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Highly efficient, remarkable sensor activity and energy storage properties of MXenes and borophene nanomaterials MXenes和硼罗芬纳米材料的高效、卓越的传感器活性和储能性能
IF 12 2区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2023-06-01 DOI: 10.1016/j.progsolidstchem.2023.100392
Chuan Li , Ayesha Khan Tareen , Karim Khan , JianYu Long , Iftikhar Hussain , Muhammad Farooq Khan , Muhammad Iqbal , Zhongjian Xie , Ye Zhang , Asif Mahmood , Nasir Mahmood , Waqas Ahmad , Han Zhang

Sensors are regarded as a fundamental vector for sustainable development of future advanced civilization. To satisfy the demands of future generations, fabrication of advanced sensor systems integrated with artificial intelligence (AI), fifth generation (5G) connectivity, machine learning (ML), and internet of things (IoTs) is growing very fast. Incorporation of two-dimensional (2D) nanomaterials (NMs) with IoTs/5G/AI/ML technologies has transformed wide range of sensor applications in healthcare, wearable electronics for, safety, environment, military, space, and agriculture sectors. Finally, to operate those sensors we need powerful energy storage devices (ESDs) and hence advance 2D NMs. Since the discovery of MXenes NMs in 2011, and 2D boron nanosheets (NSs) (borophene) on Ag substrates (2015) their research has been accelerated in the domains of advanced nanotechnological world. Borophene and MXenes NMs have came out as an outstanding 2D NMs to construct next generation novel sensors and ESDs due to their novel physicochemical properties and surface functions. By lowering costs, requiring fewer resources (including labor), and minimizing contamination, ML/AI based theoretical simulation has effectively directed the study and manufacturing of improved 2D NMs based sensors/ESDs applications on large scale industrial level. Modern 2D NMs based flexible sensors and ESDs can fundamentally alter the traditional sensing/ESDs technologies since they are adaptable, wearable, intelligent, portable, biocompatible, energy-efficient, self-sustaining, point-of-care, affordable etc. this review summarized the MXenes and borophene NMs synthesis with corresponding achievements, and there advancement, limitations, and challenges in sensors/ESDs technological applications.

传感器被认为是未来先进文明可持续发展的基本载体。为了满足未来几代人的需求,与人工智能(AI)、第五代(5G)连接、机器学习(ML)和物联网(iot)相结合的先进传感器系统的制造正在快速增长。将二维(2D)纳米材料(NMs)与物联网/5G/人工智能/机器学习技术相结合,已经改变了医疗保健、可穿戴电子产品、安全、环境、军事、太空和农业领域的广泛传感器应用。最后,为了操作这些传感器,我们需要强大的能量存储设备(ESDs),从而推进二维NMs。自2011年发现MXenes纳米片和2015年在Ag衬底上发现2D硼纳米片(NSs)(硼苯)以来,它们在先进纳米技术领域的研究得到了加速。Borophene和MXenes纳米材料由于其新颖的物理化学性质和表面功能而成为构建下一代新型传感器和esd的优秀二维纳米材料。通过降低成本,需要更少的资源(包括劳动力),并最大限度地减少污染,基于ML/AI的理论模拟有效地指导了大规模工业水平上改进的基于二维NMs的传感器/ esd应用的研究和制造。现代基于二维纳米材料的柔性传感器和esd具有适应性强、可穿戴、智能、便携、生物相容性强、节能、自我维持、即时护理、价格合理等特点,可以从根本上改变传统的传感/ esd技术。本文综述了MXenes和硼罗芬纳米材料的合成及其相关成果,以及传感器/ esd技术应用的进展、局限性和挑战。
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引用次数: 4
Electrochemical aspects of supercapacitors in perspective: From electrochemical configurations to electrode materials processing 透视超级电容器的电化学方面:从电化学结构到电极材料加工
IF 12 2区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2023-03-01 DOI: 10.1016/j.progsolidstchem.2023.100390
Manickam Minakshi, Kethaki Wickramaarachchi

An electrochemical asymmetric capacitor is a device fabricated with a dissimilar electrode configuration possessing a pseudocapacitive (Faradaic process) or capacitive (non-Faradaic process) nature with different charge storage mechanisms leading to high power and long cycle life. However, the energy density and power density are improved by increasing the specific capacitance and the operating voltage of the device through novel materials processing. In this perspective, electrochemical techniques (in different cell configurations) will be analyzed to divulge the electrochemical aspects of supercapacitors (SCs). The two different active materials for cathode and anode in SCs using abundant, low-cost, environmentally friendly materials processed via facile experimental methods, exploiting green energy transition, are presented. In view of these facts, manganese dioxide (MnO2) with the occurrence of a redox reaction (diffusion-controlled kinetics), and activated carbon (AC) with the electrostatic contribution (surface-controlled kinetics) are paired as positive and negative electrodes that can be principal electrode materials for SCs. MnO2 can be synthesized using different techniques, the electrochemical technique yields the highly pure electrolytic manganese dioxide (EMD). On the other hand, AC is synthesized via the thermochemical conversion process of carbonization and activation. Here, a brief description of the procedures and schematics of the methods to produce EMD and AC in bulk has been summarised. The electrochemical analysis of materials processing inspires and enables simple modifications to the synthesis that could catalyze changes in storage properties.

电化学不对称电容器是一种具有假电容性(法拉第过程)或电容性(非法拉第过程)的不同电极结构的器件,具有不同的电荷存储机制,从而具有高功率和长循环寿命。通过新型材料加工,提高器件的比电容和工作电压,提高了器件的能量密度和功率密度。从这个角度来看,电化学技术(在不同的电池配置下)将被分析,以揭示超级电容器(SCs)的电化学方面。本文介绍了利用丰富的、低成本的、环境友好的材料,通过简单的实验方法加工而成的两种不同的阴极和阳极活性材料,利用绿色能源转型。考虑到这些事实,二氧化锰(MnO2)发生氧化还原反应(扩散控制动力学)和活性炭(AC)的静电贡献(表面控制动力学)配对作为正负极,可以作为主要电极材料的SCs。二氧化锰的合成可以采用不同的工艺,电化学技术可以得到高纯度的电解二氧化锰(EMD)。另一方面,AC是通过炭化活化的热化学转化过程合成的。在此,简要介绍了批量生产EMD和AC的方法的程序和原理图。材料加工过程的电化学分析激发并使简单的合成修改成为可能,从而催化存储性能的变化。
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引用次数: 13
Recent progress on optical properties of double perovskite phosphors 双钙钛矿荧光粉光学性质研究进展
IF 12 2区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2023-03-01 DOI: 10.1016/j.progsolidstchem.2023.100391
Sadhana Yadav , Dinesh Kumar , Ram Sagar Yadav , Akhilesh Kumar Singh

The double perovskite phosphor materials are physically, chemically and thermally stable in nature. The generalized formula of double perovskite is AA'BB'O6 type. The transition metal and lanthanide ions can be doped in the double perovskite materials. The structure of perovskite materials is the key factor for optical properties of the phosphor materials. The transition metal ions produce broad emission band covering from near blue to NIR regions. They can even produce white light. Some combinations of transition metal ions show the energy transfer between them. On the other hand, the lanthanide ions emit sharp and narrow band emissions from UV to NIR regions because their transitions are not affected by the outer environment due to the shielding effect. The combinations of transition metals and lanthanide ions also involve in the energy transfer. This article comprises the recent development on the optical properties of transition metal (Mn4+) and lanthanide metal (Eu3+) doped double perovskite phosphor materials. The optical processes involved in photoluminescence have been discussed in detail. The applications of transition metal and lanthanide doped and co-doped double perovskite phosphor materials have also been summarized herein.

双钙钛矿荧光粉材料具有物理、化学和热稳定性。双钙钛矿的概式为AA'BB'O6型。在双钙钛矿材料中可以掺杂过渡金属和镧系离子。钙钛矿材料的结构是影响其光学性能的关键因素。过渡金属离子产生从近蓝色到近红外的宽发射带。它们甚至可以发出白光。过渡金属离子的某些组合表现出它们之间的能量转移。另一方面,由于屏蔽效应,镧系离子的跃迁不受外界环境的影响,从紫外到近红外区域发射出尖锐的窄带辐射。过渡金属和镧系离子的结合也参与了能量转移。本文综述了过渡金属(Mn4+)和镧系金属(Eu3+)掺杂双钙钛矿磷光材料光学性质的最新研究进展。详细讨论了光致发光的光学过程。本文还综述了过渡金属和镧系掺杂及共掺杂双钙钛矿磷光材料的应用。
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引用次数: 4
Higher lanthanum molybdates: Structures, crystal chemistry and properties 高等钼酸镧:结构、晶体化学和性质
IF 12 2区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2023-03-01 DOI: 10.1016/j.progsolidstchem.2022.100382
Antoine Pautonnier, Sandrine Coste, Maud Barré, Philippe Lacorre

The synthesis, structure and properties of all the compounds known to date in the phase diagram La2O3–MoO3 are reviewed. Special attention is given to the most studied oxide-ion conductor La2Mo2O9, and to fluorite-type La6-xMoO12-3x/2 phases with in-depth analysis of crystallographic interrelation and evolution as a function of the Mo:La ratio. Structural relationships between these fluorites and non-stoechiometric scheelite-type La6Mo8O33 and La2Mo3O12 are also analyzed. The crystal chemical peculiarities of all these phases are reported, together with their chemical and physical characteristics, as well as possible application fields. Aside ionic conduction, catalysis, luminescence and giant electrostriction are some of the many properties displayed by lanthanum molybdates. Fostered by their uncovering, the renewed interest in this phase diagram led to the recent identification of a few additional, more structurally isolated phases, with higher Mo amount. Their structures are also presented, even though their properties have not yet been fully explored. The richness of the explored system, both in terms of existing structural characteristics and properties, makes it an exciting area to dig and unveil. As far as atomic distribution and oxide-ion conduction are concerned, both global trends and singular features are depicted, which might promote insightful investigations about the specificity or universality of the surveyed behaviours.

综述了La2O3-MoO3相图中已知化合物的合成、结构和性质。特别关注了研究最多的氧化离子导体La2Mo2O9和萤石型La6-xMoO12-3x/2相,并深入分析了晶体学的相互关系和演变作为Mo:La比的函数。并分析了这些萤石与非化学计量白钨矿La6Mo8O33和La2Mo3O12的结构关系。报道了这些相的晶体化学特性,以及它们的化学和物理特性,以及可能的应用领域。钼酸镧除具有离子导电性外,还具有催化、发光和超电致伸缩等特性。由于它们的发现,对这一相图重新产生的兴趣导致最近发现了一些额外的、结构上更孤立的、Mo含量更高的相。它们的结构也被呈现出来,尽管它们的性质尚未被充分探索。勘探系统的丰富性,无论是在现有的结构特征和性质方面,都使其成为一个令人兴奋的挖掘和揭示领域。就原子分布和氧化离子传导而言,描述了整体趋势和单一特征,这可能有助于对所调查行为的特异性或普遍性进行有见地的研究。
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引用次数: 2
Recent advances and prospects of metal oxynitrides for supercapacitor 超级电容器用金属氮氧化物的研究进展与展望
IF 12 2区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2022-12-01 DOI: 10.1016/j.progsolidstchem.2022.100381
Anit Joseph, Tiju Thomas

There has been a search for new supercapacitor materials that offer superior storage qualities during the past ten years, owing to the needs of the electrochemical energy storage sector. Supercapacitors, which have a higher power density than batteries but a lower energy density, are among the most promising energy storage technologies. Creating innovative materials that increase energy storage efficiency is essential to fulfilling the world's growing energy needs. Recent research has centred on the application of various electrode materials in supercapacitors. This review discusses the parameters of an efficient supercapacitor and the usage of metal oxynitrides as electrode materials. Due to their high cyclability (up to 105 cycles), strong intrinsic conductivity (30000–35000 S cm−1), good wettability, corrosion resistance, and chemical inertness, metal oxynitrides are considered prospective candidates for electrochemical energy storage. This review elaborates on the recent advances in transition metal oxynitrides and compares the properties of transition metal oxynitrides with post-transition and non-transition metal oxynitrides in supercapacitor applications. We envision future paths for this category of energy storage materials in light of this critical study.

在过去的十年里,由于电化学储能领域的需要,人们一直在寻找能够提供卓越存储质量的新型超级电容器材料。超级电容器具有比电池更高的功率密度,但能量密度较低,是最有前途的储能技术之一。创造能够提高能源储存效率的创新材料对于满足世界日益增长的能源需求至关重要。最近的研究集中在各种电极材料在超级电容器中的应用。本文综述了高效超级电容器的参数及金属氮氧化物作为电极材料的应用。由于其高可循环性(高达105次循环),强固有电导率(30,000 - 35000 S cm−1),良好的润湿性,耐腐蚀性和化学惰性,金属氮氧化物被认为是电化学储能的潜在候选者。本文综述了过渡金属氮氧化物的最新研究进展,并比较了过渡金属氮氧化物与后过渡金属氮氧化物和非过渡金属氮氧化物在超级电容器中的应用。根据这项重要的研究,我们设想了这类储能材料的未来发展道路。
{"title":"Recent advances and prospects of metal oxynitrides for supercapacitor","authors":"Anit Joseph,&nbsp;Tiju Thomas","doi":"10.1016/j.progsolidstchem.2022.100381","DOIUrl":"https://doi.org/10.1016/j.progsolidstchem.2022.100381","url":null,"abstract":"<div><p><span><span><span>There has been a search for new supercapacitor materials that offer superior storage qualities during the past ten years, owing to the needs of the electrochemical energy storage sector. </span>Supercapacitors, which have a higher power density than batteries but a lower </span>energy density<span>, are among the most promising energy storage technologies. Creating innovative materials that increase energy storage efficiency is essential to fulfilling the world's growing energy needs. Recent research has centred on the application of various electrode materials in supercapacitors. This review discusses the parameters of an efficient supercapacitor and the usage of metal oxynitrides as electrode materials. Due to their high cyclability (up to 10</span></span><sup>5</sup><span> cycles), strong intrinsic conductivity (30000–35000 S cm</span><sup>−1</sup><span><span><span>), good wettability, </span>corrosion resistance, and chemical inertness, metal oxynitrides are considered prospective candidates for electrochemical energy storage. This review elaborates on the recent advances in transition metal oxynitrides and compares the properties of transition metal oxynitrides with post-transition and non-transition metal oxynitrides in supercapacitor applications. We envision future paths for this category of </span>energy storage materials in light of this critical study.</span></p></div>","PeriodicalId":415,"journal":{"name":"Progress in Solid State Chemistry","volume":"68 ","pages":"Article 100381"},"PeriodicalIF":12.0,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"1677300","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 7
Current challenges and developments of inorganic/organic materials for the abatement of toxic nitrogen oxides (NOx) – A critical review 无机/有机材料用于减少有毒氮氧化物(NOx)的当前挑战和发展-综述
IF 12 2区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2022-12-01 DOI: 10.1016/j.progsolidstchem.2022.100380
Tamanna Harihar Panigrahi , Satya Ranjan Sahoo , Gajiram Murmu , Dipak Maity , Sumit Saha

Nitrogen oxides (NOx) are toxic gases produced from various anthropogenic and natural sources. It causes acid rain, ozone depletion, photochemical smog, corrosion of buildings, and various health hazards. The removal of these toxic gases is vital to safeguard the health of living organisms and the air quality on the earth. These can be done by complying with government regulations and using efficient gas capture techniques in industries. However, the challenge remains in arresting these toxic gases with high efficiency, selectivity, and sustainability using low-cost materials. The present review summarizes the recent advances in the detention and diminution of NOx (NO2, NO, and N2O) by inorganic and organic materials. We have discussed different processes for capturing nitrogen dioxides (NO2) using various materials namely metal-organic framework, activated carbon, functionalized metal oxides, transition metals, and zeolites. Moreover, a variety of materials such as ionic liquid, deep eutectic liquid, and selective catalytic reduction-based materials, including metal oxides and zeolites, are described for the abatement of nitric oxides (NO). Finally, the methods of capturing nitrous oxides (N2O) are deliberated, including direct and photocatalytic decomposition, followed by various adsorbent materials. Overall, different materials/methods and mechanisms for NOx detention and/or abatement are well presented and their efficiency is compared in this review. The present article also showcases all the examples of recently developed high-performance materials for efficient NOx capturing/abating.

氮氧化物(NOx)是由各种人为和自然来源产生的有毒气体。它造成酸雨、臭氧损耗、光化学烟雾、建筑物腐蚀和各种健康危害。清除这些有毒气体对保护生物的健康和地球上的空气质量至关重要。这些可以通过遵守政府法规和在工业中使用有效的气体捕获技术来实现。然而,利用低成本材料高效、选择性和可持续性地捕获这些有毒气体仍然是一个挑战。本文综述了无机材料和有机材料在滞留和减少NOx (NO2、NO和N2O)方面的最新进展。我们讨论了利用不同材料捕获二氧化氮(NO2)的不同方法,这些材料包括金属有机骨架、活性炭、功能化金属氧化物、过渡金属和沸石。此外,各种材料,如离子液体、深度共晶液体和选择性催化还原材料,包括金属氧化物和沸石,都被描述为减少一氧化氮(NO)。最后,讨论了捕获氧化亚氮(N2O)的方法,包括直接分解和光催化分解,然后是各种吸附材料。总的来说,不同的材料/方法和机制的氮氧化物滞留和/或减排很好地提出,并在这篇综述中比较了它们的效率。本文还展示了最近开发的用于高效捕获/减少氮氧化物的高性能材料的所有示例。
{"title":"Current challenges and developments of inorganic/organic materials for the abatement of toxic nitrogen oxides (NOx) – A critical review","authors":"Tamanna Harihar Panigrahi ,&nbsp;Satya Ranjan Sahoo ,&nbsp;Gajiram Murmu ,&nbsp;Dipak Maity ,&nbsp;Sumit Saha","doi":"10.1016/j.progsolidstchem.2022.100380","DOIUrl":"https://doi.org/10.1016/j.progsolidstchem.2022.100380","url":null,"abstract":"<div><p><span>Nitrogen oxides<span> (NOx) are toxic gases produced from various anthropogenic and natural sources. It causes acid rain, ozone depletion, photochemical smog, corrosion of buildings, and various health hazards. The removal of these toxic gases is vital to safeguard the health of living organisms and the air quality on the earth. These can be done by complying with government regulations and using efficient gas capture techniques in industries. However, the challenge remains in arresting these toxic gases with high efficiency, selectivity, and sustainability using low-cost materials. The present review summarizes the recent advances in the detention and diminution of NOx (NO</span></span><sub>2</sub><span>, NO, and N</span><sub>2</sub>O) by inorganic and organic materials. We have discussed different processes for capturing nitrogen dioxides (NO<sub>2</sub><span><span>) using various materials namely metal-organic framework, activated carbon, functionalized metal oxides, transition metals, and </span>zeolites<span>. Moreover, a variety of materials such as ionic liquid<span>, deep eutectic liquid, and selective catalytic reduction-based materials, including metal oxides and zeolites, are described for the abatement of nitric oxides (NO). Finally, the methods of capturing nitrous oxides (N</span></span></span><sub>2</sub>O) are deliberated, including direct and photocatalytic decomposition, followed by various adsorbent materials. Overall, different materials/methods and mechanisms for NOx detention and/or abatement are well presented and their efficiency is compared in this review. The present article also showcases all the examples of recently developed high-performance materials for efficient NOx capturing/abating.</p></div>","PeriodicalId":415,"journal":{"name":"Progress in Solid State Chemistry","volume":"68 ","pages":"Article 100380"},"PeriodicalIF":12.0,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"1527683","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 7
Bond valence sum analysis of pyrochlore oxides including the novel dielectric Te6+ pyrochlores: ABiMTeO7-y (A = Cd, Ca; M = Cr, Ga, Sc, In, Fe) 新型介质Te6+焦绿石:ABiMTeO7-y (A = Cd, Ca)M = Cr, Ga, Sc, In, Fe)
IF 12 2区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2022-12-01 DOI: 10.1016/j.progsolidstchem.2022.100378
Elizabeth Sobalvarro Converse , Gabriella King , Jun Li , M.A. Subramanian

Bond valence sum analysis is a powerful tool used in evaluating and validating crystal structures; especially when those structures are complex in nature. The pyrochlore structure type is versatile in not only the unique bonding that it exhibits, but also in the properties that results from the structure. This paper aims to center the discussion of evaluating the pyrochlore structure using the bond valence sum method. In this study, novel quaternary pyrochlores with a general stoichiometry of ABiMTeO7 (A = Cd, Ca; M = Cr, Ga, Sc, In, Fe) were synthesized and characterized for their structural, magnetic, and dielectric properties. Two representative compounds within this series of pyrochlores, BiCaFeTeO7 and BiCdFeTeO7, were structurally characterized utilizing a combination of high-resolution synchrotron X-ray diffraction and neutron diffraction revealing oxygen deficient pyrochlore systems which were off from the expected stoichiometry with respect to the M site. The A site of both pyrochlores were found to be moved off-center from the expected 16d site to the 96h displaced position at a magnitude of 0.25 Å and 0.22 Å for the Bi/Ca and Bi/Cd systems, respectively. These structures were evaluated using the bond valence sum method and compared with trends in the literature. The properties are also reported for the Bi/Ca system for the first time, showing relatively high dielectric constants with a low dielectric loss which are primarily independent of frequency and temperature. The magnetic measurements for the Bi/Ca system for the magnetic substitutions reveal a paramagnet and antiferromagnetic properties for the Fe and Cr analogs, respectively. The novel BiCaMTeO7 quaternary pyrochlore system shows great promise as an emerging dielectric material.

键价和分析是评价和验证晶体结构的有力工具;尤其是当这些结构本质上很复杂的时候。焦绿石结构类型是通用的,不仅在其独特的键,而且在其结构的结果性质。本文主要讨论了用键价和法评价焦绿石结构的方法。在本研究中,具有ABiMTeO7 (a = Cd, Ca;合成了M = Cr, Ga, Sc, In, Fe),并对其结构,磁性和介电性能进行了表征。利用高分辨率同步x射线衍射和中子衍射的结合,对该系列中两个具有代表性的化合物BiCaFeTeO7和BiCdFeTeO7进行了结构表征,揭示了与M位点的化学计量学不同的缺氧焦绿石系统。在Bi/Ca和Bi/Cd体系中,两种焦绿石的A位点从预期的16d位置偏移到96h位置,其偏移幅度分别为0.25 Å和0.22 Å。用键价和法对这些结构进行了评价,并与文献趋势进行了比较。Bi/Ca体系的性质也首次被报道,表现出相对较高的介电常数和较低的介电损耗,主要不受频率和温度的影响。磁取代的Bi/Ca体系的磁测量结果显示,Fe和Cr类似物分别具有顺磁性和反铁磁性。新型BiCaMTeO7季焦氯化物体系作为一种新兴的介电材料,具有广阔的应用前景。
{"title":"Bond valence sum analysis of pyrochlore oxides including the novel dielectric Te6+ pyrochlores: ABiMTeO7-y (A = Cd, Ca; M = Cr, Ga, Sc, In, Fe)","authors":"Elizabeth Sobalvarro Converse ,&nbsp;Gabriella King ,&nbsp;Jun Li ,&nbsp;M.A. Subramanian","doi":"10.1016/j.progsolidstchem.2022.100378","DOIUrl":"https://doi.org/10.1016/j.progsolidstchem.2022.100378","url":null,"abstract":"<div><p><span>Bond valence sum analysis is a powerful tool used in evaluating and validating crystal structures; especially when those structures are complex in nature. The pyrochlore structure type is versatile in not only the unique bonding that it exhibits, but also in the properties that results from the structure. This paper aims to center the discussion of evaluating the pyrochlore structure using the bond valence sum method. In this study, novel quaternary pyrochlores with a general stoichiometry of </span><em>A</em>Bi<em>M</em>TeO<sub>7</sub> (<em>A</em> = Cd, Ca; <em>M</em><span> = Cr, Ga, Sc, In, Fe) were synthesized and characterized for their structural, magnetic, and dielectric properties. Two representative compounds within this series of pyrochlores, BiCaFeTeO</span><sub>7</sub> and BiCdFeTeO<sub>7</sub><span>, were structurally characterized utilizing a combination of high-resolution synchrotron X-ray diffraction and neutron diffraction revealing oxygen deficient pyrochlore systems which were off from the expected stoichiometry with respect to the </span><em>M</em> site. The <em>A</em> site of both pyrochlores were found to be moved off-center from the expected 16<em>d</em> site to the 96<em>h</em><span> displaced position at a magnitude of 0.25 Å and 0.22 Å for the Bi/Ca and Bi/Cd systems, respectively. These structures were evaluated using the bond valence sum method and compared with trends in the literature. The properties are also reported for the Bi/Ca system for the first time, showing relatively high dielectric constants with a low dielectric loss which are primarily independent of frequency and temperature. The magnetic measurements for the Bi/Ca system for the magnetic substitutions reveal a paramagnet and antiferromagnetic properties for the Fe and Cr analogs, respectively. The novel BiCa</span><em>M</em>TeO<sub>7</sub> quaternary pyrochlore system shows great promise as an emerging dielectric material.</p></div>","PeriodicalId":415,"journal":{"name":"Progress in Solid State Chemistry","volume":"68 ","pages":"Article 100378"},"PeriodicalIF":12.0,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"1811649","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Structure and functional properties of oxides in the BaO–Al2O3 system: Phosphors, pigments and catalysts BaO-Al2O3体系中氧化物的结构和功能性质:荧光粉、颜料和催化剂
IF 12 2区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2022-12-01 DOI: 10.1016/j.progsolidstchem.2022.100379
Zhiwei Wang , Yuqian Wang , M.A. Subramanian , Peng Jiang

Oxides such as BaAl12O19 and BaAl2O4 in the BaO–Al2O3 system demonstrate potential for optical applications due to the abundant tetrahedral and octahedral sites in their structures, as well as their high thermal stability, good chemical stability, high surface area and strong light absorption capacity. Rare earth element doping or transition metal ion doping in oxides in the BaO–Al2O3 system contributes to promising photoluminescent, visible color and catalytic properties. In this review, the structures of BaAl12O19, BaAl2O4, Ba3Al2O6, Ba4Al2O7, and Ba7Al2O10 in the BaO–Al2O3 system are introduced. Their applications in phosphors, pigments and catalysts are also summarized herein.

BaO-Al2O3体系中的BaAl12O19和BaAl2O4等氧化物由于其结构中含有丰富的四面体和八面体位,并且具有高的热稳定性、良好的化学稳定性、高的比表面积和强的光吸收能力,具有潜在的光学应用前景。在BaO-Al2O3体系的氧化物中掺杂稀土元素或过渡金属离子,具有良好的光致发光、显色和催化性能。本文介绍了BaAl12O19、BaAl2O4、Ba3Al2O6、Ba4Al2O7和Ba7Al2O10在BaO-Al2O3体系中的结构。综述了它们在荧光粉、颜料和催化剂等方面的应用。
{"title":"Structure and functional properties of oxides in the BaO–Al2O3 system: Phosphors, pigments and catalysts","authors":"Zhiwei Wang ,&nbsp;Yuqian Wang ,&nbsp;M.A. Subramanian ,&nbsp;Peng Jiang","doi":"10.1016/j.progsolidstchem.2022.100379","DOIUrl":"https://doi.org/10.1016/j.progsolidstchem.2022.100379","url":null,"abstract":"<div><p>Oxides such as BaAl<sub>12</sub>O<sub>19</sub> and BaAl<sub>2</sub>O<sub>4</sub> in the BaO–Al<sub>2</sub>O<sub>3</sub><span> system demonstrate potential for optical applications due to the abundant tetrahedral and octahedral sites in their structures, as well as their high thermal stability, good chemical stability, high surface area and strong light absorption<span><span> capacity. Rare earth element doping or transition </span>metal ion doping in oxides in the BaO–Al</span></span><sub>2</sub>O<sub>3</sub> system contributes to promising photoluminescent, visible color and catalytic properties. In this review, the structures of BaAl<sub>12</sub>O<sub>19</sub>, BaAl<sub>2</sub>O<sub>4</sub>, Ba<sub>3</sub>Al<sub>2</sub>O<sub>6</sub>, Ba<sub>4</sub>Al<sub>2</sub>O<sub>7</sub>, and Ba<sub>7</sub>Al<sub>2</sub>O<sub>10</sub> in the BaO–Al<sub>2</sub>O<sub>3</sub> system are introduced. Their applications in phosphors, pigments and catalysts are also summarized herein.</p></div>","PeriodicalId":415,"journal":{"name":"Progress in Solid State Chemistry","volume":"68 ","pages":"Article 100379"},"PeriodicalIF":12.0,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"1811650","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Recent advance in MXenes: New horizons in electrocatalysis and environmental remediation technologies MXenes的最新进展:电催化与环境修复技术的新视野
IF 12 2区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2022-12-01 DOI: 10.1016/j.progsolidstchem.2022.100370
Karim Khan , Ayesha Khan Tareen , Muhammad Iqbal , Ye Zhang , Asif Mahmood , Nasir Mahmood , Jinde Yin , Rabia Khatoon , Han Zhang

A strong electrocatalytic activity of the MXenes nanomaterials (NMs) has gained a lot of concentration as cutting edge materials in a variety of electrocatalytic devices in a broad range of industrial uses. In recent years, the production and utilization of the MXenes NMs as an electrocatalysts has progressed, with more than 50 distinct variants found and used. We reviewed and discussed in this article the latest detail progress in the synthesis, selected properties and potential applications of the MXenes as an electrocatalysts for the hydrogen evolution reaction (HER), oxygen evolution reaction (OER), overall water splitting, oxygen reduction reaction (ORR), nitrogen reduction reaction (N2RR), CO2 reduction reaction (CO2RR) etc. We will also discuss the numerous approaches for increasing MXenes electrocatalytic activity for target products. At the end, we will also talk about the present obstacles and future suggestions for the MXenes as HER, ORR, OER, NO2RR and CO2RR electrocatalysts.

具有较强电催化活性的MXenes纳米材料(NMs)作为各种电催化装置的前沿材料在广泛的工业应用中得到了广泛的关注。近年来,MXenes NMs作为电催化剂的生产和利用取得了进展,已经发现和使用了50多种不同的变体。本文综述了MXenes作为析氢反应(HER)、析氧反应(OER)、全水分解、氧还原反应(ORR)、氮还原反应(N2RR)、CO2还原反应(CO2RR)等电催化剂的合成、性能及应用前景等方面的最新进展。我们还将讨论提高目标产物MXenes电催化活性的多种方法。最后,我们还讨论了MXenes作为HER、ORR、OER、NO2RR和CO2RR电催化剂目前存在的障碍和未来的建议。
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引用次数: 4
A review on recent developments in structural modification of TiO2 for food packaging applications 二氧化钛在食品包装中的结构改性研究进展
IF 12 2区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2022-09-01 DOI: 10.1016/j.progsolidstchem.2022.100369
Piyumi Kodithuwakku , Dilushan R. Jayasundara , Imalka Munaweera , Randika Jayasinghe , Tharanga Thoradeniya , Manjula Weerasekera , Pulickel M. Ajayan , Nilwala Kottegoda

Structural modification of titanium dioxide has offered a novel template to develop advanced functional materials which demonstrate visible light photocatalytic activity. There had been many attempts to modify the band gap of TiO2 in order to realize its potential as an antimicrobial material in food coatings and packaging. This review gathers most recent advancements of developing TiO2 based functional nanohybrids which include doping with metals, non-metals, co-doping, and development of hybrids with 2-D nanomaterials. In particular, nanohybrids prepared with of TiO2 with graphene incorporation has opened up a novel platform to reduce the band gap while minimizing the inherent drawback of electron pair recombination in TiO2. In this review, critical analysis of the recent literature on the mechanisms involved in structural modifications are discussed broadly and the electronic and functional properties of resulting materials are presented with a greater scientific depth. In addition, the available structural modification techniques have been compared with a particular emphasis on food preservation and post-harvest loss mitigation applications. More importantly, an outlook on the industrial applications, future directions and challenges have been suggested and discussed.

二氧化钛的结构改性为开发具有可见光催化活性的先进功能材料提供了新的模板。为了实现二氧化钛作为食品涂料和包装中的抗菌材料的潜力,人们已经尝试了许多方法来修饰二氧化钛的带隙。本文综述了近年来基于TiO2的功能纳米杂化材料的研究进展,包括金属掺杂、非金属掺杂、共掺杂以及与二维纳米材料的杂化材料的研究进展。特别是,石墨烯掺杂TiO2制备的纳米杂化物为减小带隙开辟了一个新的平台,同时最大限度地减少了TiO2中电子对重组的固有缺点。在这篇综述中,对涉及结构修饰的机制的最新文献进行了广泛的分析,并以更大的科学深度介绍了所产生材料的电子和功能特性。此外,还将现有的结构改性技术与特别强调食品保存和减少收获后损失的应用进行了比较。并对其工业应用前景、未来发展方向和面临的挑战进行了展望。
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引用次数: 6
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Progress in Solid State Chemistry
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