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Experimental Investigations and Characterization of Surfactant Activated Mixed Metal Oxide (MMO) Nanomaterial 表面活性剂活化混合金属氧化物 (MMO) 纳米材料的实验研究与表征
IF 2.1 4区 工程技术 Q3 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-10-02 DOI: 10.1109/TNANO.2024.3472728
Poundoss Chellamuthu;Kirubaveni Savarimuthu;Mohammed Gulam Nabi Alsath;Govindaraj Rajamanickam
A wide range of industrial, environmental, and biomedical applications depend greatly on the development of sensitive and reliable humidity sensors. This work reports an extensive investigation of a nanostructured surfactant such as Sodium Dodecyl Sulfate (SDS) and Cetyltrimethyl Ammonium Bromide (CTAB) activated mixed metal oxide (Zinc Oxide / Nickel Oxide) nanomaterial. The crystal study demonstrates an increase in the ZnO/NiO characteristic peaks (101) and (200), due to surface reactive agents. The increment of CTAB molar ratio has significantly increased the crystallite size, such that the bandgap of ZnO/NiO composite is reduced from 3.37eV to 2.80 eV. Brunauer-Emmitt-Teller (BET) surface area study revealed the production of a mesoporous ZnO with an improvement in the specific surface area from 7.82 to 52.01 m2g−1 with a mean diameter reducing from 22.28 to 18.94 nm for the CTAB molar concentration range of 0.0, 0.5, 1.0, 1.5 and 2.0 M namely SC-1, SC-2, SC-3, SC-4, and SC-5 respectively. The internal resistance achieved for the 2M sample is 1 KΩ, which is suitable for better humidity and gas sensing properties. Hence, the proposed ZnO/NiO metal oxide material is more sensitive to a plurality of analytes by providing an increased BET surface area.
广泛的工业、环境和生物医学应用在很大程度上依赖于灵敏可靠的湿度传感器的开发。本研究报告对十二烷基硫酸钠(SDS)和十六烷基三甲基溴化铵(CTAB)等纳米结构表面活性剂激活的混合金属氧化物(氧化锌/氧化镍)纳米材料进行了广泛研究。晶体研究表明,由于表面活性剂的作用,氧化锌/氧化镍特征峰(101)和(200)有所增加。CTAB 摩尔比的增加显著增大了晶粒尺寸,从而使氧化锌/氧化镍复合材料的带隙从 3.37eV 减小到 2.80eV。布鲁瑙尔-艾美特-泰勒(BET)表面积研究表明,在 CTAB 摩尔浓度分别为 0.0、0.5、1.0、1.5 和 2.0 M(即 SC-1、SC-2、SC-3、SC-4 和 SC-5)的范围内,产生了介孔 ZnO,比表面积从 7.82 m2g-1 增加到 52.01 m2g-1,平均直径从 22.28 nm 减小到 18.94 nm。2M 样品的内阻为 1 KΩ,适用于更好的湿度和气体传感特性。因此,拟议的 ZnO/NiO 金属氧化物材料通过提供更大的 BET 表面积,对多种分析物更加敏感。
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引用次数: 0
Low Temperature One-Pot Synthesis of rGO Nanorod-PVDF Composite and Fabrication of a Thin Film Solid-State Fractional Order Device rGO 纳米棒-PVDF 复合材料的低温一锅合成及薄膜固态分数阶器件的制作
IF 2.1 4区 工程技术 Q3 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-09-27 DOI: 10.1109/TNANO.2024.3469973
Manas R. Samantaray;Agniv Tapadar;Santanu Das;Nikhil Chander;Avishek Adhikary
This work proposes a novel, cost-effective, and simplified method to fabricate(reduced graphene oxide (rGO) nanorods. It is demonstrated that when a composite film made of polyvinylidene fluoride (PVDF) and the fabricated rGO is formed on a silver substrate, a unique structural morphology appears. This structure is unlike the general morphological structures of PVDF and rGO. The fabricated rGO has a nanorod-shapes of 0.54 nm to 1.15 $mu$m length and diameter in the 51$-$ 64 nm range. The presence of $alpha$ and $beta$ phase PVDF and rGO in the composite has been confirmed using both X-ray diffractometer and Raman spectroscopy. Impedance characterization of the fabricated device shows constant phase characteristics in the frequency range of 126 kHz to 2 MHz with a constant phase angle at $-63^{circ }$ to $-78^{circ }$. This indicates that the proposed rGO Nanorod-PVDF composite is suitable for the fabrication of a thin film fractor (fractional order device) with fractional order $eta$ = 0.70 to 0.88 and fractance value 0.08 to 3.08 nF$s^{eta }$.
本研究提出了一种新颖、经济、简化的还原氧化石墨烯(rGO)纳米棒制造方法。研究表明,当在银基底上形成由聚偏氟乙烯(PVDF)和所制备的 rGO 组成的复合薄膜时,会出现一种独特的结构形态。这种结构不同于 PVDF 和 rGO 的一般形态结构。制备的 rGO 具有长度为 0.54 纳米到 1.15 英寸的纳米棒形状,直径在 51 纳米到 64 纳米之间。X 射线衍射仪和拉曼光谱都证实了复合材料中存在 PVDF 和 rGO 相。所制造器件的阻抗表征显示,在 126 kHz 至 2 MHz 的频率范围内,相位特性恒定,相位角在 $-63^{circ }$ 至 $-78^{circ }$。这表明所提出的 rGO 纳米棒-PVDF 复合材料适用于制造薄膜分形器(分数阶器件),其分数阶为 $eta$ = 0.70 至 0.88,分数值为 0.08 至 3.08 nF$s^{eta }$。
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引用次数: 0
First Realization of Batch Normalization in Flash-Based Binary Neural Networks Using a Single Voltage Shifter 使用单电压变换器首次实现基于闪存的二进制神经网络批量归一化
IF 2.1 4区 工程技术 Q3 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-09-23 DOI: 10.1109/TNANO.2024.3466128
Sungmin Hwang;Wangjoo Lee;Jeong Woo Park;Dongwoo Suh
Batch normalization (BN) is a technique used to enhance training speed and generalization performance by mitigating internal covariate shifts. However, implementing BN in hardware presents challenges due to the need for an additional complex circuit to normalize, scale and shift activations. We proposed a hardware binary neural network (BNN) system capable of BN in hardware, which is consist of an AND-type flash memory array as a synapse and a voltage sense amplifier (VSA) as a neuron. In this system, hardware BN was implemented using a voltage shifter by adjusting the threshold of the binary neuron. To validate the effectiveness of the proposed hardware-based BNN system, we fabricated a charge trap flash with a gate stack of SiO2/Si3N4/SiO2. The electrical characteristics were modelled by using BSIM3 model parameters so that the proposed circuit was successfully demonstrated by a SPICE simulation. Moreover, variation effects of the voltage shifter were also analyzed using Monte Carlo simulation. Finally, the performance of the proposed system was proved by incorporating the SPICE results into a high-level simulation of binary LeNet-5 for MNIST pattern recognition, resulting in the improvement of the proposed system in terms of power and area, compared to the previous studies.
批量归一化(BN)是一种通过减轻内部协变量偏移来提高训练速度和泛化性能的技术。然而,由于需要额外的复杂电路来对激活进行归一化、缩放和移位,在硬件中实现 BN 存在挑战。我们提出了一种能够在硬件中实现 BNN 的硬件二元神经网络(BNN)系统,该系统由一个作为突触的 AND 型闪存阵列和一个作为神经元的电压感应放大器(VSA)组成。在该系统中,通过调整二进制神经元的阈值,使用电压移位器实现了硬件 BN。为了验证所提出的基于硬件的 BNN 系统的有效性,我们制作了一个电荷阱闪存,栅极堆叠为 SiO2/Si3N4/SiO2。我们使用 BSIM3 模型参数对其电气特性进行了建模,并通过 SPICE 仿真成功演示了所提出的电路。此外,还利用蒙特卡罗仿真分析了电压变换器的变化效应。最后,通过将 SPICE 结果纳入用于 MNIST 模式识别的二进制 LeNet-5 高级仿真,证明了所提系统的性能,与之前的研究相比,所提系统在功耗和面积方面都有所改进。
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引用次数: 0
Pioneering Multi-Functionality through VO2-Infused Polarization Insensitive Conformal Meta-Structures in Terahertz Regime 通过注入 VO2 的极化不敏感共形元结构,率先实现太赫兹波段的多功能性
IF 2.1 4区 工程技术 Q3 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-09-17 DOI: 10.1109/TNANO.2024.3462802
Aks Raj;Ravi Kumar Gangwar;Raghvendra Kumar Chaudhary
This letter introduces a conformal multifunctional Terahertz Metamaterial-Resonator (TMR) that achieves ultra-wideband absorption (4.6–9.3 THz) without extra circuit components. Its isotropic design ensures angular and polarization stability on flat and curved surfaces. Utilizing phase-changing Vanadium Oxide (VO2), the TMR reconfigures as an absorber, reflector, or transmissive structure, with simulation results aligning with the derived equivalent circuit model.
这封信介绍了一种共形多功能太赫兹超材料谐振器(TMR),它无需额外的电路元件即可实现超宽带吸收(4.6-9.3 太赫兹)。其各向同性设计确保了平面和曲面上的角度和偏振稳定性。利用相变氧化钒(VO2),TMR 可重新配置为吸收器、反射器或透射结构,仿真结果与推导出的等效电路模型一致。
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引用次数: 0
An Analytical Model Accounting for the Pertinence of Hybrid Tunneling in Bio-TFETs 解释生物场效应晶体管中混合隧道效应重要性的分析模型
IF 2.1 4区 工程技术 Q3 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-09-17 DOI: 10.1109/TNANO.2024.3462605
Joy Chowdhury;Kamalakanta Mahapatra;Angsuman Sarkar;J. K. Das
TFETs are being widely considered for next generation computing and sensing applications. They surpass conventional bulk MOSFETs in terms of subthreshold slope, leakage current and short channel effects. This paper presents a semi-analytical model accounting for both point tunneling and line tunneling schemes in a modified split-channel gate overlap source TFET(SC-GOSTFET) architecture. Considering both the tunneling schemes simultaneously along with the added line component enhances the ON-state current thus making the TFETs a better candidate for nano bio-sensors. The increase in length of the tunneling path is the major advantage of this hybrid model. This also helps to ameliorate the effect of quantum confinement in the band edges during band bending. The proposed biosensor shows reasonable agreement with the simulation data obtained from TCAD and 44.21% and 75.62% higher sensitivity over conventional biosensors. Further, the improved ambipolar characteristics can be exploited to influence the detection of a certain category of biomolecules thus increasing the detection range of this hybrid tunneling-based biosensor.
TFET 正被广泛考虑用于下一代计算和传感应用。就亚阈值斜率、漏电流和短沟道效应而言,它们超越了传统的体 MOSFET。本文提出了一个半分析模型,该模型考虑了改进型分裂沟道栅重叠源 TFET(SC-GOSTFET)结构中的点隧道和线隧道方案。同时考虑这两种隧道方案以及增加的线分量会增强导通态电流,从而使 TFET 成为纳米生物传感器的更佳候选器件。隧道路径长度的增加是这种混合模型的主要优势。这也有助于在带弯曲过程中改善带边缘的量子约束效应。所提出的生物传感器与 TCAD 获得的模拟数据显示出合理的一致性,灵敏度比传统生物传感器分别高出 44.21% 和 75.62%。此外,改进的伏极特性可用于影响某类生物分子的检测,从而扩大这种基于混合隧道技术的生物传感器的检测范围。
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引用次数: 0
Research on Photovoltaic Measurement and Electrochemical Impedance Spectroscopy Analysis of Dye-Sensitized Solar Cells With Modification of Photoanodes by TiO2 Nanofibers Composited With Zn2SnO4-SnO2 Under Various Illuminances 用 Zn2SnO4-SnO2 复合 TiO2 纳米纤维修饰光阳极的染料敏化太阳能电池在各种光照条件下的光伏测量和电化学阻抗谱分析研究
IF 2.1 4区 工程技术 Q3 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-09-16 DOI: 10.1109/TNANO.2024.3460869
Yu-Hsun Nien;Yu-Han Huang;Jung-Chuan Chou;Chih-Hsien Lai;Po-Yu Kuo;Po-Hui Yang;Jhih-Wei Zeng;Chia-Wei Wang
This study involves the utilization of electrostatic access techniques and the development of ZTO-SnO2/TiO2 nanofibers (NFs) in different ratios of 1%, 3%, and 5%. The dye-sensitized solar cells (DSSCs) efficiency was enhanced through the utilization of ZTO-SnO2 nanofiber composites in photoanodes. According to this study, the 3% ZTO-SnO2/TiO2 nanofiber-modified DSSCs conversion efficiency was better than that of other DSSCs at different light intensities. When the light intensity is 100 mW/cm2, there is a rise in efficiency by 30.91% compared with pure TiO2. The EIS (Electrochemical Impedance Spectroscopy) usage demonstrated that adding ZTO-SnO2 efficiently lowered the photoanode's electron transfer impedance. The higher scattering potential and powerful electron transfer capability have been demonstrated to have a positive effect on increasing the JSC of DSSCs using quantum efficiency studies.
本研究涉及利用静电接入技术和开发不同比例(1%、3% 和 5%)的 ZTO-SnO2/TiO2 纳米纤维 (NF)。通过在光阳极中使用 ZTO-SnO2 纳米纤维复合材料,提高了染料敏化太阳能电池(DSSC)的效率。根据这项研究,在不同光照强度下,3% ZTO-SnO2/TiO2 纳米纤维改性 DSSC 的转换效率优于其他 DSSC。当光照强度为 100 mW/cm2 时,效率比纯 TiO2 提高了 30.91%。电化学阻抗光谱(EIS)研究表明,添加 ZTO-SnO2 能有效降低光阳极的电子转移阻抗。量子效率研究表明,更高的散射电位和强大的电子转移能力对提高 DSSC 的 JSC 有积极作用。
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引用次数: 0
Compact and Efficient Transverse Spliced Waveguide Grating Antenna for Integrated Optical Phased Array 用于集成光学相控阵的紧凑高效横向拼接波导光栅天线
IF 2.1 4区 工程技术 Q3 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-09-12 DOI: 10.1109/TNANO.2024.3459472
Diksha Maurya;Devendra Chack;G. Vickey
Waveguide grating antenna with compact size and high diffraction efficiency remains a significant challenge in beam steering applications for integrated Optical Phased Arrays (OPA). Traditional waveguide grating antennas have large footprints, limiting antenna arrays' density. High diffraction efficiency is essential for effective signal transmission, making it a crucial aspect of antenna design. Optical antennas need higher diffraction efficiency, compact size, and broader field of view to achieve this. The proposed work aims to design a single-etch grating antenna on a silicon-on-insulator (SOI) platform that emits light off-chip. The methodology combines the initial grating antenna designed using Finite-difference time-domain (FDTD) simulations and optimizes it with a genetic algorithm. The proposed design uses a transverse spliced grating, Bragg reflectors, and bottom reflector to achieve an impressive upward diffraction efficiency of nearly 88% operating in C -band centered at 1550 nm. The size of the proposed antenna is 2.8 μm and offers a wide far-field beam width of 38 ° x 136 °. This work enables new advancements in integrated waveguide grating antenna development, with potential applications in free-space optical interconnects and on-chip optical phased arrays.
波导光栅天线具有体积小、衍射效率高的特点,在集成光相控阵(OPA)的波束转向应用中仍是一项重大挑战。传统的波导光栅天线占地面积大,限制了天线阵列的密度。高衍射效率对有效的信号传输至关重要,因此是天线设计的一个关键方面。为此,光学天线需要更高的衍射效率、更小的尺寸和更宽的视场。本研究旨在在硅绝缘体(SOI)平台上设计一种单蚀刻光栅天线,该天线可在芯片外发射光线。该方法结合了利用有限差分时域 (FDTD) 仿真设计的初始光栅天线,并利用遗传算法对其进行优化。拟议的设计使用了横向拼接光栅、布拉格反射器和底部反射器,在以 1550 nm 为中心的 C 波段实现了近 88% 的惊人向上衍射效率。拟议的天线尺寸为 2.8 μm,远场波束宽度为 38 ° x 136 °。这项工作推动了集成波导光栅天线开发的新进展,有望应用于自由空间光互连和片上光学相控阵。
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引用次数: 0
Reduced Graphene Oxide-Polydimethylsiloxane Based Flexible Dry Electrodes for Electrophysiological Signal Monitoring 基于还原石墨烯氧化物-多二甲基硅氧烷的柔性干电极用于电生理信号监测
IF 2.1 4区 工程技术 Q3 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-09-12 DOI: 10.1109/TNANO.2024.3459931
Suraj Baloda;Sashank Krishna Sriram;Sumitra Singh;Navneet Gupta
Graphene-based dry electrodes have shown considerable promise in electrophysiological signal monitoring applications by providing a comfortable, irritant-free alternative to traditional wet electrodes. The proposed electrode was fabricated using a spray-coating technique by depositing reduced graphene oxide (rGO) on a polydimethylsiloxane (PDMS) substrate. The rGO/PDMS dry electrodes exhibit the capability to capture and transmit weak bio-electrical signals such as Electrocardiogram (ECGs) and Electromyogram (EMGs) without significant attenuation or distortion. Experimental results show that when compared to conventional wet Ag/AgCl electrodes, the fabricated rGO/PDMS electrodes measure higher-quality ECG signals with improved SNRs while offering similar contact quality and electrode-skin impedance despite being a dry electrode. The fabricated rGO/PDMS electrodes demonstrated excellent performance and applicability making them suitable for use in wearable long-term health monitoring devices.
石墨烯基干式电极为电生理信号监测应用提供了一种舒适、无刺激性的替代传统湿式电极的方法,从而显示出了巨大的应用前景。通过在聚二甲基硅氧烷(PDMS)基底上沉积还原氧化石墨烯(rGO),利用喷涂技术制造出了这种电极。rGO/PDMS 干电极能够捕捉和传输微弱的生物电信号,如心电图(ECG)和肌电图(EMG),而不会出现明显的衰减或失真。实验结果表明,与传统的湿式 Ag/AgCl 电极相比,制造的 rGO/PDMS 电极能测量出更高质量的心电信号,信噪比更高,同时尽管是干式电极,也能提供类似的接触质量和电极-皮肤阻抗。制成的 rGO/PDMS 电极表现出卓越的性能和适用性,适合用于可穿戴式长期健康监测设备。
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引用次数: 0
MXene- and Graphene-Assisted THz Metamaterial for Cancer Cells Detection Based on Refractive Index Sensing 基于折射率传感的 MXene 和石墨烯辅助太赫兹超材料用于检测癌细胞
IF 2.1 4区 工程技术 Q3 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-09-11 DOI: 10.1109/TNANO.2024.3458427
Muhammad Saqlain;Muhammad Abuzar Baqir;Pankaj Kumar Choudhury
An ultrathin metasurface-based polarization-insensitive single-band terahertz (THz) sensor comprising graphene concentric rings and a thin layer of MXene was investigated for the human body cancer cells detection. The overall metamaterial configuration exhibits single narrow-band nearly-perfect absorption with a high value of quality factor due to a full-width-half-maximum of 0.033 THz at the resonance frequency of 3.793 THz. The results show a high sensitivity of the metamaterial configuration along with a stable operation under different incidence polarizations. The results reveal the designed structure is of potential in biomedical applications.
研究了一种基于超薄超表面的极化不敏感单波段太赫兹(THz)传感器,该传感器由石墨烯同心环和一层薄薄的 MXene 组成,用于人体癌细胞检测。整个超材料结构在 3.793 太赫兹的共振频率下具有 0.033 太赫兹的全宽-半最大值,从而表现出单个窄带近乎完美的吸收和较高的品质因数值。研究结果表明,超材料结构具有很高的灵敏度,并能在不同的入射极化条件下稳定工作。结果表明,所设计的结构具有生物医学应用潜力。
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引用次数: 0
A Review of Ising Machines Implemented in Conventional and Emerging Technologies 传统和新兴技术中的伊辛机综述
IF 2.1 4区 工程技术 Q3 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-09-10 DOI: 10.1109/TNANO.2024.3457533
Tingting Zhang;Qichao Tao;Bailiang Liu;Andrea Grimaldi;Eleonora Raimondo;Manuel Jiménez;María José Avedillo;Juan Nuñez;Bernabé Linares-Barranco;Teresa Serrano-Gotarredona;Giovanni Finocchio;Jie Han
Ising machines have received growing interest as efficient and hardware-friendly solvers for combinatorial optimization problems (COPs). They search for the absolute or approximate ground states of the Ising model with a proper annealing process. In contrast to Ising machines built with superconductive or optical circuits, complementary metal-oxide-semiconductor (CMOS) Ising machines offer inexpensive fabrication, high scalability, and easy integration with mainstream semiconductor chips. As low-energy and CMOS-compatible emerging technologies, spintronics and phase-transition devices offer functionalities that can enhance the scalability and sampling performance of Ising machines. In this article, we survey various approaches in the process flow for solving COPs using CMOS, hybrid CMOS-spintronic, and phase-transition devices. First, the methods for formulating COPs as Ising problems and embedding Ising formulations to the topology of the Ising machine are reviewed. Then, Ising machines are classified by their underlying operational principles and reviewed from a perspective of hardware implementation. CMOS solutions are advantageous with denser connectivity, whereas hybrid CMOS-spintronic and phase-transition device-based solutions show great potential in energy efficiency and high performance. Finally, the challenges and prospects are discussed for the Ising formulation, embedding process, and implementation of Ising machines.
作为组合优化问题(COPs)的高效且硬件友好的求解器,伊辛机受到越来越多的关注。它们通过适当的退火过程来搜索伊辛模型的绝对或近似基态。与采用超导或光学电路制造的伊辛机相比,互补金属氧化物半导体(CMOS)伊辛机具有制造成本低、可扩展性强、易于与主流半导体芯片集成等优点。作为低能耗且与 CMOS 兼容的新兴技术,自旋电子学和相位转换器件提供的功能可提高伊兴机的可扩展性和采样性能。在本文中,我们将探讨使用 CMOS、混合 CMOS-自旋电子和相位转换器件解决 COP 的工艺流程中的各种方法。首先,我们回顾了将 COP 表述为 Ising 问题以及将 Ising 表述嵌入 Ising 机器拓扑的方法。然后,根据其基本运行原理对伊辛机进行分类,并从硬件实现的角度进行评述。CMOS 解决方案在密集连接方面具有优势,而基于 CMOS-Spinronic 和相位转换器件的混合解决方案则在能效和高性能方面显示出巨大潜力。最后,还讨论了伊辛公式、嵌入过程和伊辛机的实现所面临的挑战和前景。
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引用次数: 0
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IEEE Transactions on Nanotechnology
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