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Heterogeneous velocity and dispersions coefficient influence on ionic transport model in creeks 非均匀流速和色散系数对溪流中离子输运模式的影响
Pub Date : 2022-09-02 DOI: 10.15406/mseij.2022.06.00186
Eluozo Sn, Ikebude Cf
This paper shows the rate of ionic concentration in the creek, different station point were used to monitor their variation rates of concentration in the creek, the transport system were developed based on the investigation carried out to observed the source of contamination in the study environment, the process were applied in other to determine the significant parameters that influence the transport process of the contaminant, these generates variations of the creek velocity and dispersion coefficient, the flow rates experienced heterogeneity in its depositions through its velocity rates at different station points, such parameters were integrated in the system to generated derived simulation values, the graphical representation experience decrease with respect to increase in distance, these condition observed were due to variations of the creek flow rates through velocity of flows in different figures, such conditions were observed to pressured the system that determine the concentration rates at different figures, these figures reflects different station points that validated the predictive values through experimental data for model validation, the generated results were above the permissible limited as an acceptable standard of 0.3Mg/L, the study is imperative because the rate of ionic content in different locations has been determined, their influential parameters has be observed in the study environment, there rates of concentrations which reflects the significant parameters that pressured it transport process in the creek has been observed, these were all determined in the study environment, proofing the validation of the model for ionic concentration in the study area.
本文给出了河流中离子浓度的变化速率,利用不同的监测点监测其在河流中的浓度变化速率,在对研究环境中的污染源进行调查的基础上开发了传输系统,并将该过程应用于其他环境中,以确定影响污染物传输过程的重要参数。这些变化产生了小溪流速和弥散系数的变化,流速通过不同站点的流速在其沉积过程中表现出非均质性,将这些参数集成到系统中生成导出的模拟值,图形表示体验随着距离的增加而减小,这些观测到的情况是由于不同图中水流流速的变化导致小溪流速的变化。观察这些条件对系统施加压力,确定不同的浓度率,这些数字反映了不同的站点,通过实验数据验证了预测值,进行模型验证,生成的结果超过了允许的限制,作为0.3Mg/L的可接受标准,由于确定了不同位置的离子含量率,因此研究势在必行。在研究环境中观察到它们的影响参数,观察到反映在溪流中施加压力的重要参数的浓度率,这些都是在研究环境中确定的,证明了研究区域离子浓度模型的有效性。
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引用次数: 0
The fluorescence study of the quenching of nanoemulsion by protoporphyrin IX (PPIX) 原卟啉IX (PPIX)猝灭纳米乳的荧光研究
Pub Date : 2022-08-15 DOI: 10.15406/mseij.2022.06.00185
Maurice O Iwunze
Nanoemulsion is a unique and versatile fluid that solubilizes both ionic and non-ionic molecules. It has been used extensively for drug delivery. Nanoemulsion, prepared with water-oil-surfactant and co-surfactant, is fluorescent at or the near IR region of electromagnetic spectrum. However, when protoporphyrin (PPIX), a useful photosensitizer in PDT modality, and a poorly water-soluble compound, is introduced into the nanoemulsion medium, the observed fluorescence of the nanoemulsion is quenched. We have used the steady-state fluorescence technique to study the mechanism of this quenching. It is observed that the interaction between nanoemulsion and PPIX is 1:1 and the interaction constant, Ka, is about 2.37 x 105/mol and the Free energy of interactions, Ga, is -30.66 kJ/mol.
纳米乳液是一种独特的多功能流体,可溶解离子和非离子分子。它已被广泛用于药物输送。以水-油表面活性剂和助表面活性剂制备的纳米乳在电磁波谱的红外区或近红外区呈荧光。然而,当原卟啉(PPIX),一种在PDT模式下有用的光敏剂,和一种水溶性差的化合物,被引入到纳米乳液介质中时,观察到的纳米乳液的荧光被猝灭。我们利用稳态荧光技术研究了这种猝灭的机理。结果表明,纳米乳与PPIX的相互作用为1:1,相互作用常数Ka约为2.37 × 105/mol,相互作用的自由能Ga为-30.66 kJ/mol。
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引用次数: 0
Capturing formaldehyde in cigarette smoke by zeolite and porous sorbents 用沸石和多孔吸附剂捕获香烟烟雾中的甲醛
Pub Date : 2022-07-28 DOI: 10.15406/mseij.2022.06.00184
X. Sun, Jing Yang, Yi Cao, J. Zhu
A spectrophotometric method of pararosaniline hydrochloride is reported for rapid determination of formaldehyde (HCHO) content in cigarette smoke in common lab and it has been used to assess the removal of HCHO by zeolites and other porous sorbents conveniently. Through the evaluation in nitrogen flow and cigarette smoke, some porous sorbents were found to exert the attractive performance in capture of HCHO in smoke even in the harsh experiment, which is proven by ISO standard test and provided some candidates for environment protection.
报道了一种用盐酸副罗什苯胺分光光度法快速测定普通实验室卷烟烟气中甲醛(HCHO)含量的方法,并用于评价沸石和其他多孔吸附剂对甲醛(HCHO)的去除效果。通过对氮气流和卷烟烟雾的评价,发现一些多孔吸附剂即使在严酷的实验条件下,也能在烟气中发挥良好的捕集性能,并通过ISO标准试验证明了这一点,为环保提供了一些候选材料。
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引用次数: 0
Human exposure to heavy metals: toxicity mechanisms and health implications 人体接触重金属:毒性机制和健康影响
Pub Date : 2022-07-15 DOI: 10.15406/mseij.2022.06.00183
Franklyn Okechukwu Ohiagu, PAUL CHIDOKA CHIKEZIE, C. C. Ahaneku, C. Chikezie
Human exposure to heavy metals is inevitable as heavy metals are continually present in air, water and food. Anthropogenic and industrial activities have rapidly increased the level of human exposure to heavy metals. Some heavy metals elicit deleterious health effects even at low levels in the body system. Every heavy metal has its own specific unique mechanistic process through which it exhibits toxicity. The major mechanisms through which most heavy metals such as Cr, As, Pb, Cu, Fe, Cd, Zn, Ni cause toxicity include the generation of reactive oxygen species (ROS), inhibition of enzyme activities and attenuation of antioxidant defense systems. Heavy metal ions are known to interfere with DNA and nuclear proteins leading to DNA structural and functional impairments as well as changes that initiate carcinogenesis, apoptosis as well as modulation of cell cycle. Heavy metal toxicity alters the activity of the central nervous system, and thereby causes mental disorder, alters blood composition, and liver, kidneys, lungs functions as well as other important body organs, resulting in the escalation of assorted human diseases. Prolonged human exposure and accumulation of heavy metals in the body aggravate the progression of physical, muscular and neurological degenerative processes that mimic certain diseases such as Alzheimer’s disease and Parkinson’s disease. Heavy metals mimic hormonal activities that alter the functions of the endocrine system. Thus, efforts must be made to mitigate the extent of human exposure and accumulation of heavy metals in the body as a result of anthropogenic and industrial activities in order to prevent incidences of deleterious health challenges.
人体接触重金属是不可避免的,因为重金属持续存在于空气、水和食物中。人为活动和工业活动迅速增加了人类接触重金属的水平。一些重金属即使在体内含量很低的情况下也会对健康产生有害影响。每种重金属都有其特定的、独特的机制过程,从而表现出毒性。Cr、as、Pb、Cu、Fe、Cd、Zn、Ni等重金属引起毒性的主要机制包括活性氧(ROS)的产生、酶活性的抑制和抗氧化防御系统的衰减。已知重金属离子干扰DNA和核蛋白,导致DNA结构和功能损伤,以及引发致癌、凋亡和细胞周期调节的变化。重金属中毒改变中枢神经系统的活动,从而引起精神障碍,改变血液成分和肝、肾、肺等重要身体器官的功能,导致各种人类疾病的升级。人体长期接触和在体内积累重金属会加剧身体、肌肉和神经退化过程的进展,类似于阿尔茨海默病和帕金森病等某些疾病。重金属模拟荷尔蒙活动,改变内分泌系统的功能。因此,必须努力减少由于人为活动和工业活动导致的人体接触和积累重金属的程度,以防止有害健康挑战的发生。
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引用次数: 5
Optical properties of low-refractive index polymers 低折射率聚合物的光学性质
Pub Date : 2022-07-11 DOI: 10.15406/mseij.2022.06.00182
Nuggehalli M Ravindra, Airefetalo Sadoh, S. Hossain, Sheldon Fereira
The study of optical properties of polymers is an integral part of smart materials research. It has immense potential in diverse fields spanning from structural health monitoring and underwater surveillance to medical imaging and automobile industries. Polymers are excellent candidates for these purposes due to their adaptable physical properties, one of which is their optical response to external stimuli such as temperature, pressure, magnetic fields, humidity, surrounding gases etc. Thus, being able to predict these responses is invaluable in the formulation of devices that are relevant to these applications. This paper presents a study of the simulation of the optical properties of several polymers when exposed to electromagnetic radiation, ranging from Ultra Violet to Near-Infra Red. A simulation of the influence of varying thicknesses of polymers (10, 50, 100 µm) on substrates [silicon (10, 50, 100 µm) and metal (Au) (0.025, 0.053, 0.117 µm)], on the optical properties, is presented in this study. Consequently, the results of these simulations serve as a guideline for selecting the best material configuration for the desired application. The optical bandgap of some of the polymer candidates is examined in light of Tauc’s method of analysis of the absorption coefficient variation with energy.
聚合物光学性质的研究是智能材料研究的重要组成部分。从结构健康监测和水下监测到医学成像和汽车工业,它在各个领域都有巨大的潜力。聚合物是这些用途的优秀候选者,因为它们具有适应性强的物理特性,其中之一是它们对外部刺激(如温度、压力、磁场、湿度、周围气体等)的光学响应。因此,能够预测这些响应在制定与这些应用相关的设备是无价的。本文介绍了几种聚合物暴露在从紫外线到近红外的电磁辐射下的光学特性的模拟研究。本研究模拟了在衬底[硅(10、50、100微米)和金属(Au)(0.025、0.053、0.117微米)]上不同厚度的聚合物(10、50、100微米)对光学性能的影响。因此,这些模拟的结果可作为为所需应用选择最佳材料配置的指导方针。利用陶克吸收系数随能量变化的分析方法,研究了一些候选聚合物的光学带隙。
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引用次数: 1
Influence of esterification and neutralization in the production of biodiesel: a comparison study 酯化和中和对生物柴油生产影响的比较研究
Pub Date : 2022-06-27 DOI: 10.15406/mseij.2022.06.00181
Ajadi Ik, Abdullahi Nb, Musa Q, Hassan Y, Oyegoke T
The challenges of emission of greenhouse gases (GhG) have triggered researchers all over the world to come up with alternative fuel sources that reduce greenhouse gas emissions. One of such alternatives is Biodiesel production from Neem and Jatropha seed oils. However, the presence of Free Fatty Acids (FFA) in the oil obtained from these seeds reduces the yield of produced biodiesel. Two common methods proposed in previous literature to reduce the free fatty acids value are the Esterification and Neutralization methods. This study focused on comparing the esterification and neutralization method as a preliminary stage of biodiesel production from Neem seed and Jatropha seed oils, in an effort to advance biodiesel production in terms of yield from its process. The Neem and Jatropha seed oils were esterified with concentrated sulphuric acid and were tested for free fatty acids. Both seed oils were then refined via the degumming process, after which they were neutralized with sodium hydroxide. The study shows the neutralization method with a yield of 96% and 94% for Neem seed oil and Jatropha seed oil respectively to be more efficient than the Esterification method which produced a yield of 93.2% for Neem seed oil and 91.4% for Jatropha seed oil.
温室气体排放的挑战促使世界各地的研究人员提出了减少温室气体排放的替代燃料来源。其中一种替代品是用印度楝树和麻疯树种子油生产生物柴油。然而,从这些种子中获得的油中游离脂肪酸(FFA)的存在降低了生产的生物柴油的产量。以往文献中提出的降低游离脂肪酸值的两种常用方法是酯化法和中和法。本研究的重点是比较印度楝籽和麻疯树籽油的酯化和中和法作为生产生物柴油的初级阶段,以期从其工艺的产量方面推进生物柴油的生产。用浓硫酸酯化印楝树和麻疯树籽油,测定其游离脂肪酸。然后通过脱胶过程提炼两种种子油,然后用氢氧化钠中和。研究表明,中和法对印楝籽油和麻疯树籽油的收率分别为96%和94%,比酯化法对印楝籽油和麻疯树籽油的收率分别为93.2%和91.4%更有效。
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引用次数: 0
On the shape and size of liquid droplets on flat solid surfaces 在平坦的固体表面上液滴的形状和大小
Pub Date : 2022-06-26 DOI: 10.15406/mseij.2022.06.00180
Mestechkin M
This article introduces two dimensionless positive geometric parameters that characterize the shape of a liquid droplet on a flat solid surface, which formed by the surface tension. The first parameter, “shape coefficient” K, is defined by the ratio of volume to surface and is always >3 (3 is the space dimension). The second parameter, “holding limit” κ0, is defined by the fraction of osculating surface and K and is <1. The ratio of the surface tension energy of a droplet attached to a substrate in zero gravity to the energy of the same droplet floating in zero gravity is presented through these parameters as 1-(K-3)(κ0-κ)/3(1-κ0), where the material parameter κ (which appears in the Young equation κ=cosθ) indicates the decrease in liquid surface tension by the solid The relative energy of the surface tension, K and κ0, are explicitly expressed for a droplet of an elliptical rounded segment (ERS) shape through its eccentricity e, relative height χ, and relative rounding radius η. It is shown that the Young equation is a self-consistent (i.e., leading to η=0) minimum condition of the energy only in the spherical (e=0) case. The rounding, either inner or outer, is specified by the legs of a triangle with zero angles and the median as a slope line. The main result obtained is the proof that the outer rounded ERS weighty droplets with inflection points, due to weight and hydrostatic forces, cannot exist if their radii larger than 2-4 capillary length. This proscription is absent in zero gravity.
本文介绍了表征平面固体表面上液滴形状的两个无量纲正几何参数,它们是由表面张力形成的。第一个参数“形状系数”K,由体积与表面的比值定义,且总是>3(3为空间维度)。第二个参数“保持极限”κ0,由接触面与K的分数定义,且<1。在失重状态下附着在衬底上的液滴的表面张力能与在失重状态下漂浮的液滴的表面张力能之比通过这些参数表示为1-(K-3)(κ0-κ)/3(1-κ0),其中材料参数κ(出现在Young方程κ= cost θ中)表示固体对液体表面张力的降低。通过偏心率e、相对高度χ和相对圆弧半径η来明确表示椭圆圆弧段(ERS)形状的液滴。结果表明,只有在e=0的球形情况下,Young方程是能量的自洽(即导致η=0)最小条件。内部或外部的舍入由三角形的腿指定,三角形的角为零,中间为斜线。得到的主要结果是证明了具有拐点的外圆形ERS重液滴,由于重量和流体静力的作用,当其半径大于2-4毛细长度时,不可能存在。这种禁止在零重力下是不存在的。
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引用次数: 2
Improved engineered scoring system for bicycle lane mapping development 改进了自行车道测绘工程计分系统
Pub Date : 2022-06-17 DOI: 10.15406/mseij.2022.06.00179
Mena I Souliman, Nitish R Bastola
This paper intends to present the development of the Improved Bicycle Lane Engineered Scoring System (iBLESS). The iBLESS consists of a numerical ranking table that compares traffic volume data; speed limit; number of lanes; road width; presence of the vehicle parking; presence of night street light; road grade; overall travel length; and presence of existing bicycle lanes that is utilized to design and map the optimum achievable locations for the implementation of bicycle lanes. The City of Tyler, Texas, is utilizing the iBLESS to design a Hub-and-Spoke bicycle lane network around the city. The current map design utilizing the iBLESS is comprised of eleven bicycle spokes, and seven bicycle spoke-connections, reaching a total distance of over 55 miles (88.5km) of bicycle lanes. The presence of bicycle lanes will extend throughout the entire city, resulting in the introduction of a new mode of transportation to the City of Tyler. Results indicate that the iBLESS is a simple and useful methodology to compare and analyze roads for bicycle lane development. Since this system selects the optimal road candidates, the bicycle users feel more comfortable using bicycle lanes as opposed to riding in a roadway.
本文介绍了改进的自行车道工程评分系统(iBLESS)的开发。iBLESS包括一个比较交通量数据的数值排名表;速度限制;车道数;道路宽度;车辆停车场的存在;夜路灯的存在;道路等级;总行程长度;并利用现有自行车道的存在来设计和绘制自行车道实施的最佳可实现位置。德克萨斯州泰勒市正在利用iBLESS在城市周围设计一个轮辐式自行车道网络。目前使用iBLESS的地图设计由11个自行车辐条和7个自行车辐条连接组成,总长度超过55英里(88.5公里)的自行车道。自行车道的存在将延伸到整个城市,从而为泰勒市引入一种新的交通方式。结果表明,iBLESS是一种简便、有效的道路对比分析方法。由于该系统选择了最优的候选道路,因此自行车使用者使用自行车道比在道路上骑行更舒适。
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引用次数: 0
Classifying the gravitational waves using the deep learning technique 使用深度学习技术对引力波进行分类
Pub Date : 2022-06-14 DOI: 10.15406/mseij.2022.06.00178
Al Mahmud Al Mamun, Md. Ashik Iqbal
Gravitational waves are related to the concept of vibration of space-time curvature. When the body of heavy masses lies on the four-dimensional space-time and changes their position with turbulence motion then actually they create a disturbance in the space. The disturbance travels outward from the origin having light velocity is known as gravitational waves. Laser Interferometer Gravitational-Wave Observatory (LIGO) scientific teamwork declared the identification of these waves. In this paper, we review Gravitational waves, Detection of gravitational waves, deep learning for the classification of gravitational waves. We design and develop a deep learning system to classification gravitational waves of the dataset ‘Gravity Spy (Gravitational waves)’ that is made up of the LIGO images. The goals of this research are to gain a piece of reasonable and useful knowledge about Gravitational waves and propose an effective deep learning network system to classify the gravitational waves. The accuracy achieved by our model is 99.34%.
引力波与时空曲率的振动概念有关。当大质量物体位于四维时空上,并随着湍流运动而改变其位置时,实际上会在空间中产生扰动。以光速从原点向外传播的扰动被称为引力波。激光干涉仪引力波天文台(LIGO)的科学团队宣布确认了这些引力波。本文综述了引力波、引力波探测、引力波分类的深度学习。我们设计并开发了一个深度学习系统,用于对由LIGO图像组成的数据集“Gravity Spy(引力波)”中的引力波进行分类。本研究的目标是获得关于引力波的合理和有用的知识,并提出一种有效的深度学习网络系统来对引力波进行分类。该模型的准确率为99.34%。
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引用次数: 1
Structural changes of TiO2 as a result of CNTs incorporation CNTs掺入后TiO2的结构变化
Pub Date : 2022-05-27 DOI: 10.15406/mseij.2022.06.00177
A. Grozdanov, P. Paunović, P. Makreski, Iva Dimitrievska, A. Petrovski
The subject of this research work was to analyze the structural and morphological changes of TiO2 as a result of incorporation of CNTs and interpret the underlying principles for the observed interactions. Hybrid TiO2/CNTs nanostructures were prepared by simplified sol-gel method followed by monitoring the thermally-induced alterations occurring up to 400 ºC. The effects of different type of CNTs (activated MWCNTs and as prepared SWCNTs) as well as the variation of the content of MWCNTs in association with the metal-dopant (Pt or Co) influencing the structural parameters of TiO2 was monitored. Addition of CNTs and metallic phase causes reduction of TiO2 (anatase) crystallite size. The applied instrumental techniques such as XRPD, Raman spectroscopy and thermal (TG, DTA and DTG) analysis points out on achieved interaction between TiO2 and incorporated CNTs. Morphological changes, observed from the SEM micrographs, revealed better inter-locking of the TiO2 matrix with SWCNTs than with MWCNTs. Formation of a more structurally disordered and non-stoichiometric anatase phase seemed to be a preferred choice for the obtained TiO2-CNT-metalic phase nanocomposites for further utilization in sensor-design products.
本研究工作的主题是分析CNTs掺入后TiO2的结构和形态变化,并解释所观察到的相互作用的基本原理。采用简化的溶胶-凝胶法制备了TiO2/CNTs杂化纳米结构,并监测了在高达400℃时发生的热致改变。研究了不同类型的CNTs(活化的MWCNTs和制备的SWCNTs)以及MWCNTs含量随金属掺杂剂(Pt或Co)的变化对TiO2结构参数的影响。CNTs和金属相的加入使TiO2(锐钛矿)晶粒尺寸减小。应用的仪器技术如XRPD、拉曼光谱和热分析(TG、DTA和DTG)指出了TiO2与掺入的CNTs之间实现的相互作用。从SEM显微图中观察到的形态变化表明,与MWCNTs相比,SWCNTs能更好地互锁TiO2基体。对于获得的二氧化钛-碳纳米管金属相纳米复合材料来说,形成结构更无序和非化学计量的锐钛矿相似乎是进一步应用于传感器设计产品的首选。
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引用次数: 1
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Material Science &amp; Engineering International Journal
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