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Highly Sensitive and Mechanically Stable MXene Textile Sensors for Adaptive Smart Data Glove Embedded with Near-Sensor Edge Intelligence 用于嵌入近传感器边缘智能的自适应智能数据手套的高灵敏度和机械稳定性 MXene 纺织品传感器
IF 16.1 1区 工程技术 Q1 Materials Science Pub Date : 2024-05-28 DOI: 10.1007/s42765-024-00434-4
Shengshun Duan, Yucheng Lin, Qiongfeng Shi, Xiao Wei, Di Zhu, Jianlong Hong, Shengxin Xiang, Wei Yuan, Guozhen Shen, Jun Wu

Smart data gloves capable of monitoring finger activities and inferring hand gestures are of significance to human–machine interfaces, robotics, healthcare, and Metaverse. Yet, most current smart data gloves present unstable mechanical contacts, limited sensitivity, as well as offline training and updating of machine learning models, leading to uncomfortable wear and suboptimal performance during practical applications. Herein, highly sensitive and mechanically stable textile sensors are developed through the construction of loose MXene-modified textile interface structures and a thermal transfer printing method with the melting-infiltration-solidification adhesion procedure. Then, a smart data glove with adaptive gesture recognition is reported, based on the integration of 10-channel MXene textile bending sensors and a near-sensor adaptive machine learning model. The near-sensor adaptive machine learning model achieves a 99.5% accuracy using the proposed post-processing algorithm for 14 gestures. Also, the model features the ability to locally update model parameters when gesture types change, without additional computation on any external device. A high accuracy of 98.1% is still preserved when further expanding the dataset to 20 gestures, where the accuracy is recovered by 27.6% after implementing the model updates locally. Lastly, an auto-recognition and control system for wireless robotic sorting operations with locally trained hand gestures is demonstrated, showing the great potential of the smart data glove in robotics and human–machine interactions.

Graphical Abstract

能够监测手指活动并推断手势的智能数据手套对于人机界面、机器人、医疗保健和 Metaverse 都具有重要意义。然而,目前大多数智能数据手套都存在机械接触不稳定、灵敏度有限以及机器学习模型的离线训练和更新等问题,导致实际应用中佩戴不舒适、性能不理想。在本文中,通过构建松散的 MXene 改性纺织品界面结构和采用熔融-渗透-固化粘合程序的热转移印花方法,开发出了高灵敏度和机械稳定的纺织品传感器。然后,基于 10 通道 MXene 纺织品弯曲传感器和近传感器自适应机器学习模型的集成,报告了一种具有自适应手势识别功能的智能数据手套。近传感器自适应机器学习模型采用所提出的后处理算法,对 14 种手势的识别准确率达到 99.5%。此外,该模型还能在手势类型发生变化时本地更新模型参数,无需在任何外部设备上进行额外计算。当数据集进一步扩展到 20 种手势时,仍然保持了 98.1% 的高准确率,在本地实施模型更新后,准确率提高了 27.6%。最后,演示了一种利用本地训练的手势进行无线机器人分类操作的自动识别和控制系统,显示了智能数据手套在机器人和人机交互方面的巨大潜力。 图文摘要
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引用次数: 0
Immobilization of a Metal–Organic Framework on a Nanofiber Membrane as Artificial Platelets for Efficient Hemostasis 将金属有机框架固定在纳米纤维膜上作为人造血小板用于高效止血
IF 16.1 1区 工程技术 Q1 Materials Science Pub Date : 2024-05-22 DOI: 10.1007/s42765-024-00424-6
Binglin Bie, Zhanglong Zhu, Yonggang Lv
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引用次数: 0
A Trimode Self-Cleaning Composite Membrane with an Eco-friendly Substrate for Energy-Saving Wastewater Recycling 用于节能型废水回收的具有生态友好基质的 Trimode 自清洁复合膜
IF 16.1 1区 工程技术 Q1 Materials Science Pub Date : 2024-05-22 DOI: 10.1007/s42765-024-00430-8
Yuelin Yu, Yongtao Yu, Hongyi Wu, Jian Shi, Hideaki Morikawa, Chunhong Zhu
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引用次数: 0
Multifunctional Nanofibrous Membranes for Integrated Air Purification 用于综合空气净化的多功能纳米纤维膜
IF 16.1 1区 工程技术 Q1 Materials Science Pub Date : 2024-05-22 DOI: 10.1007/s42765-024-00427-3
Yutang Kang, Ze-Xian Low, Dong Zou, Zhaoxiang Zhong, Weihong Xing
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引用次数: 0
Highly Transparent and Flexible All-Nanofiber-Based Piezocomposite Containing BaTiO3-Embedded P(VDF-TrFE) Nanofibers for Harvesting and Monitoring Human Kinetic Movements 基于全纳米纤维的高透明柔性压电复合材料,其中含有嵌入式 P(VDF-TrFE)纳米纤维,可用于采集和监测人体运动
IF 16.1 1区 工程技术 Q1 Materials Science Pub Date : 2024-05-17 DOI: 10.1007/s42765-024-00406-8
Kiyong Kim, Daekyu Choi, Sangmin Ji, Freddy Baltazar Iniguez, Young Jae Song, Sam S. Yoon, Junki Kim, Seongpil An
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引用次数: 0
Intelligent Textiles for Visual and Smart Interaction 用于视觉和智能交互的智能纺织品
IF 16.1 1区 工程技术 Q1 Materials Science Pub Date : 2024-05-17 DOI: 10.1007/s42765-024-00431-7
Yuanyuan Zheng, Zhigang Chen, Huisheng Peng
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引用次数: 0
Unravelling the Tip Effect of Oxygen Catalysis in Integrated Cathode for High-Performance Flexible/Wearable Zn–Air Batteries 揭示高性能柔性/耐磨锌-空气电池集成阴极中氧催化的尖端效应
IF 16.1 1区 工程技术 Q1 Materials Science Pub Date : 2024-05-15 DOI: 10.1007/s42765-024-00425-5
Yirun Shen, Haoning Mao, Chen Li, Keer Li, Yi Liu, Jihai Liao, Shengsen Zhang, Yueping Fang, Xin Cai
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引用次数: 0
Injectable Electrospun Fiber-Hydrogel Composite Delivery System for Prolonged and Nociceptive-Selective Analgesia 可注射的电纺纤维-水凝胶复合给药系统,用于延长镇痛时间并具有痛觉选择性
IF 16.1 1区 工程技术 Q1 Materials Science Pub Date : 2024-05-14 DOI: 10.1007/s42765-024-00422-8
Sufang Chen, Weifeng Yao, Zhendong Ding, Jingyi Du, Tienan Wang, Xue Xiao, Linan Zhang, Jing Yang, Yu Guan, Chaojin Chen, Yu Tao, Mingqiang Li, Haixia Wang, Ziqing Hei

Nociceptive-selective analgesia is often preferred over traditional methods, providing effective pain relief with minimum systemic side effects.The quaternary lidocaine derivative QX-314, is a promising local anesthetic for achieving selective analgesia. However, due to its inability to penetrate the cell membrane, its efficacy is limited to intracellular administration. In this study, we aimed to develop an injectable electrospun fiber-hydrogel composite comprising QX-314-loaded poly(ε-caprolactone) electrospun fiber and capsaicin (Cap)-loaded F127 hydrogel (Fiber-QX314/Gel-Cap composite) for long-term and nociceptive-selective analgesia. The sequential and sustained release mechanism of Cap and QX-314 helped remarkably extend the sensory blockade duration up to 44.0 h, and prevent motor blockade. Specifically, our findings indicated that QX-314 can traverse the cell membrane through the transient receptor potential vanilloid 1 channel activated by Cap, thus targeting the intracellular Na+ channel receptor to achieve selective analgesia. Moreover, the composite effectively alleviated incision pain by suppressing c-Fos expression in the dorsal root ganglion and reducing the activation of glial cells in the dorsal horn of the spinal cord. Consequently, the Fiber-QX314/Gel-Cap composite, designed for exceptional biosafety and sustained selective analgesia, holds great promise as a non-opioid analgesic.

Graphical abstract

与传统方法相比,痛觉选择性镇痛通常更受青睐,它能有效缓解疼痛,同时将全身副作用降至最低。QX-314 是一种很有前景的局麻药,可实现选择性镇痛。然而,由于其无法穿透细胞膜,其功效仅限于细胞内给药。在这项研究中,我们旨在开发一种可注射的电纺纤维-水凝胶复合材料,它由负载 QX-314 的聚(ε-己内酯)电纺纤维和负载辣椒素(Cap)的 F127 水凝胶(Fiber-QX314/Gel-Cap 复合材料)组成,可用于长期和痛觉选择性镇痛。Cap 和 QX-314 的顺序和持续释放机制有助于显著延长感觉阻滞持续时间至 44.0 小时,并防止运动阻滞。具体而言,我们的研究结果表明,QX-314 可通过 Cap 激活的瞬时受体电位类香草素 1 通道穿越细胞膜,从而靶向细胞内 Na+ 通道受体,实现选择性镇痛。此外,该复合制剂还能抑制背根神经节中 c-Fos 的表达,减少脊髓背角神经胶质细胞的活化,从而有效缓解切口疼痛。因此,Fiber-QX314/Gel-Cap复合材料具有优异的生物安全性和持续的选择性镇痛效果,有望成为一种非阿片类镇痛剂。
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引用次数: 0
A Highly Sensitive Coaxial Nanofiber Mask for Respiratory Monitoring Assisted with Machine Learning 利用机器学习辅助呼吸监测的高灵敏度同轴纳米纤维面罩
IF 16.1 1区 工程技术 Q1 Materials Science Pub Date : 2024-05-14 DOI: 10.1007/s42765-024-00420-w
Boling Lan, Cheng Zhong, Shenglong Wang, Yong Ao, Yang Liu, Yue Sun, Tao Yang, Guo Tian, Longchao Huang, Jieling Zhang, Weili Deng, Weiqing Yang

Respiration is a critical physiological process of the body and plays an essential role in maintaining human health. Wearable piezoelectric nanofiber-based respiratory monitoring has attracted much attention due to its self-power, high linearity, noninvasiveness, and convenience. However, the limited sensitivity of conventional piezoelectric nanofibers makes it difficult to meet medical and daily respiratory monitoring requirements due to their low electromechanical conversion efficiency. Here, we present a universally applicable, highly sensitive piezoelectric nanofiber characterized by a coaxial composite structure of polyvinylidene fluoride (PVDF) and carbon nanotube (CNT), which is denoted as PS-CC. Based on elucidating the enhancement mechanism from the percolation effect, PS-CC exhibits excellent sensing performance with a high sensitivity of 3.7 V/N and a fast response time of 20 ms for electromechanical conversion. As a proof-of-concept, the nanofiber membrane is seamlessly integrated into a facial mask, facilitating accurate recognition of respiratory states. With the assistance of a one-dimensional convolutional neural network (CNN), a PS-CC-based smart mask can recognize respiratory tracts and multiple breathing patterns with a classification accuracy of up to 97.8%. Notably, this work provides an effective strategy for monitoring respiratory diseases and offers widespread utility for daily health monitoring and clinical applications.

Graphical abstract

呼吸是人体的一个重要生理过程,对维持人体健康起着至关重要的作用。基于可穿戴压电纳米纤维的呼吸监测因其自供电、高线性度、无创性和便捷性而备受关注。然而,传统压电纳米纤维的灵敏度有限,机电转换效率低,难以满足医疗和日常呼吸监测的要求。在此,我们提出了一种普遍适用的高灵敏度压电纳米纤维,其特征在于聚偏二氟乙烯(PVDF)和碳纳米管(CNT)的同轴复合结构,简称 PS-CC。在阐明渗流效应增强机制的基础上,PS-CC 表现出优异的传感性能,灵敏度高达 3.7 V/N,机电转换响应时间快达 20 ms。作为概念验证,纳米纤维膜与面罩无缝集成,有助于准确识别呼吸状态。在一维卷积神经网络(CNN)的辅助下,基于 PS-CC 的智能面罩可以识别呼吸道和多种呼吸模式,分类准确率高达 97.8%。值得注意的是,这项工作为监测呼吸系统疾病提供了一种有效的策略,并为日常健康监测和临床应用提供了广泛的实用性。
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引用次数: 0
A Superb Iron-Based Glassy-Crystal Alloy Fiber as an Ultrafast and Stable Catalyst for Advanced Oxidation 一种用于高级氧化的超快稳定催化剂--铁基玻璃晶体合金纤维
IF 16.1 1区 工程技术 Q1 Materials Science Pub Date : 2024-05-14 DOI: 10.1007/s42765-024-00426-4
Sida Jiang, Guanyu Cao, Zhe Jia, Ligang Sun, Chen Wang, Hongbo Fan, Yonghui Wang, Weizhi Xu, Yifan Cui, Zhiliang Ning, Jianfei Sun, Jianhua Li, Xiaobin Tang, Heng Liang, E. Peng

Waterborne organic pollutants pose significant threats to ecosystems and the health of billions worldwide, presenting a pressing global challenge. Advanced oxidation processes (AOPs) offer promise for efficient wastewater treatment, yet the efficacy and the reliability of current environmental catalysts hinder their widespread adoption. This study developed an as-cast nanostructured glassy fiber capable of rapidly activating persulfate and achieved the degradation of diverse organic contaminants within 60 s using the as-prepared fiber. The material is relatively robust and can be reused about 40 times. The exceptional catalytic performance of the fibers stemmed from their low atomic coordination numbers, which facilitated the generation of numerous unsaturated active sites and accelerated radical production rates through a one-electron transfer mechanism. Additionally, the glassy-nanocrystalline heterogeneous interface, achieved through our proposed nanostructuralization approach, exhibited electron delocalization behavior. This enhanced persulfate adsorption and reduced the energy barrier for heterolytic cleavage of peroxy bonds. These findings present a novel avenue for the rational structural design of high-performance environmental catalysts for advanced water remediation.

Graphical Abstract

水载有机污染物对生态系统和全球数十亿人的健康构成重大威胁,是一项紧迫的全球性挑战。高级氧化工艺(AOPs)为高效废水处理带来了希望,但目前环境催化剂的功效和可靠性阻碍了其广泛应用。本研究开发了一种能够快速活化过硫酸盐的铸模纳米玻璃纤维,并利用制备的纤维在 60 秒内实现了对多种有机污染物的降解。该材料相对坚固,可重复使用约 40 次。这种纤维的催化性能出众源于其较低的原子配位数,这有利于产生大量不饱和活性位点,并通过单电子转移机制加快自由基的产生速率。此外,通过我们提出的纳米结构化方法实现的玻璃状纳米结晶异质界面表现出了电子析出行为。这增强了过硫酸盐的吸附性,降低了过氧键异质裂解的能量障碍。这些发现为合理设计用于先进水修复的高性能环境催化剂结构提供了一条新途径。
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Advanced Fiber Materials
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