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Radiation Shielding, Structural, and Optical Properties for YBa2Cu3O7-d Ceramic Doped with TiO2 Irradiated by Different Doses 不同剂量辐照下掺杂 TiO2 的 YBa2Cu3O7-d 陶瓷的辐射屏蔽、结构和光学特性
IF 2.6 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-06-03 DOI: 10.1007/s13369-024-09211-2
Y. Slimani, M. H. A. Mhareb, M. Kh Hamad, I. Alrammah

The effective optimization of radiation shielding materials that protect individuals against potentially harmful radiant hazards is highly desired. Nonetheless, it is still a challenge that should be further investigated. The present work addresses the low-cost development of YBa2Cu3O7-d ceramic doped with TiO2 as an effective shielding product. The prepared ceramic via solid-state reaction was irradiated with different gamma-ray dosage rates of 0.0, 2.5, and 50 kGy. Then, the phase composition, structure, optical property, and radiation shielding performances were systematically investigated. Examining the structure via XRD disclosed the creation of the desired YBa2Cu3O7-d ceramic with an orthorhombic structure. A Y2BaCuO5 secondary phase with low intensities was detected. On the other hand, a decrease in the lattice parameters was observed after irradiation. The optical absorption was found to reduce after irradiation, which may induce bond rearrangements, bond breaking, and changes in the local structure within the ceramic system. On the other hand, the shielding properties of YBa2Cu3O7-d ceramic doped with TiO2 did not show any variation in competence with changing gamma-ray doses. So, the shielding properties for unexposed samples were assessed, which included the buildup factor, dose rate, a specific absorbed fraction of energy, and a specific dose constant. The dose rate values enhanced with increasing energy, while they showed a reduction with increasing distance. The buildup factor and a specific absorbed fraction of energy values increased with increasing the main free path in all energy ranges. The obtained findings manifest the potential of including the present-developed ceramic in the radiation shielding area.

人们非常希望能有效优化辐射屏蔽材料,以保护个人免受潜在的有害辐射危害。尽管如此,这仍然是一个有待进一步研究的难题。本研究以低成本开发了掺杂 TiO2 的 YBa2Cu3O7-d 陶瓷,作为一种有效的屏蔽产品。通过固态反应制备的陶瓷在不同的伽马射线剂量率(0.0、2.5 和 50 kGy)下进行辐照。随后,对其相组成、结构、光学性质和辐射屏蔽性能进行了系统研究。通过 XRD 对结构的研究发现,YBa2Cu3O7-d 陶瓷具有理想的正交菱形结构。此外,还检测到强度较低的 Y2BaCuO5 次生相。另一方面,辐照后观察到晶格参数降低。辐照后发现光吸收减少,这可能会引起陶瓷体系内的键重排、键断裂和局部结构变化。另一方面,掺杂了二氧化钛的 YBa2Cu3O7-d 陶瓷的屏蔽性能并没有随着伽马射线剂量的变化而发生变化。因此,对未暴露样品的屏蔽性能进行了评估,其中包括积聚因子、剂量率、特定能量吸收率和特定剂量常数。剂量率值随着能量的增加而增加,而随着距离的增加而减少。在所有能量范围内,随着主自由路径的增加,积聚因子和能量的特定吸收分数值都会增加。这些研究结果表明,将目前开发的陶瓷纳入辐射屏蔽领域是有潜力的。
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引用次数: 0
A Study on Optimization of Grid-Layout Earth-to-Air Heat Exchangers (EAHEs) at Constant Total Heat Transfer Surface by using Taguchi Method 利用田口方法优化总传热面恒定时的网格布局地气换热器(EAHE)的研究
IF 2.6 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-06-03 DOI: 10.1007/s13369-024-09198-w
Ali Alikhani, Mehdi Maerefat, Seyed Mohammad Jafar Sobhani

The earth-to-air heat exchanger (EAHE) is a remarkable passive system that utilizes the earth’s energy for ventilation of air circulating through buried tubes which can lead to a significant reduction in building energy consumption. EAHE’s thermal performance can be affected by the system configuration. The present study optimizes the thermal effectiveness and thermohydraulic performance factor (TPF) of U-type grid-layout EAHEs at constant total heat transfer surface using the Taguchi technique for cooling applications. For this purpose, four important factors were selected including the diameter of branch tube, diameter of main tube, number of branch tubes, and volumetric airflow rate that were taken at four different levels. The best combination for achieving maximum thermal effectiveness and TPF of U-type grid-layout EAHEs was obtained. The research results reveal that the highest effective factor for thermal effectiveness and TPF was the diameter of the branch tube with contributions of 72% and 40.6%. Also, the lowest effective factors were the volumetric airflow rate and diameter of the main tube with contributions of 1.1% and 14.7%, respectively.

土-空气热交换器(EAHE)是一种出色的被动式系统,它利用地球的能量对通过埋管循环的空气进行通风,可显著降低建筑能耗。EAHE 的热性能会受到系统配置的影响。本研究采用田口技术优化了 U 型网格布局 EAHE 在总传热面恒定的情况下的热效率和热液压性能系数(TPF),用于冷却应用。为此,选取了四个重要因素,包括支管直径、主管直径、支管数量和体积气流率,并将其置于四个不同水平。研究结果表明,U 型栅格布局 EAHE 的热效率和 TPF 最高。研究结果表明,对热效率和 TPF 影响最大的有效因子是支管直径,其贡献率分别为 72% 和 40.6%。此外,最小的有效因子是体积气流率和主管直径,贡献率分别为 1.1%和 14.7%。
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引用次数: 0
Extracting Urgent Questions from MOOC Discussions: A BERT-Based Multi-output Classification Approach 从 MOOC 讨论中提取紧急问题:基于 BERT 的多输出分类方法
IF 2.6 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-05-31 DOI: 10.1007/s13369-024-09090-7
Mujtaba Sultani, Negin Daneshpour

Online discussion forums are widely used by students to ask and answer questions related to their learning topics. However, not all questions posted by students receive timely and appropriate feedback from instructors, which can affect the quality and effectiveness of the online learning experience. Therefore, it is important to automatically identify and prioritize student questions from online discussion forums, so that instructors can provide better support and guidance to the students. In this paper, we propose a novel hybrid convolutional neural network (CNN) + bidirectional gated recurrent unit (Bi-GRU) multi-output classification model, which can perform this task with high accuracy and efficiency. Our model consists of two outputs: the first one classifies whether the post is a question or not, and the second one classifies whether the classified question is urgent or not urgent. Our model leverages the advantages of both CNN and Bi-GRU layers to capture both local and global features of the input data, as well as the Bidirectional Encoder Representations from Transformers (BERT) model to provide rich and contextualized word embeddings. The model achieves an F1-weighted score of 94.8% when classifying whether the posts are questions or not, and obtains an 88.5% F1-weighted score while classifying the question into urgent and non-urgent. Distinguishing and classifying urgent student questions with high accuracy and coverage can help instructors provide timely and appropriate feedback, a key factor in reducing dropout rates and improving completion rates.

在线论坛被学生广泛用于提出和回答与学习主题相关的问题。然而,并非所有学生发布的问题都能得到教师及时、适当的反馈,这会影响在线学习体验的质量和效果。因此,从在线论坛中自动识别学生的问题并对其进行优先排序非常重要,这样教师就能为学生提供更好的支持和指导。在本文中,我们提出了一种新型混合卷积神经网络(CNN)+ 双向门控递归单元(Bi-GRU)多输出分类模型,它可以高精度、高效率地完成这项任务。我们的模型由两个输出组成:第一个输出对帖子是否为问题进行分类,第二个输出对分类后的问题是否紧急进行分类。我们的模型充分利用了 CNN 层和 Bi-GRU 层的优势来捕捉输入数据的局部和全局特征,并利用来自变换器的双向编码器表示(BERT)模型来提供丰富的上下文化单词嵌入。在对帖子是否为问题进行分类时,该模型的 F1 加权得分达到 94.8%,在对问题进行紧急和非紧急分类时,该模型的 F1 加权得分达到 88.5%。以较高的准确率和覆盖率对学生的紧急问题进行区分和分类,可以帮助教师及时提供适当的反馈,这是降低辍学率和提高完成率的关键因素。
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引用次数: 0
Impact of Mechanical and Thermal Treatment of Kaolin Clay on the Engineering Properties of Concrete 高岭土的机械和热处理对混凝土工程特性的影响
IF 2.6 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-05-31 DOI: 10.1007/s13369-024-09028-z
Tariq Ali, Osama Zaid, Muhammed Zeeshan Qureshi

Kaolin Clay, an economical alternative to nanofillers, is an innovative mineral employed as a concrete additive. Historically, this material was used primarily as a cement substitute in concrete, owing to its inherent cementing properties. This study explores the potential of using Kaolin Clay as a partial replacement for ordinary Portland cement (OPC) and a supplemental cementitious material (SCM), potentially enhancing concrete's affordability, environmental sustainability, and overall mechanical performance and durability. Kaolin Clay exhibits pozzolanic properties, produces a significantly smaller carbon footprint compared to OPC, and is readily available in nature. This research employed thermally and mechanically activated clay, ranging from 0 to 15% (in 2.5% increments), as a partial cement substitute in concrete for performance evaluation. The evaluation encompassed mechanical properties (split tensile strength, compressive strength) and durability performance measures (water absorption, sorptivity coefficient, and acid attack resistance). It was found that concrete with 15% thermally activated (TAK) and mechanically activated (MAK) Kaolin Clay performed admirably compared to the control mix (having no kaolin clay). At 28 days, the strength of the MAK-150 (15% mechanically activated kaolin clay) mix improved by 26.8% and TAK-150 by 30% compared to the control. Likewise, the tensile strength of MAK-150 increased by 25.9% and TAK-150(15% thermally activated kaolin clay) by 33%, revealing the promising potential of Kaolin Clay in enhancing concrete performance. Furthermore, the MAK-150 absorbs 21% less water than the control mix, whereas the TAK-150 absorbs 26% less. The utilization of a composite blend TAK-150, comprising of Kaolin clay, results in a reduction in costs by 8.4% in comparison to the M0 (having no kaolin clay) blend, which includes cement.

高岭土是纳米填料的经济替代品,是一种用作混凝土添加剂的创新矿物。从历史上看,由于其固有的胶结特性,这种材料主要用作混凝土中的水泥替代品。本研究探讨了使用高岭土作为普通硅酸盐水泥(OPC)的部分替代品和补充胶凝材料(SCM)的潜力,从而有可能提高混凝土的经济性、环境可持续性以及整体机械性能和耐久性。高岭土表现出了胶凝特性,与普通硅酸盐水泥相比,它产生的碳足迹要小得多,而且在自然界中很容易获得。本研究采用热活化和机械活化粘土(0-15%,增量为 2.5%)作为混凝土中的部分水泥替代品,进行性能评估。评估内容包括机械性能(劈裂拉伸强度、抗压强度)和耐久性能(吸水率、吸水系数和耐酸侵蚀性)。结果发现,与对照组混合物(不含高岭土)相比,添加了 15%热活化(TAK)和机械活化(MAK)高岭土的混凝土表现出色。28 天时,与对照组相比,MAK-150(15% 机械活化高岭土)混合料的强度提高了 26.8%,TAK-150 提高了 30%。同样,MAK-150 的抗拉强度提高了 25.9%,TAK-150(15% 热激活高岭土)提高了 33%,这表明高岭土在提高混凝土性能方面具有巨大潜力。此外,MAK-150 的吸水率比对照组低 21%,而 TAK-150 则低 26%。与含水泥的 M0(不含高岭土)混合料相比,使用含高岭土的 TAK-150 复合混合料可降低 8.4% 的成本。
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引用次数: 0
Predicting Mechanical Properties in Geopolymer Mortars, Including Novel Precursor Combinations, Through XGBoost Method 通过 XGBoost 方法预测土工聚合物砂浆(包括新型前体组合)的力学性能
IF 2.6 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-05-31 DOI: 10.1007/s13369-024-09179-z
Yildiran Yilmaz, Talip Cakmak, Zafer Kurt, Ilker Ustabas

Concrete is the most widely used material in the building industry due to its affordability, durability, and strength. However, considering carbon emissions, it is believed that concrete will be replaced by geopolymers in the future. As numerous parameters significantly affect the strength of geopolymers, the performance of potential algorithms for strength prediction needs to be evaluated for different binders to select an appropriate algorithm. This study employs machine learning approaches to provide the best prediction method for the flexural strength and compressive strength of geopolymers. A new dataset containing 533 compressive strength and 533 flexural strength values of geopolymers with different binders such as waste glass (GW), obsidian (OB), and fly ash was created. The best prediction solution, with R2 = 0.981 for compressive strength and R2 = 0.898 for flexural strength, was obtained from the extreme gradient boosting (XGBoost) algorithm. Additionally, several other machine learning models were employed, including linear regression, k-nearest neighbors, deep neural network, and random forest, with corresponding determination coefficient (R2) values of 0.763, 0.804, 0.93, and 0.96, respectively. These models were trained and evaluated using a dataset encompassing features such as binder types, age, and heat, to forecast the mechanical properties of geopolymers. Among these models, XGBoost demonstrated the highest R2 value, indicating superior performance in predicting both compressive and flexural strengths. The findings of this study provide valuable insights into the selection of appropriate machine learning algorithms for predicting mechanical properties in geopolymers, thus contributing to advancements in sustainable construction materials.

混凝土因其经济实惠、经久耐用和强度高而成为建筑行业最广泛使用的材料。然而,考虑到碳排放问题,相信混凝土在未来将被土工聚合物所取代。由于许多参数会对土工聚合物的强度产生重大影响,因此需要针对不同的粘合剂评估潜在的强度预测算法的性能,以选择合适的算法。本研究采用机器学习方法为土工聚合物的抗折强度和抗压强度提供最佳预测方法。新数据集包含 533 个土工聚合物的抗压强度值和 533 个抗折强度值,并使用了不同的粘合剂,如废玻璃(GW)、黑曜石(OB)和粉煤灰。通过极端梯度提升(XGBoost)算法获得了最佳预测方案,抗压强度的 R2 = 0.981,抗弯强度的 R2 = 0.898。此外,还采用了其他几种机器学习模型,包括线性回归、k-近邻、深度神经网络和随机森林,相应的判定系数 (R2) 值分别为 0.763、0.804、0.93 和 0.96。使用包含粘合剂类型、龄期和热量等特征的数据集对这些模型进行了训练和评估,以预测土工聚合物的机械性能。在这些模型中,XGBoost 的 R2 值最高,表明其在预测抗压强度和抗折强度方面表现出色。这项研究的结果为选择合适的机器学习算法来预测土工聚合物的机械性能提供了宝贵的见解,从而有助于推动可持续建筑材料的发展。
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引用次数: 0
Affinity Augmentation of ZnFe2O4 Nanoparticles Toward Hexavalent Chromium Through a Facile Bi3+ Doping Process 通过简便的 Bi3+ 掺杂工艺增强 ZnFe2O4 纳米粒子对六价铬的亲和力
IF 2.6 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-05-30 DOI: 10.1007/s13369-024-09119-x
Aruna Joseph, Mariyam Thomas, Thanooja Nizam, Mathew George, Derry Holaday, P. J. Jandas

A facile method to prepare activated ZnFe2O4 nanoparticles through novel metal ion doping using Bi3+ is demonstrated. The enhanced activity of the Bi3+-doped ZnFe2O4 nanoparticle was evaluated through Cr(VI) ions adsorption capability analysis from aqueous samples since industrial effluents have the metal ion as a major source of concern. ZnFe2-xBixO4 (x = 0.0, 0.05, 0.10, 0.15, 0.2) were synthesized using sol gel method, and a comparative adsorption efficiency study of Bi3+-doped and undoped ZnFe2O4 was performed. To understand the variation in adsorption efficiency and mechanism of adsorption on the Bi3+-doped ZnFe2O4, the adsorption study was conducted under varying adsorption conditions including pH, adsorbent dosage, contact time, initial ion concentration, and temperature. All the quantification studies regarding the adsorption were done using atomic adsorption spectroscopy (AAS). The studies suggested enhanced adsorption capability via Bi3+ doping as it can enhance the effective surface area and electrostatic charge density on the surface. Adsorption equilibrium information from this study was modeled using prominent adsorption kinetics and isotherm models, for extracting information regarding the performance of the adsorbent, rate of the adsorption and adsorption mechanism, which are imperative in the design and operation of adsorption systems. Scope of regeneration and reusability of the spent adsorbents in water treatment, which is also investigated in this work, addresses the ecological and economic demands for sustainability and also makes the wastewater treatment process cost effective.

通过使用 Bi3+ 掺杂新型金属离子,展示了一种制备活化 ZnFe2O4 纳米粒子的简便方法。由于工业废水中的铬(VI)离子是主要的污染源,因此通过对水样中铬(VI)离子的吸附能力分析,评估了掺杂了 Bi3+ 的 ZnFe2O4 纳米粒子的增强活性。采用溶胶凝胶法合成了 ZnFe2-xBixO4(x = 0.0、0.05、0.10、0.15、0.2),并对掺杂 Bi3+ 和未掺杂的 ZnFe2O4 进行了吸附效率比较研究。为了了解掺杂 Bi3+ 的 ZnFe2O4 吸附效率的变化和吸附机理,吸附研究是在不同的吸附条件下进行的,包括 pH 值、吸附剂用量、接触时间、初始离子浓度和温度。所有关于吸附的定量研究都是使用原子吸附光谱(AAS)进行的。研究表明,通过掺杂 Bi3+ 可以提高表面的有效表面积和静电荷密度,从而增强吸附能力。该研究利用著名的吸附动力学和等温线模型对吸附平衡信息进行建模,以提取有关吸附剂性能、吸附速率和吸附机制的信息,这些信息对于吸附系统的设计和运行至关重要。本研究还对水处理中废旧吸附剂的再生和再利用范围进行了研究,以满足可持续发展的生态和经济要求,并使废水处理过程具有成本效益。
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引用次数: 0
Reservoir Rock Discrimination Based on Integrated Image Logs and Petrographic Analysis: A Case Study from the Early Miocene Nukhul Carbonate, Southern Gulf of Suez, Egypt 基于综合图像测井和岩相分析的储层岩石识别:埃及苏伊士湾南部早中新世 Nukhul 碳酸盐岩案例研究
IF 2.6 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-05-29 DOI: 10.1007/s13369-024-09173-5
Ahmed A. Kassem, Mohsen Abdel Fattah, Zakaria Hassan, Ahmed E. Radwan

The discrimination of rock types within the limestones and dolostones of the Nukhul Formation in the West Younis Field (Gulf of Suez Basin, Egypt) presents significant challenges due to their multi-scale compositional and diagenetic heterogeneity, diverse pore types, complex microstructures, and limited core data. This study aims to characterize the carbonate reservoir of the Early Miocene sediments and establish distinct reservoir rock types by employing textural analysis, geological interpretations (i.e., structural interpretation, fracture analysis, reservoir characteristics) using advanced imaging tools, and petrophysical measurements to model porosity/permeability profiles across the reservoir. A new dataset was obtained from the latest exploratory well in the West Younis Field, incorporating microresistivity and acoustic image logs, well logs, nuclear magnetic resonance (NMR) tools, and drill cutting petrographic analysis. The integration of these datasets provided a comprehensive understanding of the properties of the Early Miocene carbonate reservoir. Based on image logs, the carbonate facies were divided into four reservoir units. Petrographic evaluation further classified two facies (A and B) based on diagenetic factors controlling reservoir quality. The results revealed the occurrence of multiple phases of dolomitization, which influenced the reservoir quality. Early-stage dolomitization enhanced reservoir quality, while late-stage idiotopic dolomite crystal growth diminished it. The study also provided comprehensive information on the original rock fabric/texture, diagenetic processes, porosity types and origins, as well as the spatial distribution of pores (permeability index) within this complex carbonate reservoir. By employing an integrated technique, this study successfully differentiated the carbonate reservoir into distinct rock types, leading to improved reservoir characterization and field development. Additionally, the findings contribute valuable insights for the development and exploration of the Early Miocene carbonate section in the southern Gulf of Suez.

West Younis 油田(埃及苏伊士湾盆地)Nukhul 地层的石灰岩和白云岩具有多尺度的成分和成岩异质性,孔隙类型多样,微结构复杂,岩芯数据有限,因此,如何区分这些岩石类型是一项重大挑战。本研究旨在描述早中新世沉积物碳酸盐岩储层的特征,并利用先进的成像工具进行纹理分析、地质解释(即构造解释、断裂分析、储层特征)和岩石物理测量,建立整个储层的孔隙度/渗透率剖面模型,从而确定不同的储层岩石类型。从 West Younis 油田的最新一口探井中获得了一个新的数据集,其中包括微电阻率和声学图像测井记录、测井记录、核磁共振(NMR)工具以及钻头切割岩相分析。通过整合这些数据集,可以全面了解早中新世碳酸盐岩储层的性质。根据图像记录,碳酸盐岩面被划分为四个储层单元。岩相评价根据控制储层质量的成岩因素进一步划分了两个储层面(A 和 B)。结果显示,白云石化发生了多个阶段,对储层质量产生了影响。早期阶段的白云石化提高了储层质量,而晚期阶段的白云石晶体生长则降低了储层质量。该研究还提供了有关该复杂碳酸盐岩储层内原始岩石结构/质地、成岩过程、孔隙度类型和来源以及孔隙空间分布(渗透率指数)的全面信息。通过采用综合技术,该研究成功地将碳酸盐岩储层区分为不同的岩石类型,从而改进了储层特征描述和油田开发。此外,研究结果还为苏伊士湾南部早中新世碳酸盐岩段的开发和勘探提供了宝贵的见解。
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引用次数: 0
Distributed Ensemble Method Using Deep Learning to Detect DDoS Attacks in IoT Networks 利用深度学习的分布式集合方法检测物联网网络中的 DDoS 攻击
IF 2.6 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-05-29 DOI: 10.1007/s13369-024-09144-w
Praveen Shukla, C. Rama Krishna, Nilesh Vishwasrao Patil

The widespread adoption of Internet of Things (IoT) devices has increased exponentially in recent years. Consequently, the security risks and vulnerabilities related to these unsecured IoT devices are also continuously increasing. Among the significant challenges facing the IoT environment is the threat of Distributed Denial of Service (DDoS) attacks. Several solutions are available in the literature to detect DDoS attacks. However, these detection mechanisms can easily be evaded by attackers using advanced tools and techniques, posing difficulty in detecting such lethal attacks in real time. Therefore, this paper proposes a novel distributed ensemble method for detecting lethal IoT traffic-based DDoS attacks. This method comprises two key stages: first, developing a distributed ensemble method using the breathtaking capabilities of the H2O.ai distributed machine learning platform and the ensemble learning technique. Secondly, this method was deployed on the Apache Storm stream processing framework, to swiftly analyze incoming network streams and categorize them into eleven distinct classes, including benign traffic and ten types of attacks, in near real time. The proposed method accurately identifies specific target categories within a multi-attack classification scenario by utilizing the expertise of various models. Ultimately, the prediction for a target class is determined based on the model with the highest detection rate. The effectiveness of this method has been examined using different configured scenarios. The experimental results show that our method can identify various attack categories more accurately with 99%+ accuracy and 8.45 s quicker than non-ensemble methods.

近年来,物联网(IoT)设备的广泛应用呈指数级增长。因此,与这些不安全的物联网设备相关的安全风险和漏洞也在不断增加。物联网环境面临的重大挑战之一就是分布式拒绝服务(DDoS)攻击的威胁。文献中有几种检测 DDoS 攻击的解决方案。然而,这些检测机制很容易被使用先进工具和技术的攻击者规避,给实时检测此类致命攻击带来了困难。因此,本文提出了一种新型分布式集合方法,用于检测基于物联网流量的致命 DDoS 攻击。该方法包括两个关键阶段:首先,利用 H2O.ai 分布式机器学习平台的惊人能力和集合学习技术开发分布式集合方法。其次,将该方法部署在 Apache Storm 流处理框架上,以近乎实时的方式快速分析传入的网络流,并将其分为 11 个不同的类别,包括良性流量和 10 种攻击类型。通过利用各种模型的专业知识,所提出的方法能在多攻击分类场景中准确识别特定的目标类别。最终,根据检测率最高的模型确定目标类别的预测结果。我们使用不同的配置场景对该方法的有效性进行了检验。实验结果表明,我们的方法能更准确地识别各种攻击类别,准确率达到 99%以上,比非组合方法快 8.45 秒。
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引用次数: 0
Co-Hydrothermal Carbonization of Sewage Sludge and Waste Pickling Acid to Produce a Novel Adsorbent for Hydrogen Sulfide Removal From Biogas 污水污泥和废酸洗酸的共水热碳化,生成一种用于去除沼气中硫化氢的新型吸附剂
IF 2.6 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-05-29 DOI: 10.1007/s13369-024-09129-9
Mayerlin Edith Acuña Montaño, Richard de Albuquerque Felizola Romeral, Maria de Almeida Silva, Kevin Nabor Paredes Canencio, Murilo Duma, Gustavo Rafael Collere Possetti, Renata Mello Giona, Alesandro Bail

In this work, a novel approach to the co-hydrothermal carbonization (HTC) process is presented. A laboratory-scale autoclave reactor was used as an open-loop recycling station (OLORS) operating with an unusual blend formed by sewage sludge and an acidic residue from the electroplating industry with a high concentration of iron and zinc chlorides. An in situ impregnated hydrochar was successfully produced and evaluated as adsorbent in H2S removal from a synthetic biogas achieving performance of up to 65% in reducing H2S concentration after 260 min of contact in a static system. The standard gaseous mixture containing 3000 ppmv of H2S was placed into contact with the powdered hydrochar in a batch system, and the decrease in the area ratio between H2S area peak and total area peak was monitored by gas chromatography as a function of time. The best performance was achieved by the hydrochar HC-5 and may be related to the type of chemical species formed on the surface of the adsorbent. The hydrochars were characterized by XRD, SEM/EDS, N2 adsorption–desorption, and elemental analysis (CHN). Although the hydrochars did not present a high specific area (3.0–22.0 m2 g−1), in general, the massive deposition of iron and zinc chlorides on its surface, reaching up to 13.6 and 6.41 wt.%, respectively, rules the performance of the novel adsorbents. The OLORS approach highlights some aspects of sustainability due to the co-processing of two complex residues to produce a material capable of removing H2S from a synthetic biogas mixture in a static batch system.

在这项研究中,介绍了一种新型的共水热碳化(HTC)工艺。实验室规模的高压釜反应器被用作开环回收站(OLORS),使用由污水污泥和电镀工业酸性残渣(含高浓度的铁和锌氯化物)形成的不寻常混合物。成功生产并评估了一种原位浸渍炭吸附剂,用于去除合成沼气中的 H2S,在静态系统中接触 260 分钟后,降低 H2S 浓度的性能高达 65%。在批处理系统中,将含有 3000 ppmv H2S 的标准气体混合物与粉末状水碳接触,并通过气相色谱法监测 H2S 面积峰与总面积峰之间的面积比随时间的变化而减少的情况。氢炭 HC-5 的性能最佳,这可能与吸附剂表面形成的化学物种类型有关。通过 XRD、SEM/EDS、N2 吸附-解吸和元素分析(CHN)对水炭进行了表征。虽然水成渣的比表面积(3.0-22.0 m2 g-1)并不高,但总的来说,铁和锌的氯化物在其表面大量沉积,分别达到 13.6 和 6.41 wt.%,这就决定了新型吸附剂的性能。OLORS 方法突出了可持续发展的某些方面,因为它将两种复杂的残留物共同处理,生产出一种材料,能够在静态批处理系统中去除合成沼气混合物中的 H2S。
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引用次数: 0
Fatigue Evaluation of Sulphate-Attacked Industrial Waste-Based Concrete Using Concrete Damaged Plasticity Model 利用混凝土损伤塑性模型对受硫酸盐侵蚀的工业废料混凝土进行疲劳评估
IF 2.6 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-05-29 DOI: 10.1007/s13369-024-09149-5
Matthew Zhi Yeon Ting, Kwong Soon Wong, Muhammad Ekhlasur Rahman, Meheron Selowara Joo

Sulphate attack is a major cause of concrete deterioration in marine environments and its interaction with wave-induced cyclic loading exacerbates the damage. This study has evaluated strengths and fatigue performance (i.e. fatigue life, strain and residual displacement) of sulphate-attacked concrete containing silicomanganese slag, fly ash (FA) and silica fume (SF). Compressive strength, tensile strength and sulphate profile of sulphate-attacked concrete were measured experimentally. Sulphate-induced damage constitutive relations were formulated and used with concrete damaged plasticity (CDP) model to simulate fatigue loading. Experiment showed that incorporating silicomanganese slag lowered sulphate resistance by 4.8–6.6% due to increased sulphate intrusion, but synergy with FA and SF enhanced the resistance by 7.3–13.8% at 365 days. The sulphate penetration depth was 0–20 mm, and the intruded sulphate increased exponentially over time. To evaluate fatigue loading in CDP model, the non-uniform damage was determined as correlation between strength degradation and integral area of sulphate profile. Numerical results were in good agreement with experimental data from literature, with differences of 5.8–26.2% in fatigue life, 9.1–30.1% in fatigue strain and 18.1–41.9% in residual displacement. In long-term deterioration, numerical analysis found that increasing sulphate concentration significantly shortened fatigue life. Despite silicomanganese slag lowered concrete sulphate and fatigue resistance, the inclusion of FA and SF improved the durability and sustainability of concrete for potential marine applications.

硫酸盐侵蚀是海洋环境中混凝土老化的一个主要原因,它与波浪引起的循环荷载相互作用,加剧了损害。本研究评估了含硅锰渣、粉煤灰(FA)和硅灰(SF)的硫酸盐侵蚀混凝土的强度和疲劳性能(即疲劳寿命、应变和残余位移)。实验测量了硫酸盐侵蚀混凝土的抗压强度、抗拉强度和硫酸盐剖面。制定了硫酸盐诱导的损伤构成关系,并与混凝土损伤塑性(CDP)模型一起用于模拟疲劳加载。实验表明,掺入硅锰渣后,由于硫酸盐侵入增加,抗硫酸盐能力降低了 4.8-6.6%,但与 FA 和 SF 协同作用后,在 365 天时抗硫酸盐能力提高了 7.3-13.8%。硫酸盐渗透深度为 0-20 毫米,随着时间的推移,侵入的硫酸盐呈指数增长。为了评估 CDP 模型中的疲劳荷载,非均匀损伤是根据强度退化与硫酸盐剖面积分面积之间的相关性确定的。数值结果与文献中的实验数据十分吻合,疲劳寿命相差 5.8-26.2%,疲劳应变相差 9.1-30.1%,残余位移相差 18.1-41.9%。数值分析发现,在长期劣化过程中,硫酸盐浓度的增加会显著缩短疲劳寿命。尽管硅锰渣降低了混凝土的抗硫酸盐和抗疲劳性能,但加入 FA 和 SF 改善了混凝土的耐久性和可持续性,使其具有潜在的海洋应用价值。
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引用次数: 0
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Arabian Journal for Science and Engineering
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