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The effect of cavity shape on critical high-temperature regions formation pattern and structural evolution difference in explosive particle bed 空腔形状对爆炸颗粒床临界高温区形成模式和结构演化差异的影响
IF 4.5 2区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-09-23 DOI: 10.1016/j.powtec.2024.120301
The occurrence of critical high-temperature regions within explosives is a crucial factor in initiating combustion and explosion. The primary causes of hot regions in cavity-containing explosives are dissipative processes occurring inside the explosive or at its interface, such as shear, friction, viscosity, plasticity, and heat transfer. Currently, there is limited research on the generation and dissipation mechanisms of critical high-temperature regions in cavity-containing explosives during impacts, based on the mesoscale analysis that describes particle motion. In this study, a model based on the discrete element method is employed allowing for an accurate analysis of the dynamic and thermodynamic processes among particles, which systematically considers the shear history between particles, elastoplastic collisions, and heat transfer between particles. The temporal evolution of particle temperature and dissipated work contours during the impact process of explosives with different cavity shapes is analyzed. Explosives with cavities undergo three stages during the impact process: the formation of the trapezoidal high-temperature region, cavity collapse, and dispersion of the particle bed, ultimately leading to the formation of two main critical high-temperature regions: near the cavity and near the wall. The temperature rise of hot particles near the wall can be roughly divided into two stages, and the temperature rise mechanisms are different. Initially, the temperature rise is primarily attributed to plastic dissipation of hot particles, and the same initial impact velocity results in the same temperature rise. During the cavity collapsing, continuous momentum transfer occurs between the hot particles near the wall and the particles in the high-temperature shear bands, deeply influencing the development of the high-temperature shear bands through the movement of the hot particles near the cavity. Therefore, the different collapse modes of hot particles near cavities of different shapes lead to differences in the later temperature evolution of the hot particles near the wall. The unique aggregation processes of hot particles near cavities of various shapes result in distinct high-temperature region morphologies: circular cavity exhibits approximate “——” shape, triangular cavity displays arch shape, and inverted triangular cavity presents “M” shape. Significantly, a new mechanism resulting from the interaction of two opposing “jet “flows for the formation of higher-temperature hot regions near the circular cavity has been discovered.
爆炸物内出现临界高温区是引发燃烧和爆炸的关键因素。在含空腔炸药中产生高温区的主要原因是炸药内部或其界面上发生的耗散过程,如剪切、摩擦、粘度、塑性和热传导。目前,基于描述粒子运动的中尺度分析,对含空腔炸药在撞击过程中临界高温区的产生和耗散机制的研究十分有限。本研究采用了基于离散元素法的模型,可对颗粒间的动态和热力学过程进行精确分析,系统地考虑了颗粒间的剪切历史、弹塑性碰撞和颗粒间的热传递。分析了具有不同空腔形状的炸药在撞击过程中颗粒温度和耗散功轮廓的时间演变。带空腔的炸药在冲击过程中经历了三个阶段:梯形高温区的形成、空腔坍塌和颗粒床的分散,最终形成两个主要的临界高温区:空腔附近和壁附近。近壁高温粒子的温升大致可分为两个阶段,温升机理也各不相同。最初,温升主要归因于热颗粒的塑性耗散,相同的初始冲击速度会导致相同的温升。在空腔坍缩过程中,靠近壁面的热颗粒与高温剪切带中的颗粒之间发生持续的动量传递,通过空腔附近热颗粒的运动深刻影响高温剪切带的发展。因此,不同形状空腔附近热颗粒的不同塌缩模式导致了空腔壁附近热颗粒后期温度演化的差异。不同形状空腔附近热粒子的独特聚集过程导致了不同的高温区形态:圆形空腔呈现近似"--"形,三角形空腔呈现拱形,倒三角形空腔呈现 "M "形。值得注意的是,我们发现了一种新的机制,即两个对立的 "射流 "相互作用,在圆形空腔附近形成高温热区。
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引用次数: 0
Design and optimization of volute directing plate and stubble board for enhancing liquidity and anticlogging of tillering straw in spreading operation 设计并优化涡流导流板和接茬板,以提高分蘖秸秆在撒播作业中的流动性和防涝性
IF 4.5 2区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-09-21 DOI: 10.1016/j.powtec.2024.120288
In this paper, a novel volute linear directing plate and inverted “Y” structure stubble board are first designed to address the problem of straw agglomeration. Then a flexible and breakable discrete element model of tillering straw is proposed, and a discrete element coupling model of flexible tillering straw-crushing and strip-laying device is also constructed. The results show that the model can predict the operation performance of the crushing and strip-laying more accurately. Finally, the effect of spindle speed, directing plate radius and stubble board angle are investigated in-depth. In addition, the structure optimization of the directing plate and stubble board is conducted by response surface method, and the corresponding field test is also conducted. It is demonstrated that the coefficient of seed zone cleaning increased by 4.6 %, and the coefficient of straw ridge disturbance decreased by 34.6 %, meanwhile, the device performance is greatly improved after optimization.
本文针对秸秆团聚问题,首先设计了一种新型涡流直线导向板和倒 "Y "型结构接茬板。然后提出了分蘖秸秆柔性可破离散元模型,并构建了柔性分蘖秸秆粉碎铺条装置的离散元耦合模型。结果表明,该模型能较准确地预测粉碎和铺条装置的运行性能。最后,深入研究了主轴转速、导向板半径和接茬板角度的影响。此外,还采用响应面法对导向板和接茬板进行了结构优化,并进行了相应的现场试验。结果表明,优化后的播种区清选系数提高了 4.6%,秸秆脊扰动系数降低了 34.6%,装置性能大幅提高。
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引用次数: 0
Quantification of the hetero-contact formation process for a CuO/CeO2 hetero-aggregate model system prepared by double flame spray pyrolysis 量化通过双火焰喷雾热解制备的 CuO/CeO2 异质聚集模型体系的异质接触形成过程
IF 4.5 2区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-09-21 DOI: 10.1016/j.powtec.2024.120305
In hetero-aggregates, different materials form sintered hetero-contacts, which lead to new material properties. In this study, the influence of process parameters on the formation of hetero-contacts in Double Flame Spray Pyrolysis (DFSP) was quantified. The mixing of jets was monitored by Particle Image Velocimetry (PIV) measurements as well as by thermocouples and compared to the single flame setting. Overlap of the jets was evaluated using tracers to visualize the mixing zone. Ten CuO/CeO2 model material samples were prepared with different flame inclination angles, nozzle distances and different particle volume fractions. Mixing on hetero-aggregate level was quantified using Convolutional Neural Network (CNN) evaluations of STEM images, Temperature-Programmed Reduction (TPR) and Differential Centrifugal Sedimentation (DCS) disk centrifugation to determine cluster sizes and hetero-coordination numbers as mixing quantifiers. Here, good correlations between the differently measured quantifiers were observed.
在异质聚集体中,不同的材料会形成烧结异质接触,从而产生新的材料特性。本研究量化了工艺参数对双火焰喷雾热解(DFSP)中异质接触形成的影响。通过粒子图像测速仪(PIV)测量和热电偶监测了喷射流的混合情况,并与单火焰设置进行了比较。使用示踪剂对喷流的重叠进行了评估,以观察混合区。采用不同的火焰倾角、喷嘴距离和不同的颗粒体积分数制备了十种 CuO/CeO2 模型材料样品。使用卷积神经网络(CNN)评估 STEM 图像、温度编程还原(TPR)和差速离心沉降(DCS)盘式离心来确定团簇大小和异质配位数作为混合量化指标,从而量化异质团聚水平上的混合。在这里,我们观察到不同测量量化指标之间存在良好的相关性。
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引用次数: 0
CFD-based redesign of large industrial-scale cyclones 基于 CFD 的大型工业级旋风分离器的重新设计
IF 4.5 2区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-09-21 DOI: 10.1016/j.powtec.2024.120306
Cyclones represent a cost-effective solution employed for the separation of particles in gas-solid streams, wherein the enhancement of performance relies on the careful balance between pressure drop and collection efficiency. This study employs Computational Fluid Dynamics (CFD) techniques to numerically assess a large-scale first stage cyclone within a cement kiln cyclone tower. Investigating its reported low collection efficiency, we analyze the impact of geometric modifications aimed at enhancing cyclone performance. The introduction of a dipleg proves to be particularly effective, leading to a substantial increase in collection efficiency and a reduction in pressure drop. The most favorable cyclone configuration demonstrates a remarkable 6 % improvement in collection efficiency and a decrease in pressure drop of approximately 1 mbar. Consequently, particle emissions from the first-stage cyclone are reduced by approximately 30 %, while an increase in clinker production by approximately 100 tons per day is achieved. These findings showcase the potential for significant operational and environmental benefits through optimized cyclone design in cement manufacturing processes.
旋风分离器是一种用于气固流颗粒分离的经济有效的解决方案,其性能的提高取决于压力降和收集效率之间的谨慎平衡。本研究采用计算流体动力学(CFD)技术,对水泥窑旋风塔内的大型一级旋风分离器进行数值评估。针对报告中提到的收集效率低的问题,我们分析了旨在提高旋风分离器性能的几何改造的影响。事实证明,引入斜脚特别有效,可大幅提高收集效率并降低压降。最理想的旋风分离器配置显示,收集效率显著提高了 6%,压降降低了约 1 毫巴。因此,第一级旋风分离器的颗粒排放量减少了约 30%,同时熟料日产量增加了约 100 吨。这些研究结果表明,通过优化水泥生产过程中的旋风筒设计,有可能获得显著的运行和环境效益。
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引用次数: 0
Significant size change during bacterial cellulose capsule drying 细菌纤维素胶囊干燥过程中的显著尺寸变化
IF 4.5 2区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-09-20 DOI: 10.1016/j.powtec.2024.120275
Use of engineered powders, whether by manufacturers or consumers, often requires rapid hydration but is hindered if hydration rates exceed dispersion rates, leading to “fish eyes”. More work is needed to understand how powder could be engineered to actively contribute to its own dispersion while minimizing the use of additional materials and additives. A recently developed bacterial cellulose microcapsule matrix, with good mechanical integrity but minimal mass usage, exhibits remarkable deformability owing to its fibrous shell structure. When dried into powder, the cellulose microcapsules experience significant deformation of their fibrous shells, changing their diameter by orders of magnitude. We demonstrate a capsule shape recovery mechanism by coating the cellulose fibers, which damps fiber interactions. The results demonstrate that drying microfibrous cellulose microcapsules can expand the range of encapsulation modes available and greatly reduce the mass needed to provide efficient powder rehydration.
无论是制造商还是消费者在使用工程粉末时,通常都需要快速水化,但如果水化速度超过分散速度,就会造成 "鱼眼"。我们需要做更多的工作,以了解如何设计粉末,使其能够积极促进自身的分散,同时最大限度地减少额外材料和添加剂的使用。最近开发的一种细菌纤维素微胶囊基质具有良好的机械完整性,但质量用量最小,由于其纤维状外壳结构,表现出显著的可变形性。当干燥成粉末时,纤维素微胶囊的纤维壳会发生显著变形,直径会发生数量级的变化。我们展示了一种通过纤维素纤维涂层恢复胶囊形状的机制,这种涂层可以抑制纤维间的相互作用。结果表明,干燥微纤维状纤维素微胶囊可以扩大封装模式的范围,并大大减少高效粉末再水化所需的质量。
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引用次数: 0
The mechanism of nanocopper synthesis under supercritical water gasification of methanol 甲醇超临界水气化合成纳米铜的机理
IF 4.5 2区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-09-19 DOI: 10.1016/j.powtec.2024.120304
This paper studied the effect of diverse parameters (reaction time, precursor concentration and molar ratio of alkali to copper ions) on different sizes of copper particles production. In all experiments, over 99 % of Cu2+ is converted to Cu. The results show that under conditions of shorter reaction time (5 min), lower precursor concentration (0.01 M), and ideal molar ratio of alkali to copper ions ([OH]:[Cu2+] = 1), copper nanoparticles are produced with good dispersity, and an average diameter of 33.05 ± 9.34 nm. The study proposes a mechanism that involves organic adsorption on the surfaces of copper nuclei. This implies that promoting ligand adsorption on copper nuclei surfaces is key to producing smaller particles, since it limits nanoparticle growth. Furthermore, H2 and CO both contribute to the reduction of Cu2+ to Cu. H2 serves as the primary reducing agent, from the analysis of gaseous products. The study proposes a mechanism for nanocopper size control.
本文研究了不同参数(反应时间、前驱体浓度和碱与铜离子的摩尔比)对生产不同尺寸铜颗粒的影响。在所有实验中,超过 99% 的 Cu2+ 转化为铜。结果表明,在较短的反应时间(5 分钟)、较低的前体浓度(0.01 M)和理想的碱与铜离子摩尔比([OH-]: [Cu2+] = 1)条件下,生成的纳米铜粒子具有良好的分散性,平均直径为 33.05 ± 9.34 nm。该研究提出的机制涉及铜核表面的有机吸附。这意味着促进配体在铜核表面的吸附是产生更小颗粒的关键,因为它限制了纳米颗粒的生长。此外,H2 和 CO 都有助于将 Cu2+ 还原成 Cu。从气态产物的分析来看,H2 是主要的还原剂。该研究提出了一种纳米铜尺寸控制机制。
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引用次数: 0
A hierarchical linked cell method based on scale-proportional multi-level DEM grids 基于比例多级 DEM 网格的分级链接单元法
IF 4.5 2区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-09-19 DOI: 10.1016/j.powtec.2024.120296

The linked cell method is widely used in the discrete element method (DEM) to detect contact between particles because of its high efficiency for uniform particles. However, the efficiency is reduced for polydisperse particles which are common in nature and engineering applications and have a wide size range. In this paper, a hierarchical linked cell method based on scale-proportional multi-level DEM grids is developed to improve the efficiency for polydisperse particles. The performance of the hierarchical linked cell method is verified by simulating different polydisperse particles. The results show that the hierarchical linked cell method can significantly reduce the elapsed CPU time of contact detection in all simulated cases. The scale proportion and the number of levels of the DEM grids are found to be two important parameters influencing the efficiency improvement. The elapsed CPU time decreases as the scale proportion decreases or as the number of levels increases. For a given scale proportion, the optimal number of levels to achieve maximum efficiency should satisfy two conditions: (1) the grid cell granularity is less than 10; (2) the exponential decrease of the grid cell granularity with the number of levels is broken.

离散元法(DEM)中广泛使用链接单元法来检测颗粒之间的接触,因为这种方法对均匀颗粒的检测效率很高。然而,对于自然界和工程应用中常见的、尺寸范围较大的多分散颗粒,其效率就会降低。本文开发了一种基于比例多级 DEM 网格的分层链接单元法,以提高多分散颗粒的处理效率。通过模拟不同的多分散粒子,验证了分层链接单元法的性能。结果表明,在所有模拟情况下,分层链接单元法都能显著减少接触检测所耗费的 CPU 时间。DEM 网格的比例和层数是影响效率提高的两个重要参数。随着比例的减小或层数的增加,CPU 耗时也会减少。对于给定的比例,要达到最高效率的最佳层级数应满足两个条件:(1)网格单元粒度小于 10;(2)网格单元粒度随层级数的指数下降趋势被打破。
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引用次数: 0
CFD-DEM modeling for optimized liquid distribution in fluidized bed spray granulation 流化床喷雾造粒中优化液体分布的 CFD-DEM 模型
IF 4.5 2区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-09-19 DOI: 10.1016/j.powtec.2024.120299
In this work, CFD-DEM simulations of two different fluidized bed granulator geometries were performed, aiming to provide an insight into how the injected liquid behaves within the particle bed and thus an overall better understanding of the granulation process itself. Simulation results were evaluated regarding the fate of sprayed droplets, e.g. deposition on a particle, elutriation from fluidized bed, or collision with apparatus walls. For the deposited droplets, the particle–droplet collisions were tracked in order to obtain a locally resolved deposition rate. Spray parameters as well as geometric specifications of the nozzle setup were varied, investigating a broad range of different process conditions. By optimizing apparatus design, especially the air inlet, an even distribution of the liquid droplets within the fluidized bed and overall higher deposition rate can be achieved and a stable steady state with a well-defined spray zone is reached within a broad range of varied spray parameters.
在这项工作中,对两种不同的流化床造粒机几何形状进行了 CFD-DEM 模拟,旨在深入了解喷射液体在颗粒床内的表现,从而更好地理解造粒过程本身。模拟结果对喷射液滴的去向进行了评估,如沉积在颗粒上、从流化床中洗脱或与设备壁碰撞。对于沉积的液滴,对颗粒-液滴碰撞进行了跟踪,以获得局部解析的沉积率。我们改变了喷嘴设置的喷雾参数和几何规格,研究了各种不同的工艺条件。通过优化设备设计(尤其是进气口),可实现流化床内液滴的均匀分布和更高的整体沉积率,并在各种喷雾参数变化范围内达到具有明确喷射区的稳定状态。
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引用次数: 0
Experimental study on the influencing factors of particles jetting behavior in train sanding adhesion enhancement 火车打磨附着力增强过程中颗粒喷射行为影响因素的实验研究
IF 4.5 2区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-09-18 DOI: 10.1016/j.powtec.2024.120302

Sanding is the most widely used adhesion enhancing measure for trains. However, the motion of adhesion enhancement particles is vulnerable to interference from complex operating environment resulting in reduced efficiency. This work focused on the effect of sanding device parameters (sand delivery hose, air pressure and sand-blasting gun) on particles jetting behavior and particles utilization rate based on the train sanding process simulation detecting equipment. Results show that the particles utilization rate gradually improves with jetting velocity increasing and diffusion angle decreasing. Jetting velocity increases with the increase in the air pressure, nozzle diameter of sand-blasting gun and installation angle of sand delivery hose. While jetting diffusion angle decreases with the increase in the delivery hose diameter and outlet diameter of sand-blasting gun. Sanding flow rate is susceptible to the air pressure. The regression models of influencing factors on particles jetting behavior are performed for prediction and optimization.

打磨是列车最广泛使用的附着力增强措施。然而,增强附着力颗粒的运动容易受到复杂运行环境的干扰,导致效率降低。本研究基于列车打磨过程模拟检测设备,重点研究了打磨装置参数(输砂软管、气压和喷砂枪)对颗粒喷射行为和颗粒利用率的影响。结果表明,随着喷射速度的增加和扩散角的减小,颗粒利用率逐渐提高。喷射速度随空气压力、喷砂枪喷嘴直径和输砂软管安装角度的增加而增加。而喷射扩散角则随着输送软管直径和喷砂枪出口直径的增大而减小。喷砂流速易受气压影响。对颗粒喷射行为的影响因素建立回归模型,以进行预测和优化。
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引用次数: 0
Study on the separation performance of a three-product hydrocyclone with overflow reseparation 带有溢流再分离功能的三产品水力旋流器分离性能研究
IF 4.5 2区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-09-18 DOI: 10.1016/j.powtec.2024.120303

This manuscript proposes a three-product hydrocyclone with overflow reseparation to reduce the particle misplacement in overflow, which achieves secondary separation by utilizing the after-energy of internal swirling flow. Numerical simulations and physical tests were applied to investigate the separation performance. The simulation results revealed that the coarser particles entrapped were effectively recovered by sideflow, the recovery of 20 μm particles in the overflow decreased by 16.71 % ∼ 23.09 % with significant fineness improvement compared with conventional hydrocyclone. The intensity of the internal centrifugal field decreased with the overflow separation chamber expanded, which resulted in an increased probability of particle misplacement during overflow. The test results revealed that the particle content of more than 20 μm in overflow was reduced by 2.44 % compared with conventional hydrocyclone, reducing the overflow separation chamber increased the sideflow ratio and solid phase yield, increased the difference in fineness between sideflow and overflow, and improved the narrow-grain separation performance.

本手稿提出了一种具有溢流再分离功能的三产品水力旋流器,以减少溢流中的颗粒错位,通过利用内部漩涡流的余能实现二次分离。研究人员通过数值模拟和物理试验对分离性能进行了研究。模拟结果表明,侧流有效地回收了夹带的较粗颗粒,与传统水力旋流器相比,溢流中 20 μm 颗粒的回收率降低了 16.71 % ~ 23.09 %,细度显著提高。内部离心力场的强度随着溢流分离室的扩大而降低,导致溢流过程中颗粒错位的概率增加。试验结果表明,与传统水力旋流器相比,溢流中大于 20 μm 的颗粒含量减少了 2.44 %,溢流分离室的缩小提高了侧流比和固相产率,增大了侧流和溢流之间的细度差,改善了窄粒分离性能。
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引用次数: 0
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