Asphalt, a carbon-rich and chemically complex material, exhibits intricate combustion behavior under fire conditions. Despite its widespread use in over 90 % of pavements in the United States and China, its ignition dynamics under varying radiative conditions remain poorly understood. This research explored the thermal behaviors of combustible asphalt under various radiation intensities (0–50 kW/m2) and durations (0–60 min) experimentally, with smouldering reaction kinetics interpreted numerically. It is observed that under sufficient radiation duration (60 min), 5 kW/m2 is the critical limit of radiation intensity; while under high radiation intensity (50 kW/m2), nearly 1 min is the critical limit of radiation duration. 2-D Smouldering Kinetics Interpretation revealed that critical radiation intensity determines the overcoming of activation energy, and critical radiation duration determines the potential of thermal-storage capacity for ignition to trigger smouldering combustion. Moreover, the reaction kinetics reflected the transition from pyrolysis-dominated to pyrolysis/oxidation-coupled reactions, significantly varying the asphalt/char/ash proportions. The findings establish critical thresholds for asphalt smoldering ignition, which are characterized by dual logarithm correlation between the radiation intensity and ignition time. This is complemented by fundamental analysis of species evolution dynamics and chemical energy distribution, providing insights valuable to fire safety science.
扫码关注我们
求助内容:
应助结果提醒方式:
