Progress in Materials Science最新文献_第3页

Advances in structural engineering and electrochemical insights of MXene-based derivates for next generation micro-supercapacitor with tuneable ink, microelectrode design, and scalable manufacturing strategies 具有可调谐墨水、微电极设计和可扩展制造策略的下一代微型超级电容器的结构工程和电化学研究进展

IF 4 1区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY

Progress in Materials Science

Pub Date : 2025-11-10 DOI: 10.1016/j.pmatsci.2025.101599

Jyoti Prakash Das , Vempuluru Navakoteswara Rao , Sang-Jae Kim

MXenes, an exceptional class of materials that are present in all dimension forms, have garnered significant interest owing to their enormous potential in electrochemical energy storage. The article encompasses different synthesis techniques and their effect on the structure, electrical properties, and surface properties of MXenes. We highlighted the recent development in composition optimization, surface engineering, and structure design has achieved remarkable device performance with reported specific capacitance values ranging from 100 to 1000 mF/cm². The application of machine learning to surface feature optimization and MXene structure prediction is also mentioned. Furthermore, the MXene mechanistic insights by operando and in situ characterization techniques such as in situ Raman spectroscopy, synchrotron XRD, and XANS is discussed. These methods explored the structure evolution, oxidation state, and charge transport upon operation. In short, we envision the integration of MXene with advanced techniques of electrode preparation like inkjet printing, screen printing, and additive manufacturing. These methods provide high-resolution, tuneable, and scalable patterning of electrodes and hence establish possibilities for applications in microsupercapacitors. The purpose of this review is to give a holistic picture of the design approaches of MXene properties by synthesis and processing techniques, and to describe the scaling from laboratory-scale concepts to energy storage applications.

MXenes是一种特殊的材料，存在于所有维度形式中，由于其在电化学能量存储方面的巨大潜力而引起了极大的兴趣。本文介绍了不同的合成技术及其对MXenes结构、电学性能和表面性能的影响。我们强调了最近在成分优化，表面工程和结构设计方面的发展，已经取得了显着的器件性能，报道的比电容值从100到1000 mF/cm2不等。介绍了机器学习在表面特征优化和MXene结构预测中的应用。此外，还讨论了operando的有效性和原位表征技术，如原位拉曼光谱、同步加速器XRD和XANS。这些方法探索了结构演化、氧化态和运行过程中的电荷输运。简而言之，我们设想将MXene与喷墨印刷、丝网印刷和增材制造等先进电极制备技术相结合。这些方法提供了高分辨率、可调谐和可扩展的电极图案，因此为微型超级电容器的应用奠定了可能性。本文综述了MXene性能的合成和加工技术的整体设计方法，并描述了从实验室规模的概念到储能应用的扩展。

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引用次数: 0

Osmium-based materials: emerging properties for biomedical applications 锇基材料：生物医学应用的新特性

IF 4 1区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY

Progress in Materials Science

Pub Date : 2025-11-10 DOI: 10.1016/j.pmatsci.2025.101615

Shaobin He , Long Ma , Ruofei Zhang , Huanran Shen , Wei Chen , Kelong Fan

Osmium (Os), with its unique isotopic system, holds a pivotal role in unraveling the origins of the solar system and the processes of planetary formation. Although discovered in the 19th century, Os remained primarily overlooked for many years. With the advancement of scientific research, Os-based materials have emerged as players, particularly in biomedical applications, attracting growing attention for their potential in cancer therapy, bioimaging, biosensing, etc. This review explores the synthesis, characterization, properties, toxicity, and enzyme-like activity of Os-based materials, highlighting their diverse biomedical applications. Notably, the rapid evolution of nanotechnology has catalyzed the development of nanozymes—nanomaterials that mimic natural enzyme activities—ushering in the rise of Os-based nanozymes. Moving forward, future research will focus on refining the synthesis processes of Os-based materials, improving their biocompatibility, and addressing safety concerns in complex pathological environments, unlocking even more tremendous potential in biomedical applications. More significantly, Os-based materials may also play a key role in interstellar exploration, offering crucial support in catalytic reactions and life support systems.

锇（Os）以其独特的同位素系统，在揭示太阳系的起源和行星形成过程中起着关键作用。虽然在19世纪被发现，但多年来一直被忽视。随着科学研究的进步，os基材料已经崭露头角，特别是在生物医学应用中，其在癌症治疗、生物成像、生物传感等方面的潜力越来越受到关注。本文综述了锇基材料的合成、表征、性质、毒性和酶样活性，重点介绍了它们在生物医学上的广泛应用。值得注意的是，纳米技术的快速发展促进了纳米酶的发展——模仿天然酶活性的纳米材料——引领了基于os的纳米酶的兴起。展望未来，未来的研究将集中在完善os基材料的合成工艺，提高其生物相容性，解决复杂病理环境下的安全性问题，从而在生物医学应用中释放出更巨大的潜力。更重要的是，os基材料也可能在星际探索中发挥关键作用，为催化反应和生命维持系统提供关键支持。

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引用次数: 0

Tailoring interfacial chemistry of aluminum alloy anodes for high-performance aqueous aluminum-ion batteries 用于高性能铝离子电池的铝合金阳极的界面化学

IF 4 1区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY

Progress in Materials Science

Pub Date : 2025-11-09 DOI: 10.1016/j.pmatsci.2025.101611

Jieming Chen , Xue Peng , Huilin Zhang , Ling Kang , Seong Chan Jun , Yusuke Yamauchi , Shude Liu

Aqueous aluminum-ion batteries (AAIBs) hold significant promise for large-scale energy storage due to the high volumetric and gravimetric capacities of metallic aluminum, as well as its abundance and environmental benignity. However, their practical implementation is hindered by the low redox potential of aluminum, parasitic hydrogen evolution, and the formation of passivation layers at the anode–electrolyte interface. Aluminum alloys have emerged as promising anode candidates, offering enhanced corrosion resistance, reduced passivation and improved interfacial stability, enabling more reversible and stable electrochemical performance. Nevertheless, alloy anodes still face suboptimal cycling stability, primarily due to large volumetric and structural changes during charge–discharge processes, which induce mechanical degradation and exacerbate interfacial side reactions. This review presents a comprehensive overview of the interfacial chemistry of aluminum alloy anodes for AAIBs. It first outlines the fundamental energy storage mechanisms and summarizes the key issues of alloy-based anodes. Afterwards, the classification and physicochemical properties of different aluminum alloys are discussed, with emphasis on interfacial characteristics and mechanistic insights into their electrochemical behavior. Critical challenges are further analyzed, and rational design strategies are proposed to enhance performance. Finally, future directions of interfacial engineering are outlined to guide the development of aluminum alloy anodes for next-generation AAIBs.

水铝离子电池（AAIBs）由于金属铝的高体积和重量容量，以及它的丰度和环境友好性，在大规模储能方面具有重要的前景。然而，铝的低氧化还原电位、寄生析氢以及阳极-电解质界面钝化层的形成阻碍了它们的实际实施。铝合金已成为极有前途的阳极候选者，具有增强的耐腐蚀性，减少钝化和改善界面稳定性，实现更可逆和稳定的电化学性能。然而，合金阳极仍然面临着次优的循环稳定性，这主要是由于在充放电过程中体积和结构发生了很大的变化，从而导致机械降解并加剧了界面副反应。本文对aaib用铝合金阳极的界面化学进行了综述。首先概述了合金基阳极的基本储能机理，总结了合金基阳极的关键问题。然后，讨论了不同铝合金的分类和物理化学性质，重点讨论了界面特征和其电化学行为的机理。进一步分析了关键挑战，并提出了合理的设计策略以提高性能。最后，展望了界面工程的发展方向，以指导下一代aaib铝合金阳极的发展。

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引用次数: 0

Printing 3D metallic structures through reduction processes: principle, approaches, and applications 通过还原过程打印3D金属结构：原理，方法和应用

IF 4 1区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY

Progress in Materials Science

Pub Date : 2025-11-09 DOI: 10.1016/j.pmatsci.2025.101610

Guo Liang Goh , Samuel Zhuo Han Lee , Daniel Jee Seng Goh , Guo Dong Goh, Ernest Cheah, Wai Yee Yeong

3D printing holds significant promise for the fabrication of functional metal structures in various applications. This is made possible due to the unique properties of metals such as electrical conductivity, electrochemical activity, and catalytic behavior. However, existing methods are hampered by critical limitations. Traditional approaches often require high-temperature sintering and yield conductivities inferior to those of bulk metals. Similarly, existing direct writing techniques face challenges in achieving both fine feature control and high throughput, while mainstream metal 3D printing operates at resolutions too coarse for delicate electronics and metallic micro-/nanostructures. This review addresses these gaps by exploring reduction-based 3D printing strategies, where metal-containing precursors are directly transformed into conductive metals via reduction processes. By systematically examining five cutting-edge approaches, namely reactive ink printing, electroless plating of 3D printed structures, metal precursor printing followed by thermal reduction, in situ photoreduction-based laser fabrication, and electrochemical printing, this work elucidates the underlying reduction mechanisms, energetic considerations, and material behaviours that allows for the fabrication of metallic structures with either enhanced resolution, reduced thermal budget, or both. By unifying insights across these methods, the review outlines a roadmap for overcoming current limitations and advancing integration, resolution, and scalability in future applications of 3D-printed metallic materials.

3D打印在各种应用中为功能性金属结构的制造提供了巨大的希望。这是由于金属的独特性质，如导电性，电化学活性和催化行为。然而，现有的方法受到关键限制的阻碍。传统的方法通常需要高温烧结，并且屈服电导率低于大块金属。同样，现有的直接书写技术在实现精细特征控制和高吞吐量方面面临挑战，而主流金属3D打印的分辨率对于精密电子和金属微/纳米结构来说过于粗糙。本综述通过探索基于还原的3D打印策略来解决这些差距，其中含金属前体通过还原过程直接转化为导电金属。通过系统地研究五种前沿方法，即反应性油墨印刷、3D打印结构的化学镀、金属前驱体打印后的热还原、基于光还原的激光制造和电化学打印，本工作阐明了潜在的还原机制、能量考虑和材料行为，这些方法允许以提高分辨率、减少热预算或两者兼而有之的方式制造金属结构。通过统一这些方法的见解，该综述概述了克服当前限制的路线图，并在3d打印金属材料的未来应用中推进集成、分辨率和可扩展性

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引用次数: 0

Handheld electrospinning technologies: a comprehensive review 手持式静电纺丝技术综述

IF 4 1区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY

Progress in Materials Science

Pub Date : 2025-11-08 DOI: 10.1016/j.pmatsci.2025.101614

Ali Bakhshi , Mahya Bakhshi , Mojtaba Hosseine , Hedieh Sadat Shamsnia , Ali Samadi

Handheld electrospinning (HES) devices are a groundbreaking advancement over traditional electrospinning, with increased portability, operating adaptability, and on-demand nanofiber generation. In this review, the complex history of evolution, underlying principles, and system devices facilitating electrospinning are discussed in full detail, with specific emphasis given to heading towards miniaturization and user-focused HES platforms. Mechanisms of fiber formation, types of electrospinning processes, and critical parameters controlling fiber morphology, e.g., solution properties, environmental conditions, and collector geometries, are comprehensively covered. The review also presents a discussion on material selection, encapsulation techniques, and advanced surface engineering techniques to be used in the fabrication of functional nanofibers. Engineering aspects of HES apparatus design, e.g., miniaturization, power supply configurations, nozzle designs, and deposition control, are stringently discussed. Applications of HES from different disciplines, such as wound dressing, wearable electronics, rapid prototyping, and targeted biomedical and environmental applications, are addressed. Regulatory problems, market movements, and available HES products in the market are also addressed, supported by bibliometric and patent analyses that highlight the growth patterns and innovation landscape of the subject area. Preclinical and clinical studies are addressed to put translational progress into perspective, and the key problems in device operation, regulatory compliance, and commercialization are identified. Emerging new future trends, such as AI-enabled optimization, smart biomaterials, transdisciplinary integration, and eco-manufacturing, are highlighted as being essential to achieving breakthroughs in HES technologies. This review will act as a reference point for the development, implementation, and extension of HES in research and applied environments.

手持式静电纺丝（HES）设备是传统静电纺丝的突破性进步，具有更高的便携性、操作适应性和按需生产纳米纤维。在这篇综述中，详细讨论了静电纺丝复杂的发展历史、基本原理和促进静电纺丝的系统设备，并特别强调了朝着小型化和以用户为中心的HES平台的方向发展。纤维的形成机制，静电纺丝工艺的类型，以及控制纤维形态的关键参数。，解决方案的性质，环境条件和收集器的几何形状，全面覆盖。综述了功能型纳米纤维的材料选择、封装技术和先进的表面工程技术。工程方面的HES设备设计，例如，小型化，电源配置，喷嘴设计和沉积控制，严格讨论。从不同学科的应用，如伤口敷料，可穿戴电子，快速原型，有针对性的生物医学和环境应用，解决了HES。还讨论了监管问题、市场变动和市场上可用的HES产品，并通过文献计量学和专利分析提供支持，这些分析突出了主题领域的增长模式和创新前景。临床前和临床研究旨在将转化进展置于正确的角度，并确定了设备操作，法规遵从性和商业化方面的关键问题。新兴的未来趋势——如人工智能优化、智能生物材料、跨学科整合和生态制造——被强调为实现HES技术突破的关键。本综述将作为在研究和应用环境中开发、实施和扩展HES的参考点。

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引用次数: 0

Advancements in cathode materials for dual-ion batteries 双离子电池正极材料研究进展

IF 4 1区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY

Progress in Materials Science

Pub Date : 2025-11-03 DOI: 10.1016/j.pmatsci.2025.101600

Zhiqin Sun , Honglei Jiang , Pei Liu, Ting Jin, Lifang Jiao

Different from traditional batteries, dual-ion batteries (DIBs) operate via a mechanism in which both cations and anions actively participate in electrochemical reactions at their respective electrodes. This distinctive feature enables DIBs to achieve higher operating voltages, leading to greater energy output. Given that cathode materials play a pivotal role in anion storage, their performance directly determines the overall efficiency of DIBs. However, the limited specific capacity and poor interfacial stability of cathodes remain bottlenecks that hinder the advancement of DIBs. Therefore, a systematic evaluation and comprehensive overview of recent research progress are critically needed. In this review, we analyze the key challenges faced by cathode materials in DIBs and highlight strategies employed to optimize these materials for enhanced anion storage. By consolidating recent research insights, this review aims to guide the development of high-performance DIBs.

与传统电池不同的是，双离子电池（DIBs）是通过阳离子和阴离子在各自的电极上参与电化学反应的机制发挥作用的。这种独特的特性使dib能够实现更高的工作电压，从而产生更大的能量输出。由于阴极材料在阴离子存储中起着关键作用，其性能直接决定了dib的整体效率。然而，阴极有限的比容量和较差的界面稳定性仍然是阻碍dib发展的瓶颈。因此，对最近的研究进展进行系统的评价和全面的综述是必要的。在这篇综述中，我们分析了dib中阴极材料目前面临的挑战，并重点介绍了优化这些材料以增强阴离子存储的策略。通过综合这些见解，本文旨在指导高性能dib的开发。

引用次数: 0

Self-adaptive biomaterials for tissue repair: from design to application 组织修复用自适应生物材料：从设计到应用

IF 4 1区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY

Progress in Materials Science

Pub Date : 2025-10-31 DOI: 10.1016/j.pmatsci.2025.101593

Weiwei Zheng , Zeyuan Jin , Xiping Chen , Qiaoxuan Wang , Yongyuan Kang , Jieting Chang , Pai Peng , Beiduo Wang , Changyou Gao

Biomaterials that can facilitate tissue repair following injury caused by trauma, diseases and aging are highly demanded for the innovation of medicinal and pharmaceutical applications. Self-adaptive biomaterials represent a new class of functional biomaterials designed to interactively regulate the pathological tissue microenvironment post-injury to promote tissue repair in an adaptive manner. This dynamic adaptive interaction involves the biomaterials reacting to the biological cues of tissue microenvironment, which in turn influences the structure and compositions of the biomaterials, creating a feedback loop. In this review, we systematically summarize the components of the inflammatory microenvironment after tissue injury, and underscore its key characteristics and modulation principles, which are instrumental in guiding the design of self-adaptive biomaterials. Subsequently, we outline the current self-adaptive biomaterials, detailing their structures and functionalities. Furthermore, we elaborate the state-of-the-art of their biomedical applications in tissue repair. Additionally, we discuss the challenges and future perspectives of self-adaptive biomaterials in the design of therapeutic strategies and their potential for future clinical applications in tissue repair. It is anticipated that the self-adaptive biomaterials will provide valuable insights and guide the direction of biomaterial development for tissue repair applications.

生物材料可以促进创伤、疾病和衰老引起的组织损伤的修复，这是医疗和制药应用创新的高度需求。自适应生物材料是一类新型的功能生物材料，旨在通过相互作用调节损伤后病理组织微环境，以适应性方式促进组织修复。这种动态的自适应相互作用涉及到生物材料对组织微环境的生物信号的反应，这反过来影响生物材料的结构和组成，形成一个反馈回路。本文系统总结了组织损伤后炎症微环境的组成，强调了炎症微环境的主要特征和调节原理，这对指导自适应生物材料的设计具有重要意义。随后，我们概述了目前的自适应生物材料，详细介绍了它们的结构和功能。此外，我们详细介绍了最新的生物医学在组织修复中的应用。此外，我们还讨论了自适应生物材料在治疗策略设计中的挑战和未来前景，以及它们在组织修复中的未来临床应用潜力。预计自适应生物材料将为组织修复应用提供有价值的见解和指导生物材料的发展方向。

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引用次数: 0

Innovative carbon-based materials for efficient hydrogen storage: A review of solid, gaseous, and liquid systems 用于高效储氢的创新碳基材料：固体、气体和液体系统综述

IF 4 1区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY

Progress in Materials Science

Pub Date : 2025-10-31 DOI: 10.1016/j.pmatsci.2025.101596

Jieduo Guan , Chengguang Lang , Xiangdong Yao

Hydrogen (H₂) stands as a cornerstone of sustainable energy and an indispensable pathway toward achieving carbon neutrality. Yet, the advancement of the hydrogen economy is significantly impeded by challenges related to storage and transportation. Conventional storage strategies—primarily high-pressure gaseous storage—rely on expensive fiber-reinforced composite tanks that not only escalate costs but also suffer from low efficiency and notable safety concerns. This scenario underscores the critical need for hydrogen storage solutions that are safe, efficient, and economically viable. Carbon-based materials have emerged as a compelling alternative, offering robust hydrogen storage capabilities via both physical adsorption and chemical bonding. These materials promise enhanced safety and improved efficiency for hydrogen transport. This review comprehensively examines the state-of-the-art developments in hydrogen storage across three distinct categories of carbon-based materials: solid carbon materials, gaseous carbon dioxide (CO₂) hydrogen carrier, and liquid organic hydrogen carriers. Moreover, it critically evaluates the reversibility of these storage mechanisms and explores their potential for commercial application, providing insight into their role in the future of the hydrogen economy. This refined exploration aims to guide future research at the intersection of material science and energy technology, fostering innovations that may eventually overcome the current barriers in hydrogen storage and utilization.

氢（H2）是可持续能源的基石，也是实现碳中和不可或缺的途径。然而，氢经济的发展受到与储存和运输相关的挑战的严重阻碍。传统的储存策略——主要是高压气体储存——依赖于昂贵的纤维增强复合材料储罐，这不仅增加了成本，而且效率低，而且存在明显的安全问题。这种情况强调了对安全、高效、经济可行的储氢解决方案的迫切需求。碳基材料已经成为一种引人注目的替代方案，通过物理吸附和化学键结合提供强大的储氢能力。这些材料有望提高氢气运输的安全性和效率。本文全面考察了三种不同类别的碳基材料在储氢方面的最新发展：固体碳材料、气态二氧化碳（CO2）氢载体和液态有机氢载体。此外，它批判性地评估了这些储存机制的可逆性，并探索了它们的商业应用潜力，为它们在未来氢经济中的作用提供了见解。这项精细化的探索旨在指导未来材料科学和能源技术交叉领域的研究，促进创新，最终克服目前氢储存和利用方面的障碍。

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引用次数: 0

A constructive perspective on ionic self-powered pressure sensing 离子自供电压力传感的建设性观点

IF 4 1区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY

Progress in Materials Science

Pub Date : 2025-10-30 DOI: 10.1016/j.pmatsci.2025.101595

Mingfang Deng, Ziqi Ren, Jianyu Yin, Xubin Zhou, Liangxian Wang, Nishuang Liu

The growing demand from flexible and wearable electronic systems for devices that simultaneously offer autonomous energy supply and high-sensitivity pressure sensing has accelerated the development of self-powered pressure sensors. Although substantial research has been conducted on either energy harvesting or pressure sensing mechanisms, most efforts have primarily focused on performance enhancement, lacking a systematic examination of the coupling between energy conversion and pressure response processes. This absence of integration logic hinders the rational design of fully functional devices. This review centers on the critical intersection of ionic materials, self-powered energy conversion, and pressure sensing. It systematically summarizes ion-involved energy harvesting mechanisms such as triboelectric, piezoionic, along with pressure sensing methods that can be coupled with them. Structural design approaches, including porous architectures, gradient structures and so on , are further examined for their roles in enhancing ion transport regulation. Finally, the review outlines current applications in intelligent tactile interfaces, human communication aids, and other related areas. By adopting a unified perspective that connects mechanism, structure, and function, this work proposes a scalable design strategy for self-powered pressure sensors, offering a conceptual framework for future device development and system-level integration.

灵活和可穿戴电子系统对同时提供自主能源供应和高灵敏度压力传感的设备的需求不断增长，加速了自供电压力传感器的发展。尽管已经对能量收集或压力传感机制进行了大量研究，但大多数努力主要集中在性能增强上，缺乏对能量转换和压力响应过程之间耦合的系统检查。这种集成逻辑的缺失阻碍了功能齐全的器件的合理设计。本文综述了离子材料、自供电能量转换和压力传感的关键交叉点。它系统地总结了离子涉及的能量收集机制，如摩擦电，压电离子，以及可以与它们耦合的压力传感方法。结构设计方法，包括多孔结构、梯度结构等，进一步研究了它们在增强离子传输调节中的作用。最后，综述概述了目前在智能触觉界面、人类交流辅助和其他相关领域的应用。通过采用连接机制、结构和功能的统一视角，本研究提出了一种可扩展的自供电压力传感器设计策略，为未来的设备开发和系统级集成提供了概念框架。

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引用次数: 0

Corrigendum to “Roadmap for integrating deep eutectic solvents into adsorption processes: A critical review & design blueprint” [Progress Mater. Sci. 154 (2025) 101501] “将深共晶溶剂整合到吸附过程的路线图：一个关键的审查和设计蓝图”的勘误表[进展材料]。科学通报。154 (2025)101501]

IF 4 1区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY

Progress in Materials Science

Pub Date : 2025-10-29 DOI: 10.1016/j.pmatsci.2025.101598

Ghaiath Almustafa , Rawan Abu Alwan , Ho Kyong Shon , Jorge Rodriguez , Inas AlNashef

引用次数: 0