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AES/ESCA/SEM/EDX Studies of Die Bond Materials and Interfaces 模具粘结材料和界面的AES/ESCA/SEM/EDX研究
Pub Date : 1984-04-03 DOI: 10.1109/IRPS.1984.362039
Tom P. L. Li, E. Zigler, D. E. Hillyer
The choice of a die bonding material and processes for a microelectronic application, especially of accommodating the large size (up to 400 mils) and high density (up to 200 I/O connections) of VLSI chips, presents a matrix of considerations. They are the material properties, bonding surface characteristics, packaging compatibility and assembly procedures, etc. Above all, the die bond has to meet stringent reliability requirements. Die bonding failures have been reported numerously in the past. Only the failure modes and specu-lated failure mechanisms were documented. The present study uses the Perkin Elmer Auger/ESCA system to study the surface elements and their chemical states on the bonding surface; uses the Cambridge SEM/EDX system to study the failure modes and the cross-sectional profile; and uses the Dupont thermal analysi-s system to determine the physical and/or chemi-cal reactions of the die attach materials. It is the intention to provide a better understanding of the die bonding materials and material/ process related failures, and to help eliminate the problems of hot spots and thermal stressing of the interface caused by void formation.
对于微电子应用,特别是适应超大尺寸(高达400密耳)和高密度(高达200个I/O连接)的VLSI芯片,模具粘合材料和工艺的选择提出了一个考虑因素矩阵。它们是材料性能、粘接表面特性、封装兼容性和装配程序等。最重要的是,模具粘合必须满足严格的可靠性要求。模具粘接失败在过去已经报道了许多。只有失效模式和推测的失效机制被记录下来。本研究采用Perkin Elmer Auger/ESCA系统研究了表面元素及其在键合表面的化学状态;采用剑桥SEM/EDX系统研究了试件的破坏模式和截面分布;并使用杜邦热分析系统来确定模具附着材料的物理和/或化学反应。其目的是为了更好地理解模具粘合材料和材料/工艺相关的失效,并帮助消除由空洞形成引起的界面热点和热应力问题。
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引用次数: 20
Effect of Silicon Inclusions on the Reliability of Sputtered Aluminum-Silicon Metallization 硅夹杂物对溅射铝硅金属化可靠性的影响
Pub Date : 1984-04-03 DOI: 10.1109/IRPS.1984.362031
Steven B. Herschbein, Paul A. Zulpa, J. Curry
A higher than average failure rate-was recorded during high-temperature life testing of a vendor 16K SRAM. Failure analysis of the fallout determined the predominant failure mode to be open metal bit-lines at a topography step in the array. A unique method of unlayering-was used which left all metal-line constituents intact. Rather than finding physical voids in the lines, silicon nodules were found. The formation and possible subsequent growth of nodules is related to wafer-process parameters and life stress, eventually leading to an electromigration-type failure. Special test sites were used to substantiate failure modes and mechanisms found on functional product.
在厂商16K SRAM的高温寿命测试中,记录了高于平均的故障率。对辐射尘的失效分析确定了主要的失效模式是阵列地形步骤上的开放金属位线。采用了一种独特的分层方法,使所有金属线成分完好无损。他们没有在线条中发现物理空洞,而是发现了硅结节。结核的形成和可能的后续生长与晶圆工艺参数和寿命应力有关,最终导致电迁移型失效。专门的试验场地用于证实功能性产品的失效模式和机制。
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引用次数: 7
Characteristics & Reliability of 100Å Oxides 100Å氧化物的特性与可靠性
Pub Date : 1984-04-03 DOI: 10.1109/IRPS.1984.362035
D. Baglee
The electrical characteristics and the long term reliability of 100Å silicon dioxide films is examined in detail. In this paper the initial "as grown" properties are presented and the effects of subsequent process steps are discussed. The long term reliability of 100Å oxide having undergone a full double level polysilicon process is examined. An activation energy of 0.3eV was found and electric field acceleration was determined to be 100/MV/cm.
详细研究了100Å二氧化硅薄膜的电学特性和长期可靠性。本文介绍了该材料的初始“生长”特性,并讨论了后续工艺步骤的影响。考察了100Å氧化物经过完整双能级多晶硅工艺后的长期可靠性。得到活化能为0.3eV,电场加速度为100/MV/cm。
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引用次数: 16
The Effect of TaSi2/n+ Poly Gate on Hot-Electron Instability of Small Channel MOSFETs TaSi2/n+多栅极对小沟道mosfet热电子不稳定性的影响
Pub Date : 1984-04-03 DOI: 10.1109/IRPS.1984.362045
L. Manchanda
This paper reports on a comparative study on the properties of small channel TaSi2/n+ poly gate MOSFETs. Measurements of threshold voltage as a function of effective channel length show that these TaSi2 gate transistors have less short-channel effects for channel lengths ¿1.5 ¿m. In order to determine the threshold stability under voltage stress, poly gate and TaSi2/poly gate MOSFETs were subjected to various drain and gate voltage stresses for a long duration. It is observed that, after the stress, poly gate transistors with channel lengths ¿1.5 ¿m show significant change in the threshold voltage and ß of MOSFETs. This instability seems to be due to hot-electron trapping in the oxide. but under the same stress conditions, these TaSi2/poly gate transistors do not show significant instability. SEM studies show that the poly layer of the TaSi2/poly gate was undercut near the drain-gate and source-gate overlap regions. This undercutting apparently helps in making lightly doped n-junctions near the drain-gate and source-gate overlap region. We postulate that the presence of this lightly doped junction near the drain-gate overlap region moves the high-electric field near the drain junction and reduces the hot-electron instability in the small channel-length TaSi2/poly gate MOSFETs.
本文对小沟道TaSi2/n+多栅极mosfet的性能进行了比较研究。阈值电压作为有效沟道长度的函数的测量表明,这些TaSi2栅极晶体管在沟道长度为1.5 m时具有较小的短沟道效应。为了确定电压应力下的阈值稳定性,多极mosfet和TaSi2/多极mosfet经受了长时间的漏极和栅极电压应力。观察到,在应力作用后,沟道长度为¿1.5¿m的多栅极晶体管的mosfet的阈值电压和β发生了显著变化。这种不稳定性似乎是由于氧化物中的热电子捕获。但在相同的应力条件下,这些TaSi2/多栅极晶体管没有表现出明显的不稳定性。SEM研究表明,在漏极和源极重叠区域附近,TaSi2/多晶硅栅极的多晶硅层被削弱。这显然有助于在漏极和源极重叠区域附近制造轻掺杂的n结。我们假设在漏极重叠区附近的轻掺杂结的存在移动了漏极结附近的高电场,并降低了小通道长度TaSi2/多栅极mosfet中的热电子不稳定性。
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引用次数: 0
Reliability of Gate Metallization in Power GaAs MESFETs 功率GaAs mesfet栅极金属化的可靠性
Pub Date : 1984-04-03 DOI: 10.1109/IRPS.1984.362020
K. Katsukawa, Y. Kose, M. Kanamori, S. Sando
Failure modes have been studied on 0.5 ¿m gate power GaAs MESFETs with Al, Ti/Al and Ti/Al/Ti gate metallization, respectively. It has been found that the dominant failure modes are gate metal disconnection for Al gate, catastrophic burn out for the Ti/Al gate and gate breakdown voltage degradation for the Ti/Al/Ti gate under D.C. operational life tests. The degradation mechanisms have been clarified using SEM, microprobe-AES and SIMS. It is shown that Ti/Al, gate is the most reliable among these three kinds of FETS.
分别研究了Al、Ti/Al和Ti/Al/Ti栅极金属化的0.5¿m栅极功率GaAs mesfet的失效模式。在直流工作寿命试验中发现,Al栅极的主要失效模式是栅极金属断开、Ti/Al栅极的灾难性烧毁和Ti/Al/Ti栅极击穿电压下降。利用SEM、aes和SIMS等手段对其降解机理进行了研究。结果表明,在这三种fet中,Ti/Al栅极是最可靠的。
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引用次数: 9
Lifetime of Bonded Contacts on Thin Film Metallizations 金属化薄膜上键合触点的寿命
Pub Date : 1984-04-03 DOI: 10.1109/IRPS.1984.362030
H. Hieber, K. Pape
Gold beams and wires are microwelded to a stable gold/platinum/titanium thin-film sandwich on silicon wafers. The contacts are subjected to simultaneous thermal and mechanical loads. The measured times-to-fracture are analyzed by mechanisms of creep-crack propagation. A creep rupture equation contains the stress exponent and the thermal activation energy of plastic f low as the material-specific parameters. The time-to-fracture is strongly affected by the texture of the beams and wires and by the geometry of the welded contact. The equation can be used for extrapolation in a temperature interval between 300 and 650K.
金梁和金线被微焊接在硅晶圆上稳定的金/铂/钛薄膜夹层上。触点同时承受热载荷和机械载荷。根据蠕变-裂纹扩展机理,对所测断裂时间进行了分析。蠕变断裂方程以应力指数和塑性流的热激活能作为材料特性参数。断裂时间受梁和导线的织构以及焊接接触的几何形状的强烈影响。该方程可用于300 ~ 650K温度区间内的外推。
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引用次数: 2
Electromigration Study of the Al-Cu/Ti/Al-Cu System Al-Cu/Ti/Al-Cu体系的电迁移研究
Pub Date : 1984-04-03 DOI: 10.1109/IRPS.1984.362058
S. Iyer, C. Ting
We have investigated unpassivated Al-Cu(4.5%)/Ti/Al-Cu laminated structures for their electromigration behavior for linewidths between 5 ¿ and 1.5 ¿ We find that although line opens are not the dominant failure mode, significant mass accumulation occurs all along the line leading to the real possibility of extrusion induced shorts. In our experiments laminated structures had lifetimes in excess of conventional Al-Cu lines by at least a factor of 10. Cu migration takes place in the early part of the stripe life. Al migration occurs preferentially from the top layer. Furthermore, a decrease of the line resistance, unlike in conventional structures, is observed during current stress. The Ti intermetallic layer does not show any motion.
我们研究了未钝化的Al-Cu(4.5%)/Ti/Al-Cu层合结构在线宽为5¿和1.5¿之间的电迁移行为。我们发现,尽管线开口不是主要的失效模式,但沿线会发生显著的质量积累,导致挤压引起短路的真正可能性。在我们的实验中,层压结构的寿命至少比传统的铝铜线长10倍。铜的迁移发生在条带生命的早期。铝的迁移优先发生在顶层。此外,与传统结构不同,在电流应力下观察到线电阻的减少。钛金属间层不表现出任何运动。
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引用次数: 7
Characterization of Die Attach Failure Modes in Leadless Chip Carrier (LCC) Packages by Auger Electron Spectroscopy 用俄歇电子能谱表征无铅芯片载流子封装的晶片连接失效模式
Pub Date : 1984-04-03 DOI: 10.1109/IRPS.1984.362040
R. Pyle, H. Stevens
Failure to attach an IC die to its side-braze or leadless chip carrier (LCC) package can represent a serious problem in integrated circuit assembly. Consequently, the need to understand the mechanisms involved in furnace eutectic die attach failure is very critical. The purpose of this experimental investigation was to characterize the various die attach failure modes occurring in the furnace eutectic die attach process of LCC packages utilizing Pb/In/Ag preform material. Results from analytical investigations utilizing surface analysis techniques on a large number of sample die attach failures in LCC's are presented. An explanation of the causes and mechanisms involved in furnace die attach failure are proposed from both the experimental analytical results obtained and from theoretical investigations.
在集成电路组装中,未能将IC芯片连接到其侧钎焊或无引线芯片载体(LCC)封装可能是一个严重的问题。因此,需要了解机制所涉及的炉共晶模具连接失败是非常关键的。本实验研究的目的是表征利用Pb/ in /Ag预制体材料的LCC封装的炉共晶贴模过程中出现的各种贴模失效模式。本文介绍了利用表面分析技术对LCC中大量模具连接失效样品进行分析研究的结果。从实验分析结果和理论研究两方面阐述了炉模接头失效的原因和机理。
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引用次数: 8
Epoxy Degradation Induced Au-Al Intermetallic Void Formation in Plastic Encapsulated MOS Memories 环氧树脂降解诱导塑料封装MOS存储器中金铝金属间空隙的形成
Pub Date : 1984-04-03 DOI: 10.1109/IRPS.1984.362017
R. J. Gale
Previous high temperature aging studies have shown that the presence of epoxy in integrated circuit packages degrades the strength and contact resistance of Au-Al bonds [1-3]. Cl impurities in the resin or Br from the flame retardant or both are associated with this phenomenon. High temperature aging experiments were performed with Au wire bonded, Al metallized 4K NMOS Static RAMs and epoxy molding compounds in two types of DIPs. The initial study focussed on the effect of the flame retardant by using the epoxy with and without flame retardant in the cavities of epoxy sealed ceramic DIPs. The apparent activation energy for the degradation was determined by aging devices molded in DIPs using the standard flame-retardant formulation at three temperatures. The Cl and Br content of the epoxies was measured by neutron activation analysis and water extraction. Electron and ion microprobe analysis showed that Cl and Br are present in the bond zone with the Au-Al intermetallics. The median life at 180°C was only a factor of three higher without the flame retardant, even though the Br content was 600 times lower, suggesting that the Cl plays a major role. The apparent activation energy for the bond degradation in the flame-retardant molding compound is ~0.8 eV, within experimental error of that for pure Au-Al intermetallic formation [4] and that for the breakdown of the brominated flame retardant determined by water extraction. The water extraction results also indicate that the chlorinated impurities are less thermally stable than the brominated flame retardant.
先前的高温老化研究表明,集成电路封装中环氧树脂的存在会降低Au-Al键的强度和接触电阻[1-3]。树脂中的Cl杂质或阻燃剂中的Br或两者都与此现象有关。对金丝键合、铝金属化4K NMOS静态ram和环氧模化化合物在两种dip中进行了高温老化实验。初步研究了带阻燃剂和不带阻燃剂的环氧树脂在环氧密封陶瓷蘸料腔内的阻燃效果。通过使用标准阻燃剂配方在三种温度下在dip中成型的老化装置,确定了降解的表观活化能。用中子活化法和水萃取法测定了环氧树脂中Cl和Br的含量。电子探针和离子探针分析表明,在与金铝金属间化合物的结合区存在Cl和Br。在180°C下,没有阻燃剂的中位寿命只增加了3倍,尽管Br含量降低了600倍,这表明Cl起了主要作用。阻燃成型化合物中键降解的表观活化能为~0.8 eV,在纯Au-Al金属间形成的表观活化能[4]和水萃取法测定的溴化阻燃剂击穿表观活化能的实验误差范围内。水萃取结果还表明,氯化杂质的热稳定性不如溴化阻燃剂。
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引用次数: 25
Sputtered Ti-Doped Al-Si for Enhanced Interconnect Reliability 增强互连可靠性的溅射ti掺杂Al-Si
Pub Date : 1984-04-03 DOI: 10.1109/IRPS.1984.362043
F. Fischer, F. Neppl
It is shown that an Al-Si-Ti alloy containing 0.1-0.2wt.% Ti used as an IC-interconnect material reaches the electromigration strength of Al-Si-Cu and simultaneously avoids the disadvantages of Al-Si-Cu like enhanced corrosion susceptibility or dry etching problems. The stabilizing effect of Ti is demonstrated by life testing and additonally by monitoring changes of residual resistivity and heat transfer to the substrate during temperature current stress.
结果表明:Al-Si-Ti合金的质量分数为0.1 ~ 0.2wt。使用Ti作为ic互连材料达到Al-Si-Cu的电迁移强度,同时避免了Al-Si-Cu的缺点,如增强腐蚀敏感性或干蚀刻问题。通过寿命测试和温度电流应力下残余电阻率的变化以及对衬底传热的监测,证明了钛的稳定作用。
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引用次数: 14
期刊
22nd International Reliability Physics Symposium
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