This study presents a comprehensive life assessment of a Process Water Boiler affected by High-Temperature Hydrogen Attack (HTHA) after over 27 years of continuous operation. Constructed primarily from C-0.5Mo steel and subjected to elevated hydrogen partial pressures and temperatures up to 346.5 °C, the boiler was evaluated using a combination of advanced Non-Destructive Testing (NDT) techniques—Phased Array Ultrasonic Testing with Total Focusing Method (PAUT-TFM) and Magnetic Particle Inspection (MPI)—alongside hardness measurements and metallographic analysis. The PAUT-TFM revealed progressive HTHA damage in critical regions, with estimated damage progression rates ranging from 0.1 to 7.6 mm/year over a 10-month monitoring period. MPI confirmed the presence of a surface-breaking crack in the longitudinal weld near the inlet, accompanied by subsurface blistering and microcracking. Hardness testing identified significant softening, particularly at the inlet, with values falling below the typical hardness threshold for C-0.5Mo steel (157 HV), indicative of decarburization. Metallographic analysis corroborated these findings, revealing increased ferrite content and carbide depletion in HTHA-prone zones. The integration of destructive and non-destructive assessments confirms that the material has entered an advanced and irreversible degradation phase. Given the high structural risk and limited feasibility of repairs, the study recommends targeted component replacement using hydrogen-resistant alloys such as 1.25Cr-0.5Mo, guided by thermal exposure assessments and Nelson Curves. These findings emphasize the critical importance of early detection, informed material selection, strategic maintenance, and replacement planning to ensure long-term operational safety and reliability in hydrogen-intensive environments.
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