Progress in Materials Science最新文献_第5页

Toward flexible energy storage: MXene frameworks from synthesis principles to device applications 走向灵活的能量存储：从合成原理到设备应用的MXene框架

IF 4 1区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY

Progress in Materials Science

Pub Date : 2025-09-21 DOI: 10.1016/j.pmatsci.2025.101583

Andleeb Mehmood , Irfan Ijaz , Waseem Raza , Muhammad Asim Mushtaq , Munir Ahmad , Dan Luo , Yanwei Sui , Kai Zong , Zhongwei Chen

The rapid proliferation of wearable, portable, and foldable electronics has exposed critical limitations in conventional energy storage technologies, particularly in terms of mechanical adaptability and miniaturization. Addressing these challenges necessitates the development of energy storage systems that are not only electrochemically robust but also mechanically flexible and scalable. MXenes, an emerging class of two-dimensional transition metal carbides, nitrides, and carbonitrides, have emerged as compelling candidates for flexible energy storage applications owing to their distinctive structural and physicochemical attributes (electrical conductivity, tunable surface chemistries, and intrinsic mechanical flexibility). This review critically examines recent advances in the synthesis and structural modulation of MXenes tailored for flexible energy storage systems. Emphasis is placed on their integration with complementary materials, such as carbon nanostructures (e.g., nanotubes and nanofibers), transition metal oxides (e.g., V₂O₃, VO₂, and TiO₂), and porous matrices. The discussion encompasses a broad spectrum of device chemistries, ranging from diverse flexible battery applications to supercapacitors, and highlights the mechanistic roles of MXenes in charge transport, ion diffusion, and mechanical resilience. Key challenges, including structural degradation under strain, interfacial stability, and scalable processing, are identified. Alongside strategic design principles to guide the future development of mechanically compliant and high-end Mxene based flexible energy technologies are highlighted.

可穿戴、便携式和可折叠电子设备的快速发展暴露了传统储能技术的关键局限性，特别是在机械适应性和小型化方面。为了解决这些挑战，需要开发不仅具有电化学稳定性，而且具有机械灵活性和可扩展性的储能系统。MXenes是一类新兴的二维过渡金属碳化物、氮化物和碳氮化物，由于其独特的结构和物理化学属性（电导率、可调表面化学性质和内在的机械灵活性），已成为柔性储能应用的引人注目的候选者。本文综述了针对柔性储能系统量身定制的MXenes的合成和结构调制的最新进展。重点放在它们与互补材料的集成上，例如碳纳米结构（例如，纳米管和纳米纤维），过渡金属氧化物（例如，V2O3， VO2和TiO2）和多孔基质。讨论涵盖了广泛的器件化学，从各种柔性电池应用到超级电容器，并强调了MXenes在电荷传输、离子扩散和机械弹性方面的机制作用。主要挑战包括应变下的结构退化、界面稳定性和可扩展处理。除了战略设计原则外，还强调了指导未来机械兼容和高端Mxene柔性能源技术发展的战略设计原则。

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引用次数: 0

Corrigendum to “Progress in recent sustainable materials for greenhouse gas (NOx and SOx) emission mitigation”. [Prog. Mater. Sci. 132 (2023) 101033] “减少温室气体（氮氧化物和硫氧化物）排放的近期可持续材料的进展”的勘误。[掠夺。板牙。科学通报，132 (2023)101033]

IF 4 1区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY

Progress in Materials Science

Pub Date : 2025-09-21 DOI: 10.1016/j.pmatsci.2025.101566

Aminul Islam , Siow Hwa Teo , Chi Huey Ng , Yun Hin Taufiq-Yap , Shean Yaw Thomas Choong , Md. Rabiul Awual

引用次数: 0

Non-fluorinated superomniphobic surfaces 非氟超疏水表面

IF 4 1区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY

Progress in Materials Science

Pub Date : 2025-09-17 DOI: 10.1016/j.pmatsci.2025.101581

Sadaf Shabanian , Mohammad Soltani , Sudip Kumar Lahiri , Carlo Antonini , Kevin Golovin

Superomniphobic surfaces, capable of repelling a wide range of liquids including low-surface-tension oils, rely on a synergy between surface chemistry and texture. For decades, these surfaces have primarily relied on per- and polyfluoroalkyl substances (PFAS) due to their low surface energy and durability. However, the persistence of PFAS in the environment and their toxicological risks have triggered global regulations to phase out their use. This transition presents substantial challenges, especially in sectors such as textiles, food packaging, and electronics, where oil and chemical resistance are essential and fluorine-free alternatives remain limited. While recent research has made progress in developing PFAS-free superhydrophobic surfaces, there remains a significant gap in understanding and designing non-fluorinated superomniphobic systems. This review provides a comprehensive overview of recent strategies for achieving superomniphobicity without fluorinated chemistry. We discuss both texture- and chemistry-based approaches, including coatings made with silica nanoparticles, treated fabrics, and metal oxide nanostructures, as well as coating-free systems that leverage advanced 3D-printing to fabricate doubly and triply re-entrant geometries. Importantly, we highlight limitations in scalability, durability, and liquid-specific performance. By identifying key material and structural design considerations, this review offers a clear perspective on current challenges and emerging opportunities for creating sustainable, high-performance, PFAS-free superomniphobic surfaces.

超疏水表面，能够排斥各种液体，包括低表面张力的油，依赖于表面化学和质地之间的协同作用。几十年来，这些表面主要依赖于全氟烷基和多氟烷基物质（PFAS），因为它们具有优异的驱避性和耐久性。然而，PFAS在环境中的持续存在及其毒理学风险已促使全球法规逐步淘汰其使用。这种转变带来了巨大的挑战，特别是在纺织、食品包装和电子等部门，在这些部门，耐油和耐化学品是必不可少的，而无氟替代品仍然有限。虽然最近的研究在开发无pfas的超疏水表面方面取得了进展，但在理解和设计无氟超疏水系统方面仍有很大的差距。这篇综述提供了一个全面的概述，最近的策略，以实现超疏水性不含氟化学。我们讨论了基于纹理和化学的方法，包括用二氧化硅纳米颗粒、处理过的织物和金属氧化物纳米结构制成的涂层，以及利用先进的3d打印来制造双重和三重可重入几何形状的无涂层系统。重要的是，我们强调了可扩展性、耐用性和液体特定性能方面的局限性。通过确定关键的材料和结构设计考虑因素，本综述为当前的挑战和创造可持续、高性能、无pfas的超全憎表面提供了清晰的视角。

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引用次数: 0

Lithium selective membranes for direct lithium extraction from complex brine 锂选择膜直接从复杂卤水中提取锂

IF 4 1区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY

Progress in Materials Science

Pub Date : 2025-09-15 DOI: 10.1016/j.pmatsci.2025.101582

Zhi-Yuan Guo , Jing Wang , Panpan Zhan , Lei Wang , Zhiping Lai , Zhi-Yong Ji

Membrane separation technology is an effective method for lithium extraction, boasting advantages such as environmental sustainability and continuous production feasibility. As high-grade lithium resources become increasingly depleted, the extraction paradigm must shift toward processing complex brines and seawater, which are characterized by ultra-low Li⁺ concentrations and a high content of competing ions, particularly Na⁺, K⁺, and Mg²⁺. Lithium selective membranes (LSMs) have emerged as critical enablers for sustainable lithium extraction from unconventional resources. Despite various LSMs have been proposed, there is a lack of systematic summarization and analysis of their lithium selective extraction mechanism and performance. This review systematically classifies state-of-the-art LSMs based on the lithium selective mechanisms of size sieving effect, binding affinity difference and hybrid mechanisms. The relationships of composition-structure–property in LSMs are analyzed in detail. The characteristics of various functional materials (including inorganic solid-state electrolytes, ionic liquids, phosphate esters, crown ethers, lithium ion-sieves, and metal–organic frameworks) used in the fabrication of LSMs are analyzed. Additionally, this review discussed the key technical challenges of the LSMs, and presented the potential future research directions to provide viable recommendations for the design, fabrication, and application of high-performance LSMs.

膜分离技术是一种有效的锂提取方法，具有环境可持续性和连续生产可行性等优点。随着高品位锂资源的日益枯竭，提取模式必须转向处理复杂卤水和海水，这些卤水的特点是超低Li+浓度和高竞争离子含量，特别是Na+、K+和Mg2+。锂选择膜（lsm）已成为从非常规资源中可持续提取锂的关键推动因素。尽管已经提出了各种lsm，但缺乏对其锂选择性萃取机理和性能的系统总结和分析。本文从粒径筛分效应、结合亲和性差异和杂化机制三个方面对lsm进行了系统的分类。详细分析了lsm中组成-结构-性能的关系。分析了用于lsm制备的各种功能材料（包括无机固态电解质、离子液体、磷酸酯、冠醚、锂离子筛和金属有机骨架）的特性。此外，本文还讨论了lsm的关键技术挑战，并提出了未来可能的研究方向，为高性能lsm的设计、制造和应用提供可行的建议。

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引用次数: 0

Bioinspired waterproof, breathable materials: How does nature transport water across its surfaces and through its membranes? 仿生防水透气材料：大自然是如何将水输送到其表面和膜上的？

IF 4 1区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY

Progress in Materials Science

Pub Date : 2025-09-11 DOI: 10.1016/j.pmatsci.2025.101578

Sara K. Fleetwood , Maya Kleiman , Victoria French , Joice Kaschuk , E. Johan Foster

The controlled transport of water vapor and liquid water across membranes is a crucial biological process observed in natural systems for over 460 million years. Through evolution, plants have developed various methods to regulate water gradients between their internal structures and the external environment. The primary natural mechanisms used to modulate the water gradient effectively involve integrating specialized organs, like those responsible for gas exchange, in tandem with developing impermeable outer surfaces. Several applications in engineered materials – including rainwear, wound dressings, textiles, packaging, and building materials require breathability and waterproofing properties. Breathable materials can enable water vapor movement within their structure, while waterproof materials effectively resist the penetration and absorption of liquid water. Developing materials that can simultaneously exhibit waterproofness, and breathability presents a significant scientific and engineering challenge due to the inherent conflict between these properties. This review aims to delve into the physicochemical mechanisms governing plant water transport and establish a connection with developing bio-based and bio-inspired materials. We explore how plant components can give rise to hydrophobic, hydrophilic, porous, and responsively porous bio-inspired materials, addressing challenges encountered in the waterproof-breathable textile industry.

水蒸气和液态水在膜上的控制运输是一个重要的生物过程，在自然系统中已观察到超过4.6亿年。在进化过程中，植物已经发展出各种方法来调节其内部结构和外部环境之间的水分梯度。用于有效调节水梯度的主要自然机制包括整合专门的器官，如负责气体交换的器官，以及发展不渗透的外表面。工程材料中的一些应用-包括雨衣，伤口敷料，纺织品，包装和建筑材料需要透气性和防水性能。透气材料可以使水蒸气在其结构内部运动，而防水材料可以有效地抵抗液态水的渗透和吸收。由于这些特性之间的内在冲突，开发同时具有防水和透气性的材料提出了重大的科学和工程挑战。本文旨在深入探讨植物水分运移的物理化学机制，并将其与生物基和仿生材料的发展联系起来。我们探索植物成分如何产生疏水、亲水、多孔和响应多孔的仿生材料，解决防水透气纺织行业遇到的挑战。

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引用次数: 0

An invisible dartboard: Commercialization targets for metal and anode-free batteries 看不见的飞镖：金属和无阳极电池的商业化目标

IF 4 1区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY

Progress in Materials Science

Pub Date : 2025-09-11 DOI: 10.1016/j.pmatsci.2025.101580

Emily Cooper , Lingbing Ran , Ian Gentle , Ruth Knibbe

Alkali metal batteries (MBs) and anode-free batteries (AFBs) can offer high energy density and simple construction for future electric vehicles. The short lifespan of these batteries is regularly labelled as a significant commercialization barrier, however no clear targets have been defined. In this Snapshot Review, we determine lifespan and other targets for Li- and Na-MBs and AFBs using NMC Li-ion batteries (Li-IBs) as a benchmark. AFBs require lifespans over 1400 cycles to reach Li-IB parity, but currently last only a few hundred cycles. MBs are closer to parity, though large manufacturing challenges remain. Additionally, we assess other requirements including thermal operating ranges, fast charging thresholds, and fabrication demands which must be addressed in MB and AFB research to better match electric vehicle operation. These clear targets will align our efforts to bring these next-generation technologies out of the lab and into mainstream application.

碱金属电池（mb）和无阳极电池（afb）可以为未来的电动汽车提供高能量密度和简单的结构。这些电池的短寿命通常被认为是一个重大的商业化障碍，但目前还没有明确的目标。在这篇快照评论中，我们以NMC锂离子电池（Li- ibs）为基准，确定了Li- mb和na - mb和afb的寿命和其他目标。afb需要超过1400次循环才能达到Li-IB平价，但目前只能持续几百次循环。MBs更接近平价，尽管大型制造挑战依然存在。此外，我们还评估了其他要求，包括热工作范围、快速充电阈值和制造要求，这些要求必须在MB和AFB研究中得到解决，以更好地匹配电动汽车的运行。这些明确的目标将使我们努力使这些下一代技术走出实验室并进入主流应用。

引用次数: 0

Fiber-based electrochemical sweat sensors toward personalized monitoring 基于纤维的电化学汗液传感器实现个性化监测

IF 4 1区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY

Progress in Materials Science

Pub Date : 2025-09-09 DOI: 10.1016/j.pmatsci.2025.101579

Zixu Chang , Faqiang Wang , Zongqian Wang , Jianyong Yu , Bin Ding , Zhaoling Li

As skin-interfaced wearable sensors undergo rapid evolution, the real-time and non-invasive detection of health-pertinent biomarkers in human sweat has emerged as a cornerstone for gaining profound insights into our physiological status and fostering the development of tailored healthcare systems. Electrochemical sweat sensors (ECSSs) are under high pursuit for their unparalleled capabilities to enable high-performance health monitoring, movement tracking, and predictive parsing in an accurate and continuous manner. Within the realm of ECSSs fabrication, fiber materials have been served as ideal alternatives owing to their characteristic advantages. This review provides a comprehensive overview of ECSSs constructed with fiber materials for portable personalized monitoring. Initially, the recent advancements in selection of functional constructing materials, fabrication methods, and sensing mechanisms are thoughtfully demonstrated. Subsequently, hybrid multiplexed and multimodal sensors are presented, along with considerations for developing integrated electrochemical sensing systems for emerging wearable applications. Furthermore, the potential challenges and future perspectives of fiber-based ECSSs are outlined, aiming to inspire readers with insightful ideas.

随着皮肤界面可穿戴传感器的快速发展，对人体汗液中健康相关生物标志物的实时、无创检测已成为深入了解人体生理状态和促进量身定制医疗保健系统发展的基石。电化学汗液传感器（ecss）以其无与伦比的功能，以准确和连续的方式实现高性能的健康监测，运动跟踪和预测分析，受到高度追捧。在ecss制造领域，纤维材料由于其特性优势而成为理想的替代品。本文综述了用于便携式个性化监测的纤维材料ecss。首先，在选择功能性建筑材料，制造方法和传感机制方面的最新进展进行了深思熟虑的论证。随后，介绍了混合多路复用和多模态传感器，以及开发用于新兴可穿戴应用的集成电化学传感系统的考虑。此外，还概述了基于光纤的ecss的潜在挑战和未来前景，旨在为读者提供有见地的想法

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引用次数: 0

Advanced strategies to boost sustainable high-rate Ni-rich cathodes toward durable LIBs 先进的策略，促进可持续的高速率富镍阴极到耐用的锂离子电池

IF 4 1区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY

Progress in Materials Science

Pub Date : 2025-09-08 DOI: 10.1016/j.pmatsci.2025.101574

Parnaz Asghari , Farshad Boorboor Ajdari , Fereshteh Abbasi , Sasan Rostami , Ali Asghar Sadeghi Ghazvini , Ali Molaei Aghdam

The rapid rise in demand for high-performance lithium-ion batteries (LIBs) highlights the importance of high-rate nickel-rich cathode materials as a key step toward next-generation LIBs, offering high discharge capacity, increased energy density, stable operating voltage, and cost-effectiveness. However, issues such as cation mixing, side reactions, microcrack formation, and thermal instability limit their rate capability and long-term durability. This review provides a detailed assessment of these challenges. It outlines strategies to overcome them, including surface coating, doping, core–shell structures, full-concentration gradients, and particle or additive engineering. Surface coatings improve surface stability and ion transport, while doping methods, including pillar and gradient doping, reduce cation mixing and strengthen structural stability. Core–shell and full-concentration gradients designs relieve mechanical stress and suppress phase transitions, and advanced particle engineering reduces microcrack formation. Computational tools such as density functional theory and machine learning, together with in-situ characterization, provide valuable insights into degradation mechanisms, enabling more precise material optimization. Importantly, combined and modified approaches that integrate multiple strategies show the greatest potential to address these challenges while maintaining sustainability and scalability. This work clarifies operational mechanisms, aiding researchers in developing advanced high-rate Ni-rich cathode LIBs for future energy storage.

高性能锂离子电池（lib）需求的快速增长凸显了高倍率富镍阴极材料的重要性，这是迈向下一代锂离子电池的关键一步，具有高放电容量、更高的能量密度、稳定的工作电压和成本效益。然而，诸如阳离子混合、副反应、微裂纹形成和热不稳定性等问题限制了它们的速率能力和长期耐久性。本综述对这些挑战进行了详细的评估。它概述了克服它们的策略，包括表面涂层，掺杂，核壳结构，全浓度梯度以及颗粒或添加剂工程。表面涂层提高了表面稳定性和离子输运，而掺杂方法，包括柱和梯度掺杂，减少了阳离子混合，增强了结构稳定性。核壳梯度和全浓度梯度设计减轻了机械应力，抑制了相变，先进的颗粒工程减少了微裂纹的形成。密度泛函理论和机器学习等计算工具，以及现场表征，为降解机制提供了有价值的见解，从而实现了更精确的材料优化。重要的是，整合多种策略的组合和改进方法显示出解决这些挑战的最大潜力，同时保持可持续性和可扩展性。这项工作澄清了操作机制，帮助研究人员开发先进的高速率富镍阴极锂电池，用于未来的能源存储。

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引用次数: 0

Advancing ionic thermoelectric materials for heat recovery 热回收离子热电材料的研究进展

IF 4 1区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY

Progress in Materials Science

Pub Date : 2025-09-06 DOI: 10.1016/j.pmatsci.2025.101575

Yifan Wang , Ibrahim Mwamburi Mwakitawa , Hao Yang , Mingyu Song , Qian Huang , Xinzhe Li , Pengchi Zhang , Wei Fang , Lijun Hu , Yongli Zhou , Chen Li , Jianyong Ouyang , Kuan Sun

Ionic thermoelectrics (i-TEs) are emerging as a promising, sustainable technology for low-grade heat recovery, notable for their absence of moving mechanical parts. In recent years, significant advancements in i-TE materials and devices have been propelled by their advantages in thermal power generation, compatibility with room-temperature operation, and potential for integration into flexible, wearable devices. However, challenges remain to be addressed for practical future applications, primarily due to insufficient evaluations of innovative operational modes and materials. This review aims to bridge this gap by summarizing key existing theories and providing an in-depth analysis of ion migration mechanisms within i-TE capacitors. We also highlight significant contributions from leading studies, focusing on material selection, operational modes, performance characteristics, and pivotal discoveries. Ultimately, this review seeks to identify transformative approaches in i-TEs to foster innovative designs for practical applications.

离子热电（i-TEs）正成为一种有前途的、可持续的低等级热回收技术，值得注意的是它们没有移动的机械部件。近年来，i-TE材料和器件在热发电、与室温操作的兼容性以及集成到灵活可穿戴设备中的潜力方面的优势推动了它们的重大进步。然而，由于对创新操作模式和材料的评估不足，未来的实际应用仍然面临挑战。本文旨在通过总结现有的关键理论和深入分析i-TE电容器中的离子迁移机制来弥补这一空白。我们还强调了主要研究的重要贡献，重点是材料选择，操作模式，性能特征和关键发现。最后，这篇综述试图找出i-TEs的变革方法，以促进实际应用的创新设计

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引用次数: 0

Elaborately designed intelligent responsive sensing materials for development of flexible gas sensors 为开发柔性气体传感器精心设计了智能响应传感材料

IF 4 1区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY

Progress in Materials Science

Pub Date : 2025-09-04 DOI: 10.1016/j.pmatsci.2025.101565

Yonghui Deng , Luyang Liu , Yidan Chen , Yu Deng , Jichun Li , Xiaoqing Liu , Yidong Zou , Limin Wu , Wenhe Xie

With the development of artificial intelligence and Internet of Things, flexible gas sensors have emerged as vital functional devices by integrating with smart wearable electronics, which exhibit irreplaceable advantages in medical diagnosis, aerospace, environmental remediation, robotics, and electronic skin. The elaborately designed sensing materials are critical to developing high-performance gas sensors in terms of sensitivity, selectivity, stability, and response/recovery dynamics. In addition, to achieve the reliable and consistent operation of the flexible sensing devices, it is essential to ensure an effective and stable integration between sensing materials and device substrates. Consequently, it is distinctly meaningful to comprehensively summarize the design principles and surface properties of gas-sensitive materials in flexible gas sensors. This review originates from the precise synthesis, regulation and structure optimization of sensing materials for flexible gas sensors, and the new concept of “chemical microenvironment” is proposed to elucidate the sensing mechanism from molecular-atomic level. Specifically, various carrier migration models (e.g., electron, proton, ion) and surface/interfacial interaction are highlighted. Finally, the emerging opportunities and challenges in flexible gas sensors are proposed and predicted, aiming to provide insight about the development of flexible gas sensors into the next-generation sensing applications and further satisfy the growing requirements of smart sensors for long-life, biocompatibility, and real-time communication capabilities.

随着人工智能和物联网的发展，柔性气体传感器与智能可穿戴电子产品融合，成为重要的功能器件，在医疗诊断、航空航天、环境修复、机器人、电子皮肤等领域展现出不可替代的优势。精心设计的传感材料对于开发高性能气体传感器在灵敏度、选择性、稳定性和响应/恢复动力学方面至关重要。此外，为了实现柔性传感器件的可靠和一致的运行，必须确保传感材料与器件基板之间有效和稳定的集成。因此，全面总结柔性气体传感器中气敏材料的设计原理和表面特性具有重要意义。本文从柔性气体传感器传感材料的精确合成、调控和结构优化等方面入手，提出了“化学微环境”的新概念，从分子-原子水平阐述传感机理。具体来说，各种载流子迁移模型（例如，电子，质子，离子）和表面/界面相互作用被强调。最后，提出并预测了柔性气体传感器的新机遇和挑战，旨在为柔性气体传感器在下一代传感应用中的发展提供见解，并进一步满足智能传感器对长寿命、生物相容性和实时通信能力日益增长的需求。

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引用次数: 0