Pub Date : 2021-09-30DOI: 10.31025/2611-4135/2021.15118
P. Cerchier, K. Brunelli, L. Pezzato, C. Audoin, J. Rakotoniaina, Teresa Sessa, M. Tammaro, G. Sabia, A. Attanasio, Chiara Forte, A. Nisi, Harald Suitner, M. Dabalà
In Europe, an increasing amount of End of Life (EoL) photovoltaic silicon (PV) panels is expected to be collected in the next 20 years. The silicon PV modules represent a new type of electronic waste that shows challenges and opportunities. ReSiELP was a European project that aimed at recovery of valuable materials (aluminum, glass, copper, silicon, and silver) from EoL silicon PV modules. During the project a pilot plant, constituted by a furnace, a gas abatement system, an apparatus for the mechanical separation and a hydrometallurgical plant was designed and built. The pilot plan was realized to upscale recycling technology to TRL 7, with a 1500 panels/year capacity. The feasibility of industrial-scale recovery and the reintegration of all recovered materials in their appropriate value chain was investigated. The results obtained showed that 2N purity silicon and 2N purity silver can be recovered with high efficiency. In order to realize a zero-waste plant, a hydrometallurgical process was developed for the wastewater treatment. Moreover, the use of recovered glass for building materials was investigated and the obtained performance seemed comparable with commercial products.
{"title":"Innovative recycling of end of life silicon PV panels: ReSiELP","authors":"P. Cerchier, K. Brunelli, L. Pezzato, C. Audoin, J. Rakotoniaina, Teresa Sessa, M. Tammaro, G. Sabia, A. Attanasio, Chiara Forte, A. Nisi, Harald Suitner, M. Dabalà","doi":"10.31025/2611-4135/2021.15118","DOIUrl":"https://doi.org/10.31025/2611-4135/2021.15118","url":null,"abstract":"In Europe, an increasing amount of End of Life (EoL) photovoltaic silicon (PV) panels is expected to be collected in the next 20 years. The silicon PV modules represent a new type of electronic waste that shows challenges and opportunities. \u0000ReSiELP was a European project that aimed at recovery of valuable materials (aluminum, glass, copper, silicon, and silver) from EoL silicon PV modules. During the project a pilot plant, constituted by a furnace, a gas abatement system, an apparatus for the mechanical separation and a hydrometallurgical plant was designed and built. The pilot plan was realized to upscale recycling technology to TRL 7, with a 1500 panels/year capacity. The feasibility of industrial-scale recovery and the reintegration of all recovered materials in their appropriate value chain was investigated. The results obtained showed that 2N purity silicon and 2N purity silver can be recovered with high efficiency. In order to realize a zero-waste plant, a hydrometallurgical process was developed for the wastewater treatment. Moreover, the use of recovered glass for building materials was investigated and the obtained performance seemed comparable with commercial products.","PeriodicalId":44191,"journal":{"name":"Detritus","volume":null,"pages":null},"PeriodicalIF":1.7,"publicationDate":"2021-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42414090","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-09-30DOI: 10.31025/2611-4135/2021.15122
P. Hennebert
Plastics containing brominated flame retardants (BFR) currently contain both “legacy” regulated and non-regulated BFR (R-BFRs and NR-BFRs), as evidenced by the increasingly lower correspondence over time between total bromine and R-BFRs content. The portion of substitutive NR-BFR present in the plastics and their toxicity and ecotoxicity properties are documented. Data relating to plastics and foam present in electrical and electronic equipment (EEE), waste EEE, vehicles, textiles and upholstery, toys, leisure and sports equipment show how 88% of plastic waste contains bromine from NR-BFRs. BFR substances mentioned in the catalogs of the three main producers (Albemarle, ICL, Lanxess) and BFR on the official used list of 418 plastic additives in the EU were gathered and the toxic and ecotoxic properties of these compounds as listed in their ECHA registration dossier were compiled. Fifty-five preparations using 34 NR-BFRs substances, including polymers and blends, were found. Seventeen of these substances featured an incomplete dossier, 12 were equipped with a complete dossier, whilst 11 substances (including 2 ill-defined blends) should be reassessed. Eight substances have been notified for assessment by the ECHA as persistent, bioaccumulative and toxic, or as endocrine disruptors, including decabromodiphenylethane; 3 substances display functional concentrations (the concentration of additives that retards flame) exceeding the concentration limits classifying a waste as hazardous but are “reactive” (they bind to the polymer). The technical limit of 2 000 mg total Br/kg indicated for further recycling (EN 50625-3-1) relates to all brominated substances and is relevant in the sorting of all poorly classified new substances.
{"title":"THE SUBSTITUTION OF REGULATED BROMINATED FLAME RETARDANTS IN PLASTIC PRODUCTS AND WASTE AND THE DECLARED PROPERTIES OF THE SUBSTITUTES IN REACH","authors":"P. Hennebert","doi":"10.31025/2611-4135/2021.15122","DOIUrl":"https://doi.org/10.31025/2611-4135/2021.15122","url":null,"abstract":"Plastics containing brominated flame retardants (BFR) currently contain both “legacy” regulated and non-regulated BFR (R-BFRs and NR-BFRs), as evidenced by the increasingly lower correspondence over time between total bromine and R-BFRs content. The portion of substitutive NR-BFR present in the plastics and their toxicity and ecotoxicity properties are documented. Data relating to plastics and foam present in electrical and electronic equipment (EEE), waste EEE, vehicles, textiles and upholstery, toys, leisure and sports equipment show how 88% of plastic waste contains bromine from NR-BFRs. BFR substances mentioned in the catalogs of the three main producers (Albemarle, ICL, Lanxess) and BFR on the official used list of 418 plastic additives in the EU were gathered and the toxic and ecotoxic properties of these compounds as listed in their ECHA registration dossier were compiled. Fifty-five preparations using 34 NR-BFRs substances, including polymers and blends, were found. Seventeen of these substances featured an incomplete dossier, 12 were equipped with a complete dossier, whilst 11 substances (including 2 ill-defined blends) should be reassessed. Eight substances have been notified for assessment by the ECHA as persistent, bioaccumulative and toxic, or as endocrine disruptors, including decabromodiphenylethane; 3 substances display functional concentrations (the concentration of additives that retards flame) exceeding the concentration limits classifying a waste as hazardous but are “reactive” (they bind to the polymer). The technical limit of 2 000 mg total Br/kg indicated for further recycling (EN 50625-3-1) relates to all brominated substances and is relevant in the sorting of all poorly classified new substances.","PeriodicalId":44191,"journal":{"name":"Detritus","volume":null,"pages":null},"PeriodicalIF":1.7,"publicationDate":"2021-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45101998","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-09-30DOI: 10.31025/2611-4135/2021.15120
P. Hennebert
European "Technical Recommendations" have proposed, in addition to the use of substance concentrations, the use of a pH (≤ 2 or ≥ 11.5) and an acid / base buffering capacity to classify waste into according to their hazardous properties HP 4 'Irritant' and HP 8 'Corrosive'. Buffer capacity refers to a 2018 UK classification guide referring to the 'corrosive' level of a method proposed in 1988 for substances and preparations but not retained in EU regulations. The different methods of classifying products and wastes in terms of corrosivity or irritation are compared. The waste method using pH and buffering capacity is expressed as an acid / base concentration and compared to the product method (CLP). The “corrosive” level of 1988 corresponds to an average acid / base concentration ≥ 14.4Ͽie 14 times less severe than CLP (acid / base concentration ≥ 1Ͽ These methods were applied to five alkaline wastes (pH ≥ 11.5). Minimum pH waste is not classified by both methods, and three higher pH wastes are classified by both methods. Intermediate waste is classified by CLP but not by the proposed waste method. In order not to innovate and create a new divergence between products and waste, it seems preferable to use the product regulations for HP 4 and HP 8. Fortunately, the elimination of the danger HP 4 and HP 8 from acidic or alkaline waste can be obtained by neutralization (possibly by other wastes), including for alkaline wastes by (natural) carbonation by atmospheric CO2.
{"title":"Waste hazard properties HP 4 ‘Irritant’ and HP 8 ‘Corrosive’ by pH, acid/base buffer capacity and acid/base concentration","authors":"P. Hennebert","doi":"10.31025/2611-4135/2021.15120","DOIUrl":"https://doi.org/10.31025/2611-4135/2021.15120","url":null,"abstract":"European \"Technical Recommendations\" have proposed, in addition to the use of substance concentrations, the use of a pH (≤ 2 or ≥ 11.5) and an acid / base buffering capacity to classify waste into according to their hazardous properties HP 4 'Irritant' and HP 8 'Corrosive'. Buffer capacity refers to a 2018 UK classification guide referring to the 'corrosive' level of a method proposed in 1988 for substances and preparations but not retained in EU regulations. The different methods of classifying products and wastes in terms of corrosivity or irritation are compared. The waste method using pH and buffering capacity is expressed as an acid / base concentration and compared to the product method (CLP). The “corrosive” level of 1988 corresponds to an average acid / base concentration ≥ 14.4Ͽie 14 times less severe than CLP (acid / base concentration ≥ 1Ͽ These methods were applied to five alkaline wastes (pH ≥ 11.5). Minimum pH waste is not classified by both methods, and three higher pH wastes are classified by both methods. Intermediate waste is classified by CLP but not by the proposed waste method. In order not to innovate and create a new divergence between products and waste, it seems preferable to use the product regulations for HP 4 and HP 8. Fortunately, the elimination of the danger HP 4 and HP 8 from acidic or alkaline waste can be obtained by neutralization (possibly by other wastes), including for alkaline wastes by (natural) carbonation by atmospheric CO2.","PeriodicalId":44191,"journal":{"name":"Detritus","volume":null,"pages":null},"PeriodicalIF":1.7,"publicationDate":"2021-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46877162","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-09-30DOI: 10.31025/2611-4135/2021.15117
M. Dudynski
We present an analysis of influence of biomass pre-treatment and change of gasifying agent on the performance of an oxygen-steam-air updraft gasification plant and a technological process capable of delivering high quality producer gas. The results of these changes on composition of tar collected with absorption type gas purification unit, designed for dust and tar removal are also reported.
{"title":"WOOD GASIFICATION. INFLUENCE OF PROCESS PARAMETERS ON THE TAR FORMATION AND GAS CLEANING","authors":"M. Dudynski","doi":"10.31025/2611-4135/2021.15117","DOIUrl":"https://doi.org/10.31025/2611-4135/2021.15117","url":null,"abstract":"We present an analysis of influence of biomass pre-treatment and change of gasifying agent on the performance of an oxygen-steam-air updraft gasification plant and a technological process capable of delivering high quality producer gas. The results of these changes on composition of tar collected with absorption type gas purification unit, designed for dust and tar removal are also reported.","PeriodicalId":44191,"journal":{"name":"Detritus","volume":null,"pages":null},"PeriodicalIF":1.7,"publicationDate":"2021-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42185159","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-09-30DOI: 10.31025/2611-4135/2021.15119
P. S. S. Camargo, A. Domingues, J. Palomero, A. C. Kasper, P. Dias, H. Veit
ABSTRACT: This work investigated the thermal treatment to separate and concentrate economically valuable materials from laminates of crystalline silicon photovoltaic modules (i.e., photovoltaic modules without the aluminum frame and the junction box). Chemical characterization of the metal content was performed by X-Ray Fluorescence (XRF). The polymers of the backsheet were also characterized by Fourier Transform Infrared Spectroscopy (FTIR). The influence of the atmosphere (oxidizing and inert) on the decomposition of the backsheet was investigated by Thermogravimetric Analysis (TGA). Moreover, non-comminuted samples were tested for 4 thermal time lengths (30, 60, 90, and 120 min) in the furnace under ambient air. The degradation of the polymers was measured and 3 material fractions were obtained: silicon with silver and residual polymers (SS), glass and copper ribbons. Furthermore, there was no statistical difference between the mass losses of the samples submitted for 90 (13.62 ± 0.02 wt.%) and 120 min at 500 °C (p-value = 0.062). In the SS fraction, silver was 20 times more concentrated than in the ground photovoltaic laminate and 30 times more concentrated than high silver concentration ores. The SS fraction (about 6 wt.%) also presented low copper concentration and a high concentration of lead (hazardous metal). About 79 wt.% glass was obtained, as well as 1% copper ribbons (55.69 ± 6.39% copper, 23.17 ± 7.51% lead, 16.06 ± 2.12% tin). The limitations of the treatment and its environmental impact are discussed, and suggestions for industrial-scale application are given.
{"title":"PHOTOVOLTAIC MODULE RECYCLING: THERMAL TREATMENT TO DEGRADE POLYMERS AND CONCENTRATE VALUABLE METALS","authors":"P. S. S. Camargo, A. Domingues, J. Palomero, A. C. Kasper, P. Dias, H. Veit","doi":"10.31025/2611-4135/2021.15119","DOIUrl":"https://doi.org/10.31025/2611-4135/2021.15119","url":null,"abstract":"ABSTRACT: This work investigated the thermal treatment to separate and concentrate economically valuable materials from laminates of crystalline silicon photovoltaic modules (i.e., photovoltaic modules without the aluminum frame and the junction box). Chemical characterization of the metal content was performed by X-Ray Fluorescence (XRF). The polymers of the backsheet were also characterized by Fourier Transform Infrared Spectroscopy (FTIR). The influence of the atmosphere (oxidizing and inert) on the decomposition of the backsheet was investigated by Thermogravimetric Analysis (TGA). Moreover, non-comminuted samples were tested for 4 thermal time lengths (30, 60, 90, and 120 min) in the furnace under ambient air. The degradation of the polymers was measured and 3 material fractions were obtained: silicon with silver and residual polymers (SS), glass and copper ribbons. Furthermore, there was no statistical difference between the mass losses of the samples submitted for 90 (13.62 ± 0.02 wt.%) and 120 min at 500 °C (p-value = 0.062). In the SS fraction, silver was 20 times more concentrated than in the ground photovoltaic laminate and 30 times more concentrated than high silver concentration ores. The SS fraction (about 6 wt.%) also presented low copper concentration and a high concentration of lead (hazardous metal). About 79 wt.% glass was obtained, as well as 1% copper ribbons (55.69 ± 6.39% copper, 23.17 ± 7.51% lead, 16.06 ± 2.12% tin). The limitations of the treatment and its environmental impact are discussed, and suggestions for industrial-scale application are given.","PeriodicalId":44191,"journal":{"name":"Detritus","volume":null,"pages":null},"PeriodicalIF":1.7,"publicationDate":"2021-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46512584","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-09-11DOI: 10.31025/2611-4135/2021.15111
Fabian Gievers, A. Loewen, M. Nelles
The pyrolysis of sewage sludge is an alternative method to recycle the contained nutrients, such as phosphorus, by material use of the resulting biochar. However, the ecological effects of pyrolysis are not easy to evaluate. Therefore, a life cycle assessment (LCA) was carried out to determine the environmental impact of sewage sludge pyrolysis and to compare it with the common method of sewage sludge incineration. In order to identify the most sustainable applications of the resulting biochar, four different scenarios were analyzed. The modeled life cycles include dewatering, drying and pyrolysis of digested sewage sludge and utilization paths of the by-products as well as various applications of the produced biochar and associated transports. The life cycle impact assessment was carried out using the ReCiPe midpoint method. The best scenario in terms of global warming potential (GWP) was the use of biochar in horticulture with net emissions of 2 g CO2 eq./kg sewage sludge. This scenario of biochar utilization can achieve savings of 78% of CO2 eq. emissions compared to the benchmark process of sewage sludge mono-incineration. In addition, no ecological hotspots in critical categories such as eutrophication or ecotoxicity were identified for the material use of biochar compared to the benchmark. Pyrolysis of digested sewage sludge with appropriate biochar utilization can therefore be an environmentally friendly option for both sequestering carbon and closing the nutrient cycle.
{"title":"Life cycle assessment of sewage sludge pyrolysis: environmental impacts of biochar as carbon sequestrator and nutrient recycler","authors":"Fabian Gievers, A. Loewen, M. Nelles","doi":"10.31025/2611-4135/2021.15111","DOIUrl":"https://doi.org/10.31025/2611-4135/2021.15111","url":null,"abstract":"The pyrolysis of sewage sludge is an alternative method to recycle the contained nutrients, such as phosphorus, by material use of the resulting biochar. However, the ecological effects of pyrolysis are not easy to evaluate. Therefore, a life cycle assessment (LCA) was carried out to determine the environmental impact of sewage sludge pyrolysis and to compare it with the common method of sewage sludge incineration. In order to identify the most sustainable applications of the resulting biochar, four different scenarios were analyzed. The modeled life cycles include dewatering, drying and pyrolysis of digested sewage sludge and utilization paths of the by-products as well as various applications of the produced biochar and associated transports. The life cycle impact assessment was carried out using the ReCiPe midpoint method. The best scenario in terms of global warming potential (GWP) was the use of biochar in horticulture with net emissions of 2 g CO2 eq./kg sewage sludge. This scenario of biochar utilization can achieve savings of 78% of CO2 eq. emissions compared to the benchmark process of sewage sludge mono-incineration. In addition, no ecological hotspots in critical categories such as eutrophication or ecotoxicity were identified for the material use of biochar compared to the benchmark. Pyrolysis of digested sewage sludge with appropriate biochar utilization can therefore be an environmentally friendly option for both sequestering carbon and closing the nutrient cycle.","PeriodicalId":44191,"journal":{"name":"Detritus","volume":null,"pages":null},"PeriodicalIF":1.7,"publicationDate":"2021-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48120601","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-09-11DOI: 10.31025/2611-4135/2021.15110
L. Ottosen, L. B. Jensen, T. Astrup, T. McAloone, Morten Ryberg, C. Thuesen, Solbrit Christiansen, A. J. Pedersen, Mads H. Odgaard
The building and construction sector is selected by the European Commission as a key product value chain in the transition towards circular economy (CE) due to the major resource consumption, waste generation and GHG emissions from this sector. This paper reports the result from qualitative and semi-structured interviews with 30 Danish stakeholders from the sector on the current stage of implementation of CE and the research/innovation needs to scale circular construction from niche to mainstream. The interviews showed a large variety in the stakeholder’s stage of transition from hardly knowing the term to having CE as a major driver in their business. Some meant that scaling of CE is close to impossible and that material reuse will never develop to more than a niche, whereas others already offer full-scale circular solutions to clients. The interviews pointed at a need for a common definition and terminology for CE, methods for documenting the gains from the circular solutions (economic and environmental), methods for technical documentation of the quality of reused materials, processes which enables scaling, methods to implement CE in various systems such as digitalization and building passports, new value chains and framework conditions in support of circularity. Regardless these needs, demonstration projects of major importance to gain general knowledge have been built or are planned in Denmark. These demonstrations have different approaches: using todays waste from different industries as construction materials; reusing construction materials (the basic building, elements or processed materials); and designing new buildings for disassembly to enable future reuse.
{"title":"IMPLEMENTATION STAGE FOR CIRCULAR ECONOMY IN THE DANISH BUILDING AND CONSTRUCTION SECTOR","authors":"L. Ottosen, L. B. Jensen, T. Astrup, T. McAloone, Morten Ryberg, C. Thuesen, Solbrit Christiansen, A. J. Pedersen, Mads H. Odgaard","doi":"10.31025/2611-4135/2021.15110","DOIUrl":"https://doi.org/10.31025/2611-4135/2021.15110","url":null,"abstract":"The building and construction sector is selected by the European Commission as a key product value chain in the transition towards circular economy (CE) due to the major resource consumption, waste generation and GHG emissions from this sector. This paper reports the result from qualitative and semi-structured interviews with 30 Danish stakeholders from the sector on the current stage of implementation of CE and the research/innovation needs to scale circular construction from niche to mainstream. The interviews showed a large variety in the stakeholder’s stage of transition from hardly knowing the term to having CE as a major driver in their business. Some meant that scaling of CE is close to impossible and that material reuse will never develop to more than a niche, whereas others already offer full-scale circular solutions to clients. The interviews pointed at a need for a common definition and terminology for CE, methods for documenting the gains from the circular solutions (economic and environmental), methods for technical documentation of the quality of reused materials, processes which enables scaling, methods to implement CE in various systems such as digitalization and building passports, new value chains and framework conditions in support of circularity. Regardless these needs, demonstration projects of major importance to gain general knowledge have been built or are planned in Denmark. These demonstrations have different approaches: using todays waste from different industries as construction materials; reusing construction materials (the basic building, elements or processed materials); and designing new buildings for disassembly to enable future reuse.","PeriodicalId":44191,"journal":{"name":"Detritus","volume":null,"pages":null},"PeriodicalIF":1.7,"publicationDate":"2021-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47001357","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-09-11DOI: 10.31025/2611-4135/2021.15115
F. Simon, C. Vogel, U. Kalbe
Due to its large mineral fraction, incineration bottom ash (IBA) from municipal solid waste incineration is an interesting raw material that can be used for road construction or to produce secondary building materials. However, leaching chloride, sulfate, and potentially harmful heavy metals may cause problems in using IBA in civil engineering. Investigating leaching behavior is crucial for the assessment of the environmental compatibility of IBA applications. Various test procedures are available for that purpose. In the present study, a long-term leaching test of a wet-mechanically treated IBA was performed in a lysimeter for almost six years. While concentrations of chloride, sulfate and the majority of the heavy metals started to decrease rapidly with advancing liquid-to-solid ratio (L/S), antimony (Sb) and vanadium (V) behaved differently. At the beginning of the lysimeter test, the Sb and V concentrations were low, but after approximately one year of operation at an L/S ratio of around 0.8 L/kg, a steady increase was observed. It was shown that this increase is the result of low Ca concentrations due to the formation of CaCO3. With the data, the solubility products from Ca-antimonate and Ca-vanadate were calculated. The unusual leaching behavior of Sb and V should be kept in mind when considering field scenarios and evaluating the impact on the environment.
{"title":"ANTIMONY AND VANADIUM IN INCINERATION BOTTOM ASH – LEACHING BEHAVIOR AND CONCLUSIONS FOR TREATMENT PROCESSES","authors":"F. Simon, C. Vogel, U. Kalbe","doi":"10.31025/2611-4135/2021.15115","DOIUrl":"https://doi.org/10.31025/2611-4135/2021.15115","url":null,"abstract":"Due to its large mineral fraction, incineration bottom ash (IBA) from municipal solid waste incineration is an interesting raw material that can be used for road construction or to produce secondary building materials. However, leaching chloride, sulfate, and potentially harmful heavy metals may cause problems in using IBA in civil engineering. Investigating leaching behavior is crucial for the assessment of the environmental compatibility of IBA applications. Various test procedures are available for that purpose. In the present study, a long-term leaching test of a wet-mechanically treated IBA was performed in a lysimeter for almost six years. While concentrations of chloride, sulfate and the majority of the heavy metals started to decrease rapidly with advancing liquid-to-solid ratio (L/S), antimony (Sb) and vanadium (V) behaved differently. At the beginning of the lysimeter test, the Sb and V concentrations were low, but after approximately one year of operation at an L/S ratio of around 0.8 L/kg, a steady increase was observed. It was shown that this increase is the result of low Ca concentrations due to the formation of CaCO3. With the data, the solubility products from Ca-antimonate and Ca-vanadate were calculated. The unusual leaching behavior of Sb and V should be kept in mind when considering field scenarios and evaluating the impact on the environment.","PeriodicalId":44191,"journal":{"name":"Detritus","volume":null,"pages":null},"PeriodicalIF":1.7,"publicationDate":"2021-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44349192","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-09-11DOI: 10.31025/2611-4135/2021.15112
A. Haouas, C. El Modafar, A. Douira, S. Ibnsouda-Koraichi, A. Filali-Maltouf, A. Moukhli, S. Amir
Phosphate sludge (PS) is an industrial by-product produced in huge quantities by the phosphate beneficiation plants in Morocco. In order to valorize this by-product, it was examined for its potential use as a soil fertilizer. The physicochemical properties, elemental and mineral content, morphological structure, and component stability of raw PS were investigated. In addition, pathogenicity, phytotoxicity, and the capacity of PS to promote plant growth in deficient sandy soil have been studied. The obtained results showed that PS was characterized by low values of moisture (2.10%), electrical conductivity (EC) (0.77 mS/cm), and organic matter (OM) (0.61%), with a slightly alkaline pH (8.20). Nevertheless, this material carried interesting content of fertilizing elements such as phosphorus (P2O5) of 20.01%, calcium (CaO) of 39.72%, and magnesium (MgO) of 2.33%. Thus, PS did not present any pathogenic or phytotoxic risk with a high increase in tomato plant growth than the control of only soil. In conclusion, the results of this study could provide the primary practical guidance for the PS application in deficient soils characterized by sandy texture.
{"title":"Phosphate sludge: opportunities for use as a fertilizer in deficient.","authors":"A. Haouas, C. El Modafar, A. Douira, S. Ibnsouda-Koraichi, A. Filali-Maltouf, A. Moukhli, S. Amir","doi":"10.31025/2611-4135/2021.15112","DOIUrl":"https://doi.org/10.31025/2611-4135/2021.15112","url":null,"abstract":"Phosphate sludge (PS) is an industrial by-product produced in huge quantities by the phosphate beneficiation plants in Morocco. In order to valorize this by-product, it was examined for its potential use as a soil fertilizer. The physicochemical properties, elemental and mineral content, morphological structure, and component stability of raw PS were investigated. In addition, pathogenicity, phytotoxicity, and the capacity of PS to promote plant growth in deficient sandy soil have been studied. The obtained results showed that PS was characterized by low values of moisture (2.10%), electrical conductivity (EC) (0.77 mS/cm), and organic matter (OM) (0.61%), with a slightly alkaline pH (8.20). Nevertheless, this material carried interesting content of fertilizing elements such as phosphorus (P2O5) of 20.01%, calcium (CaO) of 39.72%, and magnesium (MgO) of 2.33%. Thus, PS did not present any pathogenic or phytotoxic risk with a high increase in tomato plant growth than the control of only soil. In conclusion, the results of this study could provide the primary practical guidance for the PS application in deficient soils characterized by sandy texture.","PeriodicalId":44191,"journal":{"name":"Detritus","volume":null,"pages":null},"PeriodicalIF":1.7,"publicationDate":"2021-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44405963","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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