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Acoustic, FTIR and Raman spectroscopic studies of aspartame and citric acid 阿斯巴甜和柠檬酸的声学、FTIR和拉曼光谱研究
Pub Date : 2023-05-17 DOI: 10.2174/2666145416666230517104328
Benazir Banu K M, Shubhashree N S, P. George
To study the molecular interactions between artificial sweetener and edible acid Ultrasonics, Material Science To determine the molecular interactions between artificial sweetener and edible acids using acoustical parameters Acoustical parameters, spectroscopy and stability constant The molecular interactions and functional groups that are present is found As the concentration increases, acoustical parameters like ultrasonic velocity, viscosity, density, Relaxation time, acoustic impedance while, other acoustical parameters like adiabatic compressibility and intermolecular free length decreases with the increases with concentration. This proves that there is a strong interaction between solute and solvent. Spectroscopy Experimental Study
研究人工甜味剂与食用酸之间的分子相互作用用声学参数确定人工甜味剂与食用酸之间的分子相互作用用声学参数、光谱和稳定常数发现分子相互作用和存在的官能团随着浓度的增加,超声速度、粘度、密度、弛豫时间、声阻抗等声学参数其他声学参数如绝热压缩率和分子间自由长度随浓度的增加而减小。这证明溶质和溶剂之间有很强的相互作用。光谱实验研究
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引用次数: 0
Tuning green-to-red ratio of Ho3+ Activated YPO4 dual-mode luminescence through Yb3+ sensitized nano phosphors 通过Yb3+敏化纳米荧光粉调节Ho3+激活的YPO4双模发光的绿红比
Pub Date : 2023-05-17 DOI: 10.2174/2666145416666230517152942
V. N. K. Putta, Sirisha Bandi, Girija Venkateswara Koneru, Phani Raja Kanuparthy
Yb3+/Ho3+co-doped YPO4 nano phosphors were synthesized by polyol route, which has both up-conversion (UC) and down-conversion (DC) characteristics and excellent luminescent properties. DC peaks were seen at ~460, ~550, and ~650 nm.Switching at ~750 with 300 nm excitation, a very faint P-O charge-transfer (CT) band of the Ho3+ ion and a minute non-radiative resonant energy transfer were observed. We found that YPO4: Yb3+/Ho3+ is an up-converting (UC ) nano phosphor capable of large-scale generation and enhancement of luminescence with green and red emissions.RESULT: Under strong laser irradiation at 980 nm, the up-conversion emission spectrum shows obvious peaks expected for Ho3+ ions at ~550 and ~650 nm. This process produces high-quality nanocrystalline materials with sizes in the range of tens of nm. Considering the results obtained under excitation at 300nm, YPO4:Yb3+/Ho3+ yielded high quantum yield valuesThis finding can be used to manufacture high-efficiency phosphors and demonstrates that the nano-phosphor materials covered by this method have a wide range of applications.
采用多元醇法合成了Yb3+/Ho3+共掺杂的YPO4纳米荧光粉,该荧光粉具有上转换(UC)和下转换(DC)特性,具有优异的发光性能。在~460、~550和~650 nm处可见直流峰。在~750和300 nm激发下切换,观察到Ho3+离子的P-O电荷转移(CT)带非常微弱,并观察到一分钟的非辐射共振能量转移。我们发现YPO4: Yb3+/Ho3+是一种上转换(UC)纳米荧光粉,能够大规模产生并增强绿色和红色发光。结果:在980 nm强激光照射下,Ho3+离子在~550和~650 nm处出现明显的上转换发射峰。该工艺生产出尺寸在几十纳米范围内的高质量纳米晶体材料。考虑到在300nm激发下获得的结果,YPO4:Yb3+/Ho3+获得了高量子产额值,这一发现可用于制造高效荧光粉,表明该方法所覆盖的纳米荧光粉材料具有广泛的应用前景。
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引用次数: 0
Mechanical characterization of Curaua fiber/Babool wood particle reinforced polyester hybrid composite Curaua纤维/Babool木颗粒增强聚酯杂化复合材料的力学性能
Pub Date : 2023-05-15 DOI: 10.2174/2666145416666230515113945
A. Jose, R. Suthan, A. Rao, P. Aurtherson, K. Ajan, D. S. Jenaris
The researchers are in the situation to satisfy the demand for engineering materials by developing novel eco-friendly materials. The natural fiber composites are the substitutes for the synthetic material.The mechanical properties of curaua fiber-reinforced polyester (CFRP) composites were investigated, as well as the effects of curaua fibre infusion with Babool Wood particles (BWP).The composite specimens were fabricated using a hand lay-up approach using varying amounts of curaua fibres (CF) and babool wood particles in a 1:1 ratio in order to test the tensile strength and flexural strength.The results demonstrated that before weakening, the tensile strength and flexural strength of the composite samples rose by up to 40% for hybrid reinforcements. Comparing samples made of pure resin to those made of the composite at 40 weight percent (CF20/BWP20), the tensile and bending strengths of the composite are improved by 93.42% and 86.4%, respectively.The tensile and flexural modulus values of the hybrid composites increased by up to 50% fiber, but less successfully (CF25 and BWP25). The fracture mechanism of the shattered composite samples was examined using scanning electron microscopy.
研究人员通过开发新型环保材料来满足工程材料的需求。天然纤维复合材料是合成材料的替代品。研究了库拉瓦纤维增强聚酯(CFRP)复合材料的力学性能,以及库拉瓦纤维与巴布尔木颗粒(BWP)的复合性能。为了测试拉伸强度和弯曲强度,复合材料样品采用手铺法,使用不同数量的curaua纤维(CF)和babool木颗粒以1:1的比例制作。结果表明:在弱化前,复合材料试样的抗拉强度和抗弯强度均提高了40%以上;与重量为40% (CF20/BWP20)的复合材料相比,纯树脂制备的复合材料的拉伸强度和弯曲强度分别提高了93.42%和86.4%。混合复合材料的拉伸和弯曲模量值增加了50%,但不太成功(CF25和BWP25)。利用扫描电镜对破碎后的复合材料试样的断裂机理进行了研究。
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引用次数: 0
Theoretical investigation of NH3 and NO2 affinity towards Boron-Nitride Nanosheet: A DFT Study NH3和NO2对氮化硼纳米片亲和力的理论研究:DFT研究
Pub Date : 2023-05-12 DOI: 10.2174/2666145416666230512115255
Zaheer Abbas, Shahzad Khan
Two-dimensional (2D) nanosheets have been widely explored for sensing toxic gases by investigating structural and electronic properties. However, the optical investigation could be an alternative approach to address the sensing capability of the nanosheets. In the present work, the electronic and optical investigation is performed using density functional theory (DFT) to find out the sensitivity of boron-nitride nanosheet (BNNS) towards NH3 and NO2 gas molecules. Electronic investigation suggests a weak binding of NH3 and NO2 with the 2D sheet, with appreciable changes in the BNNS electronic density of state (DOS) on NO2 interaction. NH3 interaction could not affect the BNNS DOS except for lowering of band dispersion graph across the Fermi level. NO2 interaction brings a noticeable change in spectra, primarily red-shift. Based on this information, tuning is also observed in different optical descriptors, i.e., dielectric constant, refractive index, and extinction coefficient of NO2 interacted BNNS. All these findings advocate sensitivity toward the gas molecule of the 2D sheet could be realized from the optical frame.Finding NH3 and NO2 affinity of Boron-Nitride Nanosheet Through Optical Spectrum: A DFT Study.The calculations are performed in the framework of density functional theory (DFT) using Troullier Martins’s norm-conserving pseudo-potential.The NO2 interacted BNNS shows the optical spectra get red-shifted, and the primary reason is the available NO2 molecular state below the fermi level as shown in PDOS analysis.The present investigation predicted an almost similar ε2 spectra pattern of BNNS and NH3-BNNS except in shallow region 7eV-10eV; a weak absorption band appeared in this region after NH3 absorption. The main concern for this deviation is the electronic transitions taken from the valance N-p-state of NH3 to the conduction band (primarily π* in nature) of BNNS.
二维(2D)纳米片通过研究结构和电子特性被广泛用于检测有毒气体。然而,光学研究可能是解决纳米片传感能力的另一种方法。本文利用密度泛函理论(DFT)对氮化硼纳米片(BNNS)对NH3和NO2气体分子的敏感性进行了电子和光学研究。电子研究表明,NH3和NO2与二维薄片的结合较弱,NO2相互作用时BNNS的电子态密度(DOS)有明显变化。NH3相互作用除了降低了整个费米能级的色散图外,对BNNS DOS没有影响。NO2相互作用引起光谱的明显变化,主要是红移。在此基础上,还观察到NO2相互作用的BNNS的介电常数、折射率和消光系数等不同光学描述符的调谐。这些发现表明,在光学框架上可以实现对二维薄片气体分子的灵敏度。利用DFT光谱研究氮化硼纳米片的NH3和NO2亲和力。计算是在密度泛函理论(DFT)的框架下使用Troullier Martins的范数守恒伪势进行的。NO2相互作用的BNNS光谱发生了红移,PDOS分析表明,这主要是由于NO2在费米能级以下的可用分子态。本研究预测BNNS与NH3-BNNS的ε2谱图除7eV-10eV浅层外基本相似;NH3吸收后,该区域出现弱吸收带。对这种偏差的主要关注是从NH3的n -p价态到BNNS的传导带(本质上主要是π*)的电子跃迁。
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引用次数: 0
Finite Element Analysis of Reinforced Concrete Beams Strengthened with Hybrid Fiber Reinforced Polymer Systems Using ANSYS 基于ANSYS的混杂纤维增强聚合物体系加固钢筋混凝土梁有限元分析
Pub Date : 2023-05-04 DOI: 10.2174/2666145416666230504143055
Pannirselvam N, Kalyani Gurram
Existing reinforced concrete (RC) structures can deteriorate over time due to aging, poor construction design, natural disasters, etc. In recent years, fiber-reinforced polymer (FRP) composite materials are becoming a preferred choice for concrete construction repair due to their durability, high strength, and corrosion resistance. This study aimed to study and analyze the properties of the constituent materials to identify any weaknesses and potential improvements.The present study investigated the effectiveness of flexural strengthening of RC beams using a hybrid grouping of glass-FRP (GFRP) and carbon-FRP (CFRP) unidirectional laminates. ANSYS finite element analysis (FE) software was used to investigate the failure modes of the beams and the stress-strain parameters. The impact of adopting two different grades of reinforcing bars in RC beam modeling was also contrasted in the study.Comparisons between the finite element analysis and experimental literature results were made. Based on the test findings, it could be concluded that retrofitted beams perform better than non-retrofitted beams. According to experimental results, the HY14 sheet enhanced beam had a 188.46% higher ultimate load than the unenhanced beams. Comparing experimental findings to the conclusions of the numerical analysis, a maximum difference of ultimate load and deflection at mid-span of 3.40% and 4.91%, respectively, were used to assess the accuracy of the results.
现有的钢筋混凝土(RC)结构会因老化、结构设计不良、自然灾害等原因而随着时间的推移而恶化。近年来,纤维增强聚合物(FRP)复合材料因其耐久性、高强度和耐腐蚀性而成为混凝土施工修复的首选材料。本研究旨在研究和分析组成材料的性质,以找出任何弱点和潜在的改进。本研究调查了使用玻璃-玻璃钢(GFRP)和碳-玻璃钢(CFRP)单向层压板混合分组的RC梁抗弯加固的有效性。采用ANSYS有限元分析软件对梁的破坏模式和应力-应变参数进行了研究。研究还对比了采用两种不同等级钢筋对钢筋混凝土梁模型的影响。将有限元分析结果与实验文献结果进行了比较。根据试验结果,可以得出结论,改造梁的性能优于未改造梁。实验结果表明,HY14板增强梁的极限荷载比未增强梁高188.46%。将试验结果与数值分析结果进行比较,以极限荷载和跨中挠度最大差值分别为3.40%和4.91%来评价计算结果的准确性。
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引用次数: 0
Electric Discharge Machining of AA7075/SiCP/B4CP Hybrid Composites machined with Al2O3 Mixed Used Engine Oil Dielectric fluid Al2O3混合旧机油介质液电火花加工AA7075/SiCP/B4CP复合材料
Pub Date : 2023-05-04 DOI: 10.2174/2666145416666230504155532
B. B. Nayak, S. S. Bhat, Anand Kumar Gummadi, A. Latha, R. Ganesan, Marowah H. Jehad, H. A. Almashhadani, S. Sahu
Machining hybrid composites through conventional machining technique was a challenging task as it produces excessive tool wear and exhibits poor surface roughness. In this research work, an attempt was made to electric discharge machining of AA7075/SiCP/B4CP Hybrid Composites produced through the stir casting route.The used engine oil was as the dielectric fluid with the objective of obtaining wealth from waste. The experiments were performed by varying distinct Electric Discharge Machining (EDM) process parameters with the goal of obtaining a high Material Removal Rate (MRR), low Tool Wear Rate (TWR) and least Surface Roughness (Ra). The experimental runs were optimized using the Technique for Order of Preference by Similarity to Ideal Solution (TOPSIS) optimization techniques.Experimental runs were designed using the L20 Taguchi orthogonal array in which Powder concentration, Current and Pulse on time were varied for three different levels, and two various dielectric fluids were used for investigation. The characteristics of the Used Engine Oil (UEO) were assessed to find its feasibility as a dielectric fluid.In comparison to EDM oil, the specimen machined in UEO dielectric medium has a somewhat greater MRR. Regardless of the kind of dielectric fluid employed, adding Al2O3 particles increases the MRR because of the bridging effect. Due to its high thermal conductivity, UEO oil produced electrodes with a TWR that was greater than that of EDM oil. The TWR decreases with the addition of Al2O3 particles due to an increase in the spark gap. In comparison to EDM oil, the specimen machined under UEO displays a lower Ra value. Ra decreases with the inclusion of Al2O3 particles due to the thorough flushing of machining waste.The specimen machined under Al2O3 mixed UEO dielectric medium, with the process parameters tuned at 3A current and 20µs Ton, offers better machining performance and was recommended for EDM sector.
由于复合材料的刀具磨损大,表面粗糙度差,采用传统加工技术加工复合材料是一项具有挑战性的任务。本研究对搅拌铸造工艺生产的AA7075/SiCP/B4CP复合材料进行了电火花加工的尝试。以废机油为介质,从废物中获取财富。实验通过改变不同的电火花加工(EDM)工艺参数进行,目标是获得高材料去除率(MRR),低刀具磨损率(TWR)和最小表面粗糙度(Ra)。采用理想解相似偏好排序优化技术(TOPSIS)优化实验运行。采用L20田口正交阵列设计了三种不同水平下的粉末浓度、电流和脉冲时间变化实验,并采用两种不同的介电流体进行了研究。对二手发动机油(UEO)的特性进行了评价,以确定其作为介电流体的可行性。与电火花加工油相比,在UEO介质中加工的样品具有更大的MRR。无论采用何种介电流体,由于桥接效应,添加Al2O3颗粒都会增加MRR。由于其高导热性,UEO油产生的电极的TWR大于EDM油。随着Al2O3颗粒的加入,由于火花间隙的增加,TWR降低。与电火花加工油相比,UEO下加工的样品显示出更低的Ra值。由于加工废料的彻底冲洗,随着Al2O3颗粒的加入,Ra降低。在Al2O3混合UEO介质下加工的样品,在3A电流和20µs Ton下调整工艺参数,具有更好的加工性能,推荐用于电火花加工领域。
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引用次数: 0
Hydrogenation Influences The Created Giant Dielectric Behaviors Of (Bi+W) Codoped Anatase Tio2 加氢对(Bi+W)共掺杂锐钛矿Tio2巨介电行为的影响
Pub Date : 2023-04-28 DOI: 10.2174/2666145416666230428155602
A. Dakhe
TiO2 nanoparticles ceramic (NPs) codoped with Bi and W ions have been synthesized by a hydrothermal technique. A portion of the prepared ceramic was post-hydrogenated. Ceramic NPs were characterized by traditional methods. Crystalline structures and optical properties were investigated using X-Ray diffraction (XRD) and diffuse reflection spectroscopy, respectively. The present work has focused on the creation of a colossal (giant) dielectric permittivity (GP) behavior with the TiO2 host NCs through the Bi/W codoping to construct electronic core/shell structures. In addition, the influence of post-hydrogenation on the created GP was also examined. It was found a high permittivity of 3.69×104 at 1 kHz, which was reduced to 3.29×104 by the hydrogenation of the sample. This is attributed to the densification of the itinerant electrons by the effect of the catalytic power of the doping W5+ ions to dissociate the adsorbed H2. The present values of GP are much higher than the permittivity of the pure TiO2 and the Bi-doped TiO2 ceramic, which was attributed to the construction of core/shell electronics structures. As a result, the doping process has been studied in detail in relation to scientific expectations.
采用水热法制备了铋、钨离子共掺杂的TiO2纳米陶瓷。部分制备的陶瓷被后氢化。采用传统方法对陶瓷NPs进行表征。利用x射线衍射仪(XRD)和漫反射光谱法分别对晶体结构和光学性质进行了研究。目前的工作重点是通过Bi/W共掺杂来构建电子核/壳结构,从而在TiO2宿主nc上产生巨大的介电介电常数(GP)行为。此外,还考察了后加氢对合成GP的影响。在1 kHz时介电常数为3.69×104,经样品加氢后介电常数降为3.29×104。这是由于掺杂的W5+离子对吸附的H2解离的催化能力的影响,使流动电子致密化。GP的现值远高于纯TiO2和双掺杂TiO2陶瓷的介电常数,这是由于构建了核/壳电子结构。因此,兴奋剂的过程已经被详细地研究与科学的期望有关。
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引用次数: 0
On Powder Bed Fusion Manufactured Parts: Porosity and its Measurement 粉末床熔合制件:孔隙率及其测量
Pub Date : 2023-04-27 DOI: 10.2174/2666145416666230427093421
L. Pagnotta, C. Morano
Powder Bed Fusion (PBF) is one of the earliest, most versatile, and popular AM processes, being well-suited for a great variety of materials. As in many other manufacturing processes, porosity is a phenomenon inevitably present in parts made by PBF. The quantity, shape, and distribution of pores, and the propensity to their formation depend strongly upon the type of process and on the processing conditions used to produce the part. It is well known that porosity influences in a dramatic way the quality and reliability of the manufactured materials and, therefore, it deserves special attention.In this paper, porosity and the more appropriate experimental techniques for detecting and measuring porosity are reviewed. Moreover, a comparison among the results obtained by applying different methodologies to measure the porosity of parts produced by Powder Bed Fusion is reported. The final purpose of the work is to provide the reader with the tools for the correct choice of the most suitable method for measuring the porosity of additively manufactured pieces.
粉末床融合(PBF)是最早、最通用、最流行的增材制造工艺之一,非常适合各种材料。在许多其他制造过程中,多孔性是PBF制造的零件不可避免地存在的现象。气孔的数量、形状和分布及其形成的倾向很大程度上取决于加工的类型和用于生产零件的加工条件。众所周知,孔隙率对制造材料的质量和可靠性有很大的影响,因此值得特别注意。本文综述了孔隙度的概念,以及检测和测量孔隙度的实验技术。此外,本文还报道了采用不同方法测量粉末床熔合生产的零件的孔隙率所得到的结果之间的比较。这项工作的最终目的是为读者提供正确选择最合适的方法来测量增材制造件的孔隙率的工具。
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引用次数: 3
Biomaterials in medical applications 医学应用中的生物材料
Pub Date : 2023-04-20 DOI: 10.2174/2666145416666230420094148
Virender Kumar, Sonia yadav, Sruthy Varghese, Reena Devi, D. Kumar, N. Khatri, G. Singh
Biomaterials, a fascinating and highly interdisciplinary field, have become integral to improving modern man's conditions and quality of life. It is done by many health-related problems arising from many sources. The first batch of biomaterials was produced as implants and medical equipment in the 1960s and 1970s. Biomaterials are primarily used in medicine and may be directly or indirectly exposed to biological systems. For instance, we could use them in cultures and mediums for cell development, plasma protein testing, biomolecular processing cultures, diagnostic gene chips, and packaging materials primarily for medical items. Biomaterials should have certain qualities for human-related problems, like being non-carcinogenic, not being pyrogenic or toxic, completely plasma compatible, and anti-inflammatory. This paper introduces the history, classification, and ideal parameters of biomaterials and where they are used in the current scenarios in the medical field, providing a brief outlook on the future.
生物材料是一个迷人的、高度跨学科的领域,已经成为改善现代人的条件和生活质量的组成部分。它是由许多来源引起的许多与健康有关的问题造成的。第一批生物材料是在20世纪60年代和70年代作为植入物和医疗设备生产的。生物材料主要用于医学,可直接或间接暴露于生物系统。例如,我们可以将它们用于细胞发育、血浆蛋白测试、生物分子处理培养、诊断基因芯片和主要用于医疗物品的包装材料的培养和培养基中。生物材料应具有与人类有关的某些品质,如无致癌性、无热原性或毒性、完全血浆相容和抗炎。本文介绍了生物材料的历史、分类、理想参数及其在当前医疗领域的应用,并对未来进行了简要展望。
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引用次数: 0
A Convolution Neural Network-Based Approach for Metal Surface Roughness Evaluation 基于卷积神经网络的金属表面粗糙度评价方法
Pub Date : 2023-04-20 DOI: 10.2174/2666145416666230420093435
Yanhui Liu, Zengren Pan, Zhiwei Li, Qiwen Xun, Ying Wu
Metal surface roughness detection is an essential step of quality control in the metal processing industry. Due to the high manual involvement and poor efficiency of traditional roughness testing, rapid automated vision detection has received increasing attention in product quality control. Many methods have focused on extracting features related to roughness from images by means of mathematical statistics. However, these methods often rely on extensive experiments and complex calculations, while being sensitive to external environmental disturbances.Metal surface roughness detection is an essential step of quality control in the metal processing industry. Due to the high manual involvement and poor efficiency of traditional roughness testing, the rapid automated vision detection has received increasing attention in product quality control. Many methods have focused on extracting features related to roughness from images by means of mathematical statistics. However, these methods often rely on extensive experiments and complex calculations, while being sensitive to external environmental disturbances.In this paper, a convolution neural network-based approach for metal surface roughness evaluation has been proposed. The convolutional neural network was initialized using a transfer learning strategy, and the data augmentation technique was applied to the benchmark dataset for sample expansion.To evaluate this approach, samples of 4 types of roughness classes were prepared. The samples were divided into a training set, validation set, and test set in the ratio of 7:2:1. The accuracy of the neural network on the test set was found to be above 86%.In this paper, we propose a convolution neural network-based approach for metal surface roughness evaluation. We applied migration learning to initialize the convolutional neural network and used data augmentation techniques for sample expansion on the benchmark dataset.The effectiveness of the proposed approach and its superiority over manual detection have been demonstrated in the experiments.No more
金属表面粗糙度检测是金属加工业质量控制的重要环节。由于传统粗糙度检测的人工介入程度高、效率低,快速自动化视觉检测在产品质量控制中越来越受到重视。许多方法都是利用数理统计的方法从图像中提取与粗糙度相关的特征。然而,这些方法往往依赖于大量的实验和复杂的计算,同时对外部环境的干扰很敏感。金属表面粗糙度检测是金属加工业质量控制的重要环节。传统的粗糙度检测方法由于人工介入多、效率低,在产品质量控制中越来越受到重视。许多方法都是利用数理统计的方法从图像中提取与粗糙度相关的特征。然而,这些方法往往依赖于大量的实验和复杂的计算,同时对外部环境的干扰很敏感。本文提出了一种基于卷积神经网络的金属表面粗糙度评价方法。采用迁移学习策略对卷积神经网络进行初始化,并将数据增强技术应用于基准数据集进行样本扩展。为了评估这种方法,制备了4种粗糙度等级的样品。将样本按7:2:1的比例分为训练集、验证集和测试集。神经网络在测试集上的准确率达到86%以上。本文提出了一种基于卷积神经网络的金属表面粗糙度评价方法。我们应用迁移学习来初始化卷积神经网络,并使用数据增强技术对基准数据集进行样本扩展。实验证明了该方法的有效性及其相对于人工检测的优越性。没有更多的
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引用次数: 0
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