilization, especially in anodes. To circumvent the issues, great research efforts have been dedicated to the electrode design and electrolyte optimization. In this review, reaction mechanisms, modification strategies, application feasibility and existing challenges are systematically summarized and highlighted. Additionally, insightful perspectives and research orientations are proposed for further development of AABs anodes.

Electrochemical water splitting, especially in acidic media, is a promising technology for hydrogen production and sustainable energy conversion. However, it remains a challenge to synthesize suitable acidic oxygen evolution reaction (OER) electrocatalysts that provide high activity and long-term stability according to the industrial standards. Up to date, quite few reviews provide a systematic summarization of the strategies and approaches to improve the electrocatalytic performances of the catalysts in acidic electrolytes. Herein, we analyze the electrochemical behavior of the reported state-of-the-art OER catalysts and provide a comprehensive review of the systematic strategies for preparing high-performance electrocatalysts. First, we introduce some fundamentals of OER mechanism to give readers a deeper understanding of this field. Then, we summarize and discuss various design strategies, including electronic state modulation, structural manipulation, etc. Finally, the challenges, opportunities, and future outlook regarding acidic OER electrocatalysts are delivered. This review will serve as a useful guiding resource for researchers seeking in-depth understanding of the OER mechanism in acidic media as well as learning approaches for synthesizing highly efficient and cost-effective OER electrocatalysts.

Synthetic porous carbons (SPCs) are important materials in fundamental research and industrial applications due to their diverse structures at different dimensions, intriguing physio-chemical properties, exceptional thermal and chemical stability, etc. In particular, the features including high electron conductivity, accessible active surface/interface, and developed porosity warrant their superior performances in clean energy storage and conversion. In this review, we summarize the latest advances in SPCs, serving as electrodes for this ever-increasing energy storage and conversion-related directions, e.g., supercapacitors, rechargeable batteries, fuel cells, etc. We emphasized rational design and targeted synthesis of SPCs based on bottom-up strategy, the effective methods for precise tuning of their core parameters, and the disclosure of their structure-performance correlations. The challenges of fine-tuning surface chemistry by doping heteroatoms, engineering defective sites, and optimizing compositions are discussed, which could endow the SPCs with new functions and potential applications. Finally, we outlined the developing trend and design principle of the new generation of SPCs for clean energy storage and conversion. We expect that this review could inspire interdisciplinary activities between the synthesis, physical and chemical studies of SPCs and other potential applications in addition to energy storage and conversion.

With the rapid development of nuclear industry, effective management of nuclear waste and oversight of nuclear fuel cycle are critical. Radionuclides such as uranium (U), plutonium (Pu), neptunium (Np), americium (Am), curium (Cm), technetium (Tc), rhenium (Re), iodine (I), selenium (Se), thorium (Th), cesium (Cs), and strontium (Sr) transferred into environment are dangerous. It is crucial to design the corresponding materials to exhibit high adsorption capacity and selectivity among competing species in nuclear waste. Herein, this review comprehensively summarizes the application of advanced porous materials, including metal-organic frameworks (MOFs), covalent organic frameworks (COFs), and amorphous porous organic polymers (POPs) as porous adsorbents for radionuclides removal. These porous materials feature uniform composition, large porosity, and good stability, which lay a good foundation for various applications. The tunable pore sizes, high specific surface areas, exchangeable sites, and functional groups are designed as accessible platforms for nuclides diffusion and adsorption. Specific binding mechanisms toward various radionuclides, such as complexation, electrostatic interaction, and ion exchange are presented. Beyond traditional adsorbents, the superior capacity, kinetics, selectivity, and reusability of COFs, MOFs, and POPs make them broad application prospects in radionuclides removal, providing a way for effective applications in environmental remediation.