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Research of natural remediation of the subsurface contaminated with petroleum products 石油产品污染地下的自然修复研究
Pub Date : 2019-10-16 DOI: 10.31996/mru.2019.3.49-51
O. Shpak, O. Lohvynenko
Remediation of the subsurface contaminated with petroleum products is the ecological problem on a world scale and a foreground direction of geoecological research in Ukraine. Remediation of contaminated vadose zone can be provided with the activity of microorganisms, mainly micromycets, whose features of location and vital activity depend on a depth, the level of contamination, aerobic conditions, etc. Practically, it is complicated to use artificial microbiological methods and natural remediation of contaminated subsurface due to microorganisms should be taken into consideration. Microorganisms oxidizing hydrocarbons are of particular interest. Field investigations were carried out within the fuel storage of the Boryspil airport where subsurface contamination with petroleum products was revealed in 1998. The research included sampling at contaminated and uncontaminated sites, quality analysis of petroleum product contains in soils and determination of the species composition of micromycets. Soil samples were taken in three wells at different depths – in the center of the contamination source at the depths of 0,1 m and 2,0 m (unsaturated zone) and 4,0 m (saturated zone), in the northern part of the fuel storage in the unsaturated zone at the depths of 0,1 m and 1,0 m, and out of the contamination source in the unsaturated zone at the depth of 3,7 m. Fungus culture determination data in soil samples indicate that variety of their forms depends on a contamination degree, a depth of sampling, lithology and water saturation. Regular monitoring should be carried out including soil sampling and determination of petroleum product contains to specify conclusions about natural remediation of contaminated soils due to life activity of microorganisms oxidizing hydrocarbons.
石油产品地下污染的修复是世界范围内的生态问题,也是乌克兰地质生态学研究的一个前景方向。污染气膜带的修复可以提供微生物的活性,主要是微真菌,其位置和生命活性的特征取决于深度、污染水平、好氧条件等。实际应用中,人工微生物法较为复杂,应考虑微生物污染地下的自然修复。微生物氧化碳氢化合物是特别感兴趣的。1998年,在发现石油产品地下污染的鲍里斯波尔机场燃料储存库内进行了实地调查。研究包括在污染和未污染地点取样,土壤中石油产品含量的质量分析和微菌种类组成的测定。土壤样品取自3口不同深度的井,分别位于污染源中心0,1 m和2,0 m(非饱和区)和4,0 m(饱和区),位于燃料储存库北部0,1 m和1,0 m(非饱和区),以及位于污染源外3,7 m(非饱和区)。土壤样品中的真菌培养测定数据表明,其形态的变化取决于污染程度、采样深度、岩性和含水饱和度。应定期进行监测,包括土壤采样和石油产品含量的测定,以明确微生物氧化碳氢化合物的生命活动对污染土壤的自然修复的结论。
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引用次数: 0
Contents of germanium in coal seams Lviv-Volyn basin and Donbas 利沃夫-沃林盆地和顿巴斯煤层中锗的含量
Pub Date : 2019-10-16 DOI: 10.31996/mru.2019.3.11-14
I. Vasileva
The main source of germanium sequestration in Ukraine is coal. According to modern requirements, the content of germanium in coal should be more than 10 g/t (air-dry weight), in coking - 3 g/t. Germanium can be obtained from mine water and coal rocks, as well. In Ukraine, germanium carbonate rocks are distributed in the sediments of the Lviv-Volyn and Donetsk basins. The distribution of germanium in the rocks of coal basins is different and rarely obeys laws. All coal layers tested are more or less germanium. Tectonic disturbances had no controlling effect on the accumulation and spread of germanium in the coal basin. The highest content of germanium is found in the central and western parts of the Donetsk coal basin district. The search and reconnaissance work on germanium has been widely disseminated since 1954. The work was carried out at various mineral deposits in order to identify raw materials for the related extraction of germanium. The degree of study and industrial development of these areas are different. The content of germanium in the coal of different layers varies in a wide range. Germanium is used in many industries and demand for it is constantly increasing. The scope of the metal is quite wide; it is used for the manufacture of transistors and circuits, for engineering and electronics. Radar installations use thin germanium films that are pre-applied to the glass substrate. The subsequent withdrawal of germanium is one way to improve the economic performance of the coal industry. Concomitant extraction of germanium from coal, products of its processing and mine waters of Donbass is now quite realistic and can help to increase the profitability of coal enterprises.
乌克兰锗固存的主要来源是煤炭。根据现代要求,煤中锗的含量应大于10克/吨(空气干重),在炼焦中应为-3克/吨。锗也可以从矿井水和煤岩中获得。在乌克兰,碳酸锗岩分布在利沃夫-沃林和顿涅茨克盆地的沉积物中。锗在煤盆地岩石中的分布是不同的,很少遵循规律。所有测试的煤层或多或少都含有锗。构造扰动对煤盆地锗的聚集和扩散没有控制作用。锗含量最高的地区是顿涅茨克煤炭盆地区的中部和西部。自1954年以来,对锗的搜索和侦察工作得到了广泛传播。这项工作是在各种矿床中进行的,目的是确定相关锗提取的原材料。这些地区的学习程度和工业发展程度各不相同。不同层次的煤中锗的含量变化很大。锗被用于许多行业,对它的需求不断增加。金属的范围相当广泛;它被用于制造晶体管和电路,用于工程和电子。雷达装置使用预先涂敷在玻璃基板上的锗薄膜。随后锗的退出是提高煤炭行业经济效益的一种方式。从顿巴斯的煤炭、其加工产品和矿井水中同时提取锗现在非常现实,有助于提高煤炭企业的盈利能力。
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引用次数: 0
Specific features of diamonds from ancient sedimentary thick layers on territories of crystallyne rock masses influence 钻石的特殊特征来自于结晶岩体区域的古沉积厚层
Pub Date : 2019-10-16 DOI: 10.31996/mru.2019.3.22-29
N. Zinchuk
Analysis of available materials on specific features of diamonds from Upper Paleozoic and Mesozoic sediments of main diamondiferous regions of the Siberian platform north-east (Anabar, Muna-Tyung, Nizhnelensk and Prilensk regions) allows asserting about definite in
通过对西伯利亚地台东北部主要钻石区(Anabar、Muna-Tyung、Nizhnelensk和priilensk地区)上古生界和中生界沉积物中钻石具体特征的现有资料分析,我们可以确定其成因
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引用次数: 0
Revisiting stratigraphic complexes and regional stratigraphic scheme of the lower precambrian of the Ukrainian shield 乌克兰地盾下前寒武纪地层复合体及区域地层格局重访
Pub Date : 2019-10-16 DOI: 10.31996/mru.2019.3.40-48
V. Kyrylyuk
The stratigraphic scheme of the Early Precambrian of the Ukrainian Shield bears a number of differences from the traditional regional stratigraphic schemes: 1) along with stratified subdivisions it includes intrusive and ultrametamorphic complexes that are not accounted for in the “Stratigraphic Code of Ukraine”; 2) The leading role in creating the regional stratigraphic scheme was played by isotopic dating results; 3) The Stratigraphic Scheme does not include the taxon “complex”, as it is described in the “Stratigraphic Code of Ukraine”. According to “Stratigraphic Code of Ukraine”, “Complex” is the largest regional stratigraphic unit that corresponds to a large geo-historical period. Due to the absence of the taxon of “complex” in the regional Precambrian stratigraphic scheme, the main stages of geological development of the region in the Precambrian have not been identified for the Ukrainian Shield. The first article of the cycle is devoted to the feasibility of introducing the taxon of “complex” in the regional stratigraphic scheme on the materials of the Ukrainian Shield. It notes that most of the series in the current stratigraphic scheme correspond to complexes by their level of study and their historical and geological content. Such units are Konkska, Kryvorizka, Teterivska, Ingulo-Inguletska and some other series. Each of them can be separated into several series. The Dniestrovsko-Bugska and Bugska series, the West-Priazovska and Central-Priazovska series of granulite-gneiss complexes are artificially separated and shown as different age subdivisions in the current stratigraphic scheme. These series should be included in the Bug Area and Azov Area complexes, but their volumes and names need clarification. Amphibolite-gneiss complexes can be included in the stratigraphic scheme without dismemberment into series, since they correspond to a large geohistoric stage marked by the peculiarities of their material composition and structural-tectonic position.
乌克兰地盾早前寒武纪地层方案与传统的区域地层方案有许多不同之处:1)除了分层细分外,它还包括“乌克兰地层法典”中未考虑的侵入和超变质杂岩;2)同位素测年结果对区域地层格局的形成起主导作用;3)地层方案不包括“复合体”分类群,如“乌克兰地层法典”所述。根据《乌克兰地层学法典》,“复合体”是最大的区域性地层单位,对应于一个大的地质历史时期。由于区域前寒武纪地层方案中“复合体”分类群的缺失,乌克兰地盾地区前寒武纪地质发育的主要阶段尚未确定。该周期的第一篇文章专门讨论在乌克兰地盾材料的区域地层方案中引入“复合体”分类单元的可行性。从研究水平和历史地质内容来看,当前地层方案中的大部分系列都属于复合体。这些单位是Konkska, Kryvorizka, Teterivska, Ingulo-Inguletska和其他一些系列。它们中的每一个都可以分成几个系列。麻粒-片麻岩杂岩体的德涅斯特罗夫斯科-布格斯卡系列和布格斯卡系列、西-普里亚佐夫斯卡系列和中-普里亚佐夫斯卡系列在目前的地层方案中被人为分隔成不同的年龄分区。这些系列应包括在虫区和亚速区复合体,但他们的体积和名称需要澄清。角闪岩-片麻岩杂岩的物质组成和构造位置的特殊性决定了它们对应于一个大的地历史阶段,因此可以不被分解成系列而纳入地层方案。
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引用次数: 1
Indicators of reserves and extraction of combustible minerals in Ukraine from 2013 to 2018 from the standpoint of technical analysis 从技术分析的角度来看,2013年至2018年乌克兰可燃矿物的储量和开采指标
Pub Date : 2019-10-16 DOI: 10.31996/mru.2019.3.30-39
Oleg Zurian, A. Liashok
Combustible minerals have a special position among others due to the fact that they are a source of substantial energy. This article outlines details of establishment in Ukraine of minerals nomenclature related to combustible minerals, and provides a list of corresponding State reserves of minerals. The article also defines trends of aposteriory changes of the outlined indicators during the period from 2013 through 2018 (and for extraction – from 2012 through 2017) in order to obtain in the future a possibility of considering the impact of other economic and organizational factors and to detect generalized regularities in the industry’s development in terms of prospects of combustible minerals extraction. This article describes the general basic features of the technical and fundamental analysis with references to works of founders of the American school of the technical and fundamental analysis. The article provides the analysis of dynamic ranks of data on reserves, the number of fields and extraction of combustible minerals during the period from 2013 to 2018 in Ukraine according to generalized information on condition of reserves of minerals laid out on the website “Mineral Resources of Ukraine”. The article also contains specific generalized data of results of analyses which are based on processing of tabular data and graphic charts. We created data tables based on processing of posteriori trends with application of standard tools and Excel calculation techniques. The article describes the main details of analysis tools and mechanisms based on Excel calculations, as well as corresponding applied dependencies, specific details of rows development for data about reserves of combustible mineral varieties and combustible mineral reserves being under exploitation. The article contains tables of source data that were applied for generalization and analysis. In this article we provide conclusions concerning dynamics of changes of indicators of reserves, the number of fields and extraction of combustible minerals.
可燃矿物在其他矿物中有着特殊的地位,因为它们是大量能源的来源。本文概述了乌克兰建立与可燃矿物有关的矿物命名法的细节,并提供了相应的国家矿产储量清单。文章还定义了2013年至2018年期间(以及2012年至2017年提取期间)概述的指标的显著变化趋势,以便在未来获得考虑其他经济和组织因素影响的可能性,并从可燃物的前景方面检测行业发展的一般规律矿物提取。本文参照美国技术和基础分析学派创始人的著作,阐述了技术和基础研究的一般基本特征。本文根据“乌克兰矿产资源”网站上列出的矿产储量状况的一般信息,对2013年至2018年期间乌克兰的储量、油田数量和可燃矿产开采的动态数据进行了分析。文章还包含了基于表格数据和图表处理的分析结果的具体广义数据。我们使用标准工具和Excel计算技术,在后验趋势处理的基础上创建了数据表。本文介绍了基于Excel计算的分析工具和机制的主要细节,以及相应的应用依赖关系,可燃矿物品种储量和正在开采的可燃矿物储量数据的行开发的具体细节。本文包含用于概括和分析的源数据表。在本文中,我们提供了关于储量指标、油田数量和可燃矿物提取的动态变化的结论。
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引用次数: 0
GASHYDRATES, GAS SEEPS AND POCKMARKS IN THE ZONES OF DEVELOPMENT OF MUD VOLCANISM MEDITERRANEAN, BLACK AND CASPIAN SEAS 地中海、黑海和里海泥火山发育带的天然气水合物、天然气渗漏和麻穴
Pub Date : 2019-07-10 DOI: 10.31996/MRU.2019.2.25-33
A. Aliyev, A. Kabulova, R. Rahmanov
Based on an analytical review of factual materials, the article discusses the peculiarities of the distribution of gas hydrates in the development zones of mud volcanism of the Mediterranean, Black and Caspian seas, which are direct indications of sedimentary gas complex. A comparative analysis of the composition of hydrate-forming fluids, sources and depths of gas hydrates distribution was performed. The article provides information on gas seeps and pokmarks. The presence of gas seepsand pokmarks in the water column and at the bottom of the Southern Caspian is assumed.
本文通过对实际资料的分析综述,论述了地中海、黑海和里海泥火山活动发育带天然气水合物分布的特殊性,这是沉积气杂岩的直接标志。对比分析了成水合物流体的组成、天然气水合物的来源和分布深度。文章提供了有关气体渗漏和斑点的信息。假设在南里海的水柱和底部存在天然气渗漏和斑点。
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引用次数: 1
SPECIFIC FEATURES OF CLAY MINERALS IN ANCIENT CRUSTS OF WEATHERING OF VARIOUS ROCKS IN DIAMONDIFEROUS REGIONS 含金刚石地区各种岩石风化古壳粘土矿物的具体特征
Pub Date : 2019-07-10 DOI: 10.31996/MRU.2019.2.13-20
N. Zinchuk
Results of complex research of different age ancient weathering crusts in various rocks (terrigenous-carbonate rocks of Lower Paleozoic, dolerites, tuffs and tufogene formations, kimberlites) within the main diamondiferous regions of the Siberian platform indicated that complicated multicomponent composition of initial formations (with the exception of terrigenous-carbonate rocks), containing di- and trioctahedral minerals, the structure of which has tri- and bivalent rock-forming elements, stipulated decelerated transformation of the initial material. Development of incomplete weathering profiles is first of all caused by weak ejection of bivalent cations from primary minerals. That is why newly emerging phases will be dioctahedral and often preserve mixed composition of cations. The most important typomorphic indications of clay formations in the studied weathering crusts are as follows: a) omnipresent dioctahedral hydromica (2М1) in the weathering crust of terrigenouscarbonate rocks and its association in the most mature profiles with kaolinite of relatively ordered structure, than of kaolinite, having been formed at the expense of other rocks; b) constant availability of trappean formation (tuffs, tufogene rocks, dolerites) in sections of crusts of weathering together with di- and trioctahedral montmorillonite, as well as disordered vermiculite-montmorillonite mixed-layered formation, to this or that degree disordered kaolinite, associated in the weathering crust of tufogene rocks with halloysite (at complete absence of micaceous minerals in the products of weathering); c) the content in the crust of weathering of kimberlites together with polycationic montmorillonite of a significant quantity of trioctahedral chlorite (packets δ and δ'), serpentine (structural types A and B) and altered to various degree phlogopite, including related with it hydromica 1M.
对西伯利亚地台主要含钻石区域内各种岩石(下古生代陆生-碳酸盐岩、白云岩、凝灰岩和凝灰岩、金伯利岩)中不同年代古风化壳的复杂研究结果表明,初始地层(除陆生-碳酸盐岩外)具有复杂的多组分组成,含有二、三八面体矿物,其结构具有三价和二价造岩元素;规定初始材料的减速变形。不完全风化剖面的形成首先是原生矿物双价阳离子的弱喷射所致。这就是为什么新出现的相将是双八面体,并且经常保持阳离子的混合组成。研究的风化壳中粘土层最重要的标型标志是:a)陆源碳酸盐岩风化壳中普遍存在双八面体水云母(2М1),在最成熟的剖面中,它与高岭石的结合结构相对有序,而不是高岭石,它们是在牺牲其他岩石的基础上形成的;B)在风化壳剖面中持续存在着套覆岩(凝灰岩、凝泥岩、白云岩)和二、三八面体蒙脱石,以及无序的蛭石—蒙脱石混合层状地层,或多或少无序的高岭石,在凝泥岩的风化壳中与高岭石伴生(在风化产物中完全没有云母矿物);c)地壳中风化金伯利岩与多阳离子蒙脱石中含有大量的三八面体绿泥石(δ包和δ′包)、蛇纹石(结构类型a和B)和不同程度蚀变的云母,包括与之相关的水云母1M。
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引用次数: 0
DOMESTIC PECULIARITIES OF FINANCING AND ORGANIZING GEOLOGICAL RESEARCH OF IRON ORES 铁矿地质研究经费筹措与组织的国内特点
Pub Date : 2019-07-10 DOI: 10.31996/MRU.2019.2.34-39
A. Balega, M. Kurylo
The mineral base of iron ores is characterized by intensive use and includes explored and pre-explored reserves, most of which belong to a distributed subsurface fund. The objects of accounting (deposits) are grouped according to the size of stocks and on the basis of involvement in industrial development. The allocated groups of deposits, for which the volumes of reserves are set, make up 100 million tons, 100–500 million tons, 500–1000 million tons. and more than 1000 million tons. The grouping of reserves of iron ore deposits by size allows us to state that about 80 % of the reserves of iron ores for the developed deposits are provided with reserves of 500 million tons. and more, which confirms the average level of their exhaustion. The degree of provision of iron ore reserves according to the existing special permits for the use of subsoil and project output for production was introduced. Groups of fields for which the terms are set are up to 30 years, 30–50 years, 50–100 years and over 100 years. It has been determined that financing of exploration works (GAR) for iron ores in the framework of the current National Program for the Development of the Mineral Base of Ukraine until 2030 is provided exclusively at state cost and non-state funding is not taken into account. In order to identify the optimal distribution of financing for exploration works by stages, comparison of funding rates under the Program up to 2030 with the distribution of the main geological risks and general risks of mining business has been made. At the stage of search and search-and-appraisal, a high level of geological risks of 50 % and mining risks in 70 % is accompanied by public funding for iron ore and reaches a critical value of 80 % with a similar indicator for the entire program at 65,7 %. The level of financing of the III stage of exploration for iron ore accounts for 20 % of the total volume, with a rather low level of geological risks of 10 % and mining risks at 10 %, respectively.
铁矿的矿物基础具有集约利用的特点,包括已探明储量和预探明储量,大部分属于分布的地下基金。会计核算的对象(存款)是根据股票的大小和参与工业发展的程度来分组的。分配的储量组分为1亿吨、1 - 5亿吨、5 - 10亿吨。超过10亿吨。将铁矿床储量按大小分组,我们可以说,在已开发矿床中,约80%的铁矿石储量为5亿吨储量。还有更多,这证实了他们的平均疲惫程度。介绍了根据现有底土利用特别许可证和项目产量提供铁矿储量的程度。设置期限的字段组为30年、30 - 50年、50-100年和100年以上。已确定,在目前的《到2030年乌克兰矿产基地发展国家计划》框架内,铁矿石勘探工程(GAR)的融资完全以国家成本提供,不考虑非国家资金。为了确定勘探工程分期融资的最优分配,将计划下至2030年的融资率与主要地质风险和采矿业务一般风险的分布进行了比较。在勘查和勘查评价阶段,高水平的地质风险为50%,高水平的采矿风险为70%,伴随着铁矿的公共资金,达到80%的临界值,整个项目的类似指标为65.7%。铁矿勘探第三阶段融资水平占总量的20%,地质风险水平较低,为10%,采矿风险水平较低,为10%。
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引用次数: 0
FEATURES OF CONDUCTING OF GEOLOGICAL EXPLORATION ON SHALE GAS IN VOLYNO-PODILLIA AT THE REGIONAL STAGE OF STUDYING 研究区域阶段火山岩-丘地页岩气地质勘探特点
Pub Date : 2019-07-10 DOI: 10.31996/MRU.2019.2.21-24
V. P. Chepil
Features of structural conditions of occurrence, gas accumulation, lithofacies, petrophysical and geochemical parameters, shielding factor, character-bearing shale gas saturation are fundamentally different from traditional gas deposits. Stratigraphic shale formation considered as a potential gas deposit. Considering this specificity its allocation and mapping must be executed at an early stage. To delineate gas bearing shale formations of Volyno-Podillia and allocation the most perspective areas offered a complexation of regional seismic survey 2D for great depths (two longitudal profiles of north-western stretch as it continued from the Lublin basin in Poland and 5 crosssections from southwest to the northeast with its total length of about 1500 linear kilometers) with electric prospecting methods of different modifications, caused polarization, electromagnetic methods of regional seismic exploration grids profiles, large-scale atmogeochemical shooting and other direct methods. As the completion of regional stage must be drilling of vertical parametric pilot wells with solid coring from perspective shale strata, laboratory studies of organic matter, of katagenesis, lithofacies and mineralogical composition of shales, their petrophysical and geochemical properties, modeling and testing perspective shale strata using multistage hydrogaps. Prospects of further exploration and it’s complex based on the results geologic-economic evaluation of perspective of petrogas of the region and obtaining results of works start-up phase.
产状构造条件、成藏特征、岩相特征、岩石物化参数特征、遮蔽因子特征、含气饱和度特征等与传统气藏有本质区别。地层页岩地层被认为是潜在的天然气矿床。考虑到这种特殊性,它的分配和映射必须在早期阶段执行。为圈定volyino - podillia含气页岩地层并分配最具远景区域,采用不同修正的电法,对大深度区域地震调查2D(从波兰卢布林盆地开始的西北段2条纵向剖面和从西南到东北的5条剖面,总长度约1500线性公里)进行了复杂处理,引起了极化。区域地震勘探的电磁法网格剖面、大尺度大气地球化学射击等直接方法。由于区域阶段的完成必须是页岩地层立体取心垂直参数试验井的钻探,页岩有机质、片生作用、岩相、矿物组成、岩石物理和地球化学性质的实验室研究,以及多级水空隙对页岩地层进行建模和测试。结果表明,该区油气远景地质经济评价及工程启动阶段取得成果,进一步勘探前景复杂。
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引用次数: 0
MODERN APPROACHES TO HYDROGEOLOGICAL ZONING OF UKRAINE 乌克兰水文地质区划的现代方法
Pub Date : 2019-07-10 DOI: 10.31996/MRU.2019.2.3-12
V. Shestopalov, G. G. Lyutyĭ, I. Sanina
The article describes the approaches to the implementation of hydrogeological zoning of Ukraine according to the structural-hydrogeological principle. In accordance with modern geostructural zoning in the Ukraine, the authors identified 10 hydrogeological regions of the first order. Each of the identified regions is characterized by its own peculiarities of the geological and hydrogeological structure, and as well as regional peculiarities of hydrogeological conditions. These patterns determine the conditions for the formation and distribution of the predicted groundwater resources and their quality indicators. The features of Ukraine’s hydrogeological regions of the first order are briefly characterized.
本文介绍了根据结构水文地质原理实施乌克兰水文地质区划的方法。根据乌克兰现代地质构造区划,作者确定了10个一级水文地质区。每个确定的区域都有其自身的地质和水文地质结构特点,以及水文地质条件的区域特点。这些模式决定了预测地下水资源的形成和分布条件及其质量指标。简要介绍了乌克兰一级水文地质区域的特征。
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引用次数: 2
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Mineral''ni resursi Ukraini
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