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Obtaining Water from Air Using Porous Metal–Organic Frameworks (MOFs) 利用多孔金属-有机骨架(mof)从空气中获取水分
IF 8.6 2区 化学 Q1 Chemistry Pub Date : 2022-10-21 DOI: 10.1007/s41061-022-00410-9
Brij Mohan, Suresh Kumar, Quansheng Chen

Water collection from moisture in air, i.e., atmospheric water harvesting, is an urgent future need for society. It can be used for water production everywhere and anytime as an alternative water source in remote areas. However, water harvesting and collection usually relies on desalination, fog, and dewing harvesting, which are energy intensive. In this respect, metal–organic frameworks (MOFs) have broad applicability for water harvesting in water-scarce areas; therefore, the current discussion focuses on this approach. Furthermore, recent progress on MOFs for moisture harvesters is critically discussed. In addition, the design, operation, and water harvesting mechanisms of MOFs are studied. Finally, we discuss critical points for future research for the design of new MOFs as moisture harvesters for use in practical applications.

Graphical Abstract

MOF adsorbents offer excellent operating capacity in various temperature and pressure ranges. Rational water harvesters can thus be developed by adjusting structural properties such as the porosity, functionalities, and metal centers, thereby enabling new devices to produce water even in remote areas.

从空气中的水分中收集水分,即大气集水,是未来社会的迫切需要。它可以随时随地用于生产水,作为偏远地区的替代水源。然而,水的收集通常依赖于海水淡化、雾和露水的收集,这些都是能源密集型的。在这方面,金属-有机框架对缺水地区的集水具有广泛的适用性;因此,当前的讨论集中在这种方法上。此外,本文还对水分采集器mof的最新进展进行了讨论。此外,还对mof的设计、运行和集水机理进行了研究。最后,我们讨论了设计用于实际应用的新型mof集湿器的未来研究要点。mof吸附剂在各种温度和压力范围内都具有良好的操作能力。因此,合理的水收集器可以通过调整孔隙度、功能和金属中心等结构特性来开发,从而使新设备即使在偏远地区也能采水。
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引用次数: 6
Isocyanide-Based Multicomponent Reactions in Water: Advanced Green Tools for the Synthesis of Heterocyclic Compounds 水中基于异氰化物的多组分反应:合成杂环化合物的先进绿色工具
IF 8.6 2区 化学 Q1 Chemistry Pub Date : 2022-09-22 DOI: 10.1007/s41061-022-00403-8
Tahereh Nasiriani, Siamak Javanbakht, Mohammad Taghi Nazeri, Hassan Farhid, Vida Khodkari, Ahmad Shaabani

Reaction rate acceleration using green methods is an intriguing area of research for chemists. In this regard, water as a “green solvent” plays a crucial role in the acceleration of some organic transformations and reveals exclusive selectivity and reactivity in comparison with conventional organic solvents. In particular, multicomponent reactions (MCRs) as sustainable tools lead to the rapid generation of small-molecule libraries in water and aqueous media due to the prominent role of the hydrophobic effect. MCRs, as diversity-oriented synthesis (DOS) methods, have great efficiency with simple operations, atom, pot, and step economy synthesis, and mechanistic beauty. Among diverse classes of MCRs, isocyanide-based multicomponent reactions (I-MCRs), as sustainable and versatile reactions, have gained considerable attention in the synthesis of diverse heterocycle rings, especially in drug design because of the peculiar nature of isocyanide as a particular active reactant. I-MCRs that are performed in water are mild, environmentally friendly, and easily controlled, and have a reduced number of workup, purification, and extraction steps, which fit well with the advantages of “green” chemistry. Performing these powerful organic transformations in water and aqueous media is accompanied by acceleration owing to negative activation volumes, which originate from connecting several reactants together to generate a single product. It should be noted that the combination of MCR strategy and aqueous phase reaction is of growing interest for the development of sustainable synthetic techniques in organic conversions. However, an exclusive account focusing on the recent progress in eco-friendly I-MCRs for the construction of heterocycles in water and aqueous media is particularly lacking. This review highlights the progress of various kinds of I-MCRs in water and aqueous media as benign methods for the efficient construction of vital heterocyclic scaffolds, with a critical discussion of the subject in the period 2000–2021. We hope that this themed collection will be of interest and beneficial for organic and pharmaceutical chemists and will inspire more reaction development in this fascinating field.

Graphical Abstract

对化学家来说,利用绿色方法加速反应速率是一个有趣的研究领域。在这方面,水作为一种“绿色溶剂”在加速某些有机转化方面起着至关重要的作用,与传统有机溶剂相比,它显示出独特的选择性和反应性。特别是,多组分反应(mcr)作为可持续的工具,由于疏水效应的突出作用,导致水和水介质中小分子文库的快速生成。mcr作为一种面向多样性的合成方法,具有操作简单、原子、锅、步合成经济、机械美观等优点。在各类多组分反应中,基于异氰化物的多组分反应(i - mcr)作为一种可持续的多用途反应,由于异氰化物作为一种特殊的活性反应物的特性,在各种杂环的合成中,特别是在药物设计中受到了相当大的关注。在水中进行的i - mcr温和、环保、易于控制,并且减少了作业、净化和提取步骤,非常符合“绿色”化学的优势。在水和水介质中进行这些强大的有机转化伴随着负激活体积的加速,这源于将几个反应物连接在一起产生单一产物。应该指出的是,MCR策略与水相反应的结合对有机转化中可持续合成技术的发展越来越有兴趣。然而,关于在水和含水介质中构建杂环的生态友好型i - mcr的最新进展的独家报道尤其缺乏。本文重点介绍了各种i - mcr在水和水介质中作为高效构建重要杂环支架的良性方法的进展,并在2000-2021年期间对该主题进行了批判性讨论。我们希望这个主题的集合将引起有机和药物化学家的兴趣和有益的,并将在这个迷人的领域激发更多的反应发展。图形抽象
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引用次数: 10
Recent Trends in Photocatalytic Enantioselective Reactions 光催化对映选择反应的最新进展
IF 8.6 2区 化学 Q1 Chemistry Pub Date : 2022-09-16 DOI: 10.1007/s41061-022-00402-9
Renu Verma, Palvi Jindal, Jagdish Prasad, S. L. Kothari, Narendra Pal Lamba, Anshu Dandia, Rama Kanwar Khangarot, Manmohan Singh Chauhan

Enantioselective synthesis through photocatalysis is one of the highly preferred approaches towards preparation of optically active compounds. This review elaborates and critically analyzes the different strategies of photocatalytic enantioselective reactions through H-bonding, transition metal catalysis, phase-transfer catalysis (PTC), chiral Lewis acid catalysis, N-heterocyclic carbene catalysis, and amine catalysis, and also explores ion pairs. In addition, it explains the different catalysis modes with multifunctional approaches for enantioselective photocatalytic reactions.

通过光催化对映选择性合成是制备光学活性化合物的首选方法之一。本文通过对h键、过渡金属催化、相转移催化(PTC)、手性Lewis酸催化、n -杂环碳烯催化、胺催化等不同的光催化对映选择反应策略进行了阐述和批判性分析,并对离子对进行了探讨。此外,它解释了不同的催化模式与多功能方法的对映选择性光催化反应。
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引用次数: 4
Functionalized Triazines and Tetrazines: Synthesis and Applications 功能化三嗪和四嗪:合成及应用
IF 8.6 2区 化学 Q1 Chemistry Pub Date : 2022-06-23 DOI: 10.1007/s41061-022-00385-7
Joydip Mondal, Akella Sivaramakrishna

The molecules possessing triazine and tetrazine moieties belong to a special class of heterocyclic compounds. Both triazines and tetrazines are building blocks and have provided a new dimension to the design of biologically important organic molecules. Several of their derivatives with fine-tuned electronic properties have been identified as multifunctional, adaptable, switchable, remarkably antifungal, anticancer, antiviral, antitumor, cardiotonic, anti-HIV, analgesic, anti-protozoal, etc. The objective of this review is to comprehensively describe the recent developments in synthesis, coordination properties, and various applications of triazine and tetrazine molecules. The rich literature demonstrates various synthetic routes for a variety of triazines and tetrazines through microwave-assisted, solid-phase, metal-based, [4+2] cycloaddition, and multicomponent one-pot reactions. Synthetic approaches contain linear, angular, and fused triazine and tetrazine heterocycles through a combinatorial method. Notably, the triazines and tetrazines undergo a variety of organic transformations, including electrophilic addition, coupling, nucleophilic displacement, and intramolecular cyclization. The mechanistic aspects of these heterocycles are discussed in a detailed way. The bioorthogonal application of these polyazines with various strained alkenes and alkynes provides a new prospect for investigations in chemical biology. This review systematically encapsulates the recent developments and challenges in the synthesis and possible potential applications of various triazine and tetrazine systems.

Graphical Abstract

含有三嗪和四嗪基团的分子属于一类特殊的杂环化合物。三嗪和四嗪都是构建单元,为设计生物学上重要的有机分子提供了一个新的维度。它们的一些衍生物具有精细的电子特性,已被鉴定为多功能、适应性强、可切换、显著的抗真菌、抗癌、抗病毒、抗肿瘤、强心、抗hiv、镇痛、抗原虫等。本文综述了三嗪和四嗪分子的合成、配位性质及其应用的最新进展。丰富的文献展示了微波辅助、固相、金属基、[4+2]环加成和多组分一锅反应等多种合成三嗪和四嗪的途径。通过组合方法,合成方法包含线性、角化和融合的三嗪和四嗪杂环。值得注意的是,三嗪和四嗪经历了各种有机转化,包括亲电加成、偶联、亲核位移和分子内环化。对这些杂环的机理进行了详细的讨论。这些多嗪类化合物与各种应变烯烃和炔烃的生物正交应用为化学生物学的研究提供了新的前景。本文系统地综述了各种三嗪和四嗪体系的合成和潜在应用的最新进展和挑战。图形抽象
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引用次数: 9
Conjugated Polymer Polypyrrole Nanostructures: Synthesis and Photocatalytic Applications 共轭高分子聚吡咯纳米结构:合成及其光催化应用
IF 8.6 2区 化学 Q1 Chemistry Pub Date : 2022-06-18 DOI: 10.1007/s41061-022-00388-4
Xiaojiao Yuan, Hynd Remita

Conjugated polymers (CPs) have been recently widely investigated for their properties and their applications in different fields including photocatalysis. Among the family of CPs, polypyrrole (PPy) has been the most extensively studied owing to its good environmental stability, high electrical conductivity, superior redox properties and easy synthesis. Besides, nanostructured polypyrrole-based nanomaterials are a type of active organic materials for photocatalysis, which is one of their emerging applications. Nanostructuration of polypyrrole can reduce the electron-hole recombination because of short charge transfer distances and reactant adsorption, and product desorption can be enhanced owing to the high surface area offered by nanostructures. This review summarizes synthesis of different nanostructures based on π-conjugated polymer polypyrrole and the latest developments for photocatalytic applications, including degradation of organic pollutants and hydrogen generation.

共轭聚合物(CPs)的性质及其在光催化等不同领域的应用近年来得到了广泛的研究。聚吡咯(PPy)因其具有良好的环境稳定性、高导电性、优异的氧化还原性能和易于合成等优点,在聚吡咯家族中得到了最广泛的研究。此外,纳米结构聚吡咯基纳米材料是一类用于光催化的活性有机材料,是其新兴的应用领域之一。聚吡咯的纳米结构由于电荷转移距离短和对反应物的吸附,可以减少电子-空穴复合,并且由于纳米结构提供的高表面积,可以增强产物的脱附。本文综述了基于π共轭聚合物聚吡咯的不同纳米结构的合成及其光催化应用的最新进展,包括降解有机污染物和制氢。
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引用次数: 9
Evolution of the Automatic Rhodopsin Modeling (ARM) Protocol 自动视紫红质建模(ARM)协议的发展
IF 8.6 2区 化学 Q1 Chemistry Pub Date : 2022-03-15 DOI: 10.1007/s41061-022-00374-w
Laura Pedraza-González, Leonardo Barneschi, Daniele Padula, Luca De Vico, Massimo Olivucci

In recent years, photoactive proteins such as rhodopsins have become a common target for cutting-edge research in the field of optogenetics. Alongside wet-lab research, computational methods are also developing rapidly to provide the necessary tools to analyze and rationalize experimental results and, most of all, drive the design of novel systems. The Automatic Rhodopsin Modeling (ARM) protocol is focused on providing exactly the necessary computational tools to study rhodopsins, those being either natural or resulting from mutations. The code has evolved along the years to finally provide results that are reproducible by any user, accurate and reliable so as to replicate experimental trends. Furthermore, the code is efficient in terms of necessary computing resources and time, and scalable in terms of both number of concurrent calculations as well as features. In this review, we will show how the code underlying ARM achieved each of these properties.

近年来,视紫红质等光活性蛋白已成为光遗传学前沿研究的共同目标。除了湿实验室研究之外,计算方法也在迅速发展,为分析和合理化实验结果提供了必要的工具,最重要的是,推动了新系统的设计。自动视紫红质建模(ARM)协议的重点是提供必要的计算工具来研究视紫红质,无论是自然的还是由突变产生的。该代码经过多年的发展,最终提供了任何用户都可以复制的结果,准确可靠,以便复制实验趋势。此外,代码在必要的计算资源和时间方面是高效的,并且在并发计算数量和特性方面是可扩展的。在本文中,我们将展示ARM底层的代码是如何实现这些属性的。
{"title":"Evolution of the Automatic Rhodopsin Modeling (ARM) Protocol","authors":"Laura Pedraza-González,&nbsp;Leonardo Barneschi,&nbsp;Daniele Padula,&nbsp;Luca De Vico,&nbsp;Massimo Olivucci","doi":"10.1007/s41061-022-00374-w","DOIUrl":"10.1007/s41061-022-00374-w","url":null,"abstract":"<div><p>In recent years, photoactive proteins such as rhodopsins have become a common target for cutting-edge research in the field of optogenetics. Alongside wet-lab research, computational methods are also developing rapidly to provide the necessary tools to analyze and rationalize experimental results and, most of all, drive the design of novel systems. The Automatic Rhodopsin Modeling (<b>ARM</b>) protocol is focused on providing exactly the necessary computational tools to study rhodopsins, those being either natural or resulting from mutations. The code has evolved along the years to finally provide results that are <b>reproducible</b> by any user, <b>accurate</b> and <b>reliable</b> so as to replicate experimental trends. Furthermore, the code is <b>efficient</b> in terms of necessary computing resources and time, and <b>scalable</b> in terms of both number of concurrent calculations as well as features. In this review, we will show how the code underlying ARM achieved each of these properties.</p></div>","PeriodicalId":54344,"journal":{"name":"Topics in Current Chemistry","volume":null,"pages":null},"PeriodicalIF":8.6,"publicationDate":"2022-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s41061-022-00374-w.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4619433","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 6
Enantioselective Allylic C–H Bond Oxidation of Olefins Using Copper Complexes of Chiral Oxazoline Based Ligands 手性恶唑啉配体铜配合物对烯丙基碳氢键氧化烯烃的影响
IF 8.6 2区 化学 Q1 Chemistry Pub Date : 2022-03-10 DOI: 10.1007/s41061-022-00375-9
Saadi Samadi, Hamid Arvinnezhad, Saber Nazari, Shiva Majidian

This review article discusses historical and contemporary research studies of asymmetric allylic oxidation of olefins using homogeneous and heterogeneous copper complexes of various kinds of oxazoline-based ligands, until the end of 2021. It is revealed that this strategy is a powerful method to form a new stereogenic center bearing an oxygen substituent adjacent to an unchanged C=C bond. Enantioselectivities as well as chemical yields, and also the reactivity, are strongly dependent on the type of substrate, oxidant, the copper salt and its oxidation state, ligand structure, temperature, nature of the solvent, and additives such as phenylhydrazine and porous materials.

这篇综述文章讨论了使用各种恶唑啉基配体的均相和非均相铜配合物对烯烃进行不对称烯丙基氧化的历史和当代研究,直到2021年底。结果表明,该策略是形成新的立体中心的有效方法,该中心带有一个氧取代基,毗邻不变的C=C键。对映选择性、化学产率和反应活性都与底物类型、氧化剂、铜盐及其氧化态、配体结构、温度、溶剂性质和添加剂(如苯肼和多孔材料)密切相关。
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引用次数: 5
Reaction Space Projector (ReSPer) for Visualizing Dynamic Reaction Routes Based on Reduced-Dimension Space 基于降维空间的动态反应路径可视化反应空间投影(ReSPer)
IF 8.6 2区 化学 Q1 Chemistry Pub Date : 2022-03-10 DOI: 10.1007/s41061-022-00377-7
Takuro Tsutsumi, Yuriko Ono, Tetsuya Taketsugu

To analyze chemical reaction dynamics based on a reaction path network, we have developed the “Reaction Space Projector” (ReSPer) method with the aid of the dimensionality reduction method. This program has two functions: the construction of a reduced-dimensionality reaction space from a molecular structure dataset, and the projection of dynamic trajectories into the low-dimensional reaction space. In this paper, we apply ReSPer to isomerization and bifurcation reactions of the Au5 cluster and succeed in analyzing dynamic reaction routes involved in multiple elementary reaction processes, constructing complicated networks (called “closed islands”) of nuclear permutation-inversion (NPI) isomerization reactions, and elucidating dynamic behaviors in bifurcation reactions with reference to bundles of trajectories. Interestingly, in the second application, we find a correspondence between the contribution ratios in the ability to visualize and the symmetry of the morphology of closed islands. In addition, the third application suggests the existence of boundaries that determine the selectivity in bifurcation reactions, which was discussed in the phase space. The ReSPer program is a versatile and robust tool to clarify dynamic reaction mechanisms based on the reduced-dimensionality reaction space without prior knowledge of target reactions.

为了分析基于反应路径网络的化学反应动力学,我们借助降维方法开发了“反应空间投影”(ReSPer)方法。该程序具有两个功能:从分子结构数据集构建降维反应空间,以及将动态轨迹投影到低维反应空间中。本文将ReSPer应用于Au5簇的异构化和分岔反应,成功地分析了多个基本反应过程中涉及的动态反应路线,构建了核置换-反演(NPI)异构化反应的复杂网络(称为“闭岛”),并参考轨迹束阐明了分岔反应的动态行为。有趣的是,在第二个应用中,我们发现可视化能力的贡献率与封闭岛屿形态的对称性之间存在对应关系。此外,第三个应用表明,在分岔反应中存在决定选择性的边界,这在相空间中进行了讨论。ReSPer程序是一个多功能和强大的工具,用于阐明基于降维反应空间的动态反应机制,而无需预先了解目标反应。
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引用次数: 3
Recent Progress in Indacenodithiophene-Based Acceptor Materials for Non-Fullerene Organic Solar Cells 非富勒烯有机太阳能电池用吲哚二噻吩基受体材料的研究进展
IF 8.6 2区 化学 Q1 Chemistry Pub Date : 2022-03-05 DOI: 10.1007/s41061-022-00372-y
Rashid Ilmi, Houda Al-Sharji, Muhammad S. Khan

Domesticating solar energy by exploiting photovoltaic technology has become a quintessential strategy for future global energy production. Since 2015, non-fullerene organic solar cells (NF-OSC) have attracted a great deal of attention owing to the marvellous properties of non-fullerene acceptors (NFA) such as structural versability, broad absorption, suitable energy levels, tunable charge transport and morphology, leading to remarkable accomplishments in power conversion efficiency (PCE) from 1% to nearly 20%. One class of materials is provided by the fused ring aromatic indacenodithiophene (IDT) and its derivatives, which are emerging continuously as promising next-generation building blocks to construct high performance photovoltaic materials. Encouraging PCEs of more than 15% have been achieved in their binary NF-OSCs, while careful device engineering and proper amalgamation of a third component have led to PCEs of almost 18% in ternary devices. This review surveys recent developments in the area of IDT-based materials for photovoltaic applications. Different strategies to develop efficient IDT-based NFA and factors influencing the bandgaps, molecular energy levels, charge transport properties, and film morphologies, as well as the photovoltaic performance of these materials, are discussed.

Graphical abstract

利用光伏技术实现太阳能的国产化已经成为未来全球能源生产的一个典型战略。自2015年以来,非富勒烯有机太阳能电池(non-fullerene organic solar cells, NF-OSC)由于其具有结构通用性、广泛吸收、合适的能级、可调谐的电荷输运和形态等特性而备受关注,其功率转换效率(PCE)从1%提高到近20%。一类材料是由熔融环芳香吲哚二噻吩(IDT)及其衍生物提供的,它们作为构建高性能光伏材料的下一代基石不断涌现。在他们的二进制NF-OSCs中,pce已经达到了令人鼓舞的15%以上,而仔细的设备工程和第三个组件的适当合并使得三元器件的pce接近18%。本文综述了近年来光伏应用中硅基材料的研究进展。本文讨论了开发高效基于idf的NFA的不同策略,以及影响这些材料的带隙、分子能级、电荷输运性质和薄膜形态以及光伏性能的因素。图形抽象
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引用次数: 6
The Role of Metal Nanoparticles in Promoting Photocatalysis by TiO2 金属纳米颗粒在促进TiO2光催化中的作用
IF 8.6 2区 化学 Q1 Chemistry Pub Date : 2022-03-03 DOI: 10.1007/s41061-022-00373-x
Michael Bowker, Christopher O’Rourke, Andrew Mills

In this review, we highlight the role played by metal nanoparticles (NPs) in photocatalytic oxidation with titania as a support. This is presented in two parts, namely, partial photo-oxidation in which an organic sacrificial agent is oxidised in anaerobic conditions to produce hydrogen (photo-reforming), and photo-oxidative mineralisation of organics in aerobic conditions. We present some rules for such reactions that dictate which organic molecules can react readily, and which metals are likely to be useful for such reactions. Generally, the presence of metal NPs enhances enormously the ability of titania to yield hydrogen from photo-reforming, and a wide range of molecules can be used, including biomass. The metal NPs most used are those that are easily reduced, that is, the precious metals. The large enhancement in rate seen with metal for hydrogen production is not so extreme for the oxidation reactions, but is still significant. An important factor in all of this catalysis is the nature of the interaction between the metal NPs, which can play a multiplicity of chemical and electronic roles, and the photoactive support. A sharp dependency of rate on loading of metal is found, with maximum rates at ~0.5–2 wt% loading, depending on the metal used. The source of this dependency is the bifunctional nature of the system, in which the intimacy of both materials is crucial to performance. This rate variation is linked to the interface between the two, which is then linked to the size of the metal NPs. In fact, the rate is proportional to an area adjacent to the metal particles that we call the expanding photocatalytic area and overlap (EPAO) kinetic model. This model describes the dependence well. Rising rates with increasing coverage of particles is associated with increase in this total area but, at the maximum, these areas overlap and at higher loadings the available active area diminishes, reproducing the observed behaviour well.

在这篇综述中,我们重点介绍了金属纳米颗粒(NPs)在二氧化钛作为载体的光催化氧化中的作用。这分为两部分,即部分光氧化,其中有机牺牲剂在厌氧条件下氧化产生氢气(光重整),以及在有氧条件下有机物的光氧化矿化。我们提出了这类反应的一些规则,这些规则规定了哪些有机分子容易反应,哪些金属可能对这类反应有用。一般来说,金属NPs的存在极大地增强了二氧化钛光重整产氢的能力,并且可以使用广泛的分子,包括生物质。最常用的金属NPs是那些容易被还原的,即贵金属。在氧化反应中,金属产氢速率的大幅提高并不是那么极端,但仍然很重要。在所有这些催化中,一个重要的因素是金属NPs与光活性载体之间相互作用的性质,NPs可以发挥多种化学和电子作用。速率与金属的载荷有很大的关系,根据所用金属的不同,最大速率为~0.5 - 2% wt%的载荷。这种依赖的来源是系统的双功能性质,其中两种材料的亲密性对性能至关重要。这种速率变化与两者之间的界面有关,而界面又与金属NPs的大小有关。事实上,速率与金属颗粒附近的面积成正比,我们称之为扩展光催化区域和重叠(EPAO)动力学模型。该模型很好地描述了依赖性。随着颗粒覆盖率的增加,速率的增加与总面积的增加有关,但是,在最大值时,这些区域重叠,在更高的负载下,可用的活动面积减少,很好地再现了所观察到的行为。
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引用次数: 10
期刊
Topics in Current Chemistry
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