This work aims to investigate the effect of oxygen concentration on the flame spread behavior of rocket kerosene in an oxygen-enriched environment, with a specific focus on high oxygen levels. The flame spread characteristics of rocket kerosene under oxygen concentrations ranging from 21% (air) to 100% (pure oxygen) were systematically studied via experimental and theoretical methods. The influences of oxygen concentration (especially high concentrations) on flame spread phenomena and flame spread rate were analyzed, and the characteristic initial fuel temperatures corresponding to transitions between different flame spread stages were identified. Results indicate that for all tested oxygen concentrations, the flame spread rate increases with rising initial fuel temperature. The flame spread process exhibits distinct stage divisions dependent on oxygen concentration: three stages (liquid-phase control stage, gas-liquid two-phase coupled control stage, and gas-phase control stage) under 21%–60% O2; and only two stages under 80%–100% O2 (the liquid-phase control stage is absent at high oxygen concentrations). Based on the characteristic initial fuel temperatures of each stage and theoretical analysis of gas-phase, liquid-phase, and gas-liquid two-phase coupled control mechanisms, a global model for the flame spread rate of rocket kerosene was proposed. This model incorporates the combined effects of initial fuel temperature and oxygen concentration, with experimental data showing good agreement with theoretical predictions. This work provides a fundamental dataset and a reliable model, which can support safety assessments (e.g., personnel safe escape analysis) and offer theoretical guidance for emergency management in scenarios involving rocket kerosene combustion.
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