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High‐Resolution, Multiproxy Speleothem Record of the 8.2 ka Event From Mainland Southeast Asia 东南亚大陆 8.2 ka 事件的高分辨率多代理地层记录
IF 3.5 2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2023-12-01 DOI: 10.1029/2023pa004675
C. Wood, Kathleen R. Johnson, Lindsey. E. Lewis, K. Wright, Jessica K. Wang, A. Borsato, Michael L. Griffiths, Andrew Mason, Gideon M. Henderson, Jacob B. Setera, S. Frisia, Sengphone Keophanhya, Joyce C. White
The 8.2 ka event is the most significant global climate anomaly of the Holocene epoch, but a lack of records from Mainland Southeast Asia (MSEA) currently limits our understanding of the spatial and temporal extent of the climate response. A newly developed speleothem record from Tham Doun Mai Cave, Northern Laos provides the first high‐resolution record of this event in MSEA. Our multiproxy record (δ18O, δ13C, Mg/Ca, Sr/Ca, and petrographic data), anchored in time by 9 U‐Th ages, reveals a significant reduction in local rainfall amount and weakening of the monsoon at the event onset at ∼8.29 ± 0.03 ka BP. This response lasts for a minimum of ∼170 years, similar to event length estimates from other speleothem δ18O monsoon records. Interestingly, however, our δ13C and Mg/Ca data, proxies for local hydrology, show that abrupt changes to local rainfall amounts began decades earlier (∼70 years) than registered in the δ18O. Moreover, the δ13C and Mg/Ca also show that reductions in rainfall continued for at least ∼200 years longer than the weakening of the monsoon inferred from the δ18O. Our interpretations suggest that drier conditions brought on by the 8.2 ka event in MSEA were felt beyond the temporal boundaries defined by δ18O‐inferred monsoon intensity, and an initial wet period (or precursor event) may have preceded the local drying. Most existing Asian Monsoon proxy records of the 8.2 ka event may lack the resolution and/or multiproxy information necessary to establish local and regional hydrological sensitivity to abrupt climate change.
8.2 ka事件是全新世时期最重要的全球气候异常现象,但目前东南亚大陆(MSEA)记录的缺乏限制了我们对气候响应的时空范围的了解。老挝北部 Tham Doun Mai 洞穴新发现的岩浆记录首次提供了东南亚大陆这一事件的高分辨率记录。我们的多代理记录(δ18O、δ13C、Mg/Ca、Sr/Ca 和岩石学数据)以 9 个铀-钍年龄为时间锚定,揭示了在事件开始(8.29 ± 0.03 ka BP)时当地降雨量的显著减少和季风的减弱。这种反应至少持续了 170 年,与其他岩浆δ18O 季风记录估计的事件持续时间相似。然而,有趣的是,我们的δ13C 和 Mg/Ca 数据(当地水文的代用指标)显示,当地降雨量的突然变化比δ18O 记录的时间早几十年(∼70 年)。此外,δ13C 和 Mg/Ca 还表明,降雨量的减少至少持续了 200 年,比根据δ18O 推断的季风减弱的时间要长。我们的解释表明,MSEA 8.2 ka事件带来的较干旱条件超出了δ18O推断的季风强度所定义的时间界限,在局部干燥之前可能有一个初始的湿润期(或前兆事件)。大多数关于 8.2 ka 事件的现有亚洲季风代用记录可能缺乏必要的分辨率和/或多代用信息,无法确定当地和区域水文对突变气候变化的敏感性。
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引用次数: 0
Palynofloral Change Through the Paleocene‐Eocene Thermal Maximum in the Bighorn Basin, Wyoming 怀俄明州比格霍恩盆地古新世-始新世最热时期的古植物变化
IF 3.5 2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2023-12-01 DOI: 10.1029/2023pa004741
Vera A. Korasidis, S. Wing
To better understand the effect of the Paleocene‐Eocene Thermal Maximum (PETM) on continental ecosystems, we studied 40 new palynological samples from the Bighorn Basin (BHB), northwestern Wyoming, USA. We see palm and fern abundances increase in the last 20–40 ka of the Paleocene, then dramatically with the onset of the carbon isotope excursion (CIE) defining the base of the PETM. Palynomorphs of plant groups with modern temperate climate distributions are absent from the CIE body, and this is when tropical plants are most diverse and abundant. During the CIE recovery, pollen of mesophytic/wetland plants become more common while tropical taxa persist. In the post‐CIE early Eocene tropical taxa are rare and temperate forms abundant, similar to the late but not latest Paleocene. Changes in the palynoflora are more easily detected if reworked palynomorphs are removed from analyses. We interpret palynofloral changes to indicate warming in the latest Paleocene, rapid warming and drying with the CIE onset, dry tropical climates through the CIE body, a return to wetter floodplains during a very warm CIE recovery, and cooler wet conditions in the post‐PETM early Eocene. These inferences are consistent with geochemical and paleobotanical proxies. Strikingly similar patterns in the palynoflora and megaflora suggest changes in vegetation were a basin‐wide phenomenon. These rapid, climatically forced changes in floral composition occurred without major extinction, perhaps indicating nearby refugia in which plants adapted to cooler and wetter climates persisted through the PETM.
为了更好地了解古新世-始新世极热期(PETM)对大陆生态系统的影响,我们对美国怀俄明州西北部大角盆地(Bighorn Basin, BHB)的40个孢粉样品进行了研究。我们看到棕榈和蕨类植物的丰度在古新世的最后20-40 ka增加,然后随着确定始新世基底的碳同位素偏移(CIE)的开始而急剧增加。具有现代温带气候分布的植物类群的形态在CIE体中缺失,而这正是热带植物最多样化和丰富的时候。在CIE恢复过程中,中植物/湿地植物的花粉越来越普遍,而热带分类群则持续存在。在CIE之后,早始新世的热带类群很少,温带类群丰富,与晚而不是最晚的古新世相似。如果从分析中去除重新加工的孢粉形态,孢粉区系的变化更容易被检测到。我们将孢粉植物的变化解释为古新世晚期的变暖,CIE开始时的快速升温和干燥,通过CIE身体的干燥热带气候,在非常温暖的CIE恢复期间恢复到潮湿的洪泛平原,以及后- PETM早期始新世较冷的潮湿条件。这些推断与地球化学和古植物学指标一致。孢粉植物区系和巨型植物区系中惊人相似的模式表明,植被的变化是整个盆地范围内的现象。这些快速的、气候强迫的植物组成变化没有发生大的灭绝,这可能表明附近的避难所,在那里,植物适应了更凉爽和更潮湿的气候,并在新第三纪新世持续存在。
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引用次数: 0
Astronomical Pacing of Middle Eocene Sea‐Level Fluctuations: Inferences From Shallow‐Water Carbonate Ramp Deposits 中始新世海平面波动的天文步调:来自浅水碳酸盐斜坡沉积的推论
2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2023-11-01 DOI: 10.1029/2023pa004633
T. C. Brachert, C. Agnini, C. Gagnaison, J.‐P. Gély, M. J. Henehan, T. Westerhold
Abstract Astrochronologically calibrated deep‐sea records document the Cenozoic (66–0 Ma) global climatic cooling in great detail, but the magnitude of sea‐level fluctuations of the middle Eocene Warmhouse state (47.8–37.7 Ma) and the ∼40.3 Ma warming event of the Middle Eocene Climatic Optimum (MECO) is not well constrained. Here, we present a sequence stratigraphic classification of a shallow marine mixed carbonate—clastic ramp system for this time interval in Paris basin, France. Based on sedimentologic, paleogeographic and biostratigraphic data, we hypothesize that the 22 elementary sequences recognized each correspond to the long cycle of orbital eccentricity (0.405 Myr). With the exception of the MECO, the shoreline trajectory of superimposed, third‐order depositional sequences evolved in phase with the very long cycles of orbital eccentricity (2.4 Myr), suggesting significant polar ice build‐up leading to sea level lowstands during nodes of the very long eccentricity cycle. Inferred from Fischer Plot methodology, Lutetian third‐order eustasy was in the order of 5–10 m and during the MECO 30 m or more. Furthermore, the shallow‐water record implies that third order sea‐level changes were astronomically paced in the middle Eocene Warmhouse climate state, but a decoupling occurred during the transient MECO warming.
天文年代学校准的深海记录非常详细地记录了新生代(66-0 Ma)全球气候变冷,但中始新世暖室状态(47.8-37.7 Ma)和中始新世气候优化(MECO)的~ 40.3 Ma变暖事件的海平面波动幅度没有得到很好的约束。本文对法国巴黎盆地这一时期的浅海混合碳酸盐-碎屑斜坡体系进行了层序地层分类。根据沉积学、古地理和生物地层学资料,我们假设22个已识别的基本层序对应于轨道偏心长旋回(0.405 Myr)。除MECO外,叠加的海岸线轨迹,三级沉积序列与轨道偏心旋回(2.4 Myr)相演化,表明在极长偏心旋回的节点期间,显著的极地冰积聚导致海平面低水位。根据Fischer样地方法推断,Lutetian三阶海平面上升幅度为5-10 m, MECO期间为30 m或更大。此外,浅水记录表明,在始新世中期的暖化气候状态中,三级海平面的变化是以天文速度进行的,但在短暂的MECO变暖期间发生了解耦。
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引用次数: 0
Zonal Indian Ocean Variability Drives Millennial‐Scale Precipitation Changes in Northern Madagascar 印度洋纬向变率驱动马达加斯加北部千年尺度降水变化
2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2023-11-01 DOI: 10.1029/2023pa004626
Benjamin H. Tiger, Stephen Burns, Robin R. Dawson, Nick Scroxton, Laurie R. Godfrey, Lovasoa Ranivoharimanana, Peterson Faina, David McGee
Abstract The low latitude Indian Ocean is warming faster than other tropical basins, and its interannual climate variability is projected to become more extreme under future emissions scenarios with substantial impacts on developing Indian Ocean rim countries. Therefore, it has become increasingly important to understand the drivers of regional precipitation in a changing climate. Here we present a new speleothem record from Anjohibe, a cave in northwest (NW) Madagascar well situated to record past changes in the Intertropical Convergence Zone (ITCZ). U‐Th ages date speleothem growth from 27 to 14 ka. δ 18 O, δ 13 C, and trace metal proxies reconstruct drier conditions during Heinrich Stadials 1 and 2, and wetter conditions during the Last Glacial Maximum and Bølling–Allerød. This is surprising considering hypotheses arguing for southward (northward) ITCZ shifts during North Atlantic cooling (warming) events, which would be expected to result in wetter (drier) conditions at Anjohibe in the Southern Hemisphere tropics. The reconstructed Indian Ocean zonal (west‐east) sea surface temperature (SST) gradient is in close agreement with hydroclimate proxies in NW Madagascar, with periods of increased precipitation correlating with relatively warmer conditions in the western Indian Ocean and cooler conditions in the eastern Indian Ocean. Such gradients could drive long‐term shifts in the strength of the Walker circulation with widespread effects on hydroclimate across East Africa. These results suggest that during abrupt millennial‐scale climate changes, it is not meridional ITCZ shifts, but the tropical Indian Ocean SST gradient and Walker circulation driving East African hydroclimate variability.
低纬度印度洋的变暖速度比其他热带盆地快,在未来排放情景下,其年际气候变率将变得更加极端,对发展中的印度洋沿岸国家产生重大影响。因此,了解气候变化中区域降水的驱动因素变得越来越重要。本文报道了来自马达加斯加西北部Anjohibe洞穴的一个新的洞穴记录,该洞穴记录了热带辐合带(ITCZ)的历史变化。U -年龄测定了洞穴生长的时间从27到14 ka。δ 18o、δ 13c和痕量金属指标重建了末次盛冰期和b ølling - allero ød期的干旱条件和末次盛冰期的湿润条件。考虑到在北大西洋变冷(变暖)事件期间ITCZ向南(向北)移动的假设,这是令人惊讶的,这将导致南半球热带地区Anjohibe更潮湿(更干燥)。重建的印度洋纬向(西-东)海表温度(SST)梯度与马达加斯加西北部的水文气候代用指标密切一致,降水增加的时期与西印度洋相对温暖的条件和东印度洋相对凉爽的条件相关。这样的梯度可以驱动沃克环流强度的长期变化,对东非的水文气候产生广泛的影响。这些结果表明,在千禧年尺度的气候突变过程中,驱动东非水文气候变率的不是经向ITCZ移动,而是热带印度洋海温梯度和Walker环流。
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引用次数: 0
Late Pleistocene Evolution of Tides and Tidal Dissipation 晚更新世潮汐演化与潮汐耗散
2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2023-11-01 DOI: 10.1029/2023pa004727
S.‐B. Wilmes, V. K. Pedersen, M. Schindelegger, J. A. M. Green
Abstract Studies of the Last Glacial Maximum (LGM; 26.5–19 ka) tides showed strong enhancements in open ocean tidal amplitudes and dissipation rates; however, changes prior to the LGM remain largely unexplored. Using two different ice sheet and sea level reconstructions, we explicitly simulate the evolution of the leading semi‐diurnal and diurnal tidal constituents (M 2 , S 2 , K 1 , and O 1 ) over the last glacial cycle with a global tide model. Both sets of simulations show that global changes, dominated by the Atlantic, take place for the semi‐diurnal constituents, while changes for the diurnal constituents are mainly regional. Irrespective of the reconstruction, open ocean dissipation peaks during the sea level lowstands of MIS 2 (∼20 ka) and MIS 4 (∼60 ka), although dissipation values prior to MIS 2 are sensitive to differences in reconstructed ice sheet extent. Using the statistically significant relationship between global mean sea level and dissipation, we apply regression analysis to infer open ocean and shelf dissipation, respectively, over the last four glacial cycles back to 430 ka. Our analysis shows that open ocean tidal energy was probably increased for most of this period, peaking during glacial maxima, and returning to near‐present‐day values during interglacials. Due to tidal resonance during glacial phases, small changes in bathymetry could have caused large changes in tidal amplitudes and dissipation, emphasizing the need for accurate ice margin reconstructions. During glacial phases, once global mean sea level decreased by more than ∼100 m, the amount of open ocean tidal energy available for ocean mixing approximately doubled.
末次盛冰期研究;26.5 ~ 19ka)海潮在开阔海潮幅值和耗散率上有明显增强;然而,在LGM之前的变化在很大程度上仍未被探索。利用两个不同的冰盖和海平面重建,我们用一个全球潮汐模式明确地模拟了最后一个冰旋回中主要的半日和日潮汐成分(m2、s2、k1和O 1)的演变。两组模拟结果都表明,以大西洋为主导的全球变化发生在半日分量上,而日分量的变化主要是区域性的。尽管在MIS 2之前的消散值对重建冰盖范围的差异很敏感,但不管重建情况如何,公海耗散在MIS 2 (~ 20 ka)和MIS 4 (~ 60 ka)的海平面低潮期间达到峰值。利用统计上显著的全球平均海平面与耗散之间的关系,我们应用回归分析分别推断了430 ka以来四个冰期旋回的开放海洋和陆架耗散。我们的分析表明,开阔海洋潮汐能可能在这一时期的大部分时间都在增加,在冰期高峰期达到峰值,并在间冰期恢复到接近现在的值。由于冰期的潮汐共振,测深的微小变化可能引起潮汐振幅和耗散的大变化,这强调了精确重建冰缘的必要性。在冰期,一旦全球平均海平面下降超过~ 100米,可用于海洋混合的开放海洋潮汐能量大约增加一倍。
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引用次数: 0
Estimating Plio‐Pleistocene North African Monsoon Runoff Into the Mediterranean Sea and Temperature Impacts 估计上新世-更新世北非季风径流进入地中海和温度影响
2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2023-11-01 DOI: 10.1029/2023pa004677
D. Heslop, U. Amarathunga, E. J. Rohling
Abstract Sapropels are dark, organic‐rich layers found in Mediterranean sediments that formed during periods of bottom water anoxia. While various mechanisms have been proposed to have caused anoxic conditions, a primary factor is considered to be water column stratification induced by freshwater runoff related to intensified North African monsoon precipitation during precession minima. Monsoon intensification also induced Green Sahara Periods that may have impacted North African hominin dispersal. In this study, we present a novel regression‐based deconvolution of a high‐resolution planktonic foraminiferal oxygen isotope record to estimate the combination of freshwater runoff reaching the eastern Mediterranean and associated surface warming of the water column over the past 5 million years. Sapropels are known to occur in clusters associated with periods of high orbital eccentricity. Our analysis reveals a consistent influence of orbital eccentricity in modulating the North African monsoon, and a possible shift in runoff source area induced by the initiation of Northern Hemisphere ice sheets. Our findings provide important insights into the role of the North African monsoon in shaping Mediterranean environmental changes over the past 5 million years.
腐膜是在地中海沉积物中发现的深色、富含有机物的层,形成于海底缺氧时期。虽然已经提出了各种导致缺氧条件的机制,但一个主要因素被认为是与进动极小期北非季风降水加剧有关的淡水径流引起的水柱分层。季风的增强也导致了绿色撒哈拉时期,这可能影响了北非人类的扩散。在这项研究中,我们提出了一种新的基于回归的高分辨率浮游有孔虫氧同位素记录的反褶积,以估计在过去500万年中到达地中海东部的淡水径流和相关的水柱表面变暖的组合。我们知道,星轮出现在与高轨道离心率周期相关的星团中。我们的分析揭示了轨道偏心率对北非季风的持续影响,以及北半球冰盖的形成可能导致径流源区的转移。我们的发现为了解北非季风在过去500万年中塑造地中海环境变化的作用提供了重要的见解。
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引用次数: 0
Assessing seasonal and inter‐annual marine sediment climate proxy data 评估季节性和年际海洋沉积物气候代用资料
2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2023-10-01 DOI: 10.1029/2023pa004649
Ed Hathorne, Andrew M. Dolman, Thomas Laepple
Abstract Three recently published papers including Napier et al. (2022, https://doi.org/10.1029/2021PA004355 ) utilize novel microanalytical approaches with varved marine sediments to demonstrate the potential to reconstruct seasonal and inter‐annual climate variability. Obtaining paleoclimate data at a resolution akin to the observational record is vitally important for improving our understanding of climate phenomena such as monsoons and modes of variability such as the El Niño Southern Oscillation, for which appraisals of past inter‐annual variability is critical. The ability to generate seasonal and inter annual resolution sea surface temperature proxy time series spanning a thousand years or more is revolutionary and has the potential to fill gaps in our knowledge of climate variability. Although generally limited to sediments from regions with oxygen depleted bottom waters, there is great potential to integrate shorter seasonal resolution climate “snap shots” from other archives such as annually banded corals into composite time series. But as paleoceanographic data are used more by the observational and modeling fields, we make the case for conducting a thorough case‐by‐case assessment of the processes that influence the climate signal recovered from proxies, using careful replication to validate new approaches. Understanding or exploring the potential influence of processes which effectively filter the climate signal will lead to more quantitative paleoceanographic data that will better serve the broader climate science community.
最近发表的三篇论文,包括Napier等人(2022,https://doi.org/10.1029/2021PA004355),利用新颖的微分析方法对不同的海洋沉积物进行分析,证明了重建季节和年际气候变化的潜力。以类似于观测记录的分辨率获取古气候数据对于提高我们对气候现象的理解至关重要,如季风和厄尔Niño南方涛动等变率模式,对过去年际变率的评估至关重要。生成跨越一千年或更长时间的季节性和年际分辨率海面温度代理时间序列的能力是革命性的,有可能填补我们对气候变率知识的空白。虽然通常仅限于来自缺氧底水地区的沉积物,但将来自其他档案(如每年带状珊瑚)的较短季节分辨率气候“快照”整合到复合时间序列中具有很大的潜力。但是,随着观测和模拟领域越来越多地使用古海洋学数据,我们提出了对影响从代用物中恢复的气候信号的过程进行全面个案评估的理由,并使用仔细的复制来验证新方法。了解或探索有效过滤气候信号的过程的潜在影响将带来更多定量的古海洋学数据,从而更好地为更广泛的气候科学界服务。
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引用次数: 0
Revisiting oxygen‐18 and clumped isotopes in planktic and benthic foraminifera 浮游和底栖有孔虫中氧- 18和团块同位素的研究
2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2023-10-01 DOI: 10.1029/2023pa004660
M. Daëron, W. R. Gray
Abstract Foraminiferal isotopes are widely used to study past oceans, with different species recording conditions at different depths. Their δ 18 O values record both seawater oxygen‐18 and temperature according to species‐specific fractionation factors, while their Δ 47 signatures likely depend only on temperature. We describe an open‐source framework to collect/combine data relevant to foraminiferal isotopes, by constraining species‐specific oxygen‐18 fractionation factors ( 18 α ) based on culture experiments, stratified plankton tows or core‐top sediments; compiling stratified plankton tow constraints on living depths for planktic species; extracting seawater temperature, δ 18 O, and chemistry from existing databases for any latitude, longitude, and depth‐range; inferring calcification temperatures based on the above data. We find that although 18 α differs between species, its temperature sensitivity remains indistinguishable from inorganic calcite. Based on > 2,600 observations we show that, although most planktic δ 18 O values are consistent with seawater temperature and δ 18 O over their expected living depths, a sizable minority (12%–24%) have heavier‐than‐predicted δ 18 O, best explained by calcification in deeper waters. We use this framework to revisit three recent Δ 47 calibration studies of planktic/benthic foraminifera, confirming that planktic Δ 47 varies systematically with oxygen‐18‐derived temperature estimates, even for samples whose δ 18 O disagrees with assumed climatological conditions, and demonstrating excellent agreement between planktic foraminifera and modern, largely inorganic Δ 47 calibrations. Benthic foraminifera remain ambiguous: modern benthic Δ 47 values appear offset from planktic ones, yet applying equilibrium Δ 47 calibration to the Cenozoic benthic foraminifer record of Meckler et al. (2022, https://doi.org/10.1126/science.abk0604 ) largely reconciles it with δ 18 O‐derived temperatures, with discrete Δ 47 /δ 18 O discrepancies persisting in the Late Paleocene/Eocene/Plio‐Pleistocene.
有孔虫同位素被广泛用于研究过去的海洋,不同的物种在不同的深度记录条件。它们的δ 18o值根据物种特异性分馏因子记录了海水氧- 18和温度,而它们的Δ 47特征可能仅取决于温度。我们描述了一个开源框架,通过限制基于培养实验、分层浮游生物拖带或岩心顶部沉积物的物种特异性氧- 18分馏因子(18 α)来收集/组合与有孔虫同位素相关的数据;编制分层浮游生物拖曳对浮游物种生活深度的限制;从现有数据库中提取任何纬度、经度和深度范围的海水温度、δ 18o和化学成分;根据上述数据推断钙化温度。我们发现,虽然18 α在不同的物种之间存在差异,但它的温度敏感性与无机方解石没有区别。基于>我们发现,虽然大多数浮游生物的δ 18o值与海水温度和δ 18o值在其预期生活深度上是一致的,但相当大的少数(12%-24%)的δ 18o值比预测的要重,这最好的解释是深水中的钙化。我们使用这一框架重新审视了最近的三个浮游/底栖有孔虫Δ 47校准研究,证实了浮游Δ 47随着氧- 18衍生的温度估计而系统地变化,即使样品的Δ 18 O与假设的气候条件不一致,并证明了浮游有孔虫与现代主要无机的Δ 47校准之间的良好一致性。底栖有孔虫仍然不明确:现代底栖有孔虫Δ 47值似乎与浮游有孔虫的值相偏移,但将平衡Δ 47校准应用于Meckler等人(2022,https://doi.org/10.1126/science.abk0604)的新生代底栖有孔虫记录在很大程度上与Δ 18o衍生的温度相吻合,在晚古新世/始新世/上新世-更新世期间,离散的Δ 47 / Δ 18o差异持续存在。
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引用次数: 2
Capturing Equatorial Pacific Variability with Multivariate Sr‐U Coral Thermometry 用多变量Sr - U珊瑚测温法捕获赤道太平洋变率
2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2023-10-01 DOI: 10.1029/2022pa004508
N. R. Mollica, A. L. Cohen, F. Horton, Delia W. Oppo, Andrew S. Solow, David McGee
Abstract Sr‐U, a coral‐based paleothermometer, corrects for the effects of Rayleigh Fractionation on Sr/Ca by regressing multiple, paired U/Ca and Sr/Ca values. Prior applications of Sr‐U captured mean annual sea surface temperatures (SSTs), inter‐annual variability, and long‐term trends. However, because many Sr/Ca‐U/Ca pairs are needed for a single Sr‐U value as originally formulated, the temporal resolution of the proxy is typically limited to 1 year. Here, we address this limitation by applying laser ablation inductively coupled plasma mass spectrometry (LA‐ICPMS) to three Porites colonies from Jarvis and Nikumaroro Islands in the central equatorial Pacific (CEP), generating ∼25 Sr/Ca‐U/Ca pairs per month of skeletal growth. Both Sr/Ca and U/Ca vary significantly over small (sub‐mm) length scales and support the calculation of Sr‐U values using the original regression method. Over the represented temperature range of 24–31°C, the Sr/Ca‐U/Ca‐SST relationships are nonlinear, a finding consistent with predictions of the Rayleigh model. To reflect this non‐linearity, we developed a calibration using multivariate nonlinear regression. The multivariate, three‐coral calibration was applied to 20 years of monthly resolved Sr/Ca and U/Ca of a coral interval not included in the calibration, yielding RMSE = 0.73°C and r 2 = 0.85 ( p < 0.05; df = 256). The multivariate calibration performed significantly better than Sr/Ca alone ( r 2 = 0.28). Applying the new calibration to a subfossil Porites from Kiritimati Atoll, CEP (2200 Before Present) yields equivalent phase and amplitude of interannual variability, but water temperatures ∼1.6°C cooler than they are in this region today.
Sr - U是一种基于珊瑚的古温度表,通过回归多个成对的U/Ca和Sr/Ca值来校正瑞利分选对Sr/Ca的影响。Sr - U的先前应用捕获了年平均海面温度(SSTs)、年际变率和长期趋势。然而,由于最初制定的单个Sr - U值需要许多Sr/Ca‐U/Ca对,因此代理的时间分辨率通常限制在1年。在这里,我们通过将激光烧蚀电感耦合等离子体质谱(LA‐ICPMS)应用于赤道太平洋中部(CEP) Jarvis和Nikumaroro群岛的三个Porites群落来解决这一限制,每月产生约25对Sr/Ca‐U/Ca对骨骼生长。Sr/Ca和U/Ca在小(亚毫米)长度尺度上变化显著,支持使用原始回归方法计算Sr - U值。在24-31°C的温度范围内,Sr/Ca‐U/Ca‐SST的关系是非线性的,这一发现与瑞利模式的预测一致。为了反映这种非线性,我们开发了一个使用多元非线性回归的校准。多变量三珊瑚校准应用于未包括在校准中的珊瑚区间的20年月度分解Sr/Ca和U/Ca,得到RMSE = 0.73°C和r2 = 0.85 (p <0.05;Df = 256)。多变量校准效果明显优于单独使用Sr/Ca (r 2 = 0.28)。将新的校准应用于基里蒂玛蒂环礁的亚化石Porites, CEP(2200年前)得到了等效的年际变率的相位和幅度,但水温比该地区今天的水温低1.6°C。
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引用次数: 0
Geochemical differences between alive, uncrusted and dead, crusted shells of Neogloboquadrina pachyderma: Implications for paleoreconstruction 厚皮新舌龙活壳、无壳和死壳的地球化学差异:对古构造的启示
2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2023-10-01 DOI: 10.1029/2023pa004638
Brittany N. Hupp, Jennifer S. Fehrenbacher
Planktic foraminiferal‐based trace element‐calcium ratios (TE/Ca) are a cornerstone in paleoceanographic reconstructions. While TE‐environment calibrations are often established through culturing experiments, shell growth in culture is not always consistent with growth in a natural setting. For example, many species of planktic foraminifera thicken their shell at the end of their life cycle, producing a distinct “gametogenic” crust. Crust is common in fossil foraminifers, however, shells grown in culture do not often develop a thick crust. Here, we investigate potential vital effects associated with the crusting process by comparing the trace element (Mg/Ca, Na/Ca, Ba/Ca, Sr/Ca, Mn/Ca, Zn/Ca) and stable isotope (δ13C, δ18O) composition of alive, fully mature, uncrusted shells to recently deceased, crusted shells of Neogloboquadrina pachyderma collected from the same plankton tows off the Oregon (USA) coast. We find that uncrusted (N = 55) shells yield significantly higher Ba/Ca, Na/Ca, Mn/Ca, and Sr/Ca than crusted (N = 66) shells, and crust calcite records significantly lower TE/Ca values for all elements examined. Isotopic mixing models suggest that the crust calcite accounts for ∼40%–70% of crusted shell volume. Comparison of foraminiferal and seawater isotopes indicate that N. pachyderma lives in the upper 90 m of the water column, and that crust formation occurs slightly deeper than their average living depth habitat. Results highlight the necessity to establish calibrations from crusted shells, as application of calibrations from TE‐enriched uncrusted shells may yield attenuated or misleading paleoceanographic reconstructions.
基于浮游有孔虫的微量元素钙比(TE/Ca)是古海洋重建的基石。虽然通常通过培养实验建立TE -环境校准,但培养中的贝壳生长并不总是与自然环境中的生长一致。例如,许多浮游有孔虫物种在生命周期结束时增厚外壳,产生独特的“配子体”外壳。壳在化石有孔虫中很常见,然而,在培养中生长的贝壳通常不会形成厚厚的壳。在这里,我们通过比较从美国俄勒冈州海岸的同一浮游生物海带中收集的完全成熟、未结壳的活壳和最近死亡、结壳的厚皮新舌足壳的微量元素(Mg/Ca、Na/Ca、Ba/Ca、Sr/Ca、Mn/Ca、Zn/Ca)和稳定同位素(δ 13c、δ 18o)组成,研究了与结壳过程相关的潜在生命效应。我们发现未结壳(N = 55)的壳比结壳(N = 66)的壳产生更高的Ba/Ca、Na/Ca、Mn/Ca和Sr/Ca,并且结壳方解石记录的所有元素的TE/Ca值都显著降低。同位素混合模型表明地壳方解石占地壳壳体积的约40%-70%。有孔虫与海水同位素对比表明,厚皮乳孢菌生活在水柱上部90 m处,其地壳形成深度略高于其平均生活深度。结果强调了从有壳壳建立校准的必要性,因为应用富含TE的无壳壳的校准可能会产生衰减或误导性的古海洋重建。
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Paleoceanography and Paleoclimatology
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