Lime treatment has long been used in construction for its cost-effectiveness and simplicity. In clay soils, lime induces chemical reactions that enhance workability and reduce plasticity, followed by gradual strength development. Despite extensive research on clay–lime interactions, the mechanisms behind these transformations remain partly unclear. This study focuses on the fundamental process driving strength gain. Bentonite samples were treated with lime and with other reagents, calcium chloride, barium chloride, and sodium hydroxide, chosen for their potentially similar behavior (electrolyte concentration and pH increase). Changes in plasticity, grain size distribution (GSD), and strength were assessed and compared to gain insight into the lime–clay mechanisms of reaction. A dispersing agent was also used to test the durability of lime-induced effects. Results revealed all additives reduced liquid limit, indicating increased floc size with additive content. However, only lime significantly raised the plastic limit, confirming persistence of the flocs that formed. GSD analyses showed lime caused fine clay particles to cluster, with cluster size growing with curing time. These lime-induced clusters remained intact, unlike those formed by other reagents, which broke down under manipulation or dispersant exposure. Crucially, only lime led to measurable strength development. Findings suggest clay–lime reactions begin with a resilient flocculation, followed by a slow chemical process that produces cementitious bonds within clusters. Other reagents appear to act through reversible electrostatic effects. The study also shows that low lime content fails to trigger the reaction, as the conditions of the pore water chemistry favor dispersion over flocculation. The short-term stability of lime–clay formed flocs observed in this study is attributed to an early clay–lime chemical reaction whose nature is inconclusively explained until today.
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