Electrochemical energy storage systems (EESS) participate in power system frequency modulation (FM), with frequent charge-discharge cycles and high operating power. These characteristics-induced issues, including degraded system thermal properties and intensified inconsistency, require in-depth research, posing dual challenges to temperature uniformity management and aging-related thermal management. Thus, this paper carries out the following research efforts. First, six heat dissipation configurations are proposed by increasing heat transfer area and boosting heat transfer coefficient. Eventually, the air-liquid dual-circulation heat dissipation configuration G is optimized and selected. Second, based on orthogonal simulations, the impact characteristics of temperature-control boundaries and parameter sensitivity are analyzed, obtaining the significance ranking of three factors (inlet temperature A, inlet flow rate B, fan speed C) for maximum temperature and maximum temperature difference. Finally, temperature control effectiveness analysis is performed on 15 aging grouping schemes with non-uniform State of Health (SOH) distribution, identifying modules that meet the requirements (maximum temperature <35 °C, maximum temperature difference <5 °C) throughout the full lifespan. The findings indicate that configuration g expands the heat transfer area by nearly twofold and boosts the heat transfer coefficient by around sixfold relative to configuration A. During 2p discharge, configuration G achieves a maximum temperature difference of 2.32 °C, representing a 25.40 % improvement over configuration A. Under configuration G, the factors influencing maximum temperature and maximum temperature difference follow the same significance ranking: inlet temperature A > inlet flow rate B > fan speed C. In addition, among the modules meeting temperature control effectiveness requirements throughout the full lifespan, module Ⅲ-A has the highest temperature of 32.31 °C. Module Ⅲ-C has the largest temperature difference of 4.27 °C. For modules meeting the temperature control requirements, the maximum aging degree reaches SOH = 90 %, with a maximum aging difference of 10 %. The results of this study provide design references and a theoretical basis for EESS participating in power system FM, laying a foundation for their promotion and application.
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