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Characterization of flammability and species yields for PMMA burning at constant equivalence ratios in a fire propagation apparatus 在火焰传播装置中以恒定的等效比燃烧PMMA的可燃性和物种产量的表征
IF 3.3 3区 工程技术 Q2 ENGINEERING, CIVIL Pub Date : 2025-09-06 DOI: 10.1016/j.firesaf.2025.104532
Farnaz Beygi Khosroshahi, Fernando Raffan-Montoya, Stanislav I. Stoliarov
A new method for the measurement of the heat release rate and products of combustion at constant global equivalence ratios (GERs) was developed. This method was based on a modified Fire Propagation Apparatus (FPA) equipped with O2, CO2, CO, total hydrocarbons (THC), particulate matter (PM), NO, and HCN sensors. The control of GER was achieved by administering precisely calibrated, time-varying air flow to the combustion zone. To demonstrate this method's capabilities, the combustion of poly(methyl methacrylate) (PMMA) was investigated at GER ranging from 0.63 to 1.96. The CO2 yield, expressed as mass of species per mass of pyrolyzate, and heat of combustion were found to monotonically decrease from 2.04 to 1.05 and from 23.6 kJ g−1 to 15.1 kJ g−1, respectively, with increasing GER. Conversely, CO, PM, and THC yields increased from 0.019 to 0.263, from 0.015 to 0.051, and from 0.006 to 0.301, respectively, with increasing GER. Good carbon balance, within ±5 %, was achieved across the entire GER range. The characteristic time the combusting mixture spends in the FPA's test section was identified as another key parameter, alongside GER, that affected both species production and heat release. An empirical model was developed and validated to fully capture these dependencies.
提出了一种测量恒等效比下燃烧热释放率和燃烧产物的新方法。该方法基于改进的火焰传播仪(FPA),配备O2、CO2、CO、总碳氢化合物(THC)、颗粒物(PM)、NO和HCN传感器。GER的控制是通过管理精确校准,时变气流到燃烧区实现的。为了证明这种方法的能力,研究了聚甲基丙烯酸甲酯(PMMA)在0.63至1.96的GER范围内的燃烧。随着GER的增加,CO2产率(以每质量热解产物的物质质量表示)和燃烧热分别从2.04降至1.05和从23.6 kJ g−1单调降低。相反,CO、PM和THC产率随GER的增加分别从0.019增加到0.263、从0.015增加到0.051和从0.006增加到0.301。在整个GER范围内实现了±5%的良好碳平衡。燃烧混合物在FPA测试段的特征时间与GER一起被确定为影响物种产生和热量释放的另一个关键参数。开发并验证了一个经验模型,以充分捕捉这些依赖关系。
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引用次数: 0
Revisiting the BS 8414 timber crib: An experimental investigation for enhancing facade fire safety 重新审视BS 8414木槽:提高立面防火安全的实验研究
IF 3.3 3区 工程技术 Q2 ENGINEERING, CIVIL Pub Date : 2025-09-01 DOI: 10.1016/j.firesaf.2025.104522
Konstantinos Chotzoglou , Talal Fateh
In the aftermath of the Grenfell Tower tragedy, the fire performance of external wall systems (EWS) and the timber crib fire source specified in BS 8414 have come under increasing scrutiny. This study presents a comprehensive experimental investigation into the burning characteristics and heat exposure effects of the BS 8414 timber crib. A two-scale approach was employed, combining bench-scale calorimetry (ISO 1716) and large-scale testing in both free-burn and chamber configurations, to evaluate the consistency, intensity, and thermal output of the fire source. Key parameters such as heat release rate (HRR), mass loss rate (MLR), temperature evolution, and incident heat flux on an inert façade were measured. The results demonstrate good repeatability and reveal that the actual heat output often exceeds the standard's prescribed values, exposing the façade to high-intensity thermal loads sufficient to ignite many cladding materials. The findings also indicate that the BS 8414 setup more closely resembles an external fire scenario rather than a post-flashover room fire, due to the chamber's geometry and fuel placement. This research provides valuable benchmark data that may inform regulatory bodies, standardization committees, and engineers, contributing to improved testing methodologies and the development of safer façade fire standards for high-rise buildings.
在格伦费尔大厦悲剧之后,BS 8414中规定的外墙系统(EWS)和木槽火源的防火性能受到越来越多的审查。本研究对BS 8414木槽的燃烧特性和热暴露效应进行了全面的实验研究。采用双尺度方法,结合实验尺度量热法(ISO 1716)和自由燃烧和燃烧室配置的大规模测试,来评估火源的一致性、强度和热输出。测量了惰性表面的热释放率(HRR)、质量损失率(MLR)、温度演变和入射热流密度等关键参数。结果显示了良好的重复性,并揭示了实际的热量输出往往超过标准的规定值,暴露在高强度热负荷足以点燃许多包层材料的表面。研究结果还表明,由于燃烧室的几何形状和燃料放置,BS 8414的设置更接近于外部火灾场景,而不是闪燃后的室内火灾。这项研究提供了有价值的基准数据,可以为监管机构、标准化委员会和工程师提供信息,有助于改进测试方法和制定更安全的高层建筑表面防火标准。
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引用次数: 0
Simple prediction equation for ceiling jet flow arrival time in space without vertical wall soffit 无垂壁拱度的顶棚射流到达空间时间的简单预测方程
IF 3.3 3区 工程技术 Q2 ENGINEERING, CIVIL Pub Date : 2025-09-01 DOI: 10.1016/j.firesaf.2025.104520
Hyewon Kim , Jun-ichi Yamaguchi , Hyun-woo Park , Yoshifumi Ohmiya
Currently, in two-zone models, smoke flow is calculated based on the assumption that the fire plume, which develops directly above the fire source, depends solely on the amount of entrained surrounding air. However, in large flat spaces, which have been growing larger in recent years, the horizontal travel distance of ceiling jet flow is long, and it is possible that the amount of smoke due to entrainment of air during the horizontal spread process is underestimated. In this study, we performed experiments that reproduced an unconfined ceiling without a vertical wall soffit and determined the amount of entrainment in the ceiling jet flow by analyzing the gas concentration of ceiling jet flow at various flow distances. Next, we formulated the ceiling jet flow rate by expressing this in terms of dimensionless flow rate and dimensionless flow distance. Furthermore, we derived a simple prediction equation for ceiling jet flow arrival time based on the model equation. Finally, we validated the proposed equation and range of applicability through comparison with the results of several experiments.
目前,在两区模型中,烟流的计算是基于这样的假设,即火源正上方发展的火羽完全取决于周围空气的夹带量。然而,在近年来越来越大的大型平面空间中,吊顶射流的水平传播距离较长,有可能低估了在水平传播过程中因夹带空气而产生的烟雾量。在这项研究中,我们进行了实验,再现了一个没有垂直墙拱的无约束顶棚,并通过分析不同流动距离下顶棚射流的气体浓度来确定顶棚射流中的夹带量。然后,用无因次流量和无因次流动距离的表达式来表示顶棚射流的流量。在此基础上,推导了顶棚射流到达时间的简单预测方程。最后,通过与多个实验结果的对比,验证了所提方程及其适用范围。
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引用次数: 0
A theoretical model to calculate the thermal radiation from localized fire to vertical surfaces located inside and outside the flame 一个计算局部火焰对火焰内外垂直表面热辐射的理论模型
IF 3.3 3区 工程技术 Q2 ENGINEERING, CIVIL Pub Date : 2025-08-31 DOI: 10.1016/j.firesaf.2025.104511
Junjie Wei , Chao Zhang
This paper presents a theoretical model to calculate the radiative heat fluxes from localized fires to vertical surfaces. The fire volume is modeled as a series of concentric hollow cylinders (CHCs), each treated as an isothermal graybody with uniform height and width. New methods for determining the emissivity of individual CHC elements, as well as the view factors and transmissivity between each CHC and the target surface, are introduced. The radiative contributions from each CHC element using a simplified view factor approach and incorporating transmissive radiation losses through Beer's law and Kirchoff's law to account for medium absorption. The proposed model is validated against experimental data from the literature and verified through three-dimensional (3D) simulations using the Fire Dynamics Simulator (FDS). Comparisons with experimental data and simulation results indicate that the model provides conservative and reliable predictions for vertical surfaces both inside and outside the flame. Compared to the other classic flame models, the proposed model demonstrates improved accuracy outside the flame. Furthermore, the model fills a critical methodological gap by enabling the calculation of radiative heat fluxes not only on vertical surfaces within the flame but also on vertical surfaces with arbitrary normal directions at any position in space. This makes the model a valuable tool for advancing structural fire engineering design and risk assessment in localized fire scenarios.
本文提出了一个计算局部火灾对垂直表面辐射热通量的理论模型。火灾体积被建模为一系列同心空心圆柱体(CHCs),每个圆柱体都被处理为具有均匀高度和宽度的等温灰体。介绍了确定单个CHC元素发射率的新方法,以及每个CHC与目标表面之间的视因子和透射率的新方法。每个CHC元素的辐射贡献采用简化的视因子方法,并通过比尔定律和基尔霍夫定律结合透射辐射损失来考虑介质吸收。根据文献中的实验数据验证了所提出的模型,并通过火焰动力学模拟器(FDS)的三维(3D)模拟进行了验证。与实验数据和仿真结果的比较表明,该模型对火焰内外垂直表面均提供了保守可靠的预测。与其他经典火焰模型相比,该模型在火焰外的精度得到了提高。此外,该模型不仅可以计算火焰垂直表面上的辐射热流,而且可以计算空间中任意法线方向的垂直表面上的辐射热流,从而填补了一个关键的方法空白。这使得该模型成为推进局部火灾场景下结构防火工程设计和风险评估的重要工具。
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引用次数: 0
Effect of fire department response time on fire damage in the Netherlands 荷兰消防部门反应时间对火灾损失的影响
IF 3.3 3区 工程技术 Q2 ENGINEERING, CIVIL Pub Date : 2025-08-31 DOI: 10.1016/j.firesaf.2025.104517
G.M. Montagna , P.L. van den Berg , V. Oskam , C.J. Jagtenberg , V. Oosterveen , R.D. van der Mei , J. Klooster
Fire department response times are often used as a measure of their performance, even though its influence on the outcome is not well understood. In this study, we investigate the effect of the response time on the final damage to a building after a fire. We use a partial proportional odds model to measure how one extra minute of response time influences the probability of the damage exceeding a certain threshold, using data on building fires in the Netherlands from 2018 to 2022. Our results show that the probability of large damage increases almost linearly with the response time. As a rule of thumb, the probability of large damage increases with an average of 1% with each additional minute of response time. Furthermore, to minimize the probability of total loss each minute after a response time of about 10 min becomes increasingly more valuable.
消防部门的响应时间经常被用来衡量他们的表现,尽管它对结果的影响还没有得到很好的理解。在本研究中,我们研究了火灾后反应时间对建筑物最终损害的影响。我们使用部分比例赔率模型来衡量额外一分钟的响应时间如何影响超过一定阈值的损害概率,使用的是荷兰2018年至2022年的建筑火灾数据。我们的研究结果表明,大损伤的概率几乎随响应时间线性增加。根据经验,每增加一分钟的响应时间,大伤害的概率平均增加1%。此外,在大约10分钟的响应时间之后,最小化每分钟总损失的概率变得越来越有价值。
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引用次数: 0
Beyond the worst-case scenario: Inconsistencies in dust flammability parameter determination for organic solid fuels 在最坏的情况之外:有机固体燃料的粉尘可燃性参数测定不一致
IF 3.3 3区 工程技术 Q2 ENGINEERING, CIVIL Pub Date : 2025-08-28 DOI: 10.1016/j.firesaf.2025.104518
Nieves Fernandez-Anez , Isabel Amez , Bjarne C. Hagen , Alberto Tascon , Blanca Castells
The use of solid organic fuels is expected to continue increasing during the near future, requiring bigger facilities and storage units. It is known that one of the main risks associated to these materials is the risk of fire and explosion. While flammability parameters and testing standards have been adapted from fossil fuel research, these adaptations often fail to account for the unique properties and behaviour of organic dusts. This study aims to critically evaluate the applicability of current flammability testing standards to organic solid fuels, identify inconsistencies in parameter determination, and propose improvements to enhance safety assessments. Special attention is given to the influence of particle size, moisture content, and composition on ignition sensitivity. A comprehensive literature review was conducted alongside experimental thermogravimetric analysis (TGA) of wood pellet dusts under varying conditions. The study examined how methodological variables (such as crucible size, heating rate, and gas atmosphere) affect thermal decomposition profiles and ignition-related parameters. The results reveal that current standards often overlook critical variables such as sample preparation, dispersion method, and equipment configuration, leading to inconsistent or non-representative results. TGA parameters like maximum weight loss temperature and induction temperature were found to be sensitive to test conditions. The study underscores the need for more detailed and standardized testing protocols tailored to organic dusts. It advocates for a shift beyond worst-case scenario assumptions toward more realistic, scenario-specific assessments. These improvements are essential for enhancing the reliability of flammability data and ensuring safer industrial practices involving combustible dusts.
预计在不久的将来,固体有机燃料的使用将继续增加,需要更大的设施和储存单元。众所周知,与这些材料相关的主要风险之一是火灾和爆炸的风险。虽然可燃性参数和测试标准已经从化石燃料研究中调整,但这些调整往往无法解释有机粉尘的独特性质和行为。本研究旨在批判性地评估当前可燃性测试标准对有机固体燃料的适用性,识别参数确定中的不一致之处,并提出改进措施以加强安全评估。特别注意的是颗粒大小,水分含量和组成对点火敏感性的影响。对不同条件下木屑粉尘进行了全面的文献综述和实验热重分析(TGA)。该研究考察了方法变量(如坩埚尺寸、加热速率和气体气氛)如何影响热分解剖面和点火相关参数。结果表明,目前的标准往往忽略了关键变量,如样品制备、分散方法和设备配置,导致结果不一致或不具有代表性。最大失重温度和感应温度等TGA参数对试验条件比较敏感。这项研究强调需要针对有机粉尘制定更详细和标准化的测试方案。它提倡从最坏情况的假设转向更现实的、具体情况的评估。这些改进对于提高可燃性数据的可靠性和确保涉及可燃性粉尘的更安全的工业实践至关重要。
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引用次数: 0
Bench-scale flammability testing to optimize the effectiveness of fire retardant treatment of wildland fuels 试验台可燃性测试,以优化荒地燃料阻燃处理的有效性
IF 3.3 3区 工程技术 Q2 ENGINEERING, CIVIL Pub Date : 2025-08-27 DOI: 10.1016/j.firesaf.2025.104509
C. Álvarez , N. Correa , F. Valenzuela , M. Reveco , J. Ferrer , R. Demarco , A. Fuentes , A. Simeoni , P. Reszka
This work focuses on evaluating the effectiveness of fire retardants, using bench-scale flammability apparatuses to test Pinus radiata D. Don needles. Two devices entirely developed in Chile, representative of continuous and discontinuous ignition modes, were used. The product tested was Phos-Chek LC65A-Fx, commonly used in wildfire fighting operations in Chile. The retardant was applied on the pine needles at different concentrations in order to study the effect of retardant concentration (σret) on different flammability parameters. Notable findings include a modification in flame behaviour in treated samples, with reduced smouldering and prolonged flame duration. As expected, the ignition delay times increase with the amount of retardant, showing a similar behaviour as the heat release rates (HRR). Interestingly, the critical heat flux (q̇cri) corresponding to spotting ignition was not affected by the addition of retardants, although an increase in ignition times (tig) was noticeable. Experimental observations underscore distinct flame dynamics, highlighting the potential of retardants to impede fire propagation. This study highlights the crucial role of retardants in fire management strategies and emphasizes the need for optimal application, especially in urban areas adjacent to forests.
本工作的重点是评估阻燃剂的有效性,使用台架可燃性仪器测试辐射松D. Don针。使用了两种完全在智利开发的装置,分别代表连续和不连续点火模式。测试的产品是Phos-Chek LC65A-Fx,通常用于智利的野火灭火行动。将阻燃剂应用于不同浓度的松针上,研究阻燃剂浓度(σret)对不同可燃性参数的影响。值得注意的发现包括处理过的样品中火焰行为的改变,减少了闷烧和延长了火焰持续时间。正如预期的那样,随着阻燃剂用量的增加,点火延迟时间增加,表现出与热释放率(HRR)相似的行为。有趣的是,虽然点火时间(tig)明显增加,但与点着火相对应的临界热流密度(q * cri ")不受添加阻燃剂的影响。实验观察强调了不同的火焰动力学,突出了阻燃剂阻碍火焰传播的潜力。这项研究突出了阻燃剂在火灾管理战略中的关键作用,并强调需要最佳应用,特别是在森林附近的城市地区。
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引用次数: 0
Criteria for non-combustibility tests for class 1 laminated and decorated building materials 1级层压和装饰建筑材料的不燃性试验标准
IF 3.3 3区 工程技术 Q2 ENGINEERING, CIVIL Pub Date : 2025-08-25 DOI: 10.1016/j.firesaf.2025.104519
Tzu-Yan Tseng , Ming-Yuan Lei , Chen-Ming Hsiao , Kuang-Chung Tsai
In Taiwan, the non-combustibility test for building materials has been changed from CNS 6532 (based on JIS 1321) to CNS 15694 (based on ISO 1182), but the non-combustibility performance is still ranked using the “old” criteria of CNS 6532. There consequently exists a need to evaluate the feasibility of existing criteria. This study analyzed the differences of the two non-combustibility test methods, i.e. CNS 6532 and CNS 15694, and discussed the criteria applying ISO 1182 in other countries. A series of experiments is conducted to evaluate whether the current criteria can adequately rank the non-combustibility performance of building materials. Ten specimens selected from laminated and decorated building materials are tested for the comparative experiment since their “reaction to fire” performance may be complicated.
Our analysis demonstrates that the thermal environment in CNS 6532 and CNS15694 are different. CNS 15694 specifies that no automatic thermostatic can be used to control the furnace during testing but CNS 6532 does not. The temperatures for CNS 6532 tests return closer to the furnace setting temperature. Accordingly, the criteria for CNS 6532 cannot be used for CNS 15694. Additionally, the experimental results show that there is no significant difference in mass loss percentage. Further, for ensuring better confirmation of fire safety, a stricter assessment is recommended. Conclusively, this study recommends that the criteria for a non-combustibility test should comply with the Japanese standard, although the duration of flame is not included.
在台湾,建筑材料的不燃性测试已由CNS 6532(基于JIS 1321)更改为CNS 15694(基于ISO 1182),但不燃性性能仍使用CNS 6532的“旧”标准进行排名。因此,有必要评价现有标准的可行性。本研究分析了CNS 6532和CNS 15694两种不燃性测试方法的差异,并讨论了其他国家采用ISO 1182的标准。通过一系列的实验来评价现行标准是否能够对建筑材料的不燃性进行充分的分级。由于叠层和装饰建筑材料的“火反应”性能可能比较复杂,因此选择10个试件进行对比试验。分析表明,CNS 6532和CNS15694的热环境是不同的。CNS 15694规定在测试过程中不能使用自动恒温器来控制炉子,但CNS 6532没有规定。CNS 6532测试的温度更接近炉膛设定温度。因此,CNS 6532的标准不能用于CNS 15694。此外,实验结果表明,质量损失率没有显著差异。此外,为了确保更好地确认消防安全,建议进行更严格的评估。最后,本研究建议不燃性测试的标准应符合日本标准,尽管不包括火焰持续时间。
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引用次数: 0
Data-driven and explainable AI models for evaluating bond strength in reinforced concrete at elevated temperatures 用于评估高温下钢筋混凝土粘结强度的数据驱动和可解释的人工智能模型
IF 3.3 3区 工程技术 Q2 ENGINEERING, CIVIL Pub Date : 2025-08-25 DOI: 10.1016/j.firesaf.2025.104514
Rwayda Kh.S. Al-Hamd , Asad S. Albostami , Holly Warren
The bond between steel and concrete in reinforced concrete (RC) and fibre-reinforced concrete (FRC) structures is a multifaceted and intricate phenomenon. It refers to the adhesion and mechanical interlock between the steel reinforcement bars and the surrounding concrete matrix. The bond becomes more complex at elevated temperatures; however, having an accurate estimate is a crucial factor in design. Therefore, this paper employs advanced machine learning (ML) techniques to predict bond strength (Tb) at both ambient and elevated temperatures from a 394-point experimental database, which includes additional variables such as fibre content, geometric ratios, and thermal parameter conditions. Seven models were built and assessed, including Linear Regression (LR), Gradient Boosting (GB), Extreme Gradient Boosting (XGBoost), Artificial Neural Network (ANN), k-nearest Neighbours (KNN), Decision Tree (DT), and Deep Learning (DLearning) Regressors. The GB, XGBoost, and DT models offered the best prediction results with R² above 0.95 for the testing datasets, lowest error metrics (mean absolute error (MAE) between 0.8 and 1.1 MPa), and highest reliability (a30%-index ≥ 90%), all outperforming those reported in earlier literature. According to SHapley Additive exPlanations (SHAP) analysis, the length-to-diameter ratio (ld) and failure surface temperature (T) dominated as the predictors, followed by concrete compressive strength (fc), and cover-to-diameter ratio (cd), which is according to the existing mechanics of bond and thermal degradation. This study presents resolutions regarding the promise of data-driven models to accurately, reliably, and interpretably predict bond strength in post-fire conditions, which is of great merit in terms of resilient design practice. Future work may investigate hybrid ML–mechanistic frameworks and the integration of full-scale fire testing to further enhance engineering applicability.
在钢筋混凝土(RC)和纤维增强混凝土(FRC)结构中,钢与混凝土之间的结合是一个多方面和复杂的现象。它是指钢筋与周围混凝土基体之间的附着力和机械联锁。在高温下,化学键变得更加复杂;然而,在设计中有一个准确的估计是一个关键因素。因此,本文采用先进的机器学习(ML)技术,从394点实验数据库中预测环境温度和高温下的粘结强度(Tb),其中包括纤维含量、几何比和热参数条件等附加变量。建立并评估了七个模型,包括线性回归(LR)、梯度增强(GB)、极端梯度增强(XGBoost)、人工神经网络(ANN)、k近邻(KNN)、决策树(DT)和深度学习(DLearning)回归。GB、XGBoost和DT模型的预测结果最好,R²> 0.95,误差指标最低(平均绝对误差(MAE)在0.8 ~ 1.1 MPa之间),可靠性最高(a30%-index≥90%),均优于先前文献的预测结果。根据SHapley加性解释(SHAP)分析,长径比(ld)和破坏表面温度(T)作为预测因子占主导地位,其次是混凝土抗压强度(fc)和覆盖直径比(cd),这符合现有的粘结和热降解机制。本研究提出了有关数据驱动模型的解决方案,以准确、可靠和可解释地预测火灾后条件下的粘结强度,这在弹性设计实践方面具有很大的优点。未来的工作可能会研究混合机器学习-机械框架和全尺寸火灾测试的集成,以进一步提高工程适用性。
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引用次数: 0
Large eddy simulations of weakly turbulent diffusion flames in an oxygen-reduced co-flow using a new subgrid combustion model 用一种新的亚网格燃烧模型模拟氧还原共流中弱湍流扩散火焰的大涡
IF 3.3 3区 工程技术 Q2 ENGINEERING, CIVIL Pub Date : 2025-08-25 DOI: 10.1016/j.firesaf.2025.104513
Y. Moorthamers, A. Snegirev, G. Maragkos, J. At Thabari, B. Merci
The recently proposed sub-grid combustion model (SCM) for weakly turbulent buoyant diffusion flames is applied to simulate 10 and 15 kW flames produced by a circular porous burner in an oxidizer co-flow with normal and reduced oxygen concentrations. Turbulence is modelled by the large eddy simulations technique. Soot production and radiative emission is predicted based on local resolved species concentrations and temperature, eliminating the need to prescribe soot yield and global radiative fraction. Finite-rate chemistry is incorporated via a single-step global reaction of fuel oxidation with temperature-dependent effective kinetic parameters, which are derived to fit the autoignition delay times predicted by detailed chemical mechanisms. When the oxidizer co-flow is ambient air, good agreement between the predicted and the measured spatial distributions of mean temperatures and soot volume fractions is demonstrated. In flames with reduced oxygen concentrations in the co-flow, the experimental combustion efficiency and radiative fraction are replicated in the simulations, and the critical oxygen concentration causing complete flame extinguishment is predicted well by the SCM. The predictions are shown to be weakly dependent on the values of model constants. Adequate representation of the flame shape requires the large turbulent fluctuations to be sufficiently resolved by the computational grid.
应用最近提出的弱湍流浮力扩散火焰的亚网格燃烧模型(SCM),模拟了在正常氧浓度和还原氧浓度的氧化剂共流条件下,圆形多孔燃烧器产生的10和15 kW火焰。湍流是用大涡模拟技术模拟的。烟尘的产生和辐射排放是基于当地的可分解物质浓度和温度来预测的,从而消除了规定烟尘产量和全球辐射分数的需要。有限速率化学是通过燃料氧化的单步全局反应与温度相关的有效动力学参数结合起来的,这些参数是根据详细的化学机理预测的自燃延迟时间推导出来的。当氧化剂共流为环境空气时,预测的平均温度和烟尘体积分数的空间分布与实测的很好地吻合。在共流中氧浓度降低的火焰中,模拟得到了实验燃烧效率和辐射分数,并很好地预测了火焰完全熄灭的临界氧浓度。预测结果对模型常数的依赖程度很弱。火焰形状的充分表征要求计算网格能够充分地解决大的湍流波动。
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Fire Safety Journal
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