The study of buoyant turbulent diffusion flames requires a detailed understanding of their complex dynamics, including soot formation, radiative heat transfer, and flow field behavior. Accurate prediction of fire radiation and mechanisms of fire suppression demands high-fidelity data across realistic fire scenarios — such as turbulent pool fires and line fires. This work presents a combined experimental and numerical investigation into the effects of and dilution on the far-field radiation, soot volume fraction (SVF), and the velocity field of a 15 kW buoyant turbulent line fire. Complementary one-dimensional opposed-flow diffusion flame (1D OFDF) simulations are used to interpret soot formation trends under varying dilution conditions. Planar SVF measurements show that exerts a significantly stronger soot-inhibiting effect than . For 20% dilution in the oxidizer stream, the peak mean SVF decreases by 58% with and by 92% with . Particle Image Velocimetry (PIV) measurements reveal that dilution leads to higher peak axial velocities and enhanced flow intermittency — attributed to reduced dissipation and sustained buoyancy-driven motion. Conditional statistics and velocity probability density functions confirm the increased unsteadiness in -diluted flames. 1D OFDF simulations further indicate that the pronounced soot suppression by arises from both stronger thermal effects and additional chemical pathways, such as and . At lower dilution levels (5%–10%), these chemical reactions influence flame kinetics, whereas at higher dilution levels (20%–30%), inert and thermal effects dominate.
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