Pub Date : 2021-09-30DOI: 10.31025/2611-4135/2021.15117
M. Dudynski
We present an analysis of influence of biomass pre-treatment and change of gasifying agent on the performance of an oxygen-steam-air updraft gasification plant and a technological process capable of delivering high quality producer gas. The results of these changes on composition of tar collected with absorption type gas purification unit, designed for dust and tar removal are also reported.
{"title":"WOOD GASIFICATION. INFLUENCE OF PROCESS PARAMETERS ON THE TAR FORMATION AND GAS CLEANING","authors":"M. Dudynski","doi":"10.31025/2611-4135/2021.15117","DOIUrl":"https://doi.org/10.31025/2611-4135/2021.15117","url":null,"abstract":"We present an analysis of influence of biomass pre-treatment and change of gasifying agent on the performance of an oxygen-steam-air updraft gasification plant and a technological process capable of delivering high quality producer gas. The results of these changes on composition of tar collected with absorption type gas purification unit, designed for dust and tar removal are also reported.","PeriodicalId":44191,"journal":{"name":"Detritus","volume":" ","pages":""},"PeriodicalIF":1.7,"publicationDate":"2021-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42185159","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-09-30DOI: 10.31025/2611-4135/2021.15119
P. S. S. Camargo, A. Domingues, J. Palomero, A. C. Kasper, P. Dias, H. Veit
ABSTRACT: This work investigated the thermal treatment to separate and concentrate economically valuable materials from laminates of crystalline silicon photovoltaic modules (i.e., photovoltaic modules without the aluminum frame and the junction box). Chemical characterization of the metal content was performed by X-Ray Fluorescence (XRF). The polymers of the backsheet were also characterized by Fourier Transform Infrared Spectroscopy (FTIR). The influence of the atmosphere (oxidizing and inert) on the decomposition of the backsheet was investigated by Thermogravimetric Analysis (TGA). Moreover, non-comminuted samples were tested for 4 thermal time lengths (30, 60, 90, and 120 min) in the furnace under ambient air. The degradation of the polymers was measured and 3 material fractions were obtained: silicon with silver and residual polymers (SS), glass and copper ribbons. Furthermore, there was no statistical difference between the mass losses of the samples submitted for 90 (13.62 ± 0.02 wt.%) and 120 min at 500 °C (p-value = 0.062). In the SS fraction, silver was 20 times more concentrated than in the ground photovoltaic laminate and 30 times more concentrated than high silver concentration ores. The SS fraction (about 6 wt.%) also presented low copper concentration and a high concentration of lead (hazardous metal). About 79 wt.% glass was obtained, as well as 1% copper ribbons (55.69 ± 6.39% copper, 23.17 ± 7.51% lead, 16.06 ± 2.12% tin). The limitations of the treatment and its environmental impact are discussed, and suggestions for industrial-scale application are given.
{"title":"PHOTOVOLTAIC MODULE RECYCLING: THERMAL TREATMENT TO DEGRADE POLYMERS AND CONCENTRATE VALUABLE METALS","authors":"P. S. S. Camargo, A. Domingues, J. Palomero, A. C. Kasper, P. Dias, H. Veit","doi":"10.31025/2611-4135/2021.15119","DOIUrl":"https://doi.org/10.31025/2611-4135/2021.15119","url":null,"abstract":"ABSTRACT: This work investigated the thermal treatment to separate and concentrate economically valuable materials from laminates of crystalline silicon photovoltaic modules (i.e., photovoltaic modules without the aluminum frame and the junction box). Chemical characterization of the metal content was performed by X-Ray Fluorescence (XRF). The polymers of the backsheet were also characterized by Fourier Transform Infrared Spectroscopy (FTIR). The influence of the atmosphere (oxidizing and inert) on the decomposition of the backsheet was investigated by Thermogravimetric Analysis (TGA). Moreover, non-comminuted samples were tested for 4 thermal time lengths (30, 60, 90, and 120 min) in the furnace under ambient air. The degradation of the polymers was measured and 3 material fractions were obtained: silicon with silver and residual polymers (SS), glass and copper ribbons. Furthermore, there was no statistical difference between the mass losses of the samples submitted for 90 (13.62 ± 0.02 wt.%) and 120 min at 500 °C (p-value = 0.062). In the SS fraction, silver was 20 times more concentrated than in the ground photovoltaic laminate and 30 times more concentrated than high silver concentration ores. The SS fraction (about 6 wt.%) also presented low copper concentration and a high concentration of lead (hazardous metal). About 79 wt.% glass was obtained, as well as 1% copper ribbons (55.69 ± 6.39% copper, 23.17 ± 7.51% lead, 16.06 ± 2.12% tin). The limitations of the treatment and its environmental impact are discussed, and suggestions for industrial-scale application are given.","PeriodicalId":44191,"journal":{"name":"Detritus","volume":" ","pages":""},"PeriodicalIF":1.7,"publicationDate":"2021-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46512584","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-09-11DOI: 10.31025/2611-4135/2021.15111
Fabian Gievers, A. Loewen, M. Nelles
The pyrolysis of sewage sludge is an alternative method to recycle the contained nutrients, such as phosphorus, by material use of the resulting biochar. However, the ecological effects of pyrolysis are not easy to evaluate. Therefore, a life cycle assessment (LCA) was carried out to determine the environmental impact of sewage sludge pyrolysis and to compare it with the common method of sewage sludge incineration. In order to identify the most sustainable applications of the resulting biochar, four different scenarios were analyzed. The modeled life cycles include dewatering, drying and pyrolysis of digested sewage sludge and utilization paths of the by-products as well as various applications of the produced biochar and associated transports. The life cycle impact assessment was carried out using the ReCiPe midpoint method. The best scenario in terms of global warming potential (GWP) was the use of biochar in horticulture with net emissions of 2 g CO2 eq./kg sewage sludge. This scenario of biochar utilization can achieve savings of 78% of CO2 eq. emissions compared to the benchmark process of sewage sludge mono-incineration. In addition, no ecological hotspots in critical categories such as eutrophication or ecotoxicity were identified for the material use of biochar compared to the benchmark. Pyrolysis of digested sewage sludge with appropriate biochar utilization can therefore be an environmentally friendly option for both sequestering carbon and closing the nutrient cycle.
{"title":"Life cycle assessment of sewage sludge pyrolysis: environmental impacts of biochar as carbon sequestrator and nutrient recycler","authors":"Fabian Gievers, A. Loewen, M. Nelles","doi":"10.31025/2611-4135/2021.15111","DOIUrl":"https://doi.org/10.31025/2611-4135/2021.15111","url":null,"abstract":"The pyrolysis of sewage sludge is an alternative method to recycle the contained nutrients, such as phosphorus, by material use of the resulting biochar. However, the ecological effects of pyrolysis are not easy to evaluate. Therefore, a life cycle assessment (LCA) was carried out to determine the environmental impact of sewage sludge pyrolysis and to compare it with the common method of sewage sludge incineration. In order to identify the most sustainable applications of the resulting biochar, four different scenarios were analyzed. The modeled life cycles include dewatering, drying and pyrolysis of digested sewage sludge and utilization paths of the by-products as well as various applications of the produced biochar and associated transports. The life cycle impact assessment was carried out using the ReCiPe midpoint method. The best scenario in terms of global warming potential (GWP) was the use of biochar in horticulture with net emissions of 2 g CO2 eq./kg sewage sludge. This scenario of biochar utilization can achieve savings of 78% of CO2 eq. emissions compared to the benchmark process of sewage sludge mono-incineration. In addition, no ecological hotspots in critical categories such as eutrophication or ecotoxicity were identified for the material use of biochar compared to the benchmark. Pyrolysis of digested sewage sludge with appropriate biochar utilization can therefore be an environmentally friendly option for both sequestering carbon and closing the nutrient cycle.","PeriodicalId":44191,"journal":{"name":"Detritus","volume":" ","pages":""},"PeriodicalIF":1.7,"publicationDate":"2021-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48120601","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-09-11DOI: 10.31025/2611-4135/2021.15110
L. Ottosen, L. B. Jensen, T. Astrup, T. McAloone, Morten Ryberg, C. Thuesen, Solbrit Christiansen, A. J. Pedersen, Mads H. Odgaard
The building and construction sector is selected by the European Commission as a key product value chain in the transition towards circular economy (CE) due to the major resource consumption, waste generation and GHG emissions from this sector. This paper reports the result from qualitative and semi-structured interviews with 30 Danish stakeholders from the sector on the current stage of implementation of CE and the research/innovation needs to scale circular construction from niche to mainstream. The interviews showed a large variety in the stakeholder’s stage of transition from hardly knowing the term to having CE as a major driver in their business. Some meant that scaling of CE is close to impossible and that material reuse will never develop to more than a niche, whereas others already offer full-scale circular solutions to clients. The interviews pointed at a need for a common definition and terminology for CE, methods for documenting the gains from the circular solutions (economic and environmental), methods for technical documentation of the quality of reused materials, processes which enables scaling, methods to implement CE in various systems such as digitalization and building passports, new value chains and framework conditions in support of circularity. Regardless these needs, demonstration projects of major importance to gain general knowledge have been built or are planned in Denmark. These demonstrations have different approaches: using todays waste from different industries as construction materials; reusing construction materials (the basic building, elements or processed materials); and designing new buildings for disassembly to enable future reuse.
{"title":"IMPLEMENTATION STAGE FOR CIRCULAR ECONOMY IN THE DANISH BUILDING AND CONSTRUCTION SECTOR","authors":"L. Ottosen, L. B. Jensen, T. Astrup, T. McAloone, Morten Ryberg, C. Thuesen, Solbrit Christiansen, A. J. Pedersen, Mads H. Odgaard","doi":"10.31025/2611-4135/2021.15110","DOIUrl":"https://doi.org/10.31025/2611-4135/2021.15110","url":null,"abstract":"The building and construction sector is selected by the European Commission as a key product value chain in the transition towards circular economy (CE) due to the major resource consumption, waste generation and GHG emissions from this sector. This paper reports the result from qualitative and semi-structured interviews with 30 Danish stakeholders from the sector on the current stage of implementation of CE and the research/innovation needs to scale circular construction from niche to mainstream. The interviews showed a large variety in the stakeholder’s stage of transition from hardly knowing the term to having CE as a major driver in their business. Some meant that scaling of CE is close to impossible and that material reuse will never develop to more than a niche, whereas others already offer full-scale circular solutions to clients. The interviews pointed at a need for a common definition and terminology for CE, methods for documenting the gains from the circular solutions (economic and environmental), methods for technical documentation of the quality of reused materials, processes which enables scaling, methods to implement CE in various systems such as digitalization and building passports, new value chains and framework conditions in support of circularity. Regardless these needs, demonstration projects of major importance to gain general knowledge have been built or are planned in Denmark. These demonstrations have different approaches: using todays waste from different industries as construction materials; reusing construction materials (the basic building, elements or processed materials); and designing new buildings for disassembly to enable future reuse.","PeriodicalId":44191,"journal":{"name":"Detritus","volume":" ","pages":""},"PeriodicalIF":1.7,"publicationDate":"2021-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47001357","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-09-11DOI: 10.31025/2611-4135/2021.15115
F. Simon, C. Vogel, U. Kalbe
Due to its large mineral fraction, incineration bottom ash (IBA) from municipal solid waste incineration is an interesting raw material that can be used for road construction or to produce secondary building materials. However, leaching chloride, sulfate, and potentially harmful heavy metals may cause problems in using IBA in civil engineering. Investigating leaching behavior is crucial for the assessment of the environmental compatibility of IBA applications. Various test procedures are available for that purpose. In the present study, a long-term leaching test of a wet-mechanically treated IBA was performed in a lysimeter for almost six years. While concentrations of chloride, sulfate and the majority of the heavy metals started to decrease rapidly with advancing liquid-to-solid ratio (L/S), antimony (Sb) and vanadium (V) behaved differently. At the beginning of the lysimeter test, the Sb and V concentrations were low, but after approximately one year of operation at an L/S ratio of around 0.8 L/kg, a steady increase was observed. It was shown that this increase is the result of low Ca concentrations due to the formation of CaCO3. With the data, the solubility products from Ca-antimonate and Ca-vanadate were calculated. The unusual leaching behavior of Sb and V should be kept in mind when considering field scenarios and evaluating the impact on the environment.
{"title":"ANTIMONY AND VANADIUM IN INCINERATION BOTTOM ASH – LEACHING BEHAVIOR AND CONCLUSIONS FOR TREATMENT PROCESSES","authors":"F. Simon, C. Vogel, U. Kalbe","doi":"10.31025/2611-4135/2021.15115","DOIUrl":"https://doi.org/10.31025/2611-4135/2021.15115","url":null,"abstract":"Due to its large mineral fraction, incineration bottom ash (IBA) from municipal solid waste incineration is an interesting raw material that can be used for road construction or to produce secondary building materials. However, leaching chloride, sulfate, and potentially harmful heavy metals may cause problems in using IBA in civil engineering. Investigating leaching behavior is crucial for the assessment of the environmental compatibility of IBA applications. Various test procedures are available for that purpose. In the present study, a long-term leaching test of a wet-mechanically treated IBA was performed in a lysimeter for almost six years. While concentrations of chloride, sulfate and the majority of the heavy metals started to decrease rapidly with advancing liquid-to-solid ratio (L/S), antimony (Sb) and vanadium (V) behaved differently. At the beginning of the lysimeter test, the Sb and V concentrations were low, but after approximately one year of operation at an L/S ratio of around 0.8 L/kg, a steady increase was observed. It was shown that this increase is the result of low Ca concentrations due to the formation of CaCO3. With the data, the solubility products from Ca-antimonate and Ca-vanadate were calculated. The unusual leaching behavior of Sb and V should be kept in mind when considering field scenarios and evaluating the impact on the environment.","PeriodicalId":44191,"journal":{"name":"Detritus","volume":" ","pages":""},"PeriodicalIF":1.7,"publicationDate":"2021-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44349192","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-09-11DOI: 10.31025/2611-4135/2021.15112
A. Haouas, C. El Modafar, A. Douira, S. Ibnsouda-Koraichi, A. Filali-Maltouf, A. Moukhli, S. Amir
Phosphate sludge (PS) is an industrial by-product produced in huge quantities by the phosphate beneficiation plants in Morocco. In order to valorize this by-product, it was examined for its potential use as a soil fertilizer. The physicochemical properties, elemental and mineral content, morphological structure, and component stability of raw PS were investigated. In addition, pathogenicity, phytotoxicity, and the capacity of PS to promote plant growth in deficient sandy soil have been studied. The obtained results showed that PS was characterized by low values of moisture (2.10%), electrical conductivity (EC) (0.77 mS/cm), and organic matter (OM) (0.61%), with a slightly alkaline pH (8.20). Nevertheless, this material carried interesting content of fertilizing elements such as phosphorus (P2O5) of 20.01%, calcium (CaO) of 39.72%, and magnesium (MgO) of 2.33%. Thus, PS did not present any pathogenic or phytotoxic risk with a high increase in tomato plant growth than the control of only soil. In conclusion, the results of this study could provide the primary practical guidance for the PS application in deficient soils characterized by sandy texture.
{"title":"Phosphate sludge: opportunities for use as a fertilizer in deficient.","authors":"A. Haouas, C. El Modafar, A. Douira, S. Ibnsouda-Koraichi, A. Filali-Maltouf, A. Moukhli, S. Amir","doi":"10.31025/2611-4135/2021.15112","DOIUrl":"https://doi.org/10.31025/2611-4135/2021.15112","url":null,"abstract":"Phosphate sludge (PS) is an industrial by-product produced in huge quantities by the phosphate beneficiation plants in Morocco. In order to valorize this by-product, it was examined for its potential use as a soil fertilizer. The physicochemical properties, elemental and mineral content, morphological structure, and component stability of raw PS were investigated. In addition, pathogenicity, phytotoxicity, and the capacity of PS to promote plant growth in deficient sandy soil have been studied. The obtained results showed that PS was characterized by low values of moisture (2.10%), electrical conductivity (EC) (0.77 mS/cm), and organic matter (OM) (0.61%), with a slightly alkaline pH (8.20). Nevertheless, this material carried interesting content of fertilizing elements such as phosphorus (P2O5) of 20.01%, calcium (CaO) of 39.72%, and magnesium (MgO) of 2.33%. Thus, PS did not present any pathogenic or phytotoxic risk with a high increase in tomato plant growth than the control of only soil. In conclusion, the results of this study could provide the primary practical guidance for the PS application in deficient soils characterized by sandy texture.","PeriodicalId":44191,"journal":{"name":"Detritus","volume":" ","pages":""},"PeriodicalIF":1.7,"publicationDate":"2021-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44405963","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-06-30DOI: 10.31025/2611-4135/2021.15092
A. Gallipoli, A. Gianico, S. Crognale, S. Rossetti, L. Mazzeo, V. Piemonte, M. Masi, C. Braguglia
This innovative Biorefinery platform is based on the integration of a mild thermal pre-treatment and a solid/liquid separation unit to parallel-integrated bioprocesses specifically selected on food waste distinctive chemical composition: a liquid fraction, rich in readily fermentable sugars, to be transformed into valuable biobased products, and a solid organic residue to enhance biomethane production generating a fully hygienized digestate to be recycled. The preliminary results in terms of VFAs yields and composition from the acidogenic stage, and the methane conversion rate from the anaerobic digestion of the solid residue, are here presented
{"title":"3-ROUTES PLATFORM FOR RECOVERY OF HIGH VALUE PRODUCTS, ENERGY AND BIO-FERTILIZER FROM URBAN BIOWASTE: THE REVENUE PROJECT","authors":"A. Gallipoli, A. Gianico, S. Crognale, S. Rossetti, L. Mazzeo, V. Piemonte, M. Masi, C. Braguglia","doi":"10.31025/2611-4135/2021.15092","DOIUrl":"https://doi.org/10.31025/2611-4135/2021.15092","url":null,"abstract":"This innovative Biorefinery platform is based on the integration of a mild thermal pre-treatment and a solid/liquid separation unit to parallel-integrated bioprocesses specifically selected on food waste distinctive chemical composition: a liquid fraction, rich in readily fermentable sugars, to be transformed into valuable biobased products, and a solid organic residue to enhance biomethane production generating a fully hygienized digestate to be recycled. The preliminary results in terms of VFAs yields and composition from the acidogenic stage, and the methane conversion rate from the anaerobic digestion of the solid residue, are here presented","PeriodicalId":44191,"journal":{"name":"Detritus","volume":" ","pages":""},"PeriodicalIF":1.7,"publicationDate":"2021-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43910033","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-06-30DOI: 10.31025/2611-4135/2021.15091
O. S. Shittu, I. Williams, Peter Shaw, Natalie Montiero, Rhiannon Creffield
At the heart of the circular economy model is the reorientation of consumer behaviours away from disposing of items before they reach end of their functional life as a step towards resource efficiency and reduction of environmental impacts. One way to facilitate this change is to enable proactive redistribution of electrical and electronic equipment (EEE) with reuse value from urban spaces followed by high quality recycling at end-of-life. We have conducted the first assessment and critical evaluation of a model for the recovery of reusable EEE from a distinct urban mine (DUM) - in this case, a university. The Infrastructure, Service and Behaviour (ISB) model was used as a guide for interventions. EEE recovered from two Halls of Residence at the University of Southampton were characterised and sorted. From the items inspected, 97% was reusable and were donated to participating charities for redistribution via reuse/sale. The results show that an ISB Model system designed using choice architecture to recover reusable EEE from a DUM contributes strongly to extending products’ lifetimes and promotes circular economy ambitions. The study provides strong evidence of a viable reuse-based recovery system for small EEE in a university DUM and with a potential for replicability at global scale. It is recommended that a carefully planned and tailored system based on the ISB model should be put in place in universities for the recovery and redistribution of reusable EEE (ReEEE) and that recycling is implemented only after practical options for reuse have been exhausted.
{"title":"Demonstrating reuse of EEE in a distinct urban mine: a case study","authors":"O. S. Shittu, I. Williams, Peter Shaw, Natalie Montiero, Rhiannon Creffield","doi":"10.31025/2611-4135/2021.15091","DOIUrl":"https://doi.org/10.31025/2611-4135/2021.15091","url":null,"abstract":"At the heart of the circular economy model is the reorientation of consumer behaviours away from disposing of items before they reach end of their functional life as a step towards resource efficiency and reduction of environmental impacts. One way to facilitate this change is to enable proactive redistribution of electrical and electronic equipment (EEE) with reuse value from urban spaces followed by high quality recycling at end-of-life. We have conducted the first assessment and critical evaluation of a model for the recovery of reusable EEE from a distinct urban mine (DUM) - in this case, a university. The Infrastructure, Service and Behaviour (ISB) model was used as a guide for interventions. EEE recovered from two Halls of Residence at the University of Southampton were characterised and sorted. From the items inspected, 97% was reusable and were donated to participating charities for redistribution via reuse/sale. The results show that an ISB Model system designed using choice architecture to recover reusable EEE from a DUM contributes strongly to extending products’ lifetimes and promotes circular economy ambitions. The study provides strong evidence of a viable reuse-based recovery system for small EEE in a university DUM and with a potential for replicability at global scale. It is recommended that a carefully planned and tailored system based on the ISB model should be put in place in universities for the recovery and redistribution of reusable EEE (ReEEE) and that recycling is implemented only after practical options for reuse have been exhausted.","PeriodicalId":44191,"journal":{"name":"Detritus","volume":" ","pages":""},"PeriodicalIF":1.7,"publicationDate":"2021-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41568532","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-06-30DOI: 10.31025/2611-4135/2021.15095
Lorena Figueroa-Escamilla, S. González‐Martínez, Rosalinda Campuzano, I. Valdez‐Vazquez
In some countries, garden trimmings are not considered part of urban solid wastes. Lignocellulosic substances contribute to heterogeneity, complicating the analysis of the organic fraction of municipal solid waste (OFMSW) and, subsequently, for methane production. Some of the substances contained in OFMSW are readily biodegradable, and others are not. This work analyses OFMSW from Mexico City and the methane production from its separate components. From OFMSW, nine fractions were visually identified and separated. Including bromatological and fibre analysis, the characterisation of OFMSW and its components was made to determine how the different substances influence methane production. Together, branches, dry leaves, fresh garden trimmings, unsorted wastes (mainly garden trimmings), kitchen paper, and waste vegetables represent 56 % of OFMSW in weight. Fruit waste and unsorted organics contribute to 60 % of the total methane production. Except for branches and dry leaves, methane production increases inversely with the content of lignocellulosic compounds. Animal waste, having the highest concentrations of proteins and lipids and the lowest in lignocellulosic substances, is characterised by the highest level of methane production. Fibre-rich fractions in OFMSW contributed with little or no methane production. Higher concentrations of lignocellulosic substances in the fractions resulted in lower methane production rates.
{"title":"Methane production and bromatological characteristics of the different fractions of organic municipal solid waste","authors":"Lorena Figueroa-Escamilla, S. González‐Martínez, Rosalinda Campuzano, I. Valdez‐Vazquez","doi":"10.31025/2611-4135/2021.15095","DOIUrl":"https://doi.org/10.31025/2611-4135/2021.15095","url":null,"abstract":"In some countries, garden trimmings are not considered part of urban solid wastes. Lignocellulosic substances contribute to heterogeneity, complicating the analysis of the organic fraction of municipal solid waste (OFMSW) and, subsequently, for methane production. Some of the substances contained in OFMSW are readily biodegradable, and others are not. This work analyses OFMSW from Mexico City and the methane production from its separate components. From OFMSW, nine fractions were visually identified and separated. Including bromatological and fibre analysis, the characterisation of OFMSW and its components was made to determine how the different substances influence methane production. Together, branches, dry leaves, fresh garden trimmings, unsorted wastes (mainly garden trimmings), kitchen paper, and waste vegetables represent 56 % of OFMSW in weight. Fruit waste and unsorted organics contribute to 60 % of the total methane production. Except for branches and dry leaves, methane production increases inversely with the content of lignocellulosic compounds. Animal waste, having the highest concentrations of proteins and lipids and the lowest in lignocellulosic substances, is characterised by the highest level of methane production. Fibre-rich fractions in OFMSW contributed with little or no methane production. Higher concentrations of lignocellulosic substances in the fractions resulted in lower methane production rates.","PeriodicalId":44191,"journal":{"name":"Detritus","volume":" ","pages":""},"PeriodicalIF":1.7,"publicationDate":"2021-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42908457","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-06-30DOI: 10.31025/2611-4135/2021.15097
Ababaikere Abudureheman, P. Stabile, M. Carroll, C. Santulli, E. Paris
Construction and Demolition Waste (CDW) originating from the rubble produced by the 2016 seismic events in the Marche Region (Central Italy) has been studied, focusing on its mineralogical and chemical characteristics, to investigate its recycling potentials as a component for eco-sustainable building material or in the glass industry. The aim was to obtain a full characterization of the behaviour of this material at high T in order to determine the most advantageous conditions for vitrification, considered as an effective process for volume reduction as well as for immobilization of potentially hazardous elements. Vitrification experiments, carried out with thermal treatments as function of temperature/duration/particle size and aimed at amorphization, were carried out under atmospheric conditions, at different temperatures (1000-1250°C) and durations (2-8 hours). The study demonstrated that mineralogical composition remains homogeneous for grainsize <4 mm, thus suggesting that no sieving is necessary for recycling of the fine fractions, which are the most difficult to treat. Vitrification, although not achieved for the CDW sample up to 1250°C, due to high-Ca and low-Si contents, demonstrated that this CDW can produce an interesting refractory material and a porous/insulating material. However, experiments showed that full vitrification can be easily achieved by mixing urban waste glass and CDW, suggesting applications in the glass industry. Based on the chemical and mineralogical features of the products, other significant upgrading alternatives of recycling the CDW in different fields of applications are highlighted.
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