首页 > 最新文献

Fire Safety Journal最新文献

英文 中文
Modelling the maximum ceiling temperature with bifurcated plume in tunnel fires 隧道火灾中带有分叉羽流的最高顶棚温度建模
IF 3.4 3区 工程技术 Q2 ENGINEERING, CIVIL Pub Date : 2024-09-03 DOI: 10.1016/j.firesaf.2024.104249
Tianhang Zhang , Ganyu Wang , Jiangdong Li , Ke Wu , Lizhong Wang

Evaluation of the temperature profile induced by tunnel fire is of great significance for fire detection and structural damage assessment. In this work, a special plume model, namely, the “plume bifurcation” is introduced, and its impact on the temperature distribution is analysed theoretically. Full-scale tunnel fire experiments and numerical simulations are conducted to investigate the plume evolution under various heat release rates and ventilation conditions. Results show that the plume will sperate into two sub-streams under strong ventilation condition, resulting in the multi-dimensional plume movement pattern when rising. The sub-plume impingement point location, quantified by the longitudinal vertical deflection angle θv and horizontal bifurcation angle θh, is correlated with the fire heat release rate and ventilation condition. The plume bifurcation angle is 0 when the dimensionless ventilation velocity V0.33, marking a single-stream plume; and rapidly increase and then slowly decrease with V when V>0.33, representing the sudden occurrence and decay trend of plume bifurcation with the ventilation velocity. Finally, a novel bifurcated plume-based model to estimate the maximum ceiling temperature is proposed. This study reveals the role of multi-dimensional smoke movement in reshaping the temperature field, providing new perspectives for a deeper understanding of the smoke transport behaviour in longitudinally ventilated tunnel fires.

评估隧道火灾引起的温度分布对火灾探测和结构损坏评估具有重要意义。本研究引入了一种特殊的烟羽模型,即 "烟羽分叉",并从理论上分析了其对温度分布的影响。通过全尺寸隧道火灾实验和数值模拟,研究了不同热释放率和通风条件下的烟羽演变。结果表明,在强通风条件下,烟流会分裂成两个子流,形成上升时的多维烟流运动模式。以纵向垂直偏转角θv和横向分叉角θh量化的子烟流撞击点位置与火灾热释放率和通风条件相关。当无量纲通风速度 V′≤0.33 时,烟羽分叉角为 0,表示为单流烟羽;当 V′>0.33 时,烟羽分叉角随 V′ 的增大而迅速增大,然后缓慢减小,表示烟羽分叉随通风速度的增大而突然发生并呈衰减趋势。最后,提出了一种基于羽流分叉的新型模型来估算最高天花板温度。这项研究揭示了多维烟雾运动在重塑温度场中的作用,为深入理解纵向通风隧道火灾中的烟雾传输行为提供了新的视角。
{"title":"Modelling the maximum ceiling temperature with bifurcated plume in tunnel fires","authors":"Tianhang Zhang ,&nbsp;Ganyu Wang ,&nbsp;Jiangdong Li ,&nbsp;Ke Wu ,&nbsp;Lizhong Wang","doi":"10.1016/j.firesaf.2024.104249","DOIUrl":"10.1016/j.firesaf.2024.104249","url":null,"abstract":"<div><p>Evaluation of the temperature profile induced by tunnel fire is of great significance for fire detection and structural damage assessment. In this work, a special plume model, namely, the “plume bifurcation” is introduced, and its impact on the temperature distribution is analysed theoretically. Full-scale tunnel fire experiments and numerical simulations are conducted to investigate the plume evolution under various heat release rates and ventilation conditions. Results show that the plume will sperate into two sub-streams under strong ventilation condition, resulting in the multi-dimensional plume movement pattern when rising. The sub-plume impingement point location, quantified by the longitudinal vertical deflection angle <span><math><mrow><msub><mi>θ</mi><mi>v</mi></msub></mrow></math></span> and horizontal bifurcation angle <span><math><mrow><msub><mi>θ</mi><mi>h</mi></msub></mrow></math></span>, is correlated with the fire heat release rate and ventilation condition. The plume bifurcation angle is 0 when the dimensionless ventilation velocity <span><math><mrow><msup><mi>V</mi><mo>′</mo></msup><mo>≤</mo><mn>0.33</mn></mrow></math></span>, marking a single-stream plume; and rapidly increase and then slowly decrease with <span><math><mrow><msup><mi>V</mi><mo>′</mo></msup></mrow></math></span> when <span><math><mrow><msup><mi>V</mi><mo>′</mo></msup><mo>&gt;</mo><mn>0.33</mn></mrow></math></span>, representing the sudden occurrence and decay trend of plume bifurcation with the ventilation velocity. Finally, a novel bifurcated plume-based model to estimate the maximum ceiling temperature is proposed. This study reveals the role of multi-dimensional smoke movement in reshaping the temperature field, providing new perspectives for a deeper understanding of the smoke transport behaviour in longitudinally ventilated tunnel fires.</p></div>","PeriodicalId":50445,"journal":{"name":"Fire Safety Journal","volume":"150 ","pages":"Article 104249"},"PeriodicalIF":3.4,"publicationDate":"2024-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142163697","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Numerical simulation of forest fires and possibilities to estimate aerosol emission: Recent advances 森林火灾的数值模拟和估算气溶胶排放的可能性:最新进展
IF 3.4 3区 工程技术 Q2 ENGINEERING, CIVIL Pub Date : 2024-09-01 DOI: 10.1016/j.firesaf.2024.104250
Nikolay Viktorovich Baranovskiy , Viktoriya Andreevna Vyatkina , Aleksey Mikhailovich Chernyshov

Forest fires produce many different pollutants, including soot formation and aerosol emissions. Air pollution from wildfires leads to cardiopulmonary disease and impacts on the environment and carbon cycle. Emissions of soot and aerosols from forest fires need to be assessed. The following methods exist for estimating aerosol emissions: numerical, experimental and empirical. The purpose of the review is to summarize and analyze various numerical models for simulating forest fires to estimate aerosol emissions. This review provides information on various physical, geometric, artificial intelligence, empirical, cellular automation and graph models. These models are summarized and analyzed in terms of various parameters. The review also provides some discussions and suggestions for future research. Conclusions are drawn to highlight the advantages and disadvantages of various mathematical models.

森林火灾会产生许多不同的污染物,包括烟尘形成和气溶胶排放。野火造成的空气污染会导致心肺疾病,并对环境和碳循环造成影响。需要对森林火灾产生的烟尘和气溶胶排放量进行评估。估算气溶胶排放量的方法有以下几种:数值法、实验法和经验法。本综述旨在总结和分析各种模拟森林火灾的数值模型,以估算气溶胶排放量。本综述提供了有关各种物理、几何、人工智能、经验、蜂窝自动化和图形模型的信息。本综述总结并分析了这些模型的各种参数。本综述还为未来研究提供了一些讨论和建议。最后得出结论,强调了各种数学模型的优缺点。
{"title":"Numerical simulation of forest fires and possibilities to estimate aerosol emission: Recent advances","authors":"Nikolay Viktorovich Baranovskiy ,&nbsp;Viktoriya Andreevna Vyatkina ,&nbsp;Aleksey Mikhailovich Chernyshov","doi":"10.1016/j.firesaf.2024.104250","DOIUrl":"10.1016/j.firesaf.2024.104250","url":null,"abstract":"<div><p>Forest fires produce many different pollutants, including soot formation and aerosol emissions. Air pollution from wildfires leads to cardiopulmonary disease and impacts on the environment and carbon cycle. Emissions of soot and aerosols from forest fires need to be assessed. The following methods exist for estimating aerosol emissions: numerical, experimental and empirical. The purpose of the review is to summarize and analyze various numerical models for simulating forest fires to estimate aerosol emissions. This review provides information on various physical, geometric, artificial intelligence, empirical, cellular automation and graph models. These models are summarized and analyzed in terms of various parameters. The review also provides some discussions and suggestions for future research. Conclusions are drawn to highlight the advantages and disadvantages of various mathematical models.</p></div>","PeriodicalId":50445,"journal":{"name":"Fire Safety Journal","volume":"150 ","pages":"Article 104250"},"PeriodicalIF":3.4,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142157838","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Full-scale car fire tests on FRP reinforced RC columns in piloti structures 试点结构中 FRP 加固 RC 柱的全尺寸汽车火灾试验
IF 3.4 3区 工程技术 Q2 ENGINEERING, CIVIL Pub Date : 2024-08-23 DOI: 10.1016/j.firesaf.2024.104248
In-Rak Choi , Ji-Hye Park , Jeong-Ki Min , Jinwon Shin , Sungmo Choi

Car fire tests were conducted on fiber reinforced polymer (FRP) reinforced columns to evaluate the fire effects on piloti structures. The study involved a mid-size car (1,998 cc) with fuel and tire air pressure removed to reduce the risk of explosion. The objectives were to measure the heat release rate (HRR) and temperature distributions during the fire and to evaluate the fire behavior of the columns in the piloti structure. Results from the car combustion test showed a total heat release of 5,210 MJ, with a maximum temperature of 455.0 °C at 2.5m height above the car ceiling and an internal temperature of 1025.7 °C near the ignition point at the car seat. In the piloti structure fire test, consisting of four reinforced concrete (RC) columns with and without FRP reinforcement and a roof slab, the maximum temperature reached 728.5 °C under the slab. Thicker FRP reinforcement resulted in lower temperatures on the column surface. Fire Dynamics Simulator (FDS) software was used to validate the test results and showed accurate predicted temperatures at 3m (within 10 % error). However, discrepancies were observed at 2.5m (24 % error) and below, although the simulated fire behavior agreed well with the test results for heights of 2.0m and above.

对纤维增强聚合物(FRP)加固柱进行了汽车火灾试验,以评估火灾对先导结构的影响。研究涉及一辆中型汽车(1,998 cc),为降低爆炸风险,已去除燃料和轮胎气压。目标是测量火灾期间的热释放率(HRR)和温度分布,并评估 piloti 结构中支柱的火灾行为。汽车燃烧试验的结果显示,总热量释放量为 5210 兆焦耳,汽车顶棚上方 2.5 米处的最高温度为 455.0 °C,汽车座椅着火点附近的内部温度为 1025.7 °C。在 piloti 结构火灾试验中,由四根带或不带玻璃钢加固的钢筋混凝土 (RC) 柱和一块顶板组成,顶板下的最高温度达到 728.5 °C。较厚的玻璃钢加固材料使得柱子表面温度较低。使用火灾动力学模拟器 (FDS) 软件验证了测试结果,结果显示 3 米处的预测温度准确(误差在 10% 以内)。不过,在 2.5 米(误差 24%)及以下的高度,模拟的火灾行为与 2.0 米及以上高度的测试结果吻合得很好。
{"title":"Full-scale car fire tests on FRP reinforced RC columns in piloti structures","authors":"In-Rak Choi ,&nbsp;Ji-Hye Park ,&nbsp;Jeong-Ki Min ,&nbsp;Jinwon Shin ,&nbsp;Sungmo Choi","doi":"10.1016/j.firesaf.2024.104248","DOIUrl":"10.1016/j.firesaf.2024.104248","url":null,"abstract":"<div><p>Car fire tests were conducted on fiber reinforced polymer (FRP) reinforced columns to evaluate the fire effects on piloti structures. The study involved a mid-size car (1,998 cc) with fuel and tire air pressure removed to reduce the risk of explosion. The objectives were to measure the heat release rate (HRR) and temperature distributions during the fire and to evaluate the fire behavior of the columns in the piloti structure. Results from the car combustion test showed a total heat release of 5,210 MJ, with a maximum temperature of 455.0 °C at 2.5m height above the car ceiling and an internal temperature of 1025.7 °C near the ignition point at the car seat. In the piloti structure fire test, consisting of four reinforced concrete (RC) columns with and without FRP reinforcement and a roof slab, the maximum temperature reached 728.5 °C under the slab. Thicker FRP reinforcement resulted in lower temperatures on the column surface. Fire Dynamics Simulator (FDS) software was used to validate the test results and showed accurate predicted temperatures at 3m (within 10 % error). However, discrepancies were observed at 2.5m (24 % error) and below, although the simulated fire behavior agreed well with the test results for heights of 2.0m and above.</p></div>","PeriodicalId":50445,"journal":{"name":"Fire Safety Journal","volume":"149 ","pages":"Article 104248"},"PeriodicalIF":3.4,"publicationDate":"2024-08-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142083956","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Experimental and numerical investigation on the combustion behavior of densified wood: Differences among wood species and impact of char oxidation 致密木材燃烧行为的实验和数值研究:木材种类的差异和炭氧化的影响
IF 3.4 3区 工程技术 Q2 ENGINEERING, CIVIL Pub Date : 2024-08-18 DOI: 10.1016/j.firesaf.2024.104245
Liang Yi , Yanzhen Zhuang , Zhengyang Wang , Yan Ding , Junhui Gong , Chunli Liu

Densified wood (DW) is a novel structural material with promissing application potential in construction industry due to its excellent mechanical performance. However, it could also be a disastrous fuel contributing to the development of fires. This work experimentally and numerically investigated the combustion behavior of DW. The differences among wood species (fir, pine and oak) and their char oxidation impacts are emphasized. The experimental results indicate that DW has a 44.7 K lower pyrolysis peak temperature on average, a 32.2 % lower peak mass loss rate, and a 8 % higher residual mass ratio than natural wood (NW) in N2 due to the delignification process. The hemicellulose and cellulose pyrolysis are endothermic in N2 but exothermic in air. Wood pyrolysis has an additional char oxidation reaction in air. The higher density of DW leads to longer times for ignition and flaming combustion. DW presents a higher heat release rate and average 4.7 MJ kg−1 higher effective heat of combustion of char. Two parallel pyrolysis reaction schemes based on ambiance are proposed, which well-predict the microscale characterizations but fail to represent the combustion behavior. An optimized mode was developed by adding a continuous char oxidation reaction to the N2 reaction scheme, which best predicts the combustion behaviors.

致密化木材(DW)是一种新型结构材料,由于其卓越的机械性能,在建筑行业具有广阔的应用前景。然而,它也可能成为引发火灾的灾难性燃料。这项研究通过实验和数值方法研究了 DW 的燃烧行为。重点研究了不同木种(杉木、松木和橡木)之间的差异及其炭氧化影响。实验结果表明,与天然木材(NW)相比,DW 在 N2 中的热解峰值温度平均低 44.7 K,峰值质量损失率低 32.2%,残余质量比高 8%,这是因为木质素脱除过程所致。半纤维素和纤维素热解在氮气中是内热的,但在空气中是放热的。木材热解在空气中还有一个炭氧化反应。DW 密度较高,点火和火焰燃烧时间较长。DW 的热释放率更高,木炭的有效燃烧热平均高出 4.7 兆焦耳/千克-1。提出了两种基于环境的并行热解反应方案,它们能很好地预测微尺度特性,但不能代表燃烧行为。通过在 N2 反应方案中加入连续的炭氧化反应,开发出了一种优化模式,它能最好地预测燃烧行为。
{"title":"Experimental and numerical investigation on the combustion behavior of densified wood: Differences among wood species and impact of char oxidation","authors":"Liang Yi ,&nbsp;Yanzhen Zhuang ,&nbsp;Zhengyang Wang ,&nbsp;Yan Ding ,&nbsp;Junhui Gong ,&nbsp;Chunli Liu","doi":"10.1016/j.firesaf.2024.104245","DOIUrl":"10.1016/j.firesaf.2024.104245","url":null,"abstract":"<div><p>Densified wood (DW) is a novel structural material with promissing application potential in construction industry due to its excellent mechanical performance. However, it could also be a disastrous fuel contributing to the development of fires. This work experimentally and numerically investigated the combustion behavior of DW. The differences among wood species (fir, pine and oak) and their char oxidation impacts are emphasized. The experimental results indicate that DW has a 44.7 K lower pyrolysis peak temperature on average, a 32.2 % lower peak mass loss rate, and a 8 % higher residual mass ratio than natural wood (NW) in <em>N</em><sub><em>2</em></sub> due to the delignification process. The hemicellulose and cellulose pyrolysis are endothermic in <em>N</em><sub><em>2</em></sub> but exothermic in air. Wood pyrolysis has an additional char oxidation reaction in air. The higher density of DW leads to longer times for ignition and flaming combustion. DW presents a higher heat release rate and average 4.7 MJ kg<sup>−1</sup> higher effective heat of combustion of char. Two parallel pyrolysis reaction schemes based on ambiance are proposed, which well-predict the microscale characterizations but fail to represent the combustion behavior. An optimized mode was developed by adding a continuous char oxidation reaction to the <em>N</em><sub><em>2</em></sub> reaction scheme, which best predicts the combustion behaviors.</p></div>","PeriodicalId":50445,"journal":{"name":"Fire Safety Journal","volume":"149 ","pages":"Article 104245"},"PeriodicalIF":3.4,"publicationDate":"2024-08-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142048446","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Experimental study on the flame trajectory evolution of horizontal jet fires under reduced pressures 减压条件下水平喷射火焰轨迹演变的实验研究
IF 3.4 3区 工程技术 Q2 ENGINEERING, CIVIL Pub Date : 2024-08-15 DOI: 10.1016/j.firesaf.2024.104238
Jiang Lv , Xiepeng Sun , Yujie Lin , Dongmei Li , Lin Zhao , Qiang Wang , Yuxuan Ma , Xinsheng Jiang , Longhua Hu

Jet fire including process pipeline/tank leakage, oil exploitation industry of tail gas treatment flare or other industrial combustors as a common phenomenon can be found at high altitude areas. This work characterizes the flame trajectory evolution of horizontal jet fires under reduced pressures, which is rarely studied. The experimental results show that the horizontal flame projection distance increases monotonously, but the vertical flame length first increases and afterward decreases with the increase of heat release rate and the decrease of ambient pressure. Meanwhile, flame trajectory length increases significantly and then slowly with increasing heat release rate, but first increases to a maximum value and afterward declines with decreasing ambient pressure. Meanwhile, the turning point of vertical flame length appears earlier than that of flame trajectory length with increasing heat release rate (or jet velocity at source) and decreasing ambient pressure. Then, a mathematical model based on the flame arc hypothesis and a dimensionless model were proposed to describe the flame trajectory length, the momentum-buoyancy length scale Lm=(M0/g)1/3 was used to normalize the flame trajectory length. The measured flame trajectory length in terms of the nozzle diameter, heat release rate, and ambient pressure was satisfactorily correlated by the proposed models.

喷射火包括工艺管道/油箱泄漏、石油开采业的尾气处理火炬或其他工业燃烧器,是高海拔地区的常见现象。这项工作描述了在减压条件下水平喷射火的火焰轨迹演变,而这一问题很少被研究。实验结果表明,随着热释放率的增加和环境压力的降低,水平火焰投射距离单调增加,但垂直火焰长度先增加后减小。同时,火焰轨迹长度随着放热率的增加先大幅增加后缓慢减小,但随着环境压力的减小先增加到最大值后减小。同时,随着热释放率(或源喷射速度)的增加和环境压力的降低,垂直火焰长度的转折点比火焰轨迹长度的转折点出现得更早。然后,提出了一个基于焰弧假说的数学模型和一个无量纲模型来描述火焰轨迹长度,并用动量浮力长度标度 Lm=(M0/g′)1/3 对火焰轨迹长度进行归一化。所测得的火焰轨迹长度与喷嘴直径、热释放率和环境压力的相关性与所提出的模型相符。
{"title":"Experimental study on the flame trajectory evolution of horizontal jet fires under reduced pressures","authors":"Jiang Lv ,&nbsp;Xiepeng Sun ,&nbsp;Yujie Lin ,&nbsp;Dongmei Li ,&nbsp;Lin Zhao ,&nbsp;Qiang Wang ,&nbsp;Yuxuan Ma ,&nbsp;Xinsheng Jiang ,&nbsp;Longhua Hu","doi":"10.1016/j.firesaf.2024.104238","DOIUrl":"10.1016/j.firesaf.2024.104238","url":null,"abstract":"<div><p>Jet fire including process pipeline/tank leakage, oil exploitation industry of tail gas treatment flare or other industrial combustors as a common phenomenon can be found at high altitude areas. This work characterizes the flame trajectory evolution of horizontal jet fires under reduced pressures, which is rarely studied. The experimental results show that the horizontal flame projection distance increases monotonously, but the vertical flame length first increases and afterward decreases with the increase of heat release rate and the decrease of ambient pressure. Meanwhile, flame trajectory length increases significantly and then slowly with increasing heat release rate, but first increases to a maximum value and afterward declines with decreasing ambient pressure. Meanwhile, the turning point of vertical flame length appears earlier than that of flame trajectory length with increasing heat release rate (or jet velocity at source) and decreasing ambient pressure. Then, a mathematical model based on the flame arc hypothesis and a dimensionless model were proposed to describe the flame trajectory length, the momentum-buoyancy length scale <span><math><mrow><msub><mi>L</mi><mi>m</mi></msub><mo>=</mo><msup><mrow><mo>(</mo><mrow><msub><mi>M</mi><mn>0</mn></msub><mo>/</mo><msup><mi>g</mi><mo>′</mo></msup></mrow><mo>)</mo></mrow><mrow><mn>1</mn><mo>/</mo><mn>3</mn></mrow></msup></mrow></math></span> was used to normalize the flame trajectory length. The measured flame trajectory length in terms of the nozzle diameter, heat release rate, and ambient pressure was satisfactorily correlated by the proposed models.</p></div>","PeriodicalId":50445,"journal":{"name":"Fire Safety Journal","volume":"149 ","pages":"Article 104238"},"PeriodicalIF":3.4,"publicationDate":"2024-08-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142096275","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation and CFD simulation of coal dust explosion accident in confined space: A case study of Gaohe Coal Mine Ventilation Air Methane oxidation power plant 密闭空间煤尘爆炸事故调查与 CFD 仿真:高河煤矿通风空气甲烷氧化发电厂案例研究
IF 3.4 3区 工程技术 Q2 ENGINEERING, CIVIL Pub Date : 2024-08-12 DOI: 10.1016/j.firesaf.2024.104237
Xingyu Lyu , Yonggang Qiao , Danping Yuan , Zeyu Zhang , Wenzhe Zuo , Jie Hua , Yuqiang Wang , Lijun Zhang

The study investigates a coal dust explosion accident within a confined space in Shanxi. The accident was caused by coal dust coming into contact with a high-temperature heat source under the influence of the stack effect. Based on the investigation of the coal dust explosion accident, the study uses computational fluid dynamics (CFD) simulation to reconstruct the accident scenario. The simulation results provide a detailed depiction of coal dust movement within subsurface semi-enclosed confined spaces during the ventilation diffusion stage, influenced by the stack effect, and confirm the formation of a coal dust layer at the heat source due to coal dust deposition. The simulation results of the two explosion processes indicate that excessively high coal dust concentrations within confined spaces have a negative correlation with the development of explosion flames and the peak overpressure. It resulted in a secondary explosion with a relatively low concentration of coal dust, where the peak overpressure was five times that of the primary explosion. Comparative analysis between simulation results and actual investigations the accuracy of the CFD simulation in capturing the accident process and its characteristics, providing valuable insights for preventing and controlling coal dust explosion accidents.

本研究调查了山西密闭空间内的一起煤尘爆炸事故。事故是由煤尘在烟囱效应的影响下接触高温热源引起的。在煤尘爆炸事故调查的基础上,研究使用计算流体动力学(CFD)模拟来重建事故场景。模拟结果详细描述了受烟囱效应影响的通风扩散阶段煤尘在地下半封闭密闭空间内的运动情况,并证实了由于煤尘沉积而在热源处形成的煤尘层。两个爆炸过程的模拟结果表明,密闭空间内煤尘浓度过高与爆炸火焰的发展和过压峰值呈负相关。这导致了煤尘浓度相对较低的二次爆炸,其峰值超压是一次爆炸的五倍。模拟结果与实际调查的对比分析表明,CFD 模拟能准确捕捉事故过程及其特征,为预防和控制煤尘爆炸事故提供了宝贵的见解。
{"title":"Investigation and CFD simulation of coal dust explosion accident in confined space: A case study of Gaohe Coal Mine Ventilation Air Methane oxidation power plant","authors":"Xingyu Lyu ,&nbsp;Yonggang Qiao ,&nbsp;Danping Yuan ,&nbsp;Zeyu Zhang ,&nbsp;Wenzhe Zuo ,&nbsp;Jie Hua ,&nbsp;Yuqiang Wang ,&nbsp;Lijun Zhang","doi":"10.1016/j.firesaf.2024.104237","DOIUrl":"10.1016/j.firesaf.2024.104237","url":null,"abstract":"<div><p>The study investigates a coal dust explosion accident within a confined space in Shanxi. The accident was caused by coal dust coming into contact with a high-temperature heat source under the influence of the stack effect. Based on the investigation of the coal dust explosion accident, the study uses computational fluid dynamics (CFD) simulation to reconstruct the accident scenario. The simulation results provide a detailed depiction of coal dust movement within subsurface semi-enclosed confined spaces during the ventilation diffusion stage, influenced by the stack effect, and confirm the formation of a coal dust layer at the heat source due to coal dust deposition. The simulation results of the two explosion processes indicate that excessively high coal dust concentrations within confined spaces have a negative correlation with the development of explosion flames and the peak overpressure. It resulted in a secondary explosion with a relatively low concentration of coal dust, where the peak overpressure was five times that of the primary explosion. Comparative analysis between simulation results and actual investigations the accuracy of the CFD simulation in capturing the accident process and its characteristics, providing valuable insights for preventing and controlling coal dust explosion accidents.</p></div>","PeriodicalId":50445,"journal":{"name":"Fire Safety Journal","volume":"149 ","pages":"Article 104237"},"PeriodicalIF":3.4,"publicationDate":"2024-08-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141984756","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Measurement dynamics and data treatment in fire testing 火灾测试中的测量动态和数据处理
IF 3.4 3区 工程技术 Q2 ENGINEERING, CIVIL Pub Date : 2024-08-10 DOI: 10.1016/j.firesaf.2024.104236
Bart J.G. Sette, Anneke M.R. Vandevelde

Fire testing is and will remain of paramount importance in helping industry, regulators and all other fire safety stakeholders to achieve a safer world. For this to happen, test data must be stable and reliable, regardless of the test facility that produced the data, its various operators, the measurement equipment used, and so on. The instruments and sensors used to measure heat release, smoke production and mass loss rate are susceptible to mechanical and/or electrical disturbances and all have their own dynamic behaviour. This leads to a variation in the test results. A scatter that is only due to the measurement.

This paper examines the time and frequency domain behaviour of various measurement components and hardware & software filters in use today. It proposes an instrument-independent method of eliminating noise and other interference, describes a method of adjusting the response time of the various input signals to a common value applicable to all test institutes, and proposes a method of accurately synchronising these signals in time.

The result is unambiguous qualitative measurement data that can be confidently compared with data from other sample sets or between different laboratories and researchers. It improves the stability and reproducibility of test results leading to a more stable classification of materials.

在帮助行业、监管机构和所有其他消防安全利益相关者实现一个更安全的世界方面,消防测试现在和将来都至关重要。为此,测试数据必须稳定可靠,无论产生数据的测试设施、各种操作人员、使用的测量设备等如何。用于测量热释放、烟雾产生和质量损失率的仪器和传感器很容易受到机械和/或电气干扰的影响,并且都有自己的动态行为。这就导致了测试结果的差异。本文研究了当今使用的各种测量组件、硬件和软件滤波器的时域和频域行为。它提出了一种与仪器无关的消除噪声和其他干扰的方法,描述了一种将各种输入信号的响应时间调整为适用于所有测试机构的通用值的方法,并提出了一种使这些信号在时间上准确同步的方法。其结果是获得了毫不含糊的定性测量数据,这些数据可以与其他样本集或不同实验室和研究人员之间的数据进行有把握的比较。它提高了测试结果的稳定性和可重复性,使材料分类更加稳定。
{"title":"Measurement dynamics and data treatment in fire testing","authors":"Bart J.G. Sette,&nbsp;Anneke M.R. Vandevelde","doi":"10.1016/j.firesaf.2024.104236","DOIUrl":"10.1016/j.firesaf.2024.104236","url":null,"abstract":"<div><p>Fire testing is and will remain of paramount importance in helping industry, regulators and all other fire safety stakeholders to achieve a safer world. For this to happen, test data must be stable and reliable, regardless of the test facility that produced the data, its various operators, the measurement equipment used, and so on. The instruments and sensors used to measure heat release, smoke production and mass loss rate are susceptible to mechanical and/or electrical disturbances and all have their own dynamic behaviour. This leads to a variation in the test results. A scatter that is only due to the measurement.</p><p>This paper examines the time and frequency domain behaviour of various measurement components and hardware &amp; software filters in use today. It proposes an instrument-independent method of eliminating noise and other interference, describes a method of adjusting the response time of the various input signals to a common value applicable to all test institutes, and proposes a method of accurately synchronising these signals in time.</p><p>The result is unambiguous qualitative measurement data that can be confidently compared with data from other sample sets or between different laboratories and researchers. It improves the stability and reproducibility of test results leading to a more stable classification of materials.</p></div>","PeriodicalId":50445,"journal":{"name":"Fire Safety Journal","volume":"149 ","pages":"Article 104236"},"PeriodicalIF":3.4,"publicationDate":"2024-08-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141990516","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Experimental study on the effect of preinhibition pressure on the inhibition of coal spontaneous combustion 预抑制压力对煤炭自燃抑制作用的实验研究
IF 3.4 3区 工程技术 Q2 ENGINEERING, CIVIL Pub Date : 2024-08-05 DOI: 10.1016/j.firesaf.2024.104235
Baolong Guo , Yuntao Liang , Wei Wang , Guansheng Qi , Yong Sun , Zhenzhen Zhao , Xinfeng Cui

A pressurized inhibition method is proposed based on the pre-inhibition process to study the inhibition law and mechanism of the pre-inhibition pressure on the coal spontaneous combustion, with a purpose of enhancing the inhibiting effect of chloride salt inhibitors. In this work, inhibited coal samples were prepared by immersing raw coal in high-temperature and high-pressure reactor at 1 MPa, 2 MPa, 3 MPa, 4 MPa, and 5 MPa, respectively, using MgCl2 solution with a mass concentration of 20 %. The variation rules of the characteristic parameters, such as the indicator gas concentration, inhibition rate, surface microscopic morphology, and reactive groups, of various coal samples with the elevation of the pre-inhibition pressure were investigated using the programmed temperature-raising oxidation system, infrared spectroscopy, and SEM. It was found that the pre-inhibition pressure was in the range of 1–4 MPa, and with the increase of pre-inhibition pressure, the gas-producing concentration and the content of active groups of coal decreased, and the inhibition rate increased significantly. Increasing the pre-inhibition pressure can significantly improve the inhibition effect, and the optimum pre-inhibition pressure is 4 MPa. Continuing to increase the pre-inhibition pressure will destroy the pore structure of the coal and reduce the inhibition effect.

提出了一种基于预抑制过程的加压抑制方法,研究预抑制压力对煤自燃的抑制规律和机理,以期增强氯盐抑制剂的抑制效果。本研究采用质量浓度为 20% 的氯化镁溶液,将原煤分别浸入 1 MPa、2 MPa、3 MPa、4 MPa 和 5 MPa 的高温高压反应器中,制备了抑制煤样。利用程序升温氧化系统、红外光谱和扫描电镜研究了各种煤样的指示气体浓度、抑制率、表面微观形貌和反应基团等特征参数随预抑制压力升高的变化规律。结果发现,预抑制压力在 1-4 MPa 之间,随着预抑制压力的增加,煤的产气浓度和活性基团含量降低,抑制率显著增加。提高预抑制压力可明显改善抑制效果,最佳预抑制压力为 4 MPa。继续增加预抑制压力会破坏煤的孔隙结构,降低抑制效果。
{"title":"Experimental study on the effect of preinhibition pressure on the inhibition of coal spontaneous combustion","authors":"Baolong Guo ,&nbsp;Yuntao Liang ,&nbsp;Wei Wang ,&nbsp;Guansheng Qi ,&nbsp;Yong Sun ,&nbsp;Zhenzhen Zhao ,&nbsp;Xinfeng Cui","doi":"10.1016/j.firesaf.2024.104235","DOIUrl":"10.1016/j.firesaf.2024.104235","url":null,"abstract":"<div><p>A pressurized inhibition method is proposed based on the pre-inhibition process to study the inhibition law and mechanism of the pre-inhibition pressure on the coal spontaneous combustion, with a purpose of enhancing the inhibiting effect of chloride salt inhibitors. In this work, inhibited coal samples were prepared by immersing raw coal in high-temperature and high-pressure reactor at 1 MPa, 2 MPa, 3 MPa, 4 MPa, and 5 MPa, respectively, using MgCl<sub>2</sub> solution with a mass concentration of 20 %. The variation rules of the characteristic parameters, such as the indicator gas concentration, inhibition rate, surface microscopic morphology, and reactive groups, of various coal samples with the elevation of the pre-inhibition pressure were investigated using the programmed temperature-raising oxidation system, infrared spectroscopy, and SEM. It was found that the pre-inhibition pressure was in the range of 1–4 MPa, and with the increase of pre-inhibition pressure, the gas-producing concentration and the content of active groups of coal decreased, and the inhibition rate increased significantly. Increasing the pre-inhibition pressure can significantly improve the inhibition effect, and the optimum pre-inhibition pressure is 4 MPa. Continuing to increase the pre-inhibition pressure will destroy the pore structure of the coal and reduce the inhibition effect.</p></div>","PeriodicalId":50445,"journal":{"name":"Fire Safety Journal","volume":"149 ","pages":"Article 104235"},"PeriodicalIF":3.4,"publicationDate":"2024-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141935483","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of the wood species on the fire behavior in vertical orientation 木材种类对垂直方向火灾行为的影响
IF 3.4 3区 工程技术 Q2 ENGINEERING, CIVIL Pub Date : 2024-07-30 DOI: 10.1016/j.firesaf.2024.104234
Lucas Terrei , Hassan Flity , Oualid Ikhou , Gaspard Trohel , José Luis Torero , Zoubir Acem , Gilles Parent

The objective of this study was to investigate the parameters controlling auto-ignition, degradation and auto-extinction of wood. For this purpose an extensive set of experiments was conducted varying extrinsic parameters such as external heat-flux but also the type of wood. Varying the wood species allowed to explore the role of thermal properties and wood composition. Seven wood samples were tested, some light and some heavy, both hardwood and softwood. The experimental setup was based on a double-cone calorimeter, which allowed to accurately change the imposed heat flux at a predefined moment. More than 600 tests were carried out in a vertical orientation, allowing a statistical analysis. For each test, mass loss, surface temperature and in-depth temperature of the samples were measured using a precision scale, an infrared camera and thin wire thermocouples embedded using a special machining, respectively. The auto-ignition study showed that the time to auto-ignition increases linearly with density. Despite a wide range of these times to ignition, the surface temperatures at ignition were in the same order of magnitude for all species considered: between 450 and 700 °C for auto-ignition before 2 min and between 700 and 800 °C for auto-ignition after 2 min. The onset of char oxidation was observed at low heat fluxes. It occurs at different times depending on the wood species, but at similar surface temperatures, between 380 and 400 °C. The sliding double heating cone made it possible to identify the criteria for auto-extinction: the heat flux for auto-extinction can vary from 40 to 55 kW.m−2 depending on the wood species, and a linear correlation was found between the mass loss rate at extinction and the initial density of each sample studied. The study highlights the dominant role of density for auto-ignition and auto-extinction.

这项研究的目的是调查控制木材自燃、降解和自灭的参数。为此,我们进行了一系列广泛的实验,不仅改变了外部参数,如外部热流,还改变了木材的种类。改变木材种类可以探索热性能和木材成分的作用。共测试了七种木材样本,有轻有重,既有硬木也有软木。实验装置以双锥量热仪为基础,可在预定时刻准确改变施加的热通量。在垂直方向上进行了 600 多次试验,以便进行统计分析。在每次试验中,分别使用精密刻度尺、红外摄像机和通过特殊加工嵌入的细线热电偶测量样品的质量损失、表面温度和深度温度。自燃研究表明,自燃时间随密度的增加而线性增加。尽管这些点火时间的范围很宽,但对于所考虑的所有种类,点火时的表面温度都在同一数量级:2 分钟前的自燃温度在 450 至 700 ℃ 之间,2 分钟后的自燃温度在 700 至 800 ℃ 之间。在低热通量下就能观察到炭氧化的开始。氧化发生的时间因木材种类而异,但表面温度相似,都在 380 至 400 ℃ 之间。通过滑动双加热锥可以确定自动熄灭的标准:根据木材种类的不同,自动熄灭的热通量可在 40 到 55 kW.m 之间变化,并且发现熄灭时的质量损失率与所研究的每个样品的初始密度之间存在线性相关关系。这项研究强调了密度在自燃和自熄中的主导作用。
{"title":"Effect of the wood species on the fire behavior in vertical orientation","authors":"Lucas Terrei ,&nbsp;Hassan Flity ,&nbsp;Oualid Ikhou ,&nbsp;Gaspard Trohel ,&nbsp;José Luis Torero ,&nbsp;Zoubir Acem ,&nbsp;Gilles Parent","doi":"10.1016/j.firesaf.2024.104234","DOIUrl":"10.1016/j.firesaf.2024.104234","url":null,"abstract":"<div><p>The objective of this study was to investigate the parameters controlling auto-ignition, degradation and auto-extinction of wood. For this purpose an extensive set of experiments was conducted varying extrinsic parameters such as external heat-flux but also the type of wood. Varying the wood species allowed to explore the role of thermal properties and wood composition. Seven wood samples were tested, some light and some heavy, both hardwood and softwood. The experimental setup was based on a double-cone calorimeter, which allowed to accurately change the imposed heat flux at a predefined moment. More than 600 tests were carried out in a vertical orientation, allowing a statistical analysis. For each test, mass loss, surface temperature and in-depth temperature of the samples were measured using a precision scale, an infrared camera and thin wire thermocouples embedded using a special machining, respectively. The auto-ignition study showed that the time to auto-ignition increases linearly with density. Despite a wide range of these times to ignition, the surface temperatures at ignition were in the same order of magnitude for all species considered: between 450 and 700 °C for auto-ignition before 2 min and between 700 and 800 °C for auto-ignition after 2 min. The onset of char oxidation was observed at low heat fluxes. It occurs at different times depending on the wood species, but at similar surface temperatures, between 380 and 400 °C. The sliding double heating cone made it possible to identify the criteria for auto-extinction: the heat flux for auto-extinction can vary from 40 to 55 kW.m<sup>−2</sup> depending on the wood species, and a linear correlation was found between the mass loss rate at extinction and the initial density of each sample studied. The study highlights the dominant role of density for auto-ignition and auto-extinction.</p></div>","PeriodicalId":50445,"journal":{"name":"Fire Safety Journal","volume":"148 ","pages":"Article 104234"},"PeriodicalIF":3.4,"publicationDate":"2024-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0379711224001474/pdfft?md5=d1d9101ed3360370ed47abf860f25a5a&pid=1-s2.0-S0379711224001474-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141935484","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Experimental and numerical study on data-driven prediction for wildfire spread incorporating adaptive observation error adjustment 结合自适应观测误差调整的野火蔓延数据驱动预测实验和数值研究
IF 3.4 3区 工程技术 Q2 ENGINEERING, CIVIL Pub Date : 2024-07-30 DOI: 10.1016/j.firesaf.2024.104230
Zheng Wang , Xingdong Li , Mengxia Zha , Jie Ji

In recent wildfire prediction research, data assimilation (DA) methods like Ensemble Kalman filtering have gained traction for integrating observation data to enhance prediction accuracy. Most previous studies trusted that the observation data were accurate, and set a small observation error, which causes unreliable predicted results for scenarios with large observation error. To tackle this, our study introduced a method that iteratively adjusted the potential range of observation errors by comparing observation and simulation data over time. We conducted a 30-m experiment and kilometer-scale numerical simulations. Unlike prior research, we adopted larger error ranges (the similarity index with true data ranges from 0.6 to 1) for both real and synthetic observation data. In the experiment, to increase the complexity of fire spread, a heterogeneous fuel arrangement was employed. Irregular flame fronts appeared due to incomplete combustion and were difficult to replicate in simulations. Better accuracy was achieved using real observation data to revise predictions. Furthermore, to improve the applicability of the algorithm, numerical simulations were designed to consider observation error changing over time or not. The Root Mean Square Errors for the fire front prediction using the proposed method remained lower than that of the traditional DA approach.

在最近的野火预测研究中,数据同化(DA)方法(如集合卡尔曼滤波)在整合观测数据以提高预测精度方面获得了广泛关注。以往的研究大多认为观测数据是准确的,并设定了较小的观测误差,这导致在观测误差较大的情况下,预测结果并不可靠。为了解决这个问题,我们的研究引入了一种方法,通过比较观测数据和模拟数据,反复调整观测误差的可能范围。我们进行了 30 米实验和千米尺度的数值模拟。与之前的研究不同,我们对真实和合成观测数据都采用了较大的误差范围(与真实数据的相似度指数范围为 0.6 至 1)。在实验中,为了增加火灾蔓延的复杂性,我们采用了异质燃料布置。由于燃烧不完全,出现了不规则的火焰前沿,很难在模拟中复制。利用真实观测数据对预测进行修正,可以获得更高的精度。此外,为了提高算法的适用性,在设计数值模拟时考虑了观测误差是否随时间变化的问题。使用拟议方法预测火锋的均方根误差仍然低于传统的DA方法。
{"title":"Experimental and numerical study on data-driven prediction for wildfire spread incorporating adaptive observation error adjustment","authors":"Zheng Wang ,&nbsp;Xingdong Li ,&nbsp;Mengxia Zha ,&nbsp;Jie Ji","doi":"10.1016/j.firesaf.2024.104230","DOIUrl":"10.1016/j.firesaf.2024.104230","url":null,"abstract":"<div><p>In recent wildfire prediction research, data assimilation (DA) methods like Ensemble Kalman filtering have gained traction for integrating observation data to enhance prediction accuracy. Most previous studies trusted that the observation data were accurate, and set a small observation error, which causes unreliable predicted results for scenarios with large observation error. To tackle this, our study introduced a method that iteratively adjusted the potential range of observation errors by comparing observation and simulation data over time. We conducted a 30-m experiment and kilometer-scale numerical simulations. Unlike prior research, we adopted larger error ranges (the similarity index with true data ranges from 0.6 to 1) for both real and synthetic observation data. In the experiment, to increase the complexity of fire spread, a heterogeneous fuel arrangement was employed. Irregular flame fronts appeared due to incomplete combustion and were difficult to replicate in simulations. Better accuracy was achieved using real observation data to revise predictions. Furthermore, to improve the applicability of the algorithm, numerical simulations were designed to consider observation error changing over time or not. The Root Mean Square Errors for the fire front prediction using the proposed method remained lower than that of the traditional DA approach.</p></div>","PeriodicalId":50445,"journal":{"name":"Fire Safety Journal","volume":"148 ","pages":"Article 104230"},"PeriodicalIF":3.4,"publicationDate":"2024-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141935486","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Fire Safety Journal
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1