We theoretically investigated the plasmonic properties of aluminum-aluminum antimonide (Al-AlSb) core–shell nanorods, elucidating the influence of shell thickness and core geometry on their optical cross-sections and near-field enhancement. Through systematic computational analysis, we demonstrate that the plasmonic response is governed by the hybridization between the Al core plasmon and dielectric AlSb shell. This interaction yields a highly tunable, low-energy, bonding dipolar mode, whose localized surface plasmon resonance (LSPR) exhibits a pronounced and systematic redshift from the visible to the near-infrared (NIR) region with increasing shell thickness. Meanwhile, a high-energy, anti-bonding mode emerges in the ultraviolet (UV) spectrum, manifesting as a distinct spectral peak or shoulder with quadrupolar characteristics. The interplay between core dimensions and shell thickness provides a robust mechanism for tailoring these hybridized modes, enabling, for larger-diameter () rods, a dramatic, shell-induced enhancement of absorption that switches the system from a scattering- to an absorption-dominated regime. Moreover, the nanorods exhibited intense electric field enhancement at their tips, which was spectrally tuned by the shell thickness without significant quenching. These findings establish the Al-AlSb nanorods as a versatile platform for applications in surface-enhanced spectroscopy, photocatalysis, and advanced optoelectronic devices.
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