In this work, the simulation of the behavior of an MRAC assisted solar tracker in solar trajectory tracking tasks has been developed for a prototype of a two-axis solar tracker that presents structural and performance characteristics capable of supporting PV, CPV, and HCPV-type technology. The proposal is numerically validated by developing an experimental methodology consisting of two stages. The first stage is associated with developing tests of the MRAC-assisted solar tracker to reproduce a solar trajectory (obtained offline by a numerical method) with and without the injection of disturbances (with dynamics equivalent to wind loads in reality), respectively. On the other hand, in the second stage, after replicating the conditions of the tests of stage one but with the assistance of a simple PID type controller, the analysis and comparison of the performance of each alternative is carried out, the above, in terms of tracking error or pointing accuracy. The results show that both alternatives are functional in the development of tests under favorable conditions. However, under conditions with disturbances, it can be noted that the MRAC reduces the tracking error by around 87% compared to PID control.
{"title":"Model Reference Adaptive Control (MRAC) for dual-axis solar tracker applied in CPV","authors":"S.I. Palomino-Resendiz , M.A. Peñaloza-López , D.A. Flores-Hernández , C.U. Solís-Cervantes , R.L. Palomino-Resendiz","doi":"10.1016/j.solmat.2024.113225","DOIUrl":"10.1016/j.solmat.2024.113225","url":null,"abstract":"<div><div>In this work, the simulation of the behavior of an MRAC assisted solar tracker in solar trajectory tracking tasks has been developed for a prototype of a two-axis solar tracker that presents structural and performance characteristics capable of supporting PV, CPV, and HCPV-type technology. The proposal is numerically validated by developing an experimental methodology consisting of two stages. The first stage is associated with developing tests of the MRAC-assisted solar tracker to reproduce a solar trajectory (obtained offline by a numerical method) with and without the injection of disturbances (with dynamics equivalent to wind loads in reality), respectively. On the other hand, in the second stage, after replicating the conditions of the tests of stage one but with the assistance of a simple PID type controller, the analysis and comparison of the performance of each alternative is carried out, the above, in terms of tracking error or pointing accuracy. The results show that both alternatives are functional in the development of tests under favorable conditions. However, under conditions with disturbances, it can be noted that the MRAC reduces the tracking error by around 87% compared to PID control.</div></div>","PeriodicalId":429,"journal":{"name":"Solar Energy Materials and Solar Cells","volume":"279 ","pages":"Article 113225"},"PeriodicalIF":6.3,"publicationDate":"2024-10-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142529166","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The utilization of photoelectrochemical processes for hydrogen generation from water and solar energy offers a promising avenue to replace non-renewable energy sources. Nevertheless, achieving high-performance photoanode electrodes poses a significant challenge. In this study, we present the synthesis cerium and chromium-doped TiO2 (CeCrTiO2) is produced through a simple, scalable, and cost-effective hydrothermal method on a fluorine-doped tin oxide (FTO) substrate. the introduction of Ce and Cr impurities is highlighted for its role in creating an impurity band within CeCrTiO2. This impurity band is instrumental in enhancing the separation and movement of electrons and holes, contributing to the improved performance of CeCrTiO2 as a photoanode in photoelectrochemical applications. Hence, the photocurrent density value of CeCrTiO2 is 4.5 times higher than that of bare TiO2. This suggests that CeCrTiO2 exhibits improved efficiency in generating a photocurrent when exposed to light, indicating enhanced photoelectrochemical performance. The amount of hydrogen produced by CeCrTiO2 is noted to be 4.88 times greater than that of bare TiO2. This highlights the material's effectiveness in harnessing solar energy to drive the water-splitting reaction, leading to a higher yield of hydrogen gas. The synthesis of CeCrTiO2 through a hydrothermal method results in a photoanode with significantly enhanced performance, positioning it as a promising candidate for advancing photoelectrochemical processes aimed at replacing non-renewable energy sources.
{"title":"Creating an intermediate energy band to boost the photoelectrochemical efficiency of TiO2 for solar-driven hydrogen production","authors":"Ranjith Balu , Gautham Devendrapandi , Lalitha Gnanasekaran , P.C. Karthika , Omar H. Abd-Elkader , Woo Kyoung Kim , Vasudeva Reddy Minnam Reddy , Monit Kapoor , Suresh Singh , Mahimaluru Lavanya","doi":"10.1016/j.solmat.2024.113226","DOIUrl":"10.1016/j.solmat.2024.113226","url":null,"abstract":"<div><div>The utilization of photoelectrochemical processes for hydrogen generation from water and solar energy offers a promising avenue to replace non-renewable energy sources. Nevertheless, achieving high-performance photoanode electrodes poses a significant challenge. In this study, we present the synthesis cerium and chromium-doped TiO<sub>2</sub> (CeCrTiO<sub>2</sub>) is produced through a simple, scalable, and cost-effective hydrothermal method on a fluorine-doped tin oxide (FTO) substrate. the introduction of Ce and Cr impurities is highlighted for its role in creating an impurity band within CeCrTiO<sub>2</sub>. This impurity band is instrumental in enhancing the separation and movement of electrons and holes, contributing to the improved performance of CeCrTiO<sub>2</sub> as a photoanode in photoelectrochemical applications. Hence, the photocurrent density value of CeCrTiO<sub>2</sub> is 4.5 times higher than that of bare TiO<sub>2</sub>. This suggests that CeCrTiO<sub>2</sub> exhibits improved efficiency in generating a photocurrent when exposed to light, indicating enhanced photoelectrochemical performance. The amount of hydrogen produced by CeCrTiO<sub>2</sub> is noted to be 4.88 times greater than that of bare TiO<sub>2</sub>. This highlights the material's effectiveness in harnessing solar energy to drive the water-splitting reaction, leading to a higher yield of hydrogen gas. The synthesis of CeCrTiO<sub>2</sub> through a hydrothermal method results in a photoanode with significantly enhanced performance, positioning it as a promising candidate for advancing photoelectrochemical processes aimed at replacing non-renewable energy sources.</div></div>","PeriodicalId":429,"journal":{"name":"Solar Energy Materials and Solar Cells","volume":"279 ","pages":"Article 113226"},"PeriodicalIF":6.3,"publicationDate":"2024-10-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142529160","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Energy demand has motivated the development of new technologies to make energy collection more efficient, where the use of concentrating optical elements, such as Fresnel lenses, and precise tracking of the solar path are required, motivating the development of hybrid systems that integrate concentration photovoltaics and thermoelectric modules. However, these investigations do not perform the tests under the same experimental and environmental conditions, achieving the experiments on different days under different weather conditions, complicating a fair comparison between methods and configurations to define the advantages and improvements between them; hence, the development of an open architecture test bed is presented, which allows the comparison of four technologies under the same conditions at the same time by monitoring and recording instrumentation and environmental data in real-time using a two-axis solar tracking robotic system and focus control devices. The system was validated and verified through experimentation to ensure its functionality. In addition, the open architecture approach allows addition, updating, and simply changing of components or devices for specific research constraints, increasing the connectivity to communicate with other instruments in a wired or wireless way, opening the possibility of future research that integrates concepts of the Internet of Things and cloud computing. Finally, the developed open architecture test bed opens the door to research centers and universities in the training of new researchers and developers of hybrid technology, obtaining experience in this field.
{"title":"Open architecture testbed for hybrid solar energy harvesting systems based on concentration by Fresnel lens","authors":"D.A. Flores-Hernández , J.C. Ordaz-Dehesa , C.F. López-Olvera , S.I. Palomino-Resendiz","doi":"10.1016/j.solmat.2024.113224","DOIUrl":"10.1016/j.solmat.2024.113224","url":null,"abstract":"<div><div>Energy demand has motivated the development of new technologies to make energy collection more efficient, where the use of concentrating optical elements, such as Fresnel lenses, and precise tracking of the solar path are required, motivating the development of hybrid systems that integrate concentration photovoltaics and thermoelectric modules. However, these investigations do not perform the tests under the same experimental and environmental conditions, achieving the experiments on different days under different weather conditions, complicating a fair comparison between methods and configurations to define the advantages and improvements between them; hence, the development of an open architecture test bed is presented, which allows the comparison of four technologies under the same conditions at the same time by monitoring and recording instrumentation and environmental data in real-time using a two-axis solar tracking robotic system and focus control devices. The system was validated and verified through experimentation to ensure its functionality. In addition, the open architecture approach allows addition, updating, and simply changing of components or devices for specific research constraints, increasing the connectivity to communicate with other instruments in a wired or wireless way, opening the possibility of future research that integrates concepts of the Internet of Things and cloud computing. Finally, the developed open architecture test bed opens the door to research centers and universities in the training of new researchers and developers of hybrid technology, obtaining experience in this field.</div></div>","PeriodicalId":429,"journal":{"name":"Solar Energy Materials and Solar Cells","volume":"279 ","pages":"Article 113224"},"PeriodicalIF":6.3,"publicationDate":"2024-10-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142529159","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-10-23DOI: 10.1016/j.solmat.2024.113213
Mikhail A. Mintairov, Valery V. Evstropov, Sergey A. Mintairov, Mariia V. Nakhimovich, Roman A. Salii, Maxim Z. Shvarts, Nikolay A. Kalyuzhnyy
The paper presents an overview of studies of the multi-junction (MJ) solar cells (SC) with IV characteristics having nonlinear peculiarities. It is shown that such peculiarities can arise either due to hetero-interface barriers (HB) for majority charge carriers or due to problems with tunnel diodes (TD). It is usually difficult to identify which of these hetero-structural objects is the cause of this nonlinearity, since the peculiarities appear similarly in the IV characteristics of MJ SC. The experimental method presented in this work is based on the study of IV characteristics during the overheating of MJ SCs. The behavior of nonlinear peculiarities caused by an imperfect TD or an HB is fundamentally different during the overheating of SCs, which makes it possible to identify the type of hetero-structural object. Since the number of hetero-interfaces in MJ SC is large, a method determining the position of problematic objects in the MJ structure was also developed. The method is based on the illumination of individual subcells using different laser wavelengths. Both methods considered were tested experimentally on GaInP/GaAs/Ge SCs.
{"title":"The origins of nonlinear peculiarities on the IV characteristics of multi-junction solar cells","authors":"Mikhail A. Mintairov, Valery V. Evstropov, Sergey A. Mintairov, Mariia V. Nakhimovich, Roman A. Salii, Maxim Z. Shvarts, Nikolay A. Kalyuzhnyy","doi":"10.1016/j.solmat.2024.113213","DOIUrl":"10.1016/j.solmat.2024.113213","url":null,"abstract":"<div><div>The paper presents an overview of studies of the multi-junction (MJ) solar cells (SC) with <em>IV</em> characteristics having nonlinear peculiarities. It is shown that such peculiarities can arise either due to hetero-interface barriers (HB) for majority charge carriers or due to problems with tunnel diodes (TD). It is usually difficult to identify which of these hetero-structural objects is the cause of this nonlinearity, since the peculiarities appear similarly in the <em>IV</em> characteristics of MJ SC. The experimental method presented in this work is based on the study of <em>IV</em> characteristics during the overheating of MJ SCs. The behavior of nonlinear peculiarities caused by an imperfect TD or an HB is fundamentally different during the overheating of SCs, which makes it possible to identify the type of hetero-structural object. Since the number of hetero-interfaces in MJ SC is large, a method determining the position of problematic objects in the MJ structure was also developed. The method is based on the illumination of individual subcells using different laser wavelengths. Both methods considered were tested experimentally on GaInP/GaAs/Ge SCs.</div></div>","PeriodicalId":429,"journal":{"name":"Solar Energy Materials and Solar Cells","volume":"279 ","pages":"Article 113213"},"PeriodicalIF":6.3,"publicationDate":"2024-10-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142529155","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-10-23DOI: 10.1016/j.solmat.2024.113212
Alessandro Martulli , Fabrizio Gota , Neethi Rajagopalan , Toby Meyer , Cesar Omar Ramirez Quiroz , Daniele Costa , Ulrich W. Paetzold , Robert Malina , Bart Vermang , Sebastien Lizin
In the last decade, the manufacturing capacity of silicon, the dominant PV technology, has increasingly been concentrated in China. This coincided with PV cost reduction, while, at the same time, posing risks to PV supply chain security. Recent advancements of novel perovskite tandem PV technologies as an alternative to traditional silicon-based PV provide opportunities for diversification of the PV manufacturing capacity and for increasing the GHG emission benefit of solar PV. Against this background, we estimate the current and future cost-competitiveness and GHG emissions of a set of already commercialized as well as emerging PV technologies for different production locations (China, USA, EU), both at residential and utility-scale. We find EU and USA-manufactured thin-film tandems to have 2–4 % and 0.5–2 % higher costs per kWh and 37–40 % and 32–35 % less GHG emissions per kWh at residential and utility-scale, respectively. Our projections indicate that they will also retain competitive costs (up to 2 % higher) and a 20 % GHG emissions advantage per kWh in 2050.
{"title":"Beyond silicon: Thin-film tandem as an opportunity for photovoltaics supply chain diversification and faster power system decarbonization out to 2050","authors":"Alessandro Martulli , Fabrizio Gota , Neethi Rajagopalan , Toby Meyer , Cesar Omar Ramirez Quiroz , Daniele Costa , Ulrich W. Paetzold , Robert Malina , Bart Vermang , Sebastien Lizin","doi":"10.1016/j.solmat.2024.113212","DOIUrl":"10.1016/j.solmat.2024.113212","url":null,"abstract":"<div><div>In the last decade, the manufacturing capacity of silicon, the dominant PV technology, has increasingly been concentrated in China. This coincided with PV cost reduction, while, at the same time, posing risks to PV supply chain security. Recent advancements of novel perovskite tandem PV technologies as an alternative to traditional silicon-based PV provide opportunities for diversification of the PV manufacturing capacity and for increasing the GHG emission benefit of solar PV. Against this background, we estimate the current and future cost-competitiveness and GHG emissions of a set of already commercialized as well as emerging PV technologies for different production locations (China, USA, EU), both at residential and utility-scale. We find EU and USA-manufactured thin-film tandems to have 2–4 % and 0.5–2 % higher costs per kWh and 37–40 % and 32–35 % less GHG emissions per kWh at residential and utility-scale, respectively. Our projections indicate that they will also retain competitive costs (up to 2 % higher) and a 20 % GHG emissions advantage per kWh in 2050.</div></div>","PeriodicalId":429,"journal":{"name":"Solar Energy Materials and Solar Cells","volume":"279 ","pages":"Article 113212"},"PeriodicalIF":6.3,"publicationDate":"2024-10-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142529167","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-10-21DOI: 10.1016/j.solmat.2024.113228
Pin Jin Ong , Hui Yi Shuko Lee , Suxi Wang , Warintorn Thitsartarn , Xikui Zhang , Junhua Kong , Dan Kai , Beng Hoon Tan , Pei Wang , Zhengyao Qu , Jianwei Xu , Xian Jun Loh , Qiang Zhu
As the demand for renewable and sustainable energy sources rises, considerable efforts have been dedicated to the development of energy storage materials. Phase change materials (PCMs) have garnered significant attention for their potential applications in thermal energy storage (TES) and management systems. However, the low thermal conductivity and potential leakage during phase transition hinder the widespread application of these materials. The integration of carbon nanotubes (CNTs) into PCMs has emerged as a promising strategy to enhance their thermal properties due to their exceptional thermal conductivity and structural characteristics. Herein, we provide an overview of recent advances in the utilization of different types of CNTs to improve the thermal performance of PCMs. We discuss various methods of incorporating CNTs into PCMs, including physical mixing, chemical functionalization, and hybrid nanostructures. Furthermore, we examine the effects of CNT addition on the thermal conductivity, latent heat storage capacity, light-to-thermal conversion efficiency, and thermal stability of PCMs. In addition, we discuss the current challenges and prospects for the practical implementation of CNT-enhanced PCMs in diverse TES applications.
{"title":"Recent advances in enhanced thermal property in phase change materials using carbon nanotubes: A review","authors":"Pin Jin Ong , Hui Yi Shuko Lee , Suxi Wang , Warintorn Thitsartarn , Xikui Zhang , Junhua Kong , Dan Kai , Beng Hoon Tan , Pei Wang , Zhengyao Qu , Jianwei Xu , Xian Jun Loh , Qiang Zhu","doi":"10.1016/j.solmat.2024.113228","DOIUrl":"10.1016/j.solmat.2024.113228","url":null,"abstract":"<div><div>As the demand for renewable and sustainable energy sources rises, considerable efforts have been dedicated to the development of energy storage materials. Phase change materials (PCMs) have garnered significant attention for their potential applications in thermal energy storage (TES) and management systems. However, the low thermal conductivity and potential leakage during phase transition hinder the widespread application of these materials. The integration of carbon nanotubes (CNTs) into PCMs has emerged as a promising strategy to enhance their thermal properties due to their exceptional thermal conductivity and structural characteristics. Herein, we provide an overview of recent advances in the utilization of different types of CNTs to improve the thermal performance of PCMs. We discuss various methods of incorporating CNTs into PCMs, including physical mixing, chemical functionalization, and hybrid nanostructures. Furthermore, we examine the effects of CNT addition on the thermal conductivity, latent heat storage capacity, light-to-thermal conversion efficiency, and thermal stability of PCMs. In addition, we discuss the current challenges and prospects for the practical implementation of CNT-enhanced PCMs in diverse TES applications.</div></div>","PeriodicalId":429,"journal":{"name":"Solar Energy Materials and Solar Cells","volume":"279 ","pages":"Article 113228"},"PeriodicalIF":6.3,"publicationDate":"2024-10-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142529165","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
One-dimensional Solar Cell Capacitance Simulator (SCAPS-1D) has become a widely used and popular electrical simulation tool in the photovoltaic community. Recently, with the realization of broad chemical tunability provided by perovskite materials, there has been a concerning increase in scientific papers reporting inflated solar cell device performance that deviates significantly from the best experimental results, with some even surpassing the fundamental Shockley-Queisser limit. While some of these projections might suggest significant potential for experimental advancements, it is crucial to approach such exaggerated results with caution. In this study, a comprehensive survey of over 250 reported perovskite solar cell architectures yielded the undeniable implication that such results are primarily due to unrealistic input parameters such as low radiative recombination coefficient, low defect densities, and high doping concentrations. Additionally, inconsistencies in simulation methods and the optical limitations of SCAPS-1D have also been explored. To address these issues, several recommendations, including a standard simulation protocol, have been proposed. Software-generated results may not always represent the actual cell performance as they heavily rely on the validity of inputs and software algorithms.
{"title":"A critical review of unrealistic results in SCAPS-1D simulations: Causes, practical solutions and roadmap ahead","authors":"Abhisek Saidarsan , Satyabrata Guruprasad , Ashish Malik , Pilik Basumatary , Dhriti Sundar Ghosh","doi":"10.1016/j.solmat.2024.113230","DOIUrl":"10.1016/j.solmat.2024.113230","url":null,"abstract":"<div><div>One-dimensional Solar Cell Capacitance Simulator (SCAPS-1D) has become a widely used and popular electrical simulation tool in the photovoltaic community. Recently, with the realization of broad chemical tunability provided by perovskite materials, there has been a concerning increase in scientific papers reporting inflated solar cell device performance that deviates significantly from the best experimental results, with some even surpassing the fundamental Shockley-Queisser limit. While some of these projections might suggest significant potential for experimental advancements, it is crucial to approach such exaggerated results with caution. In this study, a comprehensive survey of over 250 reported perovskite solar cell architectures yielded the undeniable implication that such results are primarily due to unrealistic input parameters such as low radiative recombination coefficient, low defect densities, and high doping concentrations. Additionally, inconsistencies in simulation methods and the optical limitations of SCAPS-1D have also been explored. To address these issues, several recommendations, including a standard simulation protocol, have been proposed. Software-generated results may not always represent the actual cell performance as they heavily rely on the validity of inputs and software algorithms.</div></div>","PeriodicalId":429,"journal":{"name":"Solar Energy Materials and Solar Cells","volume":"279 ","pages":"Article 113230"},"PeriodicalIF":6.3,"publicationDate":"2024-10-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142529164","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Thermal energy storage technology based on phase change materials (PCMs) can address the temporal and spatial mismatches in solar thermal energy conversion, thereby enhancing solar energy utilization efficiency. However, the liquid flow and poor thermal reliability of PCMs limit their large-scale application in solar thermal systems. In this study, we employ a simple “one-pot method” to prepare a form-stable and thermally reliable oxalic acid dihydrate-glutaric acid/poly 2-Acrylamido-2-methyl-1-propanesulfonic acid (OAD-GA/PAMPS) phase change gel. The OAD-GA/PAMPS phase change gel melts at 64.5 °C with a phase change enthalpy of 193.6 kJ/kg, the tensile strength is 7.707 MPa, and the compressive strength is 16.940 MPa. By incorporating 5 wt% BN particles, the thermal conductivity of OAD-GA/PAMPS phase change gel reaches 0.63 W/(m·K). After 200 heating-cooling cycles, the phase change temperature of the OAD-GA/PAMPS phase change gel remains nearly unchanged, and the phase change enthalpy decreases by only 5.7 %. The photo-thermal conversion efficiency of the OAD-GA/PAMPS phase change gel is 82.7 %. The high thermal reliability and photo-thermal conversion efficiency of the OAD-GA/PAMPS phase change gel makes it suitable for solar thermal energy storage applications.
{"title":"Preparation and thermal stability research of oxalic acid dihydrate-glutaric acid/PAMPS phase change gel for solar thermal energy utilization","authors":"Sili Zhou , Wenbo Zhang , Wenhui Yuan , Xuenong Gao , Ziye Ling , Xiaoming Fang","doi":"10.1016/j.solmat.2024.113219","DOIUrl":"10.1016/j.solmat.2024.113219","url":null,"abstract":"<div><div>Thermal energy storage technology based on phase change materials (PCMs) can address the temporal and spatial mismatches in solar thermal energy conversion, thereby enhancing solar energy utilization efficiency. However, the liquid flow and poor thermal reliability of PCMs limit their large-scale application in solar thermal systems. In this study, we employ a simple “one-pot method” to prepare a form-stable and thermally reliable oxalic acid dihydrate-glutaric acid/poly 2-Acrylamido-2-methyl-1-propanesulfonic acid (OAD-GA/PAMPS) phase change gel. The OAD-GA/PAMPS phase change gel melts at 64.5 °C with a phase change enthalpy of 193.6 kJ/kg, the tensile strength is 7.707 MPa, and the compressive strength is 16.940 MPa. By incorporating 5 wt% BN particles, the thermal conductivity of OAD-GA/PAMPS phase change gel reaches 0.63 W/(m·K). After 200 heating-cooling cycles, the phase change temperature of the OAD-GA/PAMPS phase change gel remains nearly unchanged, and the phase change enthalpy decreases by only 5.7 %. The photo-thermal conversion efficiency of the OAD-GA/PAMPS phase change gel is 82.7 %. The high thermal reliability and photo-thermal conversion efficiency of the OAD-GA/PAMPS phase change gel makes it suitable for solar thermal energy storage applications.</div></div>","PeriodicalId":429,"journal":{"name":"Solar Energy Materials and Solar Cells","volume":"279 ","pages":"Article 113219"},"PeriodicalIF":6.3,"publicationDate":"2024-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142529157","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The vulnerability of perovskite solar cells (PSCs) to reverse bias caused by partial shading in the module and current mismatch in tandem configurations present significant challenges for the commercialisation of PSCs, particularly in terms of their performance, durability, and safety. In this study, we investigated the effects of partial shading on perovskite photovoltaic (PV) modules and the temperature-dependent reverse bias behaviour in solar cells. Partial shading of perovskite PV modules degrades their performance, but light soaking restores it, indicating that the reverse-bias-induced changes are induced not only by permanent damage but also by reversible changes. Furthermore, the reverse bias effects on the solar cell, which cause the degradation of the modules under partial shading stress, are reversible. Additionally, the reverse-bias behaviour is highly dependent on temperature, indicating that temperature-dependent ion migration under an applied reverse bias leads to changes in the reverse-bias behaviour, such as reversible properties and enhanced modification at elevated temperatures. Our findings demonstrate that unravelling the properties hidden by ion migration is crucial for assessing the intrinsic durability and reliability of PSCs and understanding the effects of partial shading in perovskite PV modules.
{"title":"Effects of partial shading and temperature-dependent reverse bias behaviour on degradation in perovskite photovoltaic modules","authors":"Takeshi Tayagaki, Haruka Kobayashi, Kohei Yamamoto, Takurou N. Murakami, Masahiro Yoshita","doi":"10.1016/j.solmat.2024.113229","DOIUrl":"10.1016/j.solmat.2024.113229","url":null,"abstract":"<div><div>The vulnerability of perovskite solar cells (PSCs) to reverse bias caused by partial shading in the module and current mismatch in tandem configurations present significant challenges for the commercialisation of PSCs, particularly in terms of their performance, durability, and safety. In this study, we investigated the effects of partial shading on perovskite photovoltaic (PV) modules and the temperature-dependent reverse bias behaviour in solar cells. Partial shading of perovskite PV modules degrades their performance, but light soaking restores it, indicating that the reverse-bias-induced changes are induced not only by permanent damage but also by reversible changes. Furthermore, the reverse bias effects on the solar cell, which cause the degradation of the modules under partial shading stress, are reversible. Additionally, the reverse-bias behaviour is highly dependent on temperature, indicating that temperature-dependent ion migration under an applied reverse bias leads to changes in the reverse-bias behaviour, such as reversible properties and enhanced modification at elevated temperatures. Our findings demonstrate that unravelling the properties hidden by ion migration is crucial for assessing the intrinsic durability and reliability of PSCs and understanding the effects of partial shading in perovskite PV modules.</div></div>","PeriodicalId":429,"journal":{"name":"Solar Energy Materials and Solar Cells","volume":"279 ","pages":"Article 113229"},"PeriodicalIF":6.3,"publicationDate":"2024-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142529158","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-10-19DOI: 10.1016/j.solmat.2024.113227
Jia Hui Tan , Yuin Yue Liew , Rubina Bahar , Hieng Kiat Jun , Jaslyn Low
Solar desalination may become the sustainable solution to mitigate freshwater scarcity with growing demand. However, conventional solar stills for desalination are limited to low production efficiency caused by low/unavailable solar irradiation. Current research in thermal energy storage (TES) for solar desalination utilizes phase change materials (PCM) to store solar heat, ensuring uninterrupted energy for distillate production. Some PCMs have high melting point which would not melt entirely during low solar radiation periods; hence, this study investigates on the addition of conductive particles in PCMs. This study reports the results from experiments combining various types of PCMs and conductive particles in a solar distiller. Petroleum jelly (PJ) and paraffin wax (PW), along with aluminium scrap and aluminium oxide (Al2O3) nanopowder as conductive particles, were tested in single-slope solar stills to evaluate their performance under varying solar irradiation in a tropical climate country. It can be concluded that the addition of PW as PCM has increased the efficiency of the solar still significantly, and the addition of conductive particles has shown further notable improvements. Interestingly, the relatively expensive Aluminium oxide (Al2O3) nanoparticles and the cost-effective Aluminium scrap chip exhibited similar performance levels. Among the different sets of experiments, solar still with PW and Aluminium scrap was 17.98 % efficient with a yield of 0.457 kg/m2 per day, and its production was 2.8 times higher than the conventional solar still. The solar still with Al2O3 nanoparticle embedded PW showed an increase in productivity by 27 % compared to the still with aluminium scrap mixed PW; where the water yield is 0.342 kg/m2 per day, 0.038 kg/m2 more than the solar still with aluminium scrap mixed PW. The cost of water produced per litre was up to 0.011 US$/litre. This study opens a pathway for further investigation on the efficiency and productivity associated with different categories of conductive particles usually associated with PCM in solar still research in the tropics.
{"title":"Enhancing solar still productivity in tropical climate with conductive particle-assisted phase change material","authors":"Jia Hui Tan , Yuin Yue Liew , Rubina Bahar , Hieng Kiat Jun , Jaslyn Low","doi":"10.1016/j.solmat.2024.113227","DOIUrl":"10.1016/j.solmat.2024.113227","url":null,"abstract":"<div><div>Solar desalination may become the sustainable solution to mitigate freshwater scarcity with growing demand. However, conventional solar stills for desalination are limited to low production efficiency caused by low/unavailable solar irradiation. Current research in thermal energy storage (TES) for solar desalination utilizes phase change materials (PCM) to store solar heat, ensuring uninterrupted energy for distillate production. Some PCMs have high melting point which would not melt entirely during low solar radiation periods; hence, this study investigates on the addition of conductive particles in PCMs. This study reports the results from experiments combining various types of PCMs and conductive particles in a solar distiller. Petroleum jelly (PJ) and paraffin wax (PW), along with aluminium scrap and aluminium oxide (Al<sub>2</sub>O<sub>3</sub>) nanopowder as conductive particles, were tested in single-slope solar stills to evaluate their performance under varying solar irradiation in a tropical climate country. It can be concluded that the addition of PW as PCM has increased the efficiency of the solar still significantly, and the addition of conductive particles has shown further notable improvements. Interestingly, the relatively expensive Aluminium oxide (Al<sub>2</sub>O<sub>3</sub>) nanoparticles and the cost-effective Aluminium scrap chip exhibited similar performance levels. Among the different sets of experiments, solar still with PW and Aluminium scrap was 17.98 % efficient with a yield of 0.457 kg/m<sup>2</sup> per day, and its production was 2.8 times higher than the conventional solar still. The solar still with Al<sub>2</sub>O<sub>3</sub> nanoparticle embedded PW showed an increase in productivity by 27 % compared to the still with aluminium scrap mixed PW; where the water yield is 0.342 kg/m<sup>2</sup> per day, 0.038 kg/m<sup>2</sup> more than the solar still with aluminium scrap mixed PW. The cost of water produced per litre was up to 0.011 US$/litre. This study opens a pathway for further investigation on the efficiency and productivity associated with different categories of conductive particles usually associated with PCM in solar still research in the tropics.</div></div>","PeriodicalId":429,"journal":{"name":"Solar Energy Materials and Solar Cells","volume":"279 ","pages":"Article 113227"},"PeriodicalIF":6.3,"publicationDate":"2024-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142529156","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}