In this paper, an environmentally friendly, efficiently adiabatic, and dynamically responsive siloxane composite hydrogel is constructed. It utilises a chemically simple, stable, and biocompatible trisiloxane wetting agent as its core, with a natural cellulose derivative, methylcellulose (MC), serving as the hydrogel matrix. Additionally, it incorporates highly efficient fire-resistant and flame-retardant additives. The composite hydrogel exhibits shear-thinning behaviour (0 < n < 1), allowing for a reduction in viscosity during pipeline transport while retaining its adhesive properties upon application. Temperature-responsive phase transitions, regulated by MC and trisiloxane concentration gradients, balance flowability, high-temperature adhesion, and rapid thermal adaptation. Enhanced thermal stability is achieved through DMMP-induced char formation, which elevates the residual yield from 6.51 % to 13.91 % and forms an insulating barrier against heat and oxygen. Standard 1A wood crib fire tests demonstrate superior performance: the optimized hydrogel extinguishes flames within 126 s, achieves an average cooling rate of 6.13 °C/s, and prevents re-ignition (compared to 150 s for water and 147 s for Class A foam). Key mechanisms include oxygen-blocking phase-change layers, deep fuel penetration via high wettability, persistent insulation from carbonized gel networks, and dynamic flame inhibition. This study provides theoretical and technical support for the development of siloxane hydrogel forest fire suppression technology, demonstrating significant academic value and potential for engineering applications.
扫码关注我们
求助内容:
应助结果提醒方式:
