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Study on water and gas permeation characteristics with ZIF-8 mixed matrix membranes ZIF-8混合基质膜的水和气渗透特性研究
IF 1.9 4区 环境科学与生态学 Q2 Environmental Science Pub Date : 2023-06-26 DOI: 10.2166/aqua.2023.102
A. Gawali, S. Gawali, Surendra Sasi Kumar Jampa, M. Sinha, Jalaja B. Pandya, S. Shinde, Snigdha Khuntia
The membrane separation process lacks intrinsic permeation characteristics to compete with other separation technologies like adsorption, sedimentation, coagulation, skimming, and distillation. A mixed matrix membrane (MMM) is one of the strategies to improve the separation characteristics with embedded nanofillers particles. Zeolite imidazolate framework (ZIF) has a new subclass of inorganic–organic hybrid materials that are being introduced as new fillers for incorporation into the polymer matrix for various applications such as oily wastewater separation, wastewater treatment, natural gas dehydration, landfill gas upgrading, and mixed gas separation. In this experimental work, a metal-organic framework called ZIF-8 was synthesized and used as filler for modification of MMMs and characterized with FTIR and SEM. ZIF-8 nanoparticles up to 5 wt% loading were added to PSF casting solution then the permeation characteristics of MMMs showed an improved result like the pure water flux of the modified membrane at 2.5 bar was increased up to 456.38 L/m2h. In the case of pure gas separation, at 5 wt% ZIF-8 loading in PSF, the pure gas CO2 permeability at 9 bar pressure had increased to 10.54 barrer.
膜分离过程缺乏固有的渗透特性,无法与吸附、沉淀、混凝、脱脂和蒸馏等其他分离技术竞争。混合基质膜(MMM)是通过嵌入纳米填料颗粒来改善分离特性的策略之一。咪唑酸沸石骨架(ZIF)是一种新型无机-有机杂化材料,可作为新型填料掺入聚合物基体中,用于含油废水分离、废水处理、天然气脱水、垃圾填埋气改造和混合气体分离等各种应用。在本实验中,合成了一种名为ZIF-8的金属有机骨架,并将其用作填充剂改性mm,并用FTIR和SEM对其进行了表征。将负载为5 wt%的ZIF-8纳米粒子加入到PSF铸液中,MMMs的渗透特性得到改善,改性膜在2.5 bar下的纯水通量提高到456.38 L/m2h。在纯气体分离的情况下,在PSF中添加5 wt%的ZIF-8时,9 bar压力下的纯气体CO2渗透率增加到10.54 bar。
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引用次数: 0
Waste load allocation by integrated GMS modeling and economic evaluation for nitrate reduction in Varamin aquifer 基于综合GMS模型的废物负荷分配及Varamin含水层硝酸盐还原的经济评价
IF 1.9 4区 环境科学与生态学 Q2 Environmental Science Pub Date : 2023-06-24 DOI: 10.2166/aqua.2023.288
M. Souri, S. Jamshidi, H. K. Moghaddam
Groundwater is a dependable freshwater resource in arid and semi-arid areas where its quality management is essential. However, untreated wastewater is a risk to safe water supply from aquifers. Wastewater treatment plants (WWTPs) can reduce pollutants, but their impact on groundwater quality versus their operating costs requires case studies. This research uses the two modules of the groundwater modeling system (GMS) to simulate the Varamin Plain, south-eastern Tehran, Iran. The MODFLOW and MT3D were used for groundwater quantity and quality modeling, respectively. Through these modules, the effectiveness of two WWTPs (Pakdasht and Varamin) in six waste load allocation (WLA) scenarios was compared based on nitrate reduction in 3-year and 10-year periods. The construction and operating costs of each WLA scenario were also calculated. The best WLA is a scenario with the lowest marginal cost. Therefore, constructing Varamin WWTP with 25% nitrogen removal was the selected option. Here, the average nitrate concentration in the aquifer is reduced from 28.4 mg/L (±4.1) to less than 25 mg/L (±2.4) with an annual marginal cost of 8 M$.L/mg. It implies that constructing more WWTPs or tertiary units for nitrate removal is not recommended as they do not add significant nitrate abatement in groundwater regarding the related costs.
地下水是干旱半干旱地区一种可靠的淡水资源,其质量管理至关重要。然而,未经处理的废水对含水层的安全供水构成威胁。污水处理厂(WWTPs)可以减少污染物,但它们对地下水质量的影响与其运营成本需要进行案例研究。本研究利用地下水模拟系统(GMS)的两个模块对伊朗德黑兰东南部的瓦拉明平原进行了模拟。使用MODFLOW和MT3D分别进行地下水数量和水质模拟。通过这些模块,比较了两个污水处理厂(Pakdasht和Varamin)在6种废物负荷分配(WLA)方案中的有效性,基于3年和10年期间的硝酸盐减少。还计算了每个WLA方案的建设和运营成本。最好的WLA是边际成本最低的场景。因此,选择构建脱氮率为25%的Varamin污水处理系统。在这里,含水层中硝酸盐的平均浓度从28.4 mg/L(±4.1)降低到25 mg/L(±2.4)以下,年边际成本为800万美元/mg。这意味着不建议建造更多的污水处理厂或三级装置来去除硝酸盐,因为就相关成本而言,它们不会显著增加地下水中的硝酸盐减排。
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引用次数: 1
Assessing the performance of wheat (Triticum aestivum L.) crop by managing irrigation and nitrogen fertilizer under a semi-arid environment 半干旱环境下小麦(Triticum aestivum L.)作物生长性能的灌溉和氮肥管理
IF 1.9 4区 环境科学与生态学 Q2 Environmental Science Pub Date : 2023-06-23 DOI: 10.2166/aqua.2023.032
Anshuman Gunawat, D. Sharma, Aditya Sharma, S. K. Dubey
Understanding the linkage between crop yields, irrigation frequencies, and fertilizer rates is crucial in region-specific agriculture practices. The present study was conducted to assess the effect of nitrogen fertilizer rates and irrigation frequency on wheat crop growth and yield in the semi-arid region of Rajasthan, India. Twelve treatments with four replicas, combining four nitrogen fertilizers quantities (0, 50, 100, and 125% of recommended dose) with three irrigation intervals (15, 21, and 25 days after sowing) were used for three consecutive years (2014–15, 2015–16, and 2016–17). Crop responses were recorded for different growth stages (stem elongation stage, heading stage, and milking stage). The results showed that the high irrigation frequency and high fertilizer application significantly increased crop growth and yields. Yields observed in the first year of the experiment were higher than those in the second and third years in most treatments. One-way analysis of variance and Fisher's least significant difference pairwise multiple comparison tests were applied to determine significant changes in yield. The results showed that water and fertilizer are the key factors that can affect wheat yield in the semi-arid region of Rajasthan and should be managed according to soil and irrigation availability.
了解作物产量、灌溉频率和施肥量之间的联系对于区域特定农业实践至关重要。本研究旨在评估氮肥用量和灌溉频率对印度拉贾斯坦邦半干旱区小麦作物生长和产量的影响。12个处理,4个重复,施用4种氮肥量(0、50、100、125%推荐用量),3个灌溉间隔(播后15、21、25 d),连续3年(2014-15、2015-16、2016-17)。记录作物在不同生育期(茎伸长期、抽穗期和挤奶期)的响应。结果表明,高灌溉频率和高施肥量显著提高了作物生长和产量。大多数处理在试验第一年的产量高于第二年和第三年的产量。采用单因素方差分析和Fisher最小显著差异两两多重比较检验确定产量的显著变化。结果表明,水肥是影响拉贾斯坦邦半干旱区小麦产量的关键因素,应根据土壤和灌溉有效性进行管理。
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引用次数: 0
Adaptive operation of a reservoir in climate change condition: a case study of Maroon Dam in Iran 气候变化条件下水库的适应性运行——以伊朗Maroon大坝为例
IF 1.9 4区 环境科学与生态学 Q2 Environmental Science Pub Date : 2023-06-22 DOI: 10.2166/aqua.2023.065
Mostafa Mirmehdi, M. Shourian, A. Sharafati
The purpose of this research is to investigate the climate change impacts in Maroon Basin, Iran. To investigate the impacts of climate change on rainfall, temperature, and inflow in Maroon Dam, a simulation of four general circulation models (GCMs) was done in three future periods 2021–2040, 2041–2060, and 2061–2080. The results showed that the projected increased temperature would significantly reduce the runoff in the basin, despite the projected increase in rainfall. The most significant decrease of the average inflow to the Maroon Dam Reservoir in the near future of the RCP4.5 and RCP8.5 scenarios in March 24 and 26.4%, the middle future in March 25.4 and 29%, and the far future in March 27 and 30.6%, respectively, is predicted. Also, the MADSIM model simulation results showed that the Maroon Dam Reservoir would face a water resources shortage in the future to provide maximum demands. The average water supply reliability in climate change scenarios showed that the maximum water supply of 85% in the period 2021–2040 and the minimum of 80.4% in 2061–2080 would occur in the RCP4.5 and RCP8.5 scenarios, respectively.
本研究的目的是探讨气候变化对伊朗Maroon盆地的影响。为研究气候变化对Maroon Dam未来3个时期(2021-2040、2041-2060和2061-2080)的降雨、温度和入流的影响,对4种大气环流模式(GCMs)进行了模拟。结果表明,尽管预测降雨量增加,但预测温度升高会显著减少流域径流量。预测RCP4.5和RCP8.5情景近期平均入库量降幅最大,分别为3月24日和26.4%、3月25.4日和29%、3月27日和30.6%。同时,MADSIM模型模拟结果表明,未来褐红色大坝水库将面临水资源短缺,以提供最大需求。气候变化情景的平均供水可靠性表明,在RCP4.5和RCP8.5情景中,2021-2040年的供水量最大为85%,2061-2080年的供水量最小为80.4%。
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引用次数: 0
On the effect of green nonstructural materials on scour reduction downstream of grid dissipators 绿色非结构材料对栅格散热器下游减冲的影响
IF 1.9 4区 环境科学与生态学 Q2 Environmental Science Pub Date : 2023-06-21 DOI: 10.2166/aqua.2023.108
R. Daneshfaraz, M. Rezaie, E. Aminvash, Veli Süme, J. Abraham, A. Ghaderi
In this study, a nonstructural and eco-friendly solution has been used to reduce scouring downstream of screens. Upstream of the screen are stilling basins protected against scouring, but downstream locations are subjected to flow scouring. One of the challenges that the current research brings with it is the process of dispersing nanomaterials. In this research, to achieve its goals, three beds of channels with sedimentary materials, sedimentary materials plus clay, as well as sedimentary materials with a combination of clay and montmorillonite nanoclay have been used. The experimental results show the positive effect of clay and nanoclay on scour depth reduction downstream of the screens. The best performance occurs with the clay and montmorillonite clay mixture. The positive effect of clay and montmorillonite nanoclay mixture for scour length reduction is observed, and by utilizing this mixture, the length of scouring has decreased 33%. Furthermore, by adding clay and montmorillonite nanoclay mixture, the scour depth is reduced up to 39 and 46%, respectively. Utilizing clay and montmorillonite nanoclay mixture has a positive effect on scouring control. It could be very useful for cases such as rivers where bed protection with concrete is not possible.
在这项研究中,采用了一种非结构性和环保的解决方案来减少筛网下游的冲刷。筛网的上游是防止冲刷的静水池,但下游的位置受到水流冲刷。目前的研究带来的挑战之一是分散纳米材料的过程。为了实现这一目标,本研究采用了沉积材料、沉积材料加粘土、沉积材料加粘土和粘土与蒙脱土纳米粘土混合的三种通道层。实验结果表明,粘土和纳米粘土对筛网下游的冲刷深度降低有积极作用。粘土与蒙脱土混合后的性能最好。粘土与蒙脱土纳米粘土混合对减冲长度有积极的影响,使用该混合料,减冲长度可减少33%。此外,添加粘土和蒙脱土纳米粘土混合料后,其冲刷深度分别降低了39%和46%。粘土与蒙脱土纳米粘土混合使用对控制冲蚀具有积极的效果。对于无法用混凝土保护河床的河流等情况,它可能非常有用。
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引用次数: 0
Efficacy of solar water disinfection treatment system in improving rural and peri-urban household drinking water quality and reducing waterborne diarrhoeal diseases 太阳能水消毒处理系统在改善农村和城郊家庭饮用水质量和减少水传播腹泻疾病方面的效果
IF 1.9 4区 环境科学与生态学 Q2 Environmental Science Pub Date : 2023-06-20 DOI: 10.2166/aqua.2023.086
Dickson Baxter Phiri, Jean Pierre Bavumiragira, Hailong Yin
Consumption of untreated microbiologically contaminated water, prevalent in many developing countries, exposes the vulnerable population to inordinate health risks including most life-threatening diarrhoeal diseases like cholera and other illnesses. In response, innovative techniques for treating water at the household level, known as household water treatment (HWT), have emerged as practical and cost-effective solutions. Solar water disinfection (SODIS) has gained recognition as one such method that utilizes sunlight to inactivate harmful micro-organisms in water. This review examines the effectiveness of SODIS as an HWT technique by analysing scientifically robust evidence documenting its microbiological efficacy and the positive health gains among SODIS users. It explores the challenges and limitations that impact its inactivation efficiency and sustainability. Its novelty lies in its expanded exploration of the available strategies and techniques for enhancing the effectiveness of SODIS to address its associated limitations and challenges. By providing a comprehensive analysis of the scientific evidence, this review presents compelling reasons for the implementation and scalability of SODIS in the developing world. This novel perspective contributes to the existing literature on improving access to safe drinking water in underserved communities, offering valuable insights into the advancement of SODIS as a practical and sustainable HWT solution.
在许多发展中国家普遍饮用未经处理的受微生物污染的水,使脆弱人口面临过度的健康风险,包括霍乱和其他疾病等大多数危及生命的腹泻疾病。因此,在家庭一级处理水的创新技术,即家庭水处理(HWT),已成为实用和具有成本效益的解决办法。太阳能水消毒(SODIS)是利用阳光灭活水中有害微生物的一种方法,已得到认可。这篇综述通过分析科学可靠的证据来检验SODIS作为一种HWT技术的有效性,这些证据记录了SODIS的微生物功效和SODIS使用者的积极健康收益。它探讨了影响其失活效率和可持续性的挑战和限制。它的新颖之处在于它扩大了对现有战略和技术的探索,以提高SODIS的有效性,以解决其相关的限制和挑战。通过对科学证据的全面分析,本综述提出了在发展中国家实施SODIS和可扩展性的令人信服的理由。这一新颖的观点有助于改善服务不足社区获得安全饮用水的现有文献,为推进SODIS作为实用和可持续的HWT解决方案提供了宝贵的见解。
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引用次数: 0
Withdrawn: Numerical calculation of sediment transport capacity of land flow on slopes: method investigation and improvement 撤回:坡面流输沙能力的数值计算:方法研究与改进
4区 环境科学与生态学 Q2 Environmental Science Pub Date : 2023-06-15 DOI: 10.2166/aqua.2023.004
Yan Li, Weijun Yuan, Kuandi Zhang, ZiYan Li
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引用次数: 0
Application of system dynamics model for reservoir performance under future climatic scenarios in Gelevard Dam, Iran 伊朗Gelevard大坝未来气候情景下水库动态系统动力学模型的应用
IF 1.9 4区 环境科学与生态学 Q2 Environmental Science Pub Date : 2023-06-14 DOI: 10.2166/aqua.2023.193
A. Babolhakami, M. A. Gholami Sefidkouhi, A. Emadi
This study aimed to investigate the effects of climate change scenarios on five indicators: reliability, vulnerability, resilience, sustainability, and the deficiency of the Gelevard Dam (GD) in Iran. Downscaling was performed from 2020 to 2040 in the future using the Can Ems2-GCM based on different climate scenarios and employing the support vector machines. The IHACRES model was used to simulate the inflow of GD. The cultivation pattern optimization function was performed by utilizing the LINGO software. Similarly, the flow-storage model was created using Vensim software. The results demonstrated the reduction of inflow by 15, 36, and 37% during RCP2.6, RCP4.5, and RCP8.5 scenarios, respectively. The results showed that if the optimal cultivation pattern (OCP) were to be applied, during different climatic scenarios, water supply would not be difficult in the next 11, 5, and 4 years, respectively, yet after that, water shortage would gradually appear. The findings concluded that although the implementation of OCP would improve the five indicators in all water consumption sectors, the GD reservoir would not be able to answer the demands in the future. Therefore, it would be necessary to implement practices to increase water productivity in all sectors.
本研究旨在探讨气候变化情景对伊朗Gelevard大坝(GD)可靠性、脆弱性、恢复力、可持续性和缺乏性五个指标的影响。利用Can Ems2-GCM基于不同气候情景,采用支持向量机对未来2020 - 2040年的尺度进行了降尺度处理。采用ihaacres模型对GD的流入进行了模拟。利用LINGO软件对栽培模式进行优化。同样,利用Vensim软件创建了流库模型。结果表明,在RCP2.6、RCP4.5和RCP8.5情景下,流入分别减少了15%、36%和37%。结果表明:在不同气候情景下,采用最优栽培模式(OCP),分别在未来11年、5年和4年供水困难,但之后将逐渐出现缺水现象。结果表明,虽然实施OCP将改善所有用水部门的五项指标,但广东省水库将无法满足未来的需求。因此,有必要在所有部门实施提高水生产力的做法。
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引用次数: 0
Suitable sites for groundwater development: a capture map-based approach integrated with weighted overlay analysis 地下水开发的合适地点:基于捕获地图的方法与加权叠加分析相结合
IF 1.9 4区 环境科学与生态学 Q2 Environmental Science Pub Date : 2023-06-13 DOI: 10.2166/aqua.2023.011
M. Bajpai, S. Gaur, Ranveer Kumar, A. Ohri, H. Piégay
A novel methodology for suitable site selection for groundwater development based on river capture, pumping cost, and groundwater potential has been proposed for better groundwater utilisation. River capture and cost map have been generated from a calibrated groundwater model, simulated with forecasted hydrological time series data. The groundwater potential has been calculated with weighted overlay analysis. These three variables have been used to classify the model domain into five zones of groundwater development by K-Means clustering. The area with lower river capture, low cost of pumping, and high groundwater potential is found to be the best location for groundwater extraction. The methodology has been applied to the lower Ain River basin, in France.
为了更好地利用地下水,提出了一种基于河流捕获、抽水成本和地下水潜力的地下水开发合适选址的新方法。河流捕获和成本图是由校准的地下水模型生成的,用预测的水文时间序列数据进行模拟。采用加权叠加法计算了地下水潜力。利用这三个变量,通过K-Means聚类将模型域划分为地下水发育的5个区。河流捕获量低、抽水成本低、地下水潜力大的地区是地下水开采的最佳地点。该方法已应用于法国的艾因河下游流域。
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引用次数: 0
Water, sanitation, and hygiene practices among rural households and related health impacts: a case study from some North Indian villages 农村家庭中的水、环境卫生和个人卫生习惯及其相关的健康影响:来自印度北部一些村庄的案例研究
IF 1.9 4区 环境科学与生态学 Q2 Environmental Science Pub Date : 2023-06-01 DOI: 10.2166/aqua.2023.199
A. Malan, Meenakshi Suhag, P. Gupta, H. R. Sharma
The present study was carried out to assess the water availability, hygiene practices, and sanitary conditions in the households of open defecation-free (ODF) villages after achieving ODF status. Monitoring was conducted from 360 households of 9 ODF villages from 3 blocks of the Kurukshetra district of north India, using a questionnaire. The results interpreted that 78.33% of the surveyed population were using water supplied from government borewells and 65.55% of respondents agreed that their water is safe for drinking as they did not have any water-related diseases. Many respondents (57.2%) replied that someone in their family had suffered from waterborne disease in the preceding year. About 42.8% of households were treating their drinking water at the house level through methods like boiling, chlorination, and reverse osmosis systems. 90.8% of respondents said that they have access to a functional latrine facility. However, 5% population responded that they still prefer fields for open defecation (OD). Logistic regression results showed that the presence of garbage or litter and stagnant water near the household were associated with an increased risk of disease occurrence among the households. The findings suggested that people should maintain good sanitation and hygiene in their household surroundings to avoid health problems.
本研究旨在评估无露天排便(ODF)村家庭在达到无露天排便状态后的供水、卫生习惯和卫生条件。对印度北部Kurukshetra地区3个街区的9个ODF村的360个家庭进行了监测,使用了问卷调查。调查结果显示,78.33%的受访者使用政府提供的水井供水,65.55%的受访者认为他们的水是安全的,因为他们没有任何与水有关的疾病。许多受访者(57.2%)表示,他们的家人在过去一年曾患水媒疾病。大约42.8%的家庭通过煮沸、氯化和反渗透系统等方法在家庭层面处理饮用水。90.8%的答复者表示,他们可以使用功能性的厕所设施。然而,5%的人回答他们仍然喜欢露天排便(OD)。Logistic回归结果显示,家庭附近的垃圾或垃圾和死水与家庭中疾病发生的风险增加有关。研究结果表明,人们应该保持良好的家庭环境卫生,以避免健康问题。
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引用次数: 0
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