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Deposition of diamond films on SiO/sub 2/ surface using high power microwave enhanced chemical vapor deposition process 高功率微波增强化学气相沉积法在SiO/ sub2 /表面沉积金刚石膜
Pub Date : 1996-07-07 DOI: 10.1109/IVMC.1996.601859
Jau-Sung Lee, Kuo-Shung Liu, I. Lin
Diamonds were successfully nucleated on SiO/sub 2/-coated silicon substrates using high power microwave plasma enhanced chemical vapor deposition (CVD) process. Nucleation rate on SiO/sub 2/ surface (i.e., 0.5/spl times/10/sup 10/ cm/sup -2/) is, however, still smaller than that on Si surface (i.e., 1.0/spl times/10/sup 10/ cm/sup -2/). The growth of diamonds behaved similarly on the pre-nucleated surface, regardless of the nature of the substrates. Diamonds were of single grain columnar structure with random orientation when deposited without bias and were of multigrain columnar structure with [001] preferred orientation when deposited under -100 VDC bias. Multigrain columnar structure was ascribed to the induction of secondary nucleation at the presence of bias voltage.
采用高功率微波等离子体增强化学气相沉积(CVD)技术,成功地在SiO/ sub2 /涂层硅衬底上成核了金刚石。SiO/sub -2/表面的成核速率(即0.5/spl次/10/sup 10/ cm/sup -2/)仍小于Si表面的成核速率(即1.0/spl次/10/sup 10/ cm/sup -2/)。无论衬底的性质如何,金刚石在预成核表面的生长行为都是相似的。无偏压沉积时,金刚石为单晶柱状结构,取向随机;-100 VDC偏压沉积时,金刚石为多晶柱状结构,取向[001]优先。多晶柱状结构是在偏置电压作用下诱导二次形核的结果。
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引用次数: 0
Emission characterization of diamond coated Si FEAs 金刚石包覆Si FEAs的发射特性
Pub Date : 1996-07-07 DOI: 10.1109/IVMC.1996.601824
V. Zhirnov, E. I. Givargizov, A. V. Kandidov, B. V. Seleznev, A.N. Alimova
Large-area arrays of Si tips (10/sup 3/-10/sup 6/ tips in an array) with diamond coating were tested in pulse and DC modes. The arrays demonstrated uniform emission, reproducible I-V plots and low emission threshold. The maximum current achieved with diamond coated Si arrays was 80 mA in pulse mode. Emission characteristics were found to be superior to the uncoated Si tip arrays or diamond-coated flat cathodes.
在脉冲和直流模式下测试了金刚石涂层的大面积Si尖端阵列(10/sup 3/-10/sup 6/尖端阵列)。该阵列具有均匀发射、可重现I-V图和低发射阈值等特点。在脉冲模式下,金刚石涂层硅阵列获得的最大电流为80毫安。发射特性优于未涂覆的Si尖端阵列或涂覆金刚石的平面阴极。
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引用次数: 4
Testing of fillet emitter structures with well defined emitter-to-gate spacings 具有良好定义的发射极到栅极间距的圆角发射极结构的测试
Pub Date : 1996-07-07 DOI: 10.1109/IVMC.1996.601853
D. King, J. Fleming
Vertical metal edge emitter arrays with well defined emitter-to-gate separations have been fabricated. Preliminary tests are reported on the operation of these cylindrical emitter tips. The emitter-to-gate spacing is determined by the thickness of a deposited layer which can also serve as a current limiting resistor. Current limiting resistors can also be formed by a self aligned etch of the underlying substrate. Emitters have been fabricated using either reactive ion etching or chemical mechanical polishing. The emitting material is titanium nitride. The process does not rely on high resolution photolithography and is CMOS compatible. The process technique allows the emitter tip to be placed below, even with, or above the gate structure. The emitter edges in this configuration were approximately 0.1 /spl mu/m above the gate structure. The emitter-to-gate spacing is approximately 0.1 to 0.2 /spl mu/m. The thickness of the SiO/sub 2/ insulator between the gate and substrate is approximately 0.6 /spl mu/m. Single tip structures have been fabricated as well as arrays of 100 and 10000 tips. The emitter tip-to-tip spacing in multi-tip arrays is 5 /spl mu/m.
垂直金属边缘发射极阵列具有良好定义的发射极到栅极的分离已经被制造。对这些圆柱形发射器尖端的操作进行了初步试验。发射极到栅极的间距由沉积层的厚度决定,沉积层也可以作为限流电阻。限流电阻器也可以通过对衬底的自对准蚀刻形成。用反应离子蚀刻或化学机械抛光制备了发射体。发射材料是氮化钛。该工艺不依赖于高分辨率光刻,并且与CMOS兼容。该工艺技术允许将发射极尖端放置在栅极结构的下方,甚至与栅极结构一起放置或置于栅极结构的上方。在这种结构中,发射极边缘大约在栅极结构上方0.1 /spl mu/m。发射极到栅极的间距约为0.1至0.2 /spl mu/m。栅极和衬底之间的SiO/sub /绝缘体厚度约为0.6 /spl mu/m。单尖端结构以及100和10000尖端阵列已经被制造出来。在多尖端阵列中,发射极尖端到尖端的间距为5 /spl mu/m。
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引用次数: 0
Effects of vacuum conditions on low frequency noise in silicon field emission devices 真空条件对硅场发射器件低频噪声的影响
Pub Date : 1996-07-07 DOI: 10.1109/IVMC.1996.601790
J.T. Trujlllo, A. Chakhovskoi, C. Hunt
The effects of pressure on emission current noise have been studied. Field emission currents from silicon devices were observed over a range of pressures. The current fluctuations were analyzed in both the time and frequency domain. Signal to noise ratios between 0.9 and 6.9 were observed. These values appear to be more dependent on operation time than on pressures. Spectral density coefficients of low frequency measurements range from -1.37 to -1.81. Some pressure dependence is suggested in the lower pressure ranges. At higher pressures emission currents seem to be reduced and the current is cut off completely above a threshold pressure which is somewhere in the 10's of Torr.
研究了压力对发射电流噪声的影响。在一定压力范围内观察了硅器件的场发射电流。对电流波动进行了时域和频域分析。信噪比在0.9 ~ 6.9之间。这些值似乎更多地取决于操作时间而不是压力。低频测量的谱密度系数范围为-1.37至-1.81。在较低的压力范围内,存在一定的压力依赖性。在更高的压力下,发射电流似乎减少了,电流在阈值压力以上完全切断,阈值压力在Torr的10左右。
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引用次数: 8
DC bias effect on the synthesis of [001] textured diamond films on silicon 直流偏压对硅上合成[001]织构金刚石薄膜的影响
Pub Date : 1996-07-07 DOI: 10.1109/IVMC.1996.601860
J. Lee, K. Liu, I. Lin
A diamond film consisting of almost 100% [001] grains can be synthesized at a fast rate (/spl sim/3 /spl mu/m/h) by a two-step process. First, the nuclei are formed under -160 VDC bias with 3 mol% CH/sub 4//H/sub 2/ at 900/spl deg/C substrate temperature and then the films are grown under -100 VDC bias with around 5-6 mol% CH/sub 4//H/sub 2/ at the same temperature. The nucleation of the diamond is enhanced by using bias voltage. The a- and b-axes of [001] textured diamond films grown under large bias voltage are aligned with a- and b-axes of silicon, viz. (100)/sub dia//spl par/(100)/sub Si/ and [110]/sub dia//spl par/[110]/sub Si/. The effect of bias voltage on the growth behavior of the diamond films is accounted for by the suppression of the growth of the non-[001] grains due to the electron emission under bias.
通过两步法,可以快速(/spl sim/3 /spl mu/m/h)合成几乎100%[001]晶粒组成的金刚石膜。首先,在900/spl℃的衬底温度下,在-160 VDC的偏置条件下,以3 mol% CH/sub 4//H/sub 2/形成原子核,然后在-100 VDC的偏置条件下,以5-6 mol% CH/sub 4//H/sub 2/生长薄膜。施加偏置电压可增强金刚石的成核。在大偏置电压下生长的[001]织构金刚石薄膜的a轴和b轴与硅的a轴和b轴对齐,即(100)/sub dia//spl par/(100)/sub Si/和[110]/sub dia//spl par/[110]/sub Si/。偏置电压对金刚石薄膜生长行为的影响是由于偏压下的电子发射抑制了非[001]晶粒的生长。
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引用次数: 0
Formation of thin silicide films on Ta and Nb surfaces 在Ta和Nb表面形成硅化物薄膜
Pub Date : 1996-07-07 DOI: 10.1109/IVMC.1996.601807
E. Afanas’eva, S. M. Solov'ev
The mechanism of thin silicide film growth on Nb and Ta surfaces depended on the substrate temperature. At room temperature the layer-by-layer growth of Si on Ta and Nb took place. The surface density of Si in one monolayer was 9.3.10/sup 14/ at/cm/sup 2/ on Ta and Nb. The onset of the penetration Si into Nb and Ta was observed at T>900 K. At this temperature the composition NbSi/sub 2/ and TaSi/sub 2/ were formed. At temperature T>1360 K for Ta and T>1270 K for Nb a structural phase transition occurred and silicide Ta/sub 4/Si and Nb/sub 4/Si was formed after reaching a certain critical concentration of Si in the subsurface region. Phase transition was followed by increase of the Si atoms diffusion from the surface into the bulk.
在Nb和Ta表面生长硅化物薄膜的机理与衬底温度有关。室温下,Si在Ta和Nb上逐层生长。Si在Ta和Nb上的表面密度为9.3.10/sup 14/ at/cm/sup 2/。在温度>900 K时,Si开始渗入Nb和Ta。在此温度下形成NbSi/sub - 2/和TaSi/sub - 2/组合物。当温度T>1360 K (Ta)和T>1270 K (Nb)时发生结构相变,在地下区域达到一定临界Si浓度后形成硅化物Ta/sub - 4/Si和Nb/sub - 4/Si。相变发生后,Si原子从表面向体体扩散增加。
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引用次数: 0
A novel low-voltage ballistic-electron-emission source 一种新型低压弹道电子发射源
Pub Date : 1996-07-07 DOI: 10.1109/IVMC.1996.601841
C. Hagen, G.P.E.M. van Bakel, E. Borgonjen, P. Kruit, V. Kazmiruk, V. Kudryashov
A novel tunnel junction emitter based on ballistic electron transmission through ultra-thin metal foils is proposed as an electron source. From a simple planar tunneling model and Monte-Carlo simulations, we show that either a high-brightness monochromatic electron source can be obtained or a high-current source with energy spread comparable with a field emission source. Freestanding 5 nm thick Pt films were successfully fabricated for the construction of a tunnel junction electron source, in which a UHV-STM is used as a tip-emitter positioning device.
提出了一种基于超薄金属箔弹道电子传输的新型隧道结发射极作为电子源。通过简单的平面隧穿模型和蒙特卡罗模拟,我们证明了既可以获得高亮度单色电子源,也可以获得能量分布与场发射源相当的大电流源。成功制备了5nm厚的独立Pt薄膜,用于隧道结电子源的构建,其中UHV-STM用作尖端发射极定位装置。
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引用次数: 0
Simulation of field emission and electrodynamic characteristics for triode nearcathode modulators with edge field emitter arrays 边缘场发射极阵列三极管近阴极调制器场发射及电动力学特性模拟
Pub Date : 1996-07-07 DOI: 10.1109/IVMC.1996.601781
Y. Zakharchenko, N. I. Sinitsyn, Y. Gulyaev
On the base of the theory of conformal transformations of complex functions developed was a method to rigorously solve the electrostatic problem for two-dimensional diode and triode systems having edge arrays whose faces are formed by a periodic nanodimensional array of field emitting centers. The method proposed is used to simulate the emission and electrodynamic characteristics of near-cathode MW triode-like modulators.
在复函数保形变换理论的基础上,提出了一种严格求解二维二极管和三极管系统静电问题的方法,该系统的边缘阵列是由周期性纳米级场发射中心阵列构成的。利用该方法模拟了近阴极毫瓦类三极管调制器的发射特性和电动力学特性。
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引用次数: 0
Current bunching in static field and novel input stage for microwave devices based on spindt type cathodes 基于spindt型阴极的静态场电流聚束及微波器件新型输入级
Pub Date : 1996-07-07 DOI: 10.1109/IVMC.1996.601905
A. V. Galdetskiy
Analytical one-dimensional theory is developed, describing field emission modulation and electron bunching in static and small RF fields. It takes exactly in account the influence of the static field and space charge and is valid for various current sources, providing unidirectional electron motion. On this base a new type of input stage for klystrode-type devices is considered which consists of an FEA triode with finite transit angle. The effective gain of this modulator is an order of magnitude greater than the gain of a conventional modulator.
建立了一维解析理论,描述了静态和小射频场中的场发射调制和电子聚束。它充分考虑了静电场和空间电荷的影响,对各种电流源都有效,提供了单向的电子运动。在此基础上,提出了一种由有限过运角的FEA三极管组成的新型速调管输入级。该调制器的有效增益比传统调制器的增益大一个数量级。
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引用次数: 2
Energy spectrum of field emission 场发射能谱
Pub Date : 1996-07-07 DOI: 10.1109/IVMC.1996.601777
B. B. Rodnevich
Energy spectra of field emission were studied for various shapes of microroughness, i.e. a semiellipsoid, a cylinder with a semisphere on the top, a frustrum of cone with a semisphere on the top, a cone with an acute angle, etc., and also for various values of the nondimensional parameter M: M=/spl phi//sub 0//E/sub 0//spl middot/a, where a is the height of a microroughness.
研究了不同形状微粗糙度的场发射能谱,如半椭球体、顶部有半球的圆柱体、顶部有半球的圆锥、锐角圆锥等,以及无量纲参数M的不同取值:M=/spl φ //sub 0//E/sub 0//spl中点/a,其中a为微粗糙度的高度。
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引用次数: 1
期刊
9th International Vacuum Microelectronics Conference
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