Iron and manganese are national strategic mineral resources. Given China's urgent demand for them, fundamental research and cutting-edge technologies for ferromanganese ores are highly important. This aims to enable efficient separation and utilization of iron and manganese, while cutting resource consumption in ferromanganese ore processing. Current challenges for efficient ferromanganese ore utilization include high energy consumption, heavy reliance on chemical reducing agents, and significant pollutant emissions from traditional magnetic roasting. This study proposes a novel microwave fluidization magnetization roasting method using biomass as reducer, selecting Siberian larch biomass as the reducing medium by coupling microwave heating with a fluidized reaction system. Microwave fluidization roasting was performed by regulating core parameters: biomass-ore mixing ratio, roasting temperature, roasting time, and atmosphere composition. The reduced ore was then ground and subjected to weak magnetic separation to obtain iron and manganese concentrates. Results show optimal separation efficiency under: roasting time 20 min, temperature 650 °C, larch content 20 %, feed particle size 80 % -200 mesh, and gas flow rate 0.2 SL/min (25 % CO2). Characterization (XRD, XPS, TEM) confirmed iron oxides undergo directional reduction from Fe2O3 to Fe3O4, while manganese oxides complete reduction via stepwise conversion: MnO2 → Mn3O4 → MnO. High-resolution TEM showed Fe3O4 (311) crystal plane spacing at 0.252 ± 0.003 nm and MnO (200) at 0.206 ± 0.002 nm, highly consistent with standard theoretical values. Loose porous structures and continuous microcracks formed on mineral surfaces during roasting enhanced mass transfer efficiency and interfacial reaction kinetics.
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