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3D-Printed photocatalysts for revolutionizing catalytic conversion of solar to chemical energy 3d打印光催化剂革命性的太阳能催化转化为化学能
IF 37.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-01-07 DOI: 10.1016/j.pmatsci.2025.101427
He Lin, Ming Ma, Huan Qi, Xin Wang, Zheng Xing, Azhar Alowasheeir, Huiping Tang, Seong Chan Jun, Yusuke Yamauchi, Shude Liu
Conversion of solar to chemical energy is essential for addressing energy crisis and mitigating environmental problems by generating storable, valuable chemicals. Photocatalysts play a critical role in solar conversion systems by affecting solar energy capture, charge generation and transfer, and redox reaction rates; however, they still face significant challenges in practical manufacturing. As an additive manufacturing technology, three-dimensional (3D) printing enables the creation of complex, customizable catalytic material structures with precise control, surface area optimization, catalytic sites, and the integration of multiple materials to enhance the photocatalytic process. This review begins by examining the fundamental principles of 3D-printed photocatalysts for solar to chemical energy conversion, with a focus on metal oxides/chalcogenides, carbon-based materials, metal organic frameworks/covalent organic frameworks and their composites. Second, the key performance parameters, emerging challenges and opportunities in designing 3D-printed photocatalysts were discussed. Third, the latest advancements on 3D-printed photocatalysts are presented across various applications (water splitting, carbon dioxide reduction, nitrogen fixation, pollutant degradation, and organic synthesis), covering material design, synthesis methods, and the relationship between structure and photocatalytic performance. Finally, the review outlines future directions for integrating 3D printing with photocatalysis. This comprehensive review aims to provide insights for designing high-performance photocatalysts for sustainable energy supply.
将太阳能转化为化学能对于解决能源危机和通过产生可储存的宝贵化学品来缓解环境问题至关重要。光催化剂通过影响太阳能捕获、电荷生成和转移以及氧化还原反应速率,在太阳能转换系统中发挥着至关重要的作用;然而,光催化剂的实际制造仍面临着巨大挑战。作为一种增材制造技术,三维(3D)打印技术能够制造出复杂的、可定制的催化材料结构,并通过精确控制、表面积优化、催化位点和多种材料的整合来增强光催化过程。本综述首先探讨了用于太阳能到化学能转换的三维打印光催化剂的基本原理,重点关注金属氧化物/钙钛矿、碳基材料、金属有机框架/共价有机框架及其复合材料。其次,讨论了设计三维打印光催化剂的关键性能参数、新出现的挑战和机遇。第三,介绍了三维打印光催化剂在各种应用(水分离、二氧化碳还原、固氮、污染物降解和有机合成)方面的最新进展,包括材料设计、合成方法以及结构与光催化性能之间的关系。最后,综述概述了将 3D 打印与光催化技术相结合的未来方向。本综述旨在为设计高性能光催化剂以实现可持续能源供应提供真知灼见。
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引用次数: 0
Polymer gels for aqueous metal batteries 水金属电池用聚合物凝胶
IF 37.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-01-03 DOI: 10.1016/j.pmatsci.2025.101426
Tianfu Zhang, Keliang Wang, Hengwei Wang, Manhui Wei, Zhuo Chen, Daiyuan Zhong, Yunxiang Chen, Pucheng Pei
With the advantages of high energy density and low cost, aqueous metal batteries have received widespread attention as energy conversion and storage devices. Polymer gels are suitable electrolytes because of their high chemical stability, safety, and inhibition of metal dendrites. However, the commercial application of polymer gels is challenged by factors that include electrolyte–electrode interfaces, external forces, and extreme environments. In addition, it is challenging to design polymer gels that satisfy multiple needs due to trade-offs between different properties. In this review, we present recent advances in polymer gels for aqueous metal batteries. First, the advantages of polymer gels as electrolytes are summarized. Then, the relationship among the structural, properties, and applications of polymer gels is discussed in detail to motivate the exploitation of high-performance polymer gels. The special requirements of different metal batteries for polymer gels are also summarized, including flame retardancy, anode protection, and decomposition of parasitic products. Subsequently, synthesis strategies based on machine learning and characterization techniques for polymer gels are highlighted. Finally, the challenges and future prospects of polymer gels for applications in aqueous electrical energy storage devices are discussed. This review aims to provide guidance for the design of advanced and compatible polymer gels.
金属水电池具有能量密度高、成本低等优点,作为一种能量转换和存储装置受到了广泛的关注。聚合物凝胶具有较高的化学稳定性、安全性和对金属枝晶的抑制作用,是一种合适的电解质。然而,聚合物凝胶的商业应用受到包括电解质-电极界面、外力和极端环境在内的因素的挑战。此外,由于不同性能之间的权衡,设计满足多种需求的聚合物凝胶具有挑战性。本文综述了用于金属水电池的聚合物凝胶的最新研究进展。首先,综述了聚合物凝胶作为电解质的优点。然后,详细讨论了聚合物凝胶的结构、性能和应用之间的关系,以激励高性能聚合物凝胶的开发。总结了不同金属电池对聚合物凝胶的特殊要求,包括阻燃性、阳极保护、寄生产物分解等。随后,重点介绍了基于机器学习和表征技术的聚合物凝胶合成策略。最后,讨论了聚合物凝胶在水储能装置中的应用所面临的挑战和未来的前景。本文综述旨在为先进的相容性聚合物凝胶的设计提供指导。
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引用次数: 0
Research progress in sodium-iron-phosphate-based cathode materials for cost-effective sodium-ion batteries: Crystal structure, preparation, challenges, strategies, and developments 高性价比钠离子电池用磷酸铁钠基正极材料的研究进展:晶体结构、制备、挑战、策略和发展
IF 37.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-12-27 DOI: 10.1016/j.pmatsci.2024.101425
Kouthaman Mathiyalagan, Rubini Raja, Dongwoo Shin, Young-Chul Lee
Owing to their long cycle life, high energy density, and ecological friendliness, lithium-ion batteries (LIBs) have been widely used in portable electronic devices and electric vehicles over the past few decades. Nonetheless, the high cost and limited abundance of lithium pose significant obstacles to its widespread use. In response, sodium-ion batteries (SIBs) have gained significant attention owing to their abundant sodium resources, similar intercalation chemistry to that of lithium, and low cost. Cathode materials are key components of SIBs, as they significantly impact the electrochemical performance. Among the several cathode candidates, polyanion-type cathode materials are considered the most promising and attractive options for developing SIBs owing to their outstanding electrochemical performance. In this review, the crystal structure classification and synthesis methods of sodium iron phosphate (NaFePO4) are comprehensively examined. The issues associated with NaFePO4 cathode materials for emerging SIBs are also summarized. Furthermore, optimization strategies for enhancing electrochemical performance are discussed, including surface morphology modification, elemental ion substitution, nano-structure architecture, and the probing of innovative structures. Finally, recent research developments and perspectives on NaFePO4 cathode materials are reviewed. This article provides valuable insights into the development of NaFePO4 cathode materials for realizing high-performance SIBs for commercialization.
锂离子电池因其循环寿命长、能量密度高、生态友好等优点,在过去几十年中被广泛应用于便携式电子设备和电动汽车中。然而,锂的高成本和有限的储量对其广泛使用构成了重大障碍。因此,钠离子电池因其丰富的钠资源、与锂离子电池相似的插层化学性质以及低廉的成本而备受关注。阴极材料是sib的关键部件,对sib的电化学性能有重要影响。在几种候选阴极中,聚阴离子型阴极材料因其优异的电化学性能而被认为是发展sib的最有前途和吸引力的选择。本文综述了磷酸铁钠(NaFePO4)的晶体结构、分类和合成方法。本文还总结了新兴sib用NaFePO4正极材料的相关问题。此外,还讨论了提高电化学性能的优化策略,包括表面形貌修饰、元素离子取代、纳米结构结构和探索创新结构。最后,对近年来NaFePO4正极材料的研究进展和展望进行了综述。本文对实现高性能sib商业化的NaFePO4阴极材料的开发提供了有价值的见解。
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引用次数: 0
Progress in multi-electron sodium vanadium phosphate cathode for emerging sodium-ion batteries 新兴钠离子电池用多电子磷酸钒钠阴极研究进展
IF 37.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-12-21 DOI: 10.1016/j.pmatsci.2024.101424
Hafiz Kashif Razzaq, Chun-Chen Yang, Muhammad Norhaffis Mustafa, Arshid Numan, Mohammad Khalid
Sodium vanadium phosphate (NVP) has emerged as a promising cathode material for sodium-ion batteries (SIBs) due to its three-dimensional (3D) Sodium Super Ionic Conductor (NASICON) framework, which enables rapid sodium ion (Na+) diffusion, impressive thermal stability, and high theoretical energy density. However, the commercialization of NVP-based batteries faces challenges due to the large ionic radius of sodium (Na), which limits its electrical conductivity and structural stability. Advanced strategies have been developed to overcome these limitations, including integrating carbonaceous materials, targeted ion doping, nanosizing, and manipulating the shape and structure of NVP particles. Despite progress in Na+ migration pathways, synthesis, engineering, and electronic/ionic mobility improvements, an essential aspect of NVP is lacking, such as scalability, recycling, and electrolyte compatibility necessary for the commercial deployment of NVP-based sodium-ion batteries (SIBs). This review aims to fill this gap by comprehensively investigating these obstacles to delimit NVP-based SIBs. Moreover, a comparative analysis with lithium iron phosphate (LFP), a benchmark material in commercial LIBs, highlights NVP’s potential advantages in cost, safety, and Na availability. However, challenges in energy density and scalability remain. By evaluating the relationships between these factors and electrochemical performance, this review provides a comprehensive understanding of NVP-based batteries and identifies opportunities for further improvement.
磷酸钒钠(NVP)由于其三维(3D)钠超离子导体(NASICON)框架,使钠离子(Na+)快速扩散,令人印象深刻的热稳定性和高理论能量密度,已成为钠离子电池(sib)的一种有前途的阴极材料。然而,由于钠(Na)的离子半径大,限制了其导电性和结构稳定性,nvp基电池的商业化面临挑战。为了克服这些限制,研究人员开发了一些先进的策略,包括整合碳质材料、靶向离子掺杂、纳米化以及控制NVP颗粒的形状和结构。尽管在Na+迁移途径、合成、工程和电子/离子迁移率方面取得了进展,但NVP的一个重要方面仍然缺乏,例如NVP基钠离子电池(sib)商业部署所需的可扩展性、可回收性和电解质兼容性。本综述旨在通过全面调查这些障碍来划分基于nvp的sib来填补这一空白。此外,与商用锂离子电池的基准材料磷酸铁锂(LFP)的对比分析强调了NVP在成本、安全性和Na可用性方面的潜在优势。然而,能量密度和可扩展性方面的挑战仍然存在。通过评估这些因素与电化学性能之间的关系,本综述提供了对nvp基电池的全面了解,并确定了进一步改进的机会。
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引用次数: 0
Corrigendum to “Inorganic sonosensitizer nanomaterials for sonodynamic therapy of diseases beyond cancer” [Prog. Mater. Sci. 148 (2025) 101384] “无机声敏剂纳米材料用于癌症以外疾病的声动力治疗”的勘误表。板牙。科学通报。148 (2025)101384]
IF 37.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-12-13 DOI: 10.1016/j.pmatsci.2024.101423
Alejandro Sosnik, Ivan Zlotver, Harischandra Potthuri
Acknowledgements. The authors thank the support of the project “Innovative Tools to Treat and Model Complex Cancer Environments” (TheraTools, Ref. 101073404) from the HORIZON-MSCA-2021-DN-01 call (Doctoral Networks - Joint Doctorates modality) of the research and innovation programme of Horizon Europe 2021 under the Marie Sklodowska-Curie actions.
致谢。作者感谢玛丽-斯克洛多夫斯卡-居里(Marie Sklodowska-Curie)行动下的欧洲地平线 2021 研究与创新计划 HORIZON-MSCA-2021-DN-01 号召(博士网络 - 联合博士学位模式)的 "治疗和模拟复杂癌症环境的创新工具"(TheraTools,编号 101073404)项目的支持。
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引用次数: 0
Advances and challenges in inorganic bulk-based flexible thermoelectric devices 无机体基柔性热电器件的进展与挑战
IF 37.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-12-12 DOI: 10.1016/j.pmatsci.2024.101420
Qing-Yi Liu, Xiao-Lei Shi, Tian-Yi Cao, Wen-Yi Chen, Lan Li, Zhi-Gang Chen
The development of flexible thermoelectric devices (F-TEDs) has significantly improved their thermoelectric performance and unique flexibility, with increasing efforts directed toward standardization and commercialization. Among the various types of F-TEDs, those incorporating all-inorganic bulk materials are more practical and broadly applicable due to the superior thermoelectric performance of these materials compared to F-TEDs using flexible films and fibers. In recent years, innovative design approaches for inorganic bulk-based F-TEDs have emerged, showcasing their distinct advantages. This review provides a timely and comprehensive summary of the research progress on inorganic bulk-based F-TEDs utilizing thermoelectric materials. We begin by discussing advancements in newly developed inorganic bulks, including traditional near-room-temperature bismuth-telluride-based materials, and more recent plastic materials. We then explore design strategies and innovations in inorganic bulk-based F-TEDs, covering areas such as computational modeling, device structures, heat flow analysis, advanced fabrication techniques, diffusion barriers, flexibilization strategies, liquid metal interconnects, and flexible heat sinks. Additionally, we review the testing standards for F-TEDs and highlight the recent application advancements in flexible power generation, cooling, and heating. Finally, we address the current challenges in this field and offer insights into future development prospects. This work is essential for advancing the design, application, standardization, and commercialization of F-TEDs.
柔性热电器件(F-TEDs)的发展显著提高了其热电性能和独特的灵活性,并朝着标准化和商业化方向不断努力。在各种类型的F-TEDs中,与使用柔性薄膜和纤维的F-TEDs相比,采用全无机块体材料的F-TEDs更具实用性和广泛适用性,因为这些材料的热电性能优越。近年来,无机体基f - ted的创新设计方法已经出现,展示了它们独特的优势。本文对利用热电材料的无机块基F-TEDs的研究进展进行了及时、全面的综述。我们首先讨论新开发的无机块体的进展,包括传统的近室温碲化铋基材料和最近的塑料材料。然后,我们探索了基于无机块体的f - ted的设计策略和创新,涵盖了计算建模、器件结构、热流分析、先进制造技术、扩散屏障、柔性化策略、液态金属互连和柔性散热器等领域。此外,我们回顾了F-TEDs的测试标准,并重点介绍了柔性发电、冷却和加热方面的最新应用进展。最后,我们讨论了该领域目前面临的挑战,并对未来的发展前景提出了见解。这项工作对于推进f - ted的设计、应用、标准化和商业化至关重要。
{"title":"Advances and challenges in inorganic bulk-based flexible thermoelectric devices","authors":"Qing-Yi Liu, Xiao-Lei Shi, Tian-Yi Cao, Wen-Yi Chen, Lan Li, Zhi-Gang Chen","doi":"10.1016/j.pmatsci.2024.101420","DOIUrl":"https://doi.org/10.1016/j.pmatsci.2024.101420","url":null,"abstract":"The development of flexible thermoelectric devices (F-TEDs) has significantly improved their thermoelectric performance and unique flexibility, with increasing efforts directed toward standardization and commercialization. Among the various types of F-TEDs, those incorporating all-inorganic bulk materials are more practical and broadly applicable due to the superior thermoelectric performance of these materials compared to F-TEDs using flexible films and fibers. In recent years, innovative design approaches for inorganic bulk-based F-TEDs have emerged, showcasing their distinct advantages. This review provides a timely and comprehensive summary of the research progress on inorganic bulk-based F-TEDs utilizing thermoelectric materials. We begin by discussing advancements in newly developed inorganic bulks, including traditional near-room-temperature bismuth-telluride-based materials, and more recent plastic materials. We then explore design strategies and innovations in inorganic bulk-based F-TEDs, covering areas such as computational modeling, device structures, heat flow analysis, advanced fabrication techniques, diffusion barriers, flexibilization strategies, liquid metal interconnects, and flexible heat sinks. Additionally, we review the testing standards for F-TEDs and highlight the recent application advancements in flexible power generation, cooling, and heating. Finally, we address the current challenges in this field and offer insights into future development prospects. This work is essential for advancing the design, application, standardization, and commercialization of F-TEDs.","PeriodicalId":411,"journal":{"name":"Progress in Materials Science","volume":"28 1","pages":""},"PeriodicalIF":37.4,"publicationDate":"2024-12-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142809586","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ferroelectric Fluoropolymer/MXene composites for flexible pressure sensors: Fabrication and application 柔性压力传感器用铁电氟聚合物/MXene复合材料:制造与应用
IF 37.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-12-12 DOI: 10.1016/j.pmatsci.2024.101422
Yu-Jie Wu, Jia-Xing Guo, Xing Zhao, Chun-Yan Tang, Tao Gong, Qi Jing, Kai Ke, Yu Wang, Rui-Ying Bao, Kai Zhang, Ming-Bo Yang, Wei Yang
The rapid development of Internet of Things and artificial intelligence leads to a surge in the demand for wearable electronics in the fields of medical diagnosis, healthcare, intelligent control, and human–machine interface. Owing to excellent piezoelectric and dielectric properties of ferroelectric fluoropolymers, the composites consisting of ferroelectric polymers and MXene have shown promising applications in the field of flexible electronics as wearable sensors and flexible nanogenerators. This paper reviews the most recent advances in the processing and applications of MXene-filled ferroelectric fluoropolymer composites for pressure sensing and energy harvesting applications. Specifically, it systemically summarizes the fabrication methods of the ferroelectric fluoropolymer composites with MXene and corresponding applications in flexible pressure sensors, nanogenerators, multifunctional sensors, which provides an outlook on the future development of self-powered wearable electronics.
随着物联网和人工智能的快速发展,医疗诊断、医疗保健、智能控制、人机界面等领域对可穿戴电子产品的需求激增。由于铁电氟聚合物具有优异的压电和介电性能,由铁电聚合物和MXene组成的复合材料在可穿戴传感器和柔性纳米发电机等柔性电子领域具有广阔的应用前景。本文综述了mxene填充铁电含氟聚合物复合材料在压力传感和能量收集方面的最新研究进展。系统总结了含MXene铁电氟聚合物复合材料的制备方法及其在柔性压力传感器、纳米发电机、多功能传感器等方面的应用,展望了自供电可穿戴电子产品的未来发展。
{"title":"Ferroelectric Fluoropolymer/MXene composites for flexible pressure sensors: Fabrication and application","authors":"Yu-Jie Wu, Jia-Xing Guo, Xing Zhao, Chun-Yan Tang, Tao Gong, Qi Jing, Kai Ke, Yu Wang, Rui-Ying Bao, Kai Zhang, Ming-Bo Yang, Wei Yang","doi":"10.1016/j.pmatsci.2024.101422","DOIUrl":"https://doi.org/10.1016/j.pmatsci.2024.101422","url":null,"abstract":"The rapid development of Internet of Things and artificial intelligence leads to a surge in the demand for wearable electronics in the fields of medical diagnosis, healthcare, intelligent control, and human–machine interface. Owing to excellent piezoelectric and dielectric properties of ferroelectric fluoropolymers, the composites consisting of ferroelectric polymers and MXene have shown promising applications in the field of flexible electronics as wearable sensors and flexible nanogenerators. This paper reviews the most recent advances in the processing and applications of MXene-filled ferroelectric fluoropolymer composites for pressure sensing and energy harvesting applications. Specifically, it systemically summarizes the fabrication methods of the ferroelectric fluoropolymer composites with MXene and corresponding applications in flexible pressure sensors, nanogenerators, multifunctional sensors, which provides an outlook on the future development of self-powered wearable electronics.","PeriodicalId":411,"journal":{"name":"Progress in Materials Science","volume":"21 1","pages":""},"PeriodicalIF":37.4,"publicationDate":"2024-12-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142816251","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electrorheological fluids: A living review 电流变流体:动态回顾
IF 37.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-12-11 DOI: 10.1016/j.pmatsci.2024.101421
Lenka Munteanu, Andrei Munteanu, Michal Sedlacik
Electrorheological (ER) materials have attracted considerable attention over the decades, owning to their unique ability to rapidly change their rheological properties upon exposure to an electric field. Such feature enables these materials in numerous applications. This paper reviews the general aspects of electrorheological fluids (ERFs), and introduces the most often used ER materials. Liquid carriers are briefly compared and numerous dispersed dielectric particles are represented from both, inorganic and organic categories, along with a wide range of composites. A selection of reviewed ERF particles characteristics (their type, geometry, size, conductivity and ER efficiency) is summarized in tables. Advantages and drawbacks of state-of-the-art ERFs are outlined, along with their general requirements. Additionally, an open living online document is attached and meant to keep a summary of the key characteristics of ER particles covered in future ERF-focused publications and create a rich online resource for the scientific community over time. Fellow researchers are therefore welcomed to contact the authors for their published data to be included (the open living table is to be updated regularly).
几十年来,电流变(ER)材料由于其在暴露于电场时迅速改变其流变性能的独特能力而引起了相当大的关注。这样的特性使这些材料在许多应用中。本文综述了电流变流体的一般情况,并介绍了最常用的电流变流体材料。简要地比较了液体载体,并从无机和有机类别中代表了许多分散的介电粒子,以及广泛的复合材料。回顾ERF颗粒特性的选择(它们的类型,几何形状,尺寸,电导率和ER效率)总结在表中。概述了最先进的erf的优点和缺点,以及它们的一般要求。此外,还附上了一个开放的在线文档,旨在保留未来以erf为重点的出版物中所涵盖的ER粒子的关键特征的摘要,并随着时间的推移为科学界创建丰富的在线资源。因此,欢迎其他研究人员与作者联系,以获取其已发表的数据(开放式生活表将定期更新)。
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引用次数: 0
Recent advances in non-ionic surfactant templated synthesis of porous metal oxide semiconductors for gas sensing applications 非离子表面活性剂模板合成多孔金属氧化物半导体的研究进展
IF 37.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-12-06 DOI: 10.1016/j.pmatsci.2024.101409
Jinwu Hu, Yidong Zou, Yu Deng, Hui-Jun Li, Hui Xu, Ding Wang, Limin Wu, Yonghui Deng, Guisheng Li
With the advancement of nanomaterials science and technology, metal oxide semiconductor (MOS) has been extensively explored to develop high-performance gas sensors for various applications, especially in environmental protection, chemical industry, food safety, and disease precaution. Among various nanostructure, porous MOS materials have garnered significant attention for their outstanding features including abundant interconnected pores, numerous active sites and high specific surface area, which are particularly favorable to enhance gas–solid interactions in gas sensing. The non-ionic surfactant templates are commonly used to synthesize porous MOS because they can precisely control the porous parameters including pore structure, size, wall thickness and the pore wall surface chemistry. This review aims to present a thorough and critical analysis of the advancements and current state of porous MOS sensitive materials synthesized by non-ionic surfactant template, focusing on their designed synthesis, gas sensing performance and novel mechanism. The classification and definition of common non-ionic templates in the field of gas sensing are summarized, and the advantages of non-ionic templates in the synthesis of porous MOS are discussed. By virtue of the porosity of the as-synthesized high-crystallinity MOS materials, the sensitization strategies of porous MOS materials, including noble metal sensitization, heteroatom doping, heterojunction design, and multicomponent recombination, were also systematically reviewed and discussed. Lastly, we summarized the development trends and challenges of porous MOS sensitive materials synthesized by non-ionic template.
随着纳米材料科学技术的进步,金属氧化物半导体(MOS)被广泛地应用于开发高性能气体传感器,特别是在环境保护、化学工业、食品安全、疾病预防等领域。在各种纳米结构中,多孔MOS材料以其丰富的互连孔、众多的活性位点和高比表面积等突出的特点,尤其有利于在气敏中增强气固相互作用而备受关注。非离子表面活性剂模板可以精确地控制孔隙结构、孔径、壁厚和孔壁表面化学等孔隙参数,是制备多孔MOS的常用模板。本文综述了非离子表面活性剂模板制备多孔MOS敏感材料的研究进展和现状,重点介绍了其设计合成方法、气敏性能和新型机理。综述了气敏领域常用的非离子模板的分类和定义,讨论了非离子模板在多孔MOS合成中的优势。利用所合成的高结晶度MOS材料的多孔性,对贵金属敏化、杂原子掺杂、异质结设计和多组分复合等多孔MOS材料的敏化策略进行了系统的评述和讨论。最后,总结了非离子模板法合成多孔MOS敏感材料的发展趋势和面临的挑战。
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引用次数: 0
Layered double hydroxide-based nanomaterials for supercapacitors and batteries: Strategies and mechanisms 用于超级电容器和电池的层状双氢氧化物纳米材料:策略和机制
IF 37.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-12-06 DOI: 10.1016/j.pmatsci.2024.101410
Chuan Jing, Shengrong Tao, Bin Fu, Lu Yao, Faling Ling, Xiaolin Hu, Yuxin Zhang
Supercapacitors and batteries play crucial roles in sustainable energy storage devices. Layered double hydroxide (LDH) exhibits outstanding adaptability to various electrochemical environments. However, poor electrical conductivity, limited electrochemical activity, and insufficient stability limits the application of LDH. Overcoming these obstacles is essential to fully exploit its potential in large-scale applications. This review extensively examines the crystal structure, properties, preparation, and modification techniques of LDH, as well as its application in different energy storage devices and various in situ characterization methods. The evolution of LDH from 1842 to 2024 is systematically reviewed, with a detailed analysis of recent advancements in characterization and modification methods, including the template method, high entropy alloy, superlattice, vacancy regulation, and defect engineering. Additionally, the review discusses the utilization of LDH in various energy storage devices such as supercapacitors, lithium-ion batteries, air batteries, and halogen ion batteries. Future research directions for LDH are also outlined, such as AI assistance and in-situ characterization. In conclusion, this review provides a comprehensive analysis of the structure, properties, and challenges of LDH in supercapacitors and batteries, aiming to address the current gaps in existing reviews and serve as a valuable reference for researchers and industry professionals.
超级电容器和电池在可持续能源存储装置中起着至关重要的作用。层状双氢氧化物(LDH)对各种电化学环境具有良好的适应性。然而,LDH的导电性差、电化学活性有限、稳定性不足等缺点限制了其应用。克服这些障碍对于充分发挥其在大规模应用中的潜力至关重要。本文综述了LDH的晶体结构、性质、制备和改性技术,以及LDH在不同储能器件和各种原位表征方法中的应用。系统回顾了LDH从1842年到2024年的演变,详细分析了表征和修饰方法的最新进展,包括模板法、高熵合金、超晶格、空位调节和缺陷工程。此外,还讨论了LDH在超级电容器、锂离子电池、空气电池和卤素离子电池等各种储能器件中的应用。展望了LDH未来的研究方向,如人工智能辅助和原位表征。综上所述,本文对LDH在超级电容器和电池中的结构、性能和面临的挑战进行了全面的分析,旨在弥补现有综述中的不足,为研究人员和行业专业人士提供有价值的参考。
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引用次数: 0
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