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Asymmetric active sites originate from high-entropy metal selenides by joule heating to boost electrocatalytic water oxidation 通过焦耳加热从高熵金属硒化物中产生不对称活性位点,促进电催化水氧化
IF 38.6 1区 材料科学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2024-08-21 DOI: 10.1016/j.joule.2024.06.004

High-entropy materials (HEMs) have garnered tremendous attention for electrocatalytic water oxidation because of their extraordinary properties. Nevertheless, scant attention has been directed toward comprehending the origin of their excellent activity and intricate atomic arrangements. Herein, we demonstrate the synthesis of high-entropy metal selenides (HEMSs) using a rapid joule-heating method, effectively circumventing the immiscibility challenges inherent in combining multiple metal elements. This achievement is collectively verified by a convergence of diverse analytical techniques encompassing quasi in situ X-ray absorption spectroscopy and operando attenuated total reflectance infrared spectroscopy. The HEMS exhibits a low overpotential of 222 mV at 10 mA cm−2 and extraordinary durability with negligible degradation over a 1,000 h durability test at 10 mA cm−2 and 500 h at 100 mA cm−2. Further, our theoretical investigations establish the pronounced mechanism of asymmetric Cu-Co-Ni active units in HEMS by manipulating the interaction of oxygen-containing intermediates, which leads to enhanced OER activity and durability.

高熵材料(HEMs)因其非凡的特性,在电催化水氧化方面获得了极大的关注。然而,人们很少关注其卓越活性和复杂原子排列的起源。在本文中,我们展示了利用快速焦耳加热法合成高熵金属硒化物(HEMSs)的过程,有效地规避了多种金属元素结合所固有的不溶性难题。准原位 X 射线吸收光谱和操作衰减全反射红外光谱等多种分析技术的融合共同验证了这一成果。在 10 mA cm-2 条件下,HEMS 的过电位很低,仅为 222 mV;在 10 mA cm-2 条件下,HEMS 的耐久性测试时间为 1,000 小时,在 100 mA cm-2 条件下,HEMS 的耐久性测试时间为 500 小时,降解几乎可以忽略不计。此外,我们的理论研究通过操纵含氧中间体的相互作用,确立了 HEMS 中不对称铜-铜-镍活性单元的显著机理,从而提高了 OER 的活性和耐用性。
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引用次数: 0
Elucidating the optimal material combinations of organic photovoltaics for maximum industrial viability 阐明有机光伏的最佳材料组合,实现最大的工业可行性
IF 38.6 1区 材料科学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2024-08-21 DOI: 10.1016/j.joule.2024.06.022
Hua Tang , Zhihui Liao , Qianqian Chen , Han Xu , Jiaming Huang , Jianhua Han , Dingqin Hu , Ying Luo , Shirong Lu , Derya Baran , Gang Li , Christoph J. Brabec , Frédéric Laquai , Yakun He

The choice of donor (D) and acceptor (A) materials in organic solar cells (OSCs) determines the so-called golden triangle of organic photovoltaics (OPV), namely, cost, power conversion efficiency (PCE), and device stability. However, despite the recent advancements in material and device development, determining the optimal material combination for industrialization remains a challenge. Herein, we unveil the optimal material combination that exhibits maximum industrial viability. Specifically, the industrial figure of merit (i-FoM) of seven OPV categories is calculated and further analyzed, including blends of small-molecule donor (SMD):fullerene acceptor, SMD:non-fullerene acceptor (NFA), oligomer donor:NFA, terpolymer:NFA, polymer donor:NFA, polymer donor:polymer acceptor, and single-component materials. Because OPV is approaching wide-scale industrialization, insights into the successes and challenges of these material combinations, particularly their PCE, photostability, and synthetic complexity (SC) index, offer guidance toward accelerating the industrialization of OPV.

有机太阳能电池(OSC)中供体(D)和受体(A)材料的选择决定了所谓的有机光伏(OPV)金三角,即成本、功率转换效率(PCE)和器件稳定性。然而,尽管最近在材料和器件开发方面取得了进展,但确定工业化的最佳材料组合仍然是一项挑战。在此,我们揭示了能展现最大工业可行性的最佳材料组合。具体来说,我们计算并进一步分析了七类 OPV 的工业优越性(i-FoM),包括小分子供体(SMD):富勒烯受体、SMD:非富勒烯受体(NFA)、低聚物供体:非富勒烯受体、三元共聚物:非富勒烯受体、聚合物供体:非富勒烯受体、聚合物供体:聚合物受体的混合物以及单组分材料。由于 OPV 即将实现大规模工业化,因此深入了解这些材料组合的成功经验和挑战,特别是它们的 PCE、光稳定性和合成复杂性 (SC) 指数,可为加速 OPV 工业化提供指导。
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引用次数: 0
Asymmetric active sites originate from high-entropy metal selenides by joule heating to boost electrocatalytic water oxidation 通过焦耳加热从高熵金属硒化物中产生不对称活性位点,促进电催化水氧化
IF 38.6 1区 材料科学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2024-08-21 DOI: 10.1016/j.joule.2024.07.021
Fangren Qian, Lishan Peng, Dengfeng Cao, Wei Jiang, Chengsi Hu, Jiabao Huang, Xinping Zhang, Jiahui Luo, Shuangming Chen, Xiaojun Wu, Li Song, Qingjun Chen
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引用次数: 0
Harmonizing organic photovoltaics research and development among academia and industry 协调学术界和产业界的有机光伏研发工作
IF 38.6 1区 材料科学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2024-08-21 DOI: 10.1016/j.joule.2024.07.015
Eva M. Herzig , Feng Gao , Jonas Bergqvist , Maria A. Loi , Sebastian B. Meier

Eva M. Herzig is a professor at the Institute of Physics of the University of Bayreuth. She received her PhD from the University of Edinburgh (UK) and worked in industry on renewable energies and as a postdoc at the Technical University of Munich (Germany). Her group focuses on nanostructure control via processing and the characterization of thin films, applying time-resolved, multi-modal measurement methods to resolve structures on the nanoscale with a current focus on organic and hybrid energy materials.

Feng Gao is a professor and Wallenberg Scholar at Linköping University in Sweden. He received his PhD from the University of Cambridge (UK) in 2011, followed by a Marie Skłodowska-Curie postdoc fellowship at Linköping University. His group currently focuses on research into solution-processed energy materials and devices, mainly based on organic semiconductors and metal halide perovskites.

Jonas Bergqvist is CTO at Epishine AB. He holds a master’s degree in applied physics and a doctoral degree in biomolecular and organic electronics from Linköping University, Sweden. Jonas has 15 years of experience within organic solar cells and is one of the cofounders of Epishine AB, where he leads the technology development of roll-to-roll manufacturing of printed organic solar cells for indoor applications.

Maria A. Loi is a professor at the Zernike Institute for Advanced Materials of the University of Groningen in the Netherlands. She received a PhD in physics from the University of Cagliari, Italy, in 2001. She has been a postdoctoral fellow at the Johannes Kepler University in Linz, Austria, and at the National Research Council in Bologna, Italy. She joined the University of Groningen in 2006 as a Rosalind Franklin Fellow, and she became full professor in the same institution in 2014. She focuses on the investigation of the photophysics of unconventional semiconductors and in their application into optoelectronic devices.

Sebastian B. Meier is the director of OPV technology and manufacturing at ASCA GmbH & Co. KG. He holds a diploma degree in materials science and a doctoral degree in engineering from the Friedrich-Alexander University of Erlangen-Nuremberg, Germany. He has 15 years of industrial experience in the field of organic and printed electronics and is author and co-author of numerous scientific publications in recognized international journals as well as patents in the field of organic light-emitting devices and solar cells.

Eva M. Herzig 是拜罗伊特大学物理研究所教授。她在英国爱丁堡大学获得博士学位,曾在可再生能源行业工作,并在德国慕尼黑工业大学担任博士后。她的研究小组侧重于通过加工和薄膜表征来控制纳米结构,应用时间分辨、多模态测量方法来解析纳米尺度上的结构,目前的研究重点是有机和混合能源材料。他于 2011 年获得英国剑桥大学博士学位,随后在林雪平大学获得玛丽-斯克沃多夫斯卡-居里博士后奖学金。他的研究小组目前专注于溶液加工能源材料和设备的研究,主要基于有机半导体和金属卤化物过氧化物。Jonas Bergqvist 是 Epishine AB 公司的首席技术官。他拥有瑞典林雪平大学应用物理学硕士学位和生物分子与有机电子学博士学位。Jonas 在有机太阳能电池领域拥有 15 年的经验,是 Epishine AB 的共同创始人之一,负责室内应用印刷有机太阳能电池卷对卷制造技术的开发。她于 2001 年获得意大利卡利亚里大学物理学博士学位。她曾在奥地利林茨约翰内斯-开普勒大学和意大利博洛尼亚国家研究委员会担任博士后研究员。2006 年,她作为罗莎琳德-富兰克林研究员加入格罗宁根大学,并于 2014 年成为该校正教授。Sebastian B. Meier 是 ASCA GmbH & Co.KG 的 OPV 技术和制造总监。他拥有德国埃尔兰根-纽伦堡弗里德里希-亚历山大大学材料科学文凭和工程博士学位。他在有机和印刷电子领域拥有 15 年的行业经验,在国际知名期刊上发表过多篇科学论文,并在有机发光器件和太阳能电池领域申请了多项专利。
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引用次数: 0
Omics-enabled understanding of electric aircraft battery electrolytes 通过绪论了解电动飞机电池电解质
IF 38.6 1区 材料科学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2024-08-21 DOI: 10.1016/j.joule.2024.05.013

Omics is a discipline that identifies and quantifies molecular processes that contribute to the form and function of living systems. Here, we translate omics to study battery systems. By employing precision analytical capabilities across chemical space, we delineate the structure, function, and evolution of interphases when cycling Li-nickel manganese oxide (NMC)811 cells at high power and high voltage with mixed-salt locally superconcentrated electrolytes. Despite differences in their make-up, top-performing electrolytes converged in their cathode–electrolyte interphase (CEI) chemistries, which were unexpectedly enriched with fluoroethers (upregulation) and depleted with LiF (downregulation). Moreover, these atypical CEIs more effectively suppressed leakage current, cathode corrosion, and cathode fracturing, extending battery life. Pouch cells (130 mAh) assembled with 50-μm-thick Li foil, semi-solid NMC811 electrodes (9 mAh cm−2), and lean electrolyte (2.2 Ah g−1) showed excellent power retention over more than 100 cycles using a realistic mission for electric vertical take-off and landing.

全息技术是一门识别和量化分子过程的学科,这些分子过程对生命系统的形态和功能做出了贡献。在这里,我们将全息技术应用于研究电池系统。通过利用跨化学空间的精密分析能力,我们描绘了锂镍锰氧化物(NMC)811 电池在高功率和高电压下循环使用混合盐局部超浓缩电解质时的相间结构、功能和演化过程。尽管电解质的组成存在差异,但性能最佳的电解质在阴极-电解质间相(CEI)化学成分上趋于一致,出乎意料地富含氟醚(上调),而贫含 LiF(下调)。此外,这些非典型 CEI 还能更有效地抑制漏电流、阴极腐蚀和阴极断裂,从而延长电池寿命。使用 50μm 厚的锂箔、半固态 NMC811 电极(9 mAh cm-2)和贫电解液(2.2 Ah g-1)组装的袋装电池(130 mAh)在使用电动垂直起降的实际任务中,经过 100 多个循环后显示出卓越的功率保持能力。
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引用次数: 0
Green hydrogen pathways, energy efficiencies, and intensities for ground, air, and marine transportation 陆运、空运和海运的绿色制氢途径、能效和强度
IF 38.6 1区 材料科学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2024-08-21 DOI: 10.1016/j.joule.2024.07.012
Timothy J. Wallington , Maxwell Woody , Geoffrey M. Lewis , Gregory A. Keoleian , Eytan J. Adler , Joaquim R.R.A. Martins , Matthew D. Collette

Green hydrogen produced by electrolysis with renewable electricity can be used directly or in synthetic fuels (e-fuels) to decarbonize road, rail, marine, and air transportation. However, system inefficiencies during hydrogen or e-fuel production, storage, transportation, dispensing, and use lead to approximately 80%–90% loss of the initial electrical energy input. Electric-powered ground, marine, and air transport is approximately 3–8 times more energy efficient than hydrogen alternatives. Renewable electricity sources in the US are insufficient to support hydrogen production for light-duty vehicles. Therefore, green hydrogen should be used strategically in heavy-duty road, rail, aviation, and marine transportation, where electrification alternatives are constrained by load and range. Energy intensity for hydrogen transport measured by renewable electricity per unit of service follows the current trends for petroleum-fueled transport. For freight, ships and rail are the least intensive modes, followed by heavy-duty trucks, then aircraft: 0.04, 0.2, 2, and 20 MJ per t-km, respectively.

利用可再生电力电解产生的绿色氢气可直接用于公路、铁路、海运和空运,也可用于合成燃料(电子燃料),以实现脱碳。然而,在氢气或电子燃料的生产、储存、运输、分配和使用过程中,系统效率低下导致初始电能输入损失约 80%-90%。电力驱动的陆运、海运和空运的能效大约是氢气替代品的 3-8 倍。美国的可再生电力资源不足以支持轻型汽车的氢气生产。因此,绿色氢气应战略性地用于重型公路、铁路、航空和海洋运输,因为在这些领域,电气化替代品受到负载和续航能力的限制。以每单位服务的可再生电力来衡量氢运输的能源强度,与当前以石油为燃料的运输趋势一致。在货运方面,船舶和铁路的能源密集度最低,其次是重型卡车,然后是飞机:每吨公里分别为 0.04、0.2、2 和 20 兆焦耳。
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引用次数: 0
Modernizing rechargeable military batteries 军用充电电池的现代化
IF 38.6 1区 材料科学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2024-08-21 DOI: 10.1016/j.joule.2024.06.019
Brandon J. Hopkins , Nicholas H. Bashian

Dr. Brandon J. Hopkins is a lead battery technology engineer at MITRE in the emerging technology division with expertise in techno-economics and decarbonization strategy focused on energy storage, the grid, and electric vehicles. Previously, he worked at Ford Motor Company as a research engineer to advance Ford’s electrification strategy. At the U.S. Naval Research Laboratory, he performed research on primary and rechargeable zinc batteries. He received a BA from Harvard University and an MS and PhD from the Massachusetts Institute of Technology in mechanical engineering. He is an inventor on 5 patents and has co-authored 17 journal articles.

Dr. Nicholas H. Bashian is a senior battery technology scientist at MITRE in the emerging technology division. His research focuses on the investigation of next-generation batteries as well as the analysis of military battery usage and system integration. His previous work includes the electrochemical and in situ structural characterization of chalcogenide electrode materials for Li-ion and Na-ion batteries in addition to the development of solid electrolytes. With extensive experience in maturing battery technologies for defense applications and assessing energy storage needs for specialty applications, Dr. Bashian has co-authored 15 journal articles.

Brandon J. Hopkins 博士是 MITRE 新兴技术部门的首席电池技术工程师,擅长技术经济学和去碳化战略,重点关注能源存储、电网和电动汽车。此前,他曾在福特汽车公司担任研究工程师,负责推进福特的电气化战略。在美国海军研究实验室,他从事过原电池和可充电锌电池的研究。他拥有哈佛大学学士学位、麻省理工学院机械工程硕士和博士学位。Nicholas H. Bashian 博士是 MITRE 新兴技术部门的高级电池技术科学家。他的研究重点是研究下一代电池以及分析军用电池的使用和系统集成。除了固体电解质的开发之外,他以前的工作还包括锂离子和纳离子电池用瑀电极材料的电化学和原位结构表征。Bashian 博士在成熟国防应用电池技术和评估特殊应用的储能需求方面拥有丰富的经验,他与人合作撰写了 15 篇期刊论文。
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引用次数: 0
Device engineering of non-fullerene organic photovoltaics with extrapolated operational T80 lifetime over 45,000 h in air 非富勒烯有机光伏器件工程,在空气中的 T80 工作寿命推断超过 45,000 小时
IF 38.6 1区 材料科学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2024-08-21 DOI: 10.1016/j.joule.2024.05.014

The efficiency and stability of organic solar cells (OSCs) is often restricted by the metastable photoactive and charge transport layers. Here, we report the acquiring of stable photovoltaics via vacuum-assisted thermal annealing (VTA), which not only enhances the molecular packing of donor and acceptor but also restrains the over-growth of photovoltaic molecules and leads to a slender fibrillar network, resulting in enhanced charge transport and suppressed carrier recombination. In situ ellipsometry measurements reveal that VTA can remove the trapped solvents and reduce the free volume of the photoactive layer, leading to slower structural relaxation during operation and therefore superior morphological and operational stability. As a result, the VTA-treated D18:L8-BO and PM6:L8-BO OSCs exhibit superior PCEs of 19.7% and 19.2%, respectively, with an ITO/PEDOT:PSS/active layer/PDINN/Ag structure, and a PCE of 18.0% with a T80 lifetime of 45,200 h for the ITO/MoO3/PM6:L8-BO/C60/BCP/Ag-structured device, corresponding to an unprecedented lifetime of 30 years.

有机太阳能电池(OSCs)的效率和稳定性往往受制于可迁移的光活性层和电荷传输层。在此,我们报告了通过真空辅助热退火(VTA)获得稳定光生伏打的情况。VTA 不仅能增强供体和受体的分子堆积,还能抑制光生伏打分子的过度生长,形成细长的纤维状网络,从而增强电荷传输和抑制载流子重组。原位椭偏仪测量结果表明,VTA 可以去除被截留的溶剂,减少光活性层的自由体积,从而减慢运行过程中的结构松弛,因此具有优异的形态和运行稳定性。因此,经过 VTA 处理的 D18:L8-BO 和 PM6:L8-BO OSC 在 ITO/PEDOT:PSS/active layer/PDINN/Ag 结构下的 PCE 分别为 19.7% 和 19.2%,而在 ITO/MoO3/PM6:L8-BO/C60/BCP/Ag 结构器件下的 PCE 为 18.0%,T80 寿命为 45200 小时,相当于前所未有的 30 年寿命。
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引用次数: 0
High-efficiency air-bridge thermophotovoltaic cells 高效气桥热光电池
IF 38.6 1区 材料科学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2024-07-17 DOI: 10.1016/j.joule.2024.05.002

Thermophotovoltaic (TPV) cells generate electricity by converting infrared radiation emitted by a hot thermal source. Air-bridge TPVs have demonstrated enhanced power conversion efficiencies by recuperating a large amount of power carried by below-band-gap (out-of-band) photons. Here, we demonstrate single-junction InGaAs(P) air-bridge TPVs that exhibit up to 44% efficiency under 1,435°C blackbody illumination. The air-bridge design leads to near-unity reflectance (97%–99%) of out-of-band photons for ternary and quaternary TPVs whose band gaps range from 0.74 to 1.1 eV. These results suggest the applicability of the air-bridge cells to a range of semiconductor systems suitable for electricity generation from thermal sources found in both consumer and industrial applications, including thermal batteries.

热光电(TPV)电池通过转换热源发出的红外辐射来发电。气桥冠捷光伏电池通过回收带隙以下(带外)光子携带的大量电能,提高了功率转换效率。在这里,我们展示了单结 InGaAs(P)气桥热塑性硫化弹性体,在 1435°C 黑体照明下,其效率高达 44%。对于带隙范围在 0.74 至 1.1 eV 之间的三元和四元热塑性硫化弹性体,气桥设计可实现接近统一的带外光子反射率(97%-99%)。这些结果表明,气桥电池适用于一系列半导体系统,适合利用消费和工业应用中的热源发电,包括热电池。
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引用次数: 0
Domestic-first, climate second? Global consequences of the Inflation Reduction Act 国内第一,气候第二?减少通货膨胀法》的全球影响
IF 38.6 1区 材料科学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2024-07-17 DOI: 10.1016/j.joule.2024.06.001

Bessie Noll is a post doctoral researcher at the Energy and Technology Policy Group at ETH Zurich. Her research focuses on the effects of policy intervention on the development of clean energy technologies and transitional outcomes of modern energy systems. She holds a master’s degree in mechanical engineering from Stanford University and a PhD in energy and technology policy from ETH Zurich.

Bjarne Steffen is assistant professor and head of ETH Zurich’s Climate Finance and Policy Group. His research addresses the impact of public policy interventions on technological change in the energy sector, with a particular focus on the role of financial actors in reallocating capital. He holds a master’s degree in economics from the University of Mannheim and a PhD in energy economics from the University of Duisburg-Essen.

Tobias Schmidt is ETH Zurich’s professor of energy and technology policy and directs the Institute of Science, Technology, and Policy. His research focuses on the interaction of public policy and its underlying politics with technological change in energy-related sectors. He holds a master’s degree in electrical engineering from TU Munich and a doctorate from ETH Zurich.

贝西-诺尔(Bessie Noll)是苏黎世联邦理工学院能源与技术政策小组的博士后研究员。她的研究重点是政策干预对清洁能源技术发展和现代能源系统过渡成果的影响。她拥有斯坦福大学机械工程硕士学位和苏黎世联邦理工学院能源与技术政策博士学位。Bjarne Steffen 是苏黎世联邦理工学院助理教授兼气候金融与政策组组长。他的研究涉及公共政策干预对能源领域技术变革的影响,尤其关注金融参与者在重新分配资本方面的作用。托比亚斯-施密特(Tobias Schmidt)是苏黎世联邦理工学院的能源和技术政策教授,同时也是科学、技术和政策研究所的所长。他的研究重点是公共政策及其背后的政治与能源相关领域技术变革的相互作用。他拥有慕尼黑工业大学电气工程硕士学位和苏黎世联邦理工学院博士学位。
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引用次数: 0
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