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Progress in Superhydrophobic Structure Optimisation and Performance Enhancement: A Review 超疏水结构优化与性能提升研究进展
Pub Date : 2023-08-22 DOI: 10.2174/2666145417666230822113640
Dao-long Yang, J. Tang, B. Xing, Haichao Duan, Zijie Li
Superhydrophobic surfaces have broad application prospects in several fields due to their excellent hydrophobic properties, but the traditional methods of manufacturing superhydrophobic surfaces are time-consuming and laborious, the surface wear resistance is poor, and the chemical reagents contain toxic substances, making it difficult to promote the use of superhydrophobicity inexpensively.To solve the problems of high cost, instability, and poor mechanical properties of superhydrophobic structures, we explore the preparation methods of superhydrophobic surface structures to improve the surface superhydrophobicity and reduce manufacturing and usage costs.This paper provides an overview of the literature on preparing superhydrophobic structures and improving superhydrophobic properties. Based on the summary of the research results of other scholars, this paper focuses on the preparation of superhydrophobic surfaces by carbine-co-polymerization covalent grafting chemical reactions and the improvement of superhydrophobic properties by durable opaque coatings with vacuum-deposited layers.These two methods are simple to operate and circumvent the problem of oxidative degradation of compounds in the natural environment to produce environmental pollutants. The method I produces a low surface energy stratified micro-nano composite structure on the fiber surface of the fabric by carbon copolymerization covalent grafting reaction. The method II prepares a durable opaque coating with a vacuum-deposited layer, particularly useful on mechanical components or for any other applications not requiring an optically clear coating.This paper provides an important basis for optimizing the preparation process of superhydrophobic structures, synthesizing and developing environmentally friendly superhydrophobic materials, extending the service life of superhydrophobic materials, and provides specific guidance for improving the superhydrophobic properties and durability and enhancing the combination of superhydrophobic surfaces with additional functions.
超疏水表面由于具有优异的疏水性能,在多个领域具有广阔的应用前景,但传统的制造超疏水表面的方法耗时费力,表面耐磨性差,化学试剂中含有有毒物质,难以廉价地推广使用。为了解决超疏水结构成本高、不稳定、力学性能差的问题,我们探索了超疏水表面结构的制备方法,以提高表面的超疏水性,降低制造和使用成本。本文综述了制备超疏水结构和改善超疏水性能的相关文献。本文在总结其他学者研究成果的基础上,重点研究了碳共聚合共价接枝化学反应制备超疏水表面,以及真空沉积层的耐用不透明涂层对超疏水性能的改善。这两种方法操作简单,规避了化合物在自然环境中氧化降解产生环境污染物的问题。方法一通过碳共聚共价接枝反应在织物的纤维表面产生低表面能分层微纳复合结构。该方法II制备了具有真空沉积层的耐用不透明涂层,特别适用于机械部件或任何其他不需要光学透明涂层的应用。本文为优化超疏水结构的制备工艺、合成和开发环保型超疏水材料、延长超疏水材料的使用寿命提供了重要依据,并为提高超疏水性能和耐久性、增强超疏水表面与附加功能的结合提供了具体指导。
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引用次数: 0
A Densification prediction Model of Selective Laser Melting Based on BP Neural Network 基于BP神经网络的选择性激光熔化致密化预测模型
Pub Date : 2023-08-21 DOI: 10.2174/2666145417666230821153025
L. Pan, Bin Qian, Yaqin Wang, Xinyu Liu, Huarui Jiang, Liang Wang
During the process of Selective Laser Melting (SLM), there is a complex nonlinear relationship between forming quality (Densification, elongation, and mechanical properties) and laser process parameters, and improper laser process parameters will directly lead to forming defects, including holes, cracks and even printing failure.Forming quality is limited by a series of factors, such as raw material properties, equipment properties, laser process parameters, and the post-treatment process, etc.In this paper, the feasibility test and density data test (laser power 130-280 w, laser scanning speed 1200-1500 mm/s, laser scanning distance 0.01 mm, and thickness 0.03 mm) were carried out by experiments. And the mathematical model of the Zl205A densification prediction curve and the densification distribution cloud plot were obtained.The BP neural network prediction system for ZL205A by SLM was developed with the help of the BP neural network toolbox. The prediction system was applied to ZL205A densification prediction with an error of less than 5%.
在选择性激光熔化(SLM)过程中,成形质量(致密化、伸长率、力学性能)与激光工艺参数之间存在复杂的非线性关系,不当的激光工艺参数将直接导致成形缺陷,包括孔洞、裂纹甚至打印失效。成形质量受原材料性能、设备性能、激光工艺参数、后处理工艺等一系列因素的限制。本文通过实验进行了可行性试验和密度数据试验(激光功率130 ~ 280w,激光扫描速度1200 ~ 1500mm /s,激光扫描距离0.01 mm,厚度0.03 mm)。得到了Zl205A致密化预测曲线的数学模型和致密化分布云图。利用BP神经网络工具箱,开发了基于SLM的ZL205A BP神经网络预测系统。将该预测系统应用于ZL205A致密化预测,误差小于5%。
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引用次数: 0
In-situ gelling platform for Ocular Drug delivery system: A new Paradigm 眼内给药系统的原位胶凝平台:一种新模式
Pub Date : 2023-08-21 DOI: 10.2174/2666145417666230821151753
M. Alam, Sumbul Shadab, P. Sharma, D. Paliwal
One of the most promising novel drug delivery systems is an in-situ gel, which uses a unique 'Sol to Gel' conversion to help with the slow and steady release of pharmaceuticals. An in-situ gel system enters the body as a solution but transforms into a gel once it encounters the body's internal environment. Traditional methods of ocular drug delivery, such as suspensions, eye drops, and ointments, have a number of drawbacks. These include lacrimation, obscured vision, and, most importantly, rapid precorneal clearance. As a result, many innovative methods have been created in order to address these shortcomings. In-situ gel, minidisc, ocusert, nanosuspension, collagen shield, nanoparticulate, system, niosomes, ocular iontophoresis, liposome, ocular film, dendrimers, and other methods are among them. Ocular medication delivery systems have come a long way recently, and one of the most recent innovations is in-situ ocular gel. The polymers (natural, semisynthetic, or synthetic) that make up the in-situ ocular gel system's delivery vehicle have the unique feature of a sol-gel transition when subjected to the effect of a biological stimulus, such as a change in temperature, pH, or ions. Physical appearance, clarity, pH, gelling ability, isotonicity evaluation, sterility, viscosity, In vitro drug release, and irritancy tests are all investigated in in-situ ocular gels.
一种最有前途的新型药物输送系统是原位凝胶,它使用独特的“溶胶到凝胶”转换来帮助缓慢而稳定地释放药物。原位凝胶系统作为溶液进入人体,但一旦遇到人体内部环境就会转化为凝胶。传统的眼部药物输送方法,如悬浮液、滴眼液和软膏,有许多缺点。这些症状包括流泪、视力模糊,最重要的是,快速的角膜前清除。因此,人们创造了许多创新的方法来解决这些缺点。原位凝胶法、微型凝胶法、微孔凝胶法、纳米悬浮液法、胶原蛋白屏蔽法、纳米颗粒法、系统法、纳米小体法、眼离子导入法、脂质体法、眼膜法、树突大分子法等。眼部药物输送系统最近取得了长足的进步,其中最新的创新之一是原位眼凝胶。聚合物(天然的、半合成的或合成的)构成了原位眼凝胶系统的递送载体,当受到生物刺激的影响时,如温度、pH值或离子的变化,它们具有溶胶-凝胶转变的独特特征。物理外观,透明度,pH值,胶凝能力,等渗性评价,无菌性,粘度,体外药物释放和刺激性测试都在原位眼凝胶中进行了研究。
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引用次数: 0
A Novel Composite Material (Agave sisalana), Sisal Fiber as a Reinforced natural fiber for Sustainable and Durable Concrete 一种新型复合材料(龙舌兰),剑麻纤维作为一种增强天然纤维用于可持续和耐用混凝土
Pub Date : 2023-08-21 DOI: 10.2174/2666145417666230821162612
Mohd. Gulfam Pathan, A. Shende, A. Kadam, Rashmi G. Bade, Ram Krishna Mishra, A. Mendhe, Farhan Khan, Abdul Ghaffar Noor Mohammed, Mohammad Irshad Ansari
Conventional reinforced concrete mixes are used for building projects worldwide because they are strong and last longer. Due to its versatility with different admixtures and compositions, the conventional concrete mix has always been a research area. Researchers are investigating the compatibility of conventional concrete with natural fibers to inexpensively attain maximum strength in concrete, as conventional concrete adds strength by adding fibers.In this research, the durability test, acid and alkaline attack test, and wetting and drying test are performed to evaluate the concrete mix.The mix design for M25, M35, and M50 grade concrete with and without sisal fiber is completed in this work. Overall, findings from several analyses suggest that sisal fiber concrete outperforms conventional concrete in terms of strength and durability. According to the study, sisal fiber concrete can be used instead of conventional concrete to achieve superior outcomes and sustainability.In this research novel, composite material sisal fibre is with traditional concrete, and its strength is determined for different parameters required for any civil construction work.
传统的钢筋混凝土混合物用于世界各地的建筑工程,因为它们坚固耐用。由于其具有多种外加剂和成分,传统混凝土配合比一直是一个研究领域。研究人员正在研究传统混凝土与天然纤维的相容性,以低成本获得混凝土的最大强度,因为传统混凝土通过添加纤维来增加强度。本研究通过耐久性试验、酸碱侵蚀试验和干湿试验对混凝土配合比进行了评价。完成了添加和不添加剑麻纤维的M25、M35、M50级混凝土的配合比设计。总体而言,几项分析的结果表明,剑麻纤维混凝土在强度和耐久性方面优于传统混凝土。研究表明,剑麻纤维混凝土可以代替传统混凝土,取得更好的效果和可持续性。在本研究中,剑麻纤维复合材料与传统混凝土混合,其强度是根据任何土建工程所需的不同参数来确定的。
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引用次数: 0
Electric Discharge Machining of Titanium Alloy under Cu Mixed Dielectric Medium 铜混合介质下钛合金的电火花加工
Pub Date : 2023-08-16 DOI: 10.2174/2666145417666230816091446
T. Prakash, V. P. PradeepPradeep, T. Suresh, S. James Raja
In the current research work, an attempt has been made to machine Ti6Al4V using Powder Mixed Electric Discharge Machining (PMEDM) technique.The experiments were designed utilizing central composite response surface methodology by varying current, pulse on time, gap distance, and powder concentration at five different levels, whereas Material Removal Rate (MRR), Tool Wear Rate (TWR), and Surface Roughness (Ra) were documented as responses. The MRR reduced with an increase in powder concentration until the concentration reached 7.5g/l because incorporated particles observed the major proportion of heat, and at 10g/l, MRR increased due to the bridging effect.The TWR and Ra reduced with an escalation in powder concentration due to expansion in the spark gap, facilitating the flushing of machined debris. The surface topography revealed cracks, pits, globules, and craters. Moreover, with the addition of particles, surface quality improved owing to the elimination of re-melted layers.The parameters were optimized using the Grey Relational Analysis (GRA), and the combination of 2.5g/l powder concentration, 20A current, 50µs ton, and 4mm gap distance offers the best machining performance.
在目前的研究工作中,尝试采用粉末混合电火花加工(PMEDM)技术加工Ti6Al4V。实验采用中心复合响应面方法,通过改变电流、脉冲时间、间隙距离和粉末浓度在五个不同水平上进行设计,同时记录材料去除率(MRR)、工具磨损率(TWR)和表面粗糙度(Ra)作为响应。随着粉末浓度的增加,MRR降低,直到浓度达到7.5g/l时,由于掺入颗粒观察到热量的主要比例,MRR在10g/l时由于桥接效应而增加。随着粉末浓度的增加,由于火花间隙的扩大,TWR和Ra降低,有利于加工碎屑的冲洗。表面形貌显示出裂缝、凹坑、球体和环形山。此外,随着颗粒的加入,由于消除了重熔层,表面质量得到改善。通过灰色关联分析(GRA)对参数进行优化,得到2.5g/l粉末浓度、20A电流、50µs吨、4mm间隙距离的组合加工性能最佳。
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引用次数: 0
Optimization of synthesis of microbial bio-surfactant sophorolipids using response surface methodology 响应面法优化微生物表面活性剂皂荚脂的合成
Pub Date : 2023-08-04 DOI: 10.2174/2666145417666230804094412
Subhalaxmi Pradhan, C. Madankar, Priti K. Borde, Ninad V. Mhatre
Synthetic surfactants, when released into the environment, do not degrade completely and show harmful effects. To minimize the damage to the environment and to introduce milder surfactants, it was necessary to introduce bio-surfactants.Optimization of the yield is performed by using a design expert model. The analysis of the product was carried out by using different techniques. The formulation of the personal care product was prepared by using the sophorolipid produced.Different compositions of raw materials are used, suggested by Design expert software to optimize the yield of the sophorolipid. Fermentation was performed by the shake flask method at specified conditions in the incubator shaker for the synthesis. The extraction and separation of the sophorolipid were done by the solvent extraction method.The predicted product yield value is close to the actual value of the product obtained, which indicates the model is accurate to use. The effect of the raw materials on the yield can be studied with the design expert model. The product is analyzed for its composition and properties with different analysis methods.Mathematical modelling is very helpful in predicting the optimum reaction condition and improving the yield of a particular bio-process. The RSM model of design expert software can be further utilized to carry out the in-detail study of the various factors and their effect on optimizing the yield. The sophorolipid can be used in different formulations as a greener and safe alternative to a chemical-based surfactant.
合成的表面活性剂在释放到环境中时,不能完全降解,表现出有害的影响。为了尽量减少对环境的破坏和引入温和的表面活性剂,有必要引入生物表面活性剂。利用设计专家模型对成品率进行优化。采用不同的技术对产物进行了分析。利用所产皂荚脂制备了该个人护理产品的配方。根据Design专家软件的建议,采用不同的原料组成来优化皂荚脂的收率。采用摇瓶法在特定条件下在合成的培养摇床中进行发酵。采用溶剂萃取法对槐树脂进行提取和分离。预测的产品良率值与实际得到的产品良率值接近,表明该模型使用准确。利用设计专家模型可以研究原料对成品率的影响。用不同的分析方法对产物的组成和性能进行了分析。数学建模对预测最佳反应条件和提高特定生物工艺的产率有很大的帮助。进一步利用设计专家软件的RSM模型,对影响成品率优化的各因素及其影响进行详细研究。槐脂可以作为一种更环保、更安全的化学表面活性剂,用于不同的配方中。
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引用次数: 0
Rheology assessment of mortar materials for additive manufacturing 增材制造砂浆材料流变学评价
Pub Date : 2023-08-01 DOI: 10.2174/2666145417666230801093723
Ana Pedrosa, Florindo Gaspar
This review article discusses the relevant rheological tests to evaluate the properties of compositions applied to the 3D printing of concrete (3DCP). These materials must rapidly develop rigidity and resistance, avoiding the collapse of the printed structure, with suitable buildability and other state properties, such as extrudability. A good balance must be maintained between properties and rheological parameters, such as yield stress and viscosity. Cohesion, Young's modulus, and thixotropy are also among the parameters used in these evaluations. The rheological tests addressed are the rheometer, direct shear test, uniaxial unconfined compression test, and penetration test. Their limitations must be taken into account to obtain accurate values of the rheological parameters. It was found that the most used test is the rheometer, and the test that needs to be further studied is the penetration test. Hence, it is recommended to search for a more expeditious method related to the rheological assessment to facilitate obtaining the associated parameters in a simple way.
本文综述了用于混凝土3D打印(3DCP)的组合物性能评价的相关流变学试验。这些材料必须迅速发展刚性和阻力,避免印刷结构的崩溃,具有适当的可建造性和其他状态属性,如可挤压性。必须在性能和流变参数(如屈服应力和粘度)之间保持良好的平衡。黏聚力、杨氏模量和触变性也是这些评价中使用的参数之一。流变试验包括流变仪试验、直接剪切试验、单轴无侧限压缩试验和渗透试验。为了获得准确的流变参数值,必须考虑到它们的局限性。研究发现,目前使用最多的试验是流变仪试验,需要进一步研究的试验是渗透试验。因此,建议寻找一种与流变评估相关的更快速的方法,以便以简单的方式获得相关参数。
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引用次数: 0
Alumina Crucibles from Free Dispersant Suspensions: A Useful Labware to form Advanced Powders for Radiation Dosimetry 氧化铝坩埚从自由分散剂悬浮液:一个有用的实验室工具,形成先进的粉末辐射剂量测定
Pub Date : 2023-07-26 DOI: 10.2174/2666145417666230726153437
Santos Sc, Martins As, Araujo Tl, Rodrigues Jr O, Campos Ll
Powder technology provides conditions to control particle-particle interactions that drive the formation of final-component/material, which also includes the crystalline structure, microstructure and features. Alumina (Al2O3) is the most studied ceramic based material due to its useful properties, disposal, competitive price, and wide technological applicability. This work aims to produce alumina crucibles with controlled size and shape from free dispensant suspensions. These crucibles will be used as containers for the synthesis of new materials for radiation dosimetry.The Al2O3 powders were characterized by XRD, SEM, PCS, and EPR. The stability of alumina particles in an aqueous solvent was evaluated by zeta potential determination as a function of pH. Alumina suspensions with 30vol% were shaped by slip casting in plaster molds, followed by sintering at 1600oC for 2h in an air atmosphere. Alumina based crucibles were characterized by SEM and XRD.ɑ-Al2O3 powders exhibited a mean particle diameter size (d50) of 983nm. Besides, the stability of particles in aqueous solvent was achieved at a range of pH from 2.0-6.0, and from 8.5-11.0. EPR spectra revealed two resonance peaks P1 and P2, with g-values of 2.0004 and 2.0022, respectively. The as-sintered ɑ-alumina based crucibles presented uniform shape and controlled size with no apparent defects. In addition, the final microstructure driven by solid-state sintering revealed a dense surface and uniform distribution of grains.The ɑ-Al2O3 crucibles obtained by slip casting of free dispensant alumina suspensions, followed by sintering, exhibited mechanical strength, and controlled shape and size. These crucibles will be useful labwares for the synthesis of new materials for radiation dosimetry.
粉末技术为控制驱动最终组件/材料形成的颗粒-颗粒相互作用提供了条件,其中还包括晶体结构,微观结构和特征。氧化铝(Al2O3)是目前研究最多的陶瓷基材料,因为它具有实用的性能、可处置性、具有竞争力的价格和广泛的技术适用性。这项工作的目的是生产氧化铝坩埚控制大小和形状的自由分配悬浮液。这些坩埚将用作容器,用于合成用于辐射剂量测定的新材料。采用XRD、SEM、PCS、EPR等手段对制备的Al2O3粉体进行了表征。氧化铝颗粒在水溶液中的稳定性通过zeta电位测定作为ph的函数来评估。氧化铝悬浮液的体积为30vol%,通过在石膏模中滑动铸造成型,然后在1600℃的空气气氛中烧结2h。采用SEM和XRD对氧化铝基坩埚进行了表征。α -Al2O3粉末的平均粒径(d50)为983nm。在pH值为2.0 ~ 6.0和8.5 ~ 11.0的水溶液中,颗粒具有较好的稳定性。EPR谱显示两个共振峰P1和P2, g值分别为2.0004和2.0022。烧结后的氧化铝坩埚形状均匀,尺寸可控,无明显缺陷。此外,在固态烧结的驱动下,最终的微观组织呈现出致密的表面和均匀的晶粒分布。由游离氧化铝悬浮液进行滑铸,再进行烧结,得到了具有机械强度、形状和尺寸可控的α -Al2O3坩埚。这些坩埚将成为合成辐射剂量学新材料的有用实验室。
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引用次数: 0
Biological applications of ore materials: Chili absorption of natural Mg and Zn ions released from modified serpentinite powders 矿石材料的生物应用:辣椒吸收改性蛇纹石粉末释放的天然镁和锌离子
Pub Date : 2023-07-21 DOI: 10.2174/2666145417666230721115902
F. Hung
This study investigated the characteristics of the powder, the concentration of the ions, and the growth characteristics of Chili that were irrigated with the natural magnesium–zinc ionised water. The findings revealed that the ion dissolution rate was higher for greater water temperatures.Extended sintering of the zinc-modified natural serpentinite powder at 400°C reduced the number of dissolved magnesium ions and increased the number of dissolved zinc ions. The Chili planting experiment was performed with two groups: 1) Chili irrigated with natural magnesium–zinc ionised water (natural magnesium–zinc Chili) and 2) Chili irrigated with distilled water (distilled-water Chili).The natural magnesium–zinc Chilis were discovered to have higher concentrations of magnesium and zinc ions in various parts. Furthermore, during the later stages of growth, the natural magnesium–zinc Chili had a larger body and did not easily turn yellow, resulting in better freshness. This study used modified serpentine powder to cultivate natural magnesium–zinc Chili. Appropriate powder roasting conditions and the rates of magnesium and zinc dissolution were established, and the growth characteristics of natural magnesium–zinc Chili were determined.The Chilis can help humans ensure healthy lives and promote well-being for all at all ages by sufficient zinc and magnesium intake.
研究了用天然镁锌离子水灌溉辣椒粉的特性、离子浓度和辣椒的生长特性。研究结果表明,温度越高,离子溶解速度越快。锌改性天然蛇纹石粉体在400℃下延长烧结,镁离子的溶解量减少,锌离子的溶解量增加。辣椒种植试验分为两组:1)天然镁锌离子水灌溉辣椒(天然镁锌辣椒)和2)蒸馏水灌溉辣椒(蒸馏水辣椒)。天然镁锌辣椒在不同部位的镁和锌离子浓度较高。此外,在生长后期,天然镁锌辣椒体较大,不易变黄,新鲜度较好。采用改性蛇纹石粉栽培天然镁锌辣椒。确定了适宜的粉末焙烧条件和镁锌的溶出速率,测定了天然镁锌辣椒的生长特性。辣椒可以帮助人类确保健康的生活,并通过摄入足够的锌和镁来促进所有年龄段的人的福祉。
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引用次数: 0
Packaging Materials Design and Developing Trend 包装材料设计与发展趋势
Pub Date : 2023-07-21 DOI: 10.2174/2666145417666230721120925
Xiaojing Zheng
Packaging materials design is related to economic and social development. At the same time, it also reflects human aesthetic and emotional expression. With the continuous maturity of consumer psychology, people have a new understanding of packaging design, and the past packaging materials design concepts can no longer meet the various needs of customers. As is known, packaging plays a very important role in promoting products to customers. Therefore, attractive packaging materials design is essential. In this work, the developing history of packing materials design was reviewed in detail. Both the advantages and disadvantages of the packing materials were discussed. Packaging materials experienced the process from paper, plastic, and metal to composite materials. The functions of packaging materials have gone from single to comprehensive. Driven by the commercialization of fierce competition, although humans have made great achievements in packaging material design, there is still greater room for development in packaging material design to meet the needs of future society. For a long time from now to the future, the balance between practicality and aesthetics will still be the basic principle of material packaging design. In addition, the human experience, such as the friction coefficient of packaging materials, has begun to be considered. The artistic combination of materials, shapes, colors, and characters combined with artificial intelligence has gradually become the frontier of packaging material design. By learning from nature, it can be concluded that smart packaging, eco-friendly and sustainable development in packaging materials design combining practicality and aesthetics are the developing trend for the future.
包装材料设计关系到经济和社会的发展。同时,它也反映了人类的审美和情感表达。随着消费心理的不断成熟,人们对包装设计有了新的认识,过去的包装材料设计理念已经不能满足顾客的各种需求。众所周知,包装在向顾客推销产品方面起着非常重要的作用。因此,有吸引力的包装材料设计是必不可少的。本文详细回顾了包装材料设计的发展历史。讨论了各种包装材料的优缺点。包装材料经历了从纸、塑料、金属到复合材料的过程。包装材料的功能已经从单一走向全面。在激烈竞争的商业化的驱动下,虽然人类在包装材料设计方面取得了巨大的成就,但包装材料设计仍有更大的发展空间,以满足未来社会的需要。从现在到未来很长一段时间内,实用与美观的平衡仍将是材料包装设计的基本原则。此外,人类的经验,如包装材料的摩擦系数,已经开始被考虑。材料、形状、色彩、文字与人工智能相结合的艺术组合逐渐成为包装材料设计的前沿。通过对自然的学习,我们可以得出结论,包装材料设计中结合实用性和美观性的智能包装、环保和可持续发展是未来的发展趋势。
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引用次数: 0
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