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Radiation-induced natural convection in volumetrically absorbing solar thermal receivers: An experimental study 体积吸收型太阳能热接收器中的辐射诱导自然对流:实验研究
IF 6.7 2区 工程技术 Q1 Materials Science Pub Date : 2024-06-14 DOI: 10.1016/j.solener.2024.112661
Muhammad Taha Manzoor , Charles Wetaski , Melanie Tetreault-Friend

Volumetric solar thermal receivers are composed of semi-transparent media that are irradiated from the top and absorb solar radiation directly. Previous theoretical studies have suggested that these receivers can capture a high percentage of the incoming energy by eliminating temperature differences between the absorber and the heat transfer fluid. However, the complex interaction between radiation-induced natural convection and volumetric heating which governs the receiver thermofluid behavior has never been experimentally investigated. We present a comprehensive experimental study in which these interactions are investigated from a design perspective. A 6.5 kW solar simulator is installed in a beam-down configuration, and molten nitrate salts are used as base fluids to replicate real-life conditions. Key receiver parameters, namely the fluid absorption coefficient, receiver height, surface emissivity, input flux and heating time are varied experimentally to investigate their influence on operating regime transitions and capture efficiency. Receivers dominated by natural convection are shown to achieve capture efficiencies up to 20 times higher than those dominated by conduction. The χ2 goodness-of-fit test is employed to demonstrate that theoretical predictions regarding the receiver physics are reasonably accurate and existing models can be effectively used for design optimization. Finally, a proof of concept for chloride salts-based high-temperature volumetric receivers is presented. The design insights obtained from the experiments are summarized as design guidelines for future commercial scale-up.

体积式太阳能热接收器由半透明介质组成,从顶部照射并直接吸收太阳辐射。以往的理论研究表明,这种接收器可以通过消除吸收器和传热流体之间的温度差来捕获高比例的入射能量。然而,对于辐射诱导的自然对流与体积加热之间复杂的相互作用,以及对接收器热流体行为的影响,还从未进行过实验研究。我们介绍了一项综合实验研究,从设计角度对这些相互作用进行了研究。我们安装了一个 6.5 千瓦的太阳能模拟器,采用波束向下配置,并使用熔融硝酸盐作为基础流体来模拟现实条件。通过实验改变关键的接收器参数,即流体吸收系数、接收器高度、表面发射率、输入通量和加热时间,以研究它们对工作状态转换和捕获效率的影响。结果表明,以自然对流为主的接收器的捕获效率比以传导为主的接收器高 20 倍。采用 χ2 拟合优度测试证明,有关接收器物理特性的理论预测相当准确,现有模型可有效用于优化设计。最后,介绍了基于氯盐的高温体积式接收器的概念验证。从实验中获得的设计启示被总结为未来商业放大的设计指南。
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引用次数: 0
Investigation of the effect of dimensional and non-dimensional parameters on the performance of pitch-varied staggered arranged dimple solar air heaters 探究尺寸和非尺寸参数对间距不同的交错排列的窝状太阳能空气加热器性能的影响
IF 6.7 2区 工程技术 Q1 Materials Science Pub Date : 2024-06-13 DOI: 10.1016/j.solener.2024.112663
Sudharani Panda, Rakesh Kumar

In this study, the efficacy of a single pass, single glazed, five different types of absorber plate incorporated solar air heater (SAH) was experimentally examined in outdoor test conditions on alternative days. The experiment was carried out for flat plate solar air heater (FPSAH) and staggered arranged dimple imprinted absorber plate solar air heater (SDPSAH) maintained at four different pitch ratios (Pt/Pl: 1.0, 1.11, 1.25, and 1.67) by varying the air mass flow rate (ma) from 0.01-0.05 kg/s (corresponding Re range: 1971.66–10466.45). The results show that the performance of both FPSAH and SDPSAH improves when the ma increases. For the tested range of ma, SDPSAH outperforms FPSAH regardless of pitch ratio. SDPSAH, with a pitch ratio of 1.25, on the other hand, has a greater air temperature difference, efficiencies, heat removal factor, collector efficiencies, and averaged Nusselt number (Nuavg) while having a lower global heat loss coefficient and top loss. The Nuavg of SDPSAH at a pitch ratio of 1.25 is 1.01–1.17, 1.16–1.24, 1.26–1.57, and 1.44–1.88 times higher than SDPSAH at pitch ratios 1.0, 1.11, 1.67, and FPSAH, respectively. The higher averaged friction factor (favg) of 0.0443 is attained for SDPSAH at a pitch ratio of 1.25 due to the presence of the largest number of dimples. The ηth and ηd of SDPSAH at a pitch ratio of 1.25 are 34.5 and 35.5 % higher than those of FPSAH. The global heat loss coefficient of SDPSAH at pitch ratios 1.11, 1.0, and 1.67 is 1.05–1.84, 1.09–2.15, and 1.11–2.92 times higher, respectively, than that of SDPSAH at a pitch ratio of 1.25.

在这项研究中,我们在室外测试条件下对单通道、单层玻璃、五种不同类型的吸收板太阳能空气加热器(SAH)的功效进行了实验研究。实验针对平板式太阳能空气加热器(FPSAH)和交错排列的凹陷印记吸收板式太阳能空气加热器(SDPSAH)进行,保持四种不同的间距比(Pt/Pl:1.0、1.11、1.25 和 1.67),空气质量流量(ma)在 0.01-0.05 kg/s 之间变化(相应的 Re 范围:1971.66-10466.45)。结果表明,当 ma 增加时,FPSAH 和 SDPSAH 的性能都有所改善。在测试的 ma 范围内,无论螺距比如何,SDPSAH 的性能都优于 FPSAH。另一方面,间距比为 1.25 的 SDPSAH 具有更大的空气温差、效率、散热系数、集热器效率和平均努塞尔特数(Nuavg),同时具有更低的全局热损失系数和顶部损失。间距比为 1.25 的 SDPSAH 的 Nuavg 分别是间距比为 1.0、1.11、1.67 和 FPSAH 的 SDPSAH 的 1.01-1.17、1.16-1.24、1.26-1.57 和 1.44-1.88 倍。由于存在最多的凹痕,SDPSAH 在间距比为 1.25 时的平均摩擦因数(favg)为 0.0443。间距比为 1.25 时,SDPSAH 的 ηth 和 ηd 分别比 FPSAH 高 34.5% 和 35.5%。间距比为 1.11、1.0 和 1.67 时,SDPSAH 的总体热损失系数分别是间距比为 1.25 时 SDPSAH 的 1.05-1.84 倍、1.09-2.15 倍和 1.11-2.92 倍。
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引用次数: 0
Performance and configuration optimization for a Grid-Connected PV power supply system with Demand-Supply matching in a data center’s centralized Water-Cooling system 数据中心集中式水冷系统中具有供需匹配功能的并网光伏供电系统的性能和配置优化
IF 6.7 2区 工程技术 Q1 Materials Science Pub Date : 2024-06-13 DOI: 10.1016/j.solener.2024.112667
Rang Tu, Lu Wang, Lanbin Liu

The cooling system of a data center accounts for a significant part of its energy consumption, and the adoption of solar energy can reduce its power demand from the grid. This paper investigated the optimal configuration of a grid-connected PV power supply system to a data center’s centralized water-cooling system. Firstly, mathematical models for photovoltaic panels and storage batteries were established. Then, two operating strategies were proposed, respectively, for two systems with and without storage batteries, and the supply–demand matching performances were studied. With storage batteries, mismatch problem between electricity generated by photovoltaic panels and electricity consumed by the water-cooling system can be significantly improved. Utilization ratio of electricity generated by photovoltaic panels was increased by up to 27.64 % in the discussed typical days. Annual utilization of electricity generated by photovoltaic panels can also be significantly increased, especially when heat dissipation density is small. Lastly, the optimal configurations were discussed. To reduce carbon emission, number of battery groups were recommended for different heat dissipation density and number of photovoltaic panels. Full life-cycle carbon reduction ranged from 1.77 to 3.71 tCO2/m2 and carbon emissions reduced from 14.23 to 62.14 % as compared with the traditional system. As for the economic performance, the recommended number of photovoltaic panels are 798, 1330 and 1589 for heat dissipation density being 500, 800 and 1100 W/m2, respectively. While the recommended number of batteries was 0 if unit price of batteries is higher than 11.1 ten thousand yuan/group.

数据中心的冷却系统占其能源消耗的很大一部分,采用太阳能可以减少其对电网的电力需求。本文研究了并网光伏供电系统与数据中心集中水冷系统的最佳配置。首先,建立了光伏电池板和蓄电池的数学模型。然后,分别针对有蓄电池和无蓄电池的两个系统提出了两种运行策略,并研究了其供需匹配性能。有了蓄电池,光伏电池板发电与水冷系统耗电之间的不匹配问题可以得到明显改善。在讨论的典型天数中,光伏电池板发电量的利用率最高提高了 27.64%。光伏电池板发电的年利用率也可显著提高,尤其是在散热密度较小时。最后,讨论了最佳配置。为了减少碳排放,针对不同的散热密度和光伏板数量,推荐了电池组的数量。与传统系统相比,全生命周期碳减排量从 1.77 吨二氧化碳/平方米到 3.71 吨二氧化碳/平方米不等,碳排放量从 14.23% 到 62.14%不等。在经济效益方面,建议的光伏板数量分别为 798、1330 和 1589 块,散热密度分别为 500、800 和 1100 W/m2。如果电池单价高于 11.1 万元/组,则建议电池数量为 0。
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引用次数: 0
Solar irradiance variability around Asia Pacific: Spatial and temporal perspective for active use of solar energy 亚太地区太阳辐照度变化:积极利用太阳能的时空视角
IF 6.7 2区 工程技术 Q1 Materials Science Pub Date : 2024-06-13 DOI: 10.1016/j.solener.2024.112678
Kalingga Titon Nur Ihsan , Hideaki Takenaka , Atsushi Higuchi , Anjar Dimara Sakti , Ketut Wikantika

This study discusses solar irradiance variability in the spatial and temporal domains for the active use of solar energy. The spatial domain was calculated using the difference between one location and another in a focused small tile area. The principal component analysis (PCA) was used for this analysis in the spatial and temporal domain. The Umbrella Effect Index (UI) was calculated to determine the probability of an umbrella effect event within a specific time range. This study discusses solar irradiance variability using solar irradiance data analyzed every 10 min from high-temporal observations of geostationary satellites in the Asia-Pacific region. This study shows that solar heterogeneity around the Asia-Pacific ranges from 0–135 W/m2 with a high tendency in the area around the equator and highlands. In addition, this study also shows that the Asia Pacific region has umbrella effect events of approximately 50–2224 h/year with an index ranging approximately 0–0.34. This study presents the annual analysis and seasonal trends of solar irradiance variability over the entire study area. Determining seasonal trends is important because electricity demand fluctuates significantly as seasons progress. An integrated analysis of heterogeneity and UI revealed trends in spatiotemporal variations in solar irradiance. This approach provides useful information for optimizing and managing the locations for installing solar power plants. Moreover, an evaluation of existing solar power plants is presented. Evaluations based on spatiotemporal data reveal impossible characteristics using traditional approaches that use long-term simple averages or typical solar irradiance data. This research shows the distributed photovoltaic (PV) system in wide area can increase the stability of solar energy supply to the grid.

本研究讨论了太阳能辐照度在空间和时间域的变化,以便积极利用太阳能。空间域的计算方法是在一个集中的小瓦片区域内,利用一个地点和另一个地点之间的差异。空间域和时间域的分析采用了主成分分析法(PCA)。伞状效应指数(UI)的计算是为了确定在特定时间范围内发生伞状效应事件的概率。本研究利用亚太地区地球静止卫星高时间观测数据中每 10 分钟分析一次的太阳辐照度数据,讨论太阳辐照度的变异性。该研究表明,亚太地区的太阳异质性在 0-135 W/m2 之间,赤道和高原地区的太阳异质性较高。此外,这项研究还表明,亚太地区每年约有 50-2224 h 的伞状效应事件,指数范围约为 0-0.34。本研究介绍了整个研究区域太阳辐照度变化的年度分析和季节趋势。确定季节趋势非常重要,因为电力需求会随着季节的变化而大幅波动。对异质性和 UI 的综合分析揭示了太阳辐照度的时空变化趋势。这种方法为优化和管理太阳能发电站的安装地点提供了有用的信息。此外,还介绍了对现有太阳能发电厂的评估。基于时空数据的评估揭示了使用长期简单平均值或典型太阳辐照度数据的传统方法无法实现的特性。这项研究表明,广域分布式光伏(PV)系统可以提高向电网供应太阳能的稳定性。
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引用次数: 0
A circular economy roadmap for solar photovoltaics 太阳能光伏发电循环经济路线图
IF 6.7 2区 工程技术 Q1 Materials Science Pub Date : 2024-06-13 DOI: 10.1016/j.solener.2024.112580
Stephanie L. Shaw, Mitchell L. Rencheck, Gabriella A. Siegfried, Cara Libby

Solar photovoltaics (PV) and other clean energy technologies are increasingly being deployed as an environmentally responsible and economic approach to energy system decarbonization. The shift from fossil fuel-centric to material-centric equipment has also shifted the consideration and management of environmental and societal impacts across the technology life cycle. Societal desire to reduce raw material needs, mitigate supply chain social and governance challenges, and take advantage of the reuse and recycling capabilities of materials has enhanced interest in regenerative economic models, called circular economies (CEs). A recent critical review documented that solar PV is on a “path towards increased circularity,” but the need remains to expand activities beyond recycling to a broader set of environmental and policy activities to fully realize the benefits [1,2]. Thus, the goal of this research roadmap is to facilitate and accelerate the transition to a solar PV CE by 1) highlighting current opportunities for PV value chain stakeholders to adopt circular strategies and 2) assessing research and development (R&D) needs that can be addressed in the short term to advance a CE for the solar industry.

太阳能光伏(PV)和其他清洁能源技术作为一种对环境负责且经济的能源系统去碳化方法,正得到越来越多的应用。从以化石燃料为中心到以材料为中心的设备转变,也改变了对整个技术生命周期的环境和社会影响的考虑和管理。社会希望减少对原材料的需求,减轻供应链的社会和治理挑战,并利用材料的再利用和回收能力,这提高了人们对再生经济模式(循环经济)的兴趣。最近的一篇评论性文章指出,太阳能光伏发电正走在 "提高循环性的道路上",但仍需将活动范围从回收扩大到更广泛的环境和政策活动,以充分实现效益[1,2]。因此,本研究路线图的目标是通过以下方式促进并加快向太阳能光伏循环经济的过渡:1)强调光伏价值链利益相关者目前采用循环战略的机会;2)评估可在短期内解决的研发(R&D)需求,以推进太阳能行业的循环经济。
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引用次数: 0
Superior performance of rubidium/acetate co-doped CsPbIBr2 perovskite solar cells: A comprehensive analysis 铷/醋酸盐共掺杂 CsPbIBr2 包晶太阳能电池的卓越性能:综合分析
IF 6.7 2区 工程技术 Q1 Materials Science Pub Date : 2024-06-12 DOI: 10.1016/j.solener.2024.112674
O. Madkhali , J. Fatima Rasheed , Firoz Khan

The development of remarkably resourceful, effectively phase stable, and highly crystalline-minimal defect perovskite (PVT)-based solar cells (PSCs) is extremely needful for the existing energy requisites. The strategy of incorporating appropriate dopants such as metal cations/anions into inorganic PVT lattices has been recognized as a successful methodology to attain aforesaid PSCs. On that account, this analysis reveals the implication of rubidium (Rb)/ acetate (Ac) (cation/anion) co-doping upon cesium (Cs)-based, bromine (Br)-rich PVT: CsPbIBr2 against undoped equivalent. The thorough numerical study on recommended structure: FTO/SnO2/CsPbIBr2/CuAlO2/Ag specifying recombination profiles and performance parameters with respect to layer parameters of PVT absorber and charge transport layers conveyed supreme behavior from co-doped devices. It is evidenced that highest efficiency of 16.79 % is accomplished from Rb/Ac co-doped PSC for PVT electron mobility of 25 cm2V-1s−1. The work reveals the progress in photovoltaic characteristics of inorganic PSCs through the involvement of multi-source co-doping.

开发资源丰富、相位有效稳定、结晶度高且缺陷极小的基于光伏晶体(PVT)的太阳能电池(PSCs),对于满足现有的能源需求极为必要。在无机 PVT 晶格中加入适当的掺杂剂(如金属阳离子/阴离子)的策略已被认为是实现上述 PSC 的成功方法。因此,本分析揭示了铷(Rb)/醋酸盐(Ac)(阳离子/阴离子)共掺杂对基于铯(Cs)、富含溴(Br)的 PVT:CsPbIBr2 与未掺杂等效物的影响。对推荐结构进行了全面的数值研究:FTO/SnO2/CsPbIBr2/CuAlO2/Ag 根据 PVT 吸收层和电荷传输层的层参数,确定了重组曲线和性能参数,从而反映了共掺杂器件的最高性能。结果表明,当 PVT 电子迁移率为 25 cm2V-1s-1 时,Rb/Ac 共掺杂 PSC 的最高效率为 16.79%。这项研究揭示了多源共掺杂技术在无机 PSC 光伏特性方面取得的进展。
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引用次数: 0
Utilization of vortex flow pattern in the design of an efficient solar air heater 利用涡流模式设计高效太阳能空气加热器
IF 6.7 2区 工程技术 Q1 Materials Science Pub Date : 2024-06-12 DOI: 10.1016/j.solener.2024.112683
M. Moein Addini, S.A. Gandjalikhan Nassab

In this work, numerical and experimental analyses of a new model of circular solar air heater are carried out to examine the effect of employing vortex flow inside the air vessel of collector for convection enhancement. In three-dimensional numerical CFD-based analysis, the COMSOL Multi-physics is used to solve the flow equations for the turbulent forced convection airflow and conduction equation for the solid parts of the solar heater at different air mass flow rates in the range of 0.003 to 0.012 kg/s. In the calculation of turbulent stresses and heat fluxes, the RNG κ- turbulence model is employed. The surface to surfaces (S2S) radiation model is used to consider the radiations emitted by the hot surfaces in collaboration with the energy equation. For validation, the theoretical findings are evaluated against the experiment. For the studied test cases with different values of solar irradiation and air mass flow rate, thermal efficiencies of up to 80 % are found. In comparison to the conventional rectangular-shaped solar air heaters with smooth ducts, more than 100 % increase in the value of thermal efficiency is delineated from the theoretical and experimental findings. This gain is attributed to the unique flow pattern in the developed solar collector.

在这项工作中,对新型圆形太阳能空气加热器进行了数值和实验分析,以研究在集热器的空气容器内采用涡流增强对流的效果。在基于 CFD 的三维数值分析中,使用 COMSOL Multi-physics 求解了 0.003 至 0.012 kg/s 范围内不同空气质量流量下太阳能加热器固体部分的湍流强制对流气流和传导方程。在计算湍流应力和热通量时,采用了 RNG κ-∊ 湍流模型。表面到表面(S2S)辐射模型与能量方程相结合,用于考虑热表面发出的辐射。为了进行验证,将理论结果与实验结果进行对比评估。在所研究的测试案例中,根据不同的太阳辐照值和空气质量流量,热效率最高可达 80%。与采用光滑管道的传统矩形太阳能空气加热器相比,理论和实验结果表明热效率提高了 100%以上。这种提高归功于所开发的太阳能集热器中独特的流动模式。
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引用次数: 0
Study on saline-alkali water distillation system by reflection enhanced solar heating 利用反射增强太阳能加热的盐碱水蒸馏系统研究
IF 6.7 2区 工程技术 Q1 Materials Science Pub Date : 2024-06-12 DOI: 10.1016/j.solener.2024.112686
Yingxu Chen , Jingyang Han , Keqin Huang , Xu Ji , Ren Zhang , Mengqi Wang

A saline-alkali water distillation system by reflection enhanced solar heating is proposed to treat the saline-alkali soil washing water. In this system, the heat concentration collector employs heat collecting plate to receive solar radiation energy, and converges to small-area steam generating tube through efficiently heat transfer. Without expensive optical tracking equipment, the system also employs an external reflector to reflect the solar radiation to the surface of the heat concentration collector. Thereby the energy flow density is further increased, and the useful energy and vaporization intensity is promoted. The latent heat of the steam is reused by heat recovery to enhance the energy utilization efficiency. The optimal inclination angles of reflector in different seasons and system performance were theoretically calculated. In the spring equinox, summer solstice, autumn equinox, and winter solstice, the optimal inclination angles of the reflector were 30°, 45°, 30°, and 15°, respectively. The freshwater production, useful energy, and heat recovery efficiency of the system were investigated by experiments. The daily freshwater production of the system was 17.04 kg, and the maximum production rate was 3.44 kg/h. The reflector increased the useful energy and freshwater production of the system by 33.68% and 35%, respectively. With heat recovery, the initial temperature of the saline-alkali water was increased to 53.8 °C and the freshwater production was increased by 13.16%.

提出了一种利用反射增强太阳能加热的盐碱水蒸馏系统来处理盐碱土壤冲洗水。在该系统中,热量集中收集器采用集热板接收太阳辐射能,并通过高效传热汇聚到小面积蒸汽发生管。由于不需要昂贵的光学跟踪设备,该系统还采用了外部反射器,将太阳辐射反射到集热器表面。这样就进一步提高了能量流密度,提升了有用能量和汽化强度。蒸汽的潜热可通过热回收再利用,从而提高能源利用效率。理论计算了不同季节反射器的最佳倾角和系统性能。在春分、夏至、秋分和冬至,反射器的最佳倾角分别为 30°、45°、30° 和 15°。实验研究了该系统的淡水产量、有用能量和热回收效率。该系统的淡水日产量为 17.04 千克,最大生产率为 3.44 千克/小时。反射器使系统的有用能量和淡水产量分别增加了 33.68% 和 35%。通过热回收,盐碱水的初始温度提高到 53.8 °C,淡水产量增加了 13.16%。
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引用次数: 0
Durable and robust broadband radiative cooling coatings for multi-temperature scenarios 耐用、坚固的宽带辐射冷却涂层适用于多温度场景
IF 6.7 2区 工程技术 Q1 Materials Science Pub Date : 2024-06-12 DOI: 10.1016/j.solener.2024.112685
Qihao Dai , Xinyu Tan , Guiguang Qi , Xiongbo Yang , Bowhen Li , Zheng Guo , Junmei Zhang , Weiwei Hu , Songshan Li , Cadao Nguyen , Xiaobo Chen , Yequan Xiao , Peng Xiang

Passive daytime radiative cooling presents a promising avenue for revolutionizing cooling solutions by reflecting sunlight and radiative heat to outer space without consuming energy. Previous studies often focus on a single temperature scenario, neglecting the complexity of real-world applications in which the target object may have heat sources. Here, we have successfully prepared a Cooling Paint for Multi-Temperature Scenarios (CPMTS) by incorporating nanometer boron nitride into the photocured monomer Tricyclodecane Dimethanol Diacrylate (DCPDA). CPMTS exhibits excellent broadband thermal emittance (∼0.955), reflectance (∼0.778, from 300 nm to 2.5 μm), and thermal conductivity (∼0.51 W m−1 K−1). Notably, it achieves a maximum cooling of 20.1 °C and 8.8 °C under ∼790 W m−2 and ∼507 W m−2 of solar irradiation in the absence and presence of a 1 W heat source continuously heating, respectively. Continuous and significant radiative cooling performance has been observed on cloudy days or at night. CPMTS shows excellent radiative cooling performance in practical application scenarios. Excellent ageing resistance, adhesion, stability, and color matching ability make CPMTS expected large-scale application through spray or brush. This research provides a potential solution for cooling in real-world diverse temperature scenarios. The obtained radiative cooling coatings demonstrate scalability and durability in practical applications.

被动式日间辐射冷却通过将太阳光和辐射热反射到外层空间而不消耗能源,为冷却解决方案的变革提供了一条大有可为的途径。以往的研究通常只关注单一温度场景,而忽视了目标物体可能存在热源的实际应用的复杂性。在这里,我们通过在光固化单体三环癸烷二甲醇二丙烯酸酯(DCPDA)中加入纳米氮化硼,成功制备了一种多温度场景冷却涂料(CPMTS)。CPMTS 具有出色的宽带热发射率(∼0.955)、反射率(∼0.778,从 300 纳米到 2.5 μm)和热导率(∼0.51 W m-1 K-1)。值得注意的是,在没有 1 W 热源持续加热和有 1 W 热源持续加热的情况下,它分别在 790 W m-2 和 507 W m-2 的太阳辐照下实现了 20.1 °C和 8.8 °C的最大冷却温度。在阴天或夜间也能观察到持续和显著的辐射冷却性能。CPMTS 在实际应用场景中表现出卓越的辐射冷却性能。优异的耐老化性、附着力、稳定性和配色能力使 CPMTS 有望通过喷涂或刷涂实现大规模应用。这项研究为现实世界中不同温度场景下的冷却提供了一种潜在的解决方案。所获得的辐射冷却涂层证明了其在实际应用中的可扩展性和耐用性。
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引用次数: 0
In-depth analysis of γ-CuI as an HTM for perovskite solar cells: A comprehensive DFT study of structural, elastic, mechanical, charge density, and optoelectronic properties 深入分析作为过氧化物太阳能电池 HTM 的 γ-CuI:对结构、弹性、机械、电荷密度和光电特性的全面 DFT 研究
IF 6.7 2区 工程技术 Q1 Materials Science Pub Date : 2024-06-12 DOI: 10.1016/j.solener.2024.112680
Salma Naimi , Saida Laalioui , El Mehdi Salmani , Kawtar Belrhiti Alaoui , Hamid Ez-Zahraouy

Herein, we employed Density Functional Theory (DFT) to comprehensively investigate pristine γ-CuI properties under two computational schemes: Generalized Gradient Approximation (GGA) and GGA + Hubbard correction. Structural stability is rigorously assessed through ground state energy optimization, complemented by a meticulous examination of elastic constants to confirm mechanical stability. Later on, we analyzed the electronic properties, as well as the optical properties, incorporating parameters such as the extinction coefficient that was low and refractive index that was high in the IR and visible regions. Notably, γ-CuI exhibits low reflectivity and absorption in the critical regions of interest. Our findings demonstrate that γ-CuI can serve as a cost-effective Hole Transporting Material (HTM), effectively reducing optical losses in perovskite solar cells.

在此,我们采用密度泛函理论(DFT)在两种计算方案下全面研究了原始γ-CuI 的性质:广义梯度逼近(GGA)和 GGA + Hubbard 校正。通过基态能量优化对结构稳定性进行了严格评估,并对弹性常数进行了细致检查,以确认机械稳定性。随后,我们分析了电子特性以及光学特性,其中包括红外和可见光区域的低消光系数和高折射率等参数。值得注意的是,γ-CuI 在相关临界区域表现出较低的反射率和吸收率。我们的研究结果表明,γ-CuI 可作为一种具有成本效益的空穴传输材料 (HTM),有效减少过氧化物太阳能电池中的光学损耗。
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