European Polymer Journal最新文献_第6页

Cross-linked polysulfone membranes with controllable cross-linkers for anion-exchange membrane water electrolysis 用于阴离子交换膜电解水的带有可控交联剂的交联聚砜膜

IF 5.8 2区化学 Q1 POLYMER SCIENCE

European Polymer Journal

Pub Date : 2024-11-01 DOI: 10.1016/j.eurpolymj.2024.113543

Eun Ji An , Gi Hyo Sim , Somi Yu , Hyung Gwon Kim , Seong Jin An , Changsoo Lee , MinJoong Kim , Jong Hak Kim , Jae Hun Lee , Won Seok Chi

We report polysulfone-based anion-exchange membranes cross-linked using three distinct cross-linkers (i.e., 4,4′-trimethylenebis(1-methyl-piperidine) (BMP), N,N,N′,N′-tetramethyl-1,6-diaminohexane (TMHDA), and 1,4-diazabicyclo[2.2.2]octane (DABCO)), designed for water electrolysis application. The cross-linked chloromethylated polysulfone membranes exhibit quaternization functionality, which can facilitate hydroxide-ion transport. Additionally, the cross-linked polysulfone membranes exhibit high thermal and mechanical stability. Among the cross-linked polysulfone membranes, the BMP-induced cross-linked polysulfone membrane displays an ion-exchange capacity of 1.58 mmol/g and an ion conductivity of 53.7 mS/cm at 80 °C, along with a water uptake of 50 % and a swelling ratio of 23 %, demonstrating good electrochemical properties and high dimensional stability. Moreover, the BMP-induced cross-linked polysulfone membrane exhibits a higher anion-exchange membrane water electrolysis performance and lower impedance than the other cross-linker-induced cross-linked polysulfone membranes. More importantly, it exhibits better water electrolysis cell performance than commercial FAA-3-50 membranes.

我们报告了使用三种不同交联剂（即4,4′-三亚甲基双（1-甲基-哌啶）（BMP）、N,N,N′,N′-四甲基-1,6-二氨基己烷（TMHDA）和 1,4-二氮杂双环[2.2.2]辛烷（DABCO））交联，设计用于水电解。交联氯甲基化聚砜膜具有季铵化功能，可促进氢氧根离子的传输。此外，交联聚砜膜还具有较高的热稳定性和机械稳定性。在交联聚砜膜中，BMP 诱导的交联聚砜膜的离子交换容量为 1.58 mmol/g，80 °C 时的离子电导率为 53.7 mS/cm，吸水率为 50%，膨胀率为 23%，显示出良好的电化学特性和高度的尺寸稳定性。此外，与其他交联剂诱导的交联聚砜膜相比，BMP 诱导的交联聚砜膜具有更高的阴离子交换膜水电解性能和更低的阻抗。更重要的是，与商用 FAA-3-50 膜相比，它具有更好的水电解池性能。

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引用次数: 0

Bottlebrush polymers via ring-opening metathesis polymerization (ROMP): Synthesis, properties and applications 通过开环偏聚聚合（ROMP）制备的瓶坯聚合物：合成、性能和应用

IF 5.8 2区化学 Q1 POLYMER SCIENCE

European Polymer Journal

Pub Date : 2024-10-31 DOI: 10.1016/j.eurpolymj.2024.113546

Smruti Rekha Rout , Gowtham Kenguva , Shaaba Mansuri , Manu KR , Rambabu Dandela , Nabendu B. Pramanik

Bottlebrush polymers (BBPs) are a class of branch or graft macromolecules with polymeric side chains attached to linear backbone leading to cylindrical or worm like structures. Due to their unique architecture of polymers with long and densely grafted side chains, BBPs have attracted notable numbers of novel and unique properties useful for various applications from tissue engineering to photonics. Their unique structures characterized by densely-grafted side chains, allows for precise control of their properties and reduces issues with entanglements. This review delineates the recent advances in the synthesis of BBPs via living Ring-Opening Metathesis Polymerization (ROMP) and their properties, applications, highlighting the challenges and solutions in controlling their chemical structures, compositions and uses. Notably, the development of ROMP has transformed the polymer synthesis, specially the synthesis of bottlebrush polymers. ROMP is very powerful technique for achieving very high conversion of macromonomer for a range of concentrations and molecular weights of macromonomer leading to formation of BBPs with systemically varying backbone and side-chain lengths. The combination of BBPs’ versatility with ROMP’s precision in controlling the polymer’s size, shape, and functionality offers significant advantages in materials synthesis. By integrating these approaches, researchers can create customized bottlebrush polymeric materials with tailored properties, enhancing advancements in nanotechnology, energy storage and biomedical engineering. To the best of our knowledge there is no review reported on the synthesis of BBPs via ROMP.

Bottlebrush 聚合物（BBPs）是一类分支或接枝高分子，其聚合物侧链附着在线性骨架上，形成圆柱形或蠕虫状结构。由于其独特的聚合物结构具有长而密集的接枝侧链，BBPs 具有大量新颖独特的特性，可用于组织工程和光子学等各种应用领域。以密集接枝侧链为特征的独特结构可以精确控制其特性，并减少缠结问题。本综述介绍了通过活环开环元合成聚合法（ROMP）合成 BBPs 的最新进展及其特性和应用，重点介绍了在控制其化学结构、组成和用途方面所面临的挑战和解决方案。值得注意的是，ROMP 的发展改变了聚合物合成，特别是瓶丛聚合物的合成。ROMP 是一种非常强大的技术，可在各种浓度和分子量的大单体中实现非常高的大单体转化率，从而形成具有系统性不同骨架和侧链长度的 BBPs。BBPs 的多功能性与 ROMP 在控制聚合物大小、形状和功能方面的精确性相结合，为材料合成提供了显著优势。通过整合这些方法，研究人员可以制造出具有定制特性的瓶绒聚合物材料，从而推动纳米技术、能量存储和生物医学工程的发展。据我们所知，目前还没有关于通过 ROMP 合成 BBPs 的综述。

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引用次数: 0

Corrigendum to “Glutathione-modified hyaluronic acid nanoparticles for the targeted delivery of sulfasalazine to neuroblastoma” [Eur. Polym. J. 219 (2024) 113383]

IF 5.8 2区化学 Q1 POLYMER SCIENCE

European Polymer Journal

Pub Date : 2024-10-30 DOI: 10.1016/j.eurpolymj.2024.113534

Martyna Kasprzyk , Alicja Hinz , Monika Bzowska , Dorota Lachowicz , Karol Wolski , Anna Karewicz

引用次数: 0

Bionic octopus tentacle structure-inspired engineering of HPP@PBA nanotubes: Towards mechanically reinforced epoxy nanocomposites with outstanding flame retardancy and smoke suppression 受仿生章鱼触手结构启发的 HPP@PBA 纳米管工程：实现具有出色阻燃性和抑烟性能的机械增强环氧纳米复合材料

IF 5.8 2区化学 Q1 POLYMER SCIENCE

European Polymer Journal

Pub Date : 2024-10-29 DOI: 10.1016/j.eurpolymj.2024.113510

Zheng Zhong, Yutong Huo, Yilan An, Wei Liu, Yanli Dou

Developing high-performance epoxy (EP) nanocomposites that balance flame retardancy and mechanical properties has been a significant challenge. In this work, a novel hierarchical hybrid flame retardant HPP@PBA with a bionic octopus tentacle structure was successfully constructed. The organic coating composed of phytic acid (PA) and polyaniline (PANI), and CoFe-Prussian blue analogue nanoparticles (CoFe-PBA), effectively enhances the interfacial interaction between halloysite nanotubes (HNTs) and the EP matrix, promoting the formation of a mechanical interlocking structure. By introducing 5 wt% HPP@PBA, the tensile strength and impact strength of the composites increase by 62.4 % and 38.7 %, respectively. EP/HPP@PBA also exhibits excellent flame retardancy and smoke suppression properties. The limiting oxygen index (LOI) of the EP composites reached 33.0 %, achieving the UL-94 V0 rating. Cone calorimetry test (CCT) shows that, compared with pure EP, the peak of heat release rate (pHRR), total heat release (THR), peak of smoke production rate (pSPR), total smoke production (TSP), and peak of carbon monoxide production (COP) of EP/HPP@PBA are reduced by 40.7 %, 34.0 %, 47.2 %, 42.5 %, and 36.6 %, respectively. Additionally, the flame retardant and mechanical enhancement mechanisms of hybrids in EP composites are systematically investigated. This work provides a feasible approach for preparing multifunctional high-performance EP nanocomposites.

开发兼顾阻燃性和机械性能的高性能环氧（EP）纳米复合材料一直是一项重大挑战。在这项工作中，成功构建了一种具有仿生章鱼触手结构的新型分层混合阻燃剂 HPP@PBA。由植酸（PA）、聚苯胺（PANI）和 CoFe-Prussian blue 类似纳米粒子（CoFe-PBA）组成的有机涂层能有效增强哈洛来石纳米管（HNTs）与 EP 基体之间的界面相互作用，促进机械互锁结构的形成。通过引入 5 wt% 的 HPP@PBA，复合材料的拉伸强度和冲击强度分别提高了 62.4% 和 38.7%。EP/HPP@PBA 还具有优异的阻燃和抑烟性能。EP 复合材料的极限氧指数（LOI）达到 33.0%，达到了 UL-94 V0 等级。锥形量热试验（CCT）表明，与纯 EP 相比，EP/HPP@PBA 的放热峰值（pHRR）、总放热（THR）、产烟峰值（pSPR）、总产烟量（TSP）和一氧化碳产烟峰值（COP）分别降低了 40.7%、34.0%、47.2%、42.5% 和 36.6%。此外，还系统地研究了 EP 复合材料中混合物的阻燃和机械增强机理。这项工作为制备多功能高性能 EP 纳米复合材料提供了一种可行的方法。

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引用次数: 0

A photocurable ultra-tough eutectic gel with coordination crosslinking used for wearable sensors and TENG flexible electrodes 用于可穿戴传感器和 TENG 柔性电极的配位交联光固化超韧共晶凝胶

IF 5.8 2区化学 Q1 POLYMER SCIENCE

European Polymer Journal

Pub Date : 2024-10-29 DOI: 10.1016/j.eurpolymj.2024.113544

Youjie Rong, Xiaomin Zhang, Huijie Li, Jianhua Fei, Ruiqiang Hang, Xiangyu Zhang, Xiaobo Huang, Xiaohong Yao

Flexible polymer molecular chains are of great interest to researchers in the field of flexible wearable electronics due to their unrivaled flexibility and ductility. However, achieving high toughness, high elasticity, environmental stability and easy machining of flexible electronic materials remains a challenge. In this study, we present a photocurable eutectic gel mainly composed of DMAPS, AAc, Zr⁴⁺ and deep eutectic solvents (DES). Due to the strong coordination between zirconium ions and polymer networks, the gel can be endowed with excellent properties, such as excellent tensile strength (1.14 MPa), low hysteresis (5 kJ·m⁻³) and good adhesion (above 40 kPa). DES can not only give the gel good electrical conductivity, but also maintain the stability of the gel to ensure that the leakage or volatilization of the solvent will not occur in use. The properties mentioned above allow the gel to achieve a sensitivity factor of up to 1.7 over a small strain range, demonstrating its potential applications in the field of flexible strain sensors and triboelectric flexible electrode materials. What’s more, the gel can be used to prepare complex geometric shapes with high precision through digital light processing (DLP) based 3D printing technology. Therefore, this work introduces a novel approach for the development of highly stable flexible wearable devices, which has the potential to expand the applications of eutectic gels.

柔性聚合物分子链因其无与伦比的柔韧性和延展性而备受柔性可穿戴电子设备领域研究人员的关注。然而，实现柔性电子材料的高韧性、高弹性、环境稳定性和易加工性仍然是一项挑战。在这项研究中，我们提出了一种主要由 DMAPS、AAc、Zr4+ 和深共晶溶剂（DES）组成的光固化共晶凝胶。由于锆离子与聚合物网络之间的强配位，该凝胶具有优异的性能，如卓越的拉伸强度（1.14 MPa）、低滞后（5 kJ-m-3）和良好的粘附性（40 kPa 以上）。DES 不仅能使凝胶具有良好的导电性，还能保持凝胶的稳定性，确保在使用过程中不会发生溶剂泄漏或挥发。上述特性使凝胶在小应变范围内的灵敏度系数高达 1.7，显示了其在柔性应变传感器和三电柔性电极材料领域的应用潜力。此外，通过基于数字光处理（DLP）的三维打印技术，该凝胶还可用于制备高精度的复杂几何形状。因此，这项工作为开发高稳定性柔性可穿戴设备引入了一种新方法，有望拓展共晶凝胶的应用领域。

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引用次数: 0

Synthesis of a series of dextran-based DA-AHA hydrogels for wound healing dressings 合成一系列用于伤口愈合敷料的葡聚糖基 DA-AHA 水凝胶

IF 5.8 2区化学 Q1 POLYMER SCIENCE

European Polymer Journal

Pub Date : 2024-10-28 DOI: 10.1016/j.eurpolymj.2024.113521

Chenyu Liu , Shuli Yue , Ruizhi Li , Lin Wang , Kun Zhang , Shiwei Wang , Simiao Yu , Farishta Shafiq , Yao Liu , Weihong Qiao

In response to the pain, swelling, and redness resulting from inadequate wound hemostasis and anti-inflammatory measures, there is a pressing need to develop wound repair materials capable of promptly stopping bleeding, facilitating painless dressing changes, and expediting wound closure to enhance skin wound recovery. However, comprehensive research is deficient concerning the conformational relationship of hyaluronic acid (HA) with various molecular weights concerning the structure of hydrogel materials. This study aims to address this need by utilizing aminated hyaluronic acid (AHA) and aldehyde-modified dextran (DA) to prepare dextran-based hyaluronic acid hydrogels (DA-AHA) via Schiff base reaction, imbuing them with acute inflammation repair and wound healing promotion properties. In vitro, coagulation experiments demonstrated that the DA-AHA hydrogel could rapidly coagulate blood within 60 s. Subsequent animal experiments corroborated these findings, revealing the hydrogel’s efficacy in significantly shortening wound healing time and accelerating wound closure efficiency. Moreover, MTT and live-death experiments affirmed the non-cytotoxic nature of the synthesized hydrogel. The study delved into the structural regularity and wound-healing efficacy of DA-AHA hydrogel materials featuring various molecular weights. Additionally, it compared the hemostatic and wound-healing properties of (high molecular weight dextran-aminated hyaluronic acid hydrogel) HDA-AHA, demonstrating its superiority in both aspects.

由于伤口止血和消炎措施不当，导致伤口疼痛、肿胀和发红，因此迫切需要开发能够及时止血、方便无痛换药和加速伤口闭合的伤口修复材料，以促进皮肤伤口的恢复。然而，关于不同分子量的透明质酸（HA）在水凝胶材料结构中的构象关系，目前还缺乏全面的研究。本研究旨在利用胺化透明质酸（AHA）和醛改性右旋糖酐（DA），通过席夫碱反应制备右旋糖酐基透明质酸水凝胶（DA-AHA），使其具有急性炎症修复和促进伤口愈合的特性。体外凝血实验表明，DA-AHA 水凝胶能在 60 秒内迅速凝固血液。随后的动物实验也证实了这些发现，揭示了该水凝胶在显著缩短伤口愈合时间和加快伤口闭合效率方面的功效。此外，MTT 和活体死亡实验证实了合成水凝胶的无细胞毒性特性。该研究深入探讨了不同分子量的 DA-AHA 水凝胶材料的结构规则性和伤口愈合功效。此外，研究还比较了（高分子量葡聚糖氨基透明质酸水凝胶）HDA-AHA 的止血和伤口愈合性能，结果表明它在这两方面都更胜一筹。

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引用次数: 0

Bis-acrylate functionalized enone as photoinitiators for UV-LED photopolymerization 双丙烯酸酯官能化烯酮作为紫外线-LED 光聚合的光引发剂

IF 5.8 2区化学 Q1 POLYMER SCIENCE

European Polymer Journal

Pub Date : 2024-10-28 DOI: 10.1016/j.eurpolymj.2024.113506

YinPing Wu , JiaSheng Ke , Junhua Chen , Bo Zhang , He Zhang , Jiayun Zhong , Yunlong Zhang , Hong Huang , Xiang Li , Yue Situ

Ketene derivatives have been widely studied in photopolymerization technology system because of their advantages of excellent light absorption and strong photobleaching ability. Nevertheless, the field of research into photoinitiators derived from ketene that exhibit minimal migration and superior solubility is relatively underexplored. In this study, five new polymerizable ketene derivative photoinitiators (CPBA-1 to 5) were designed and synthesized for photoinitiated radical polymerization (FRP). The photoinitiation performance, migration after curing, and solubility of CPBA1-3 in trimethylpropane triacrylate (TMPTA) free radical polymerization (FRP) were investigated and these properties were compared with the industrial photoinitiator 2-isopropylthioxanthone (ITX). The results showed that CPBA-2 had the best C=C conversion rate in TMPTA. Additionally, the migration rate of CPBA-2 is significantly lower than that of ITX, indicating its lower mobility than conventional photoinitiators. Moreover, the higher solubility of CPBA-2 in monomers provides the great potential for its industrial applications.

烯酮衍生物具有优异的光吸收和光漂白能力强的优点，因此在光聚合技术体系中得到了广泛的研究。然而，由酮烯衍生的光引发剂具有迁移性小、溶解性强等优点，但这方面的研究却相对不足。本研究设计并合成了五种新的可聚合烯酮衍生物光引发剂（CPBA-1 至 5），用于光引发自由基聚合（FRP）。研究了 CPBA1-3 的光引发性能、固化后的迁移以及在三甲基丙烷三丙烯酸酯（TMPTA）自由基聚合（FRP）中的溶解度，并将这些性能与工业光引发剂 2-isopropylthioxanthone (ITX) 进行了比较。结果表明，CPBA-2 在 TMPTA 中的 C=C 转化率最高。此外，CPBA-2 的迁移率明显低于 ITX，表明其流动性低于传统光引发剂。此外，CPBA-2 在单体中的溶解度较高，为其工业应用提供了巨大潜力。

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引用次数: 0

Dual plant compounds-loaded chitosan hydrogel-based scaffold promotes cell proliferation for repairing liver injury 双重植物化合物负载壳聚糖水凝胶支架促进细胞增殖，修复肝损伤

IF 5.8 2区化学 Q1 POLYMER SCIENCE

European Polymer Journal

Pub Date : 2024-10-28 DOI: 10.1016/j.eurpolymj.2024.113522

Lanqing Wang , Lihui Pang , Xin Guo , Wenbo Li , Rongqian Wu , Cuiping Yao

Liver tissue engineering is an essential approach to improve liver injury repair or regeneration for compensation of donor shortage, in which the combination of scaffolds and bioactive factors play a crucial role. Until now, a minimal number of products are used in clinic for their hurdles of biocompatibility. Here a degradable scaffold system based on chitosan polymers that are cross linked by Schiff reaction was prepared, which exhibits excellent biocompatibility and degradability. Two natural plant components with protective toxicity ability and improved tissue formation were loaded in scaffold to promote the cell proliferation as well as reduced drug dosage, further lowering the bio-toxicity of the scaffold system while ensuring its duration and effectiveness. Furthermore, our scaffold system possesses suitable degradation rate that match the regeneration rate of native tissue, which can maintain mechanical properties to support tissue formation during healing. The experiments results show that the scaffold system has the ability to enhance stem cell differentiation and promote liver regeneration, with non-toxic degradation products. In summary, the non-toxic, degradable scaffold system loaded with plant components holds vast potential in the field of biomedicine, providing a new approach for constructing safe and efficient biomedical materials.

肝脏组织工程是改善肝脏损伤修复或再生以弥补供体不足的重要方法，其中支架和生物活性因子的结合发挥着至关重要的作用。迄今为止，由于生物相容性方面的障碍，只有极少数产品被用于临床。本文制备了一种基于壳聚糖聚合物的可降解支架系统，该聚合物通过希夫反应交联，具有良好的生物相容性和可降解性。支架中添加了两种具有保护毒性和改善组织形成的天然植物成分，可促进细胞增殖并减少药物用量，进一步降低支架系统的生物毒性，同时确保其持续时间和有效性。此外，我们的支架系统具有与原生组织再生速度相匹配的适当降解率，可在愈合过程中保持机械性能以支持组织形成。实验结果表明，该支架系统具有增强干细胞分化和促进肝脏再生的能力，且降解产物无毒。总之，负载植物成分的无毒可降解支架系统在生物医学领域具有巨大潜力，为构建安全高效的生物医学材料提供了一种新方法。

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引用次数: 0

Polythioacetals: From old chemistry to new perspectives 聚硫乙醛：从旧化学到新视角

IF 5.8 2区化学 Q1 POLYMER SCIENCE

European Polymer Journal

Pub Date : 2024-10-28 DOI: 10.1016/j.eurpolymj.2024.113532

Emre Akar, Umit Tunca, Hakan Durmaz

In this review, we comprehensively described the synthetic approaches for the preparation of polythioacetals (PTAs) by step-growth, chain-growth, and post-polymerization modification techniques from the past to the present. In addition, we reviewed the state-of-the-art applications of PTAs as reactive oxygen species (ROS) responsive polymers, chemosensors for Hg²⁺ ions, and polymers with dynamic covalent bond properties. Since a wide range of reactive oxygen species (ROS) applications of PTAs for cell delivery is beyond the scope of this review, some pioneering works are discussed, and the remaining items are only cited in the text. However, the utilization of PTAs as chemosensors for Hg²⁺ ions and the dynamic covalent bond properties of PTAs are extensively reviewed here. Also, as less common implementations of PTAs, the proton shelter and the polymeric bone cement examples are described in the text. The practical synthesizability of PTA and its wide range of applications in materials science and bio-based applications indicate that this fundamental reaction will proceed to be used continuously in various disciplines of chemistry in the future.

在这篇综述中，我们全面介绍了从过去到现在通过阶跃生长、链生长和聚合后改性技术制备聚硫乙醛（PTAs）的合成方法。此外，我们还回顾了 PTAs 作为活性氧（ROS）响应聚合物、Hg2+ 离子化学传感器以及具有动态共价键特性的聚合物的最新应用。由于将 PTAs 广泛应用于细胞输送活性氧 (ROS) 超出了本综述的范围，因此只讨论了一些开创性工作，其余项目仅在文中引用。不过，本文对利用 PTAs 作为 Hg2+ 离子的化学传感器以及 PTAs 的动态共价键特性进行了广泛综述。此外，文中还介绍了质子庇护所和聚合物骨水泥等不太常见的 PTA 应用实例。PTA 的实际可合成性及其在材料科学和生物基应用领域的广泛应用表明，这一基本反应在未来将不断应用于化学的各个学科。

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引用次数: 0

Glutaraldehyde-assisted crosslinking for the preparation of low dielectric loss and high energy density cellulose composites filled with poly(dopamine) modified MXene 戊二醛辅助交联用于制备填充聚（多巴胺）改性 MXene 的低介电损耗、高能量密度纤维素复合材料

IF 5.8 2区化学 Q1 POLYMER SCIENCE

European Polymer Journal

Pub Date : 2024-10-28 DOI: 10.1016/j.eurpolymj.2024.113526

Fan Zhang, Meng-hang Gao, Chao-qun Wu, Jing-hui Yang, Nan Zhang, Yong Wang

In today’s electric power systems, biodegradable and environmentally benign dielectric materials with outstanding dielectric capabilities are essential. Here, a hybrid filler MXene@PDA (M@P) was acquired by coating MXene with polydopamine (PDA), and then it was added into cellulose matrix to manufacture regenerated cellulose/M@P (RC/M@P) composite films. Finally, a crosslinking strategy with glutaraldehyde (GA) assistance was developed to further modify the RC/M@P composite films. The crosslinked composite films (CRC/M@P) had a denser structure with fewer defects, considerably decreased dielectric loss, and significantly strengthened breakdown strength. The highest energy storage density of 3.37 J/cm³ was obtained for CRC/M@P-1 composite film with only 1 wt% M@P at 361.07 MV/m, achieving significant enhancement compared with the original CRC film. Moreover, crosslinking also contributed to the CRC/M@P for achieving better mechanical properties. The excellent comprehensive performances endow CRC/M@P composite films with promising application for the next-generation dielectric capacitors.

在当今的电力系统中，可生物降解、对环境无害且具有出色介电能力的介电材料至关重要。本文通过在 MXene 上涂覆聚多巴胺（PDA），获得了混合填料 MXene@PDA（M@P），然后将其添加到纤维素基质中，制造出再生纤维素/M@P（RC/M@P）复合薄膜。最后，在戊二醛（GA）的辅助下开发了一种交联策略，以进一步改性 RC/M@P 复合膜。交联后的复合薄膜（CRC/M@P）结构更致密，缺陷更少，介电损耗大大降低，击穿强度显著增强。仅含有 1 wt% M@P 的 CRC/M@P-1 复合薄膜在 361.07 MV/m 的条件下获得了 3.37 J/cm3 的最高储能密度，与原始 CRC 薄膜相比有显著提高。此外，交联也有助于 CRC/M@P 获得更好的机械性能。优异的综合性能赋予了 CRC/M@P 复合薄膜在下一代电介质电容器中的应用前景。

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引用次数: 0