Grade 91 steel is widely used in the power plants for high-temperature applications. The tested specimens were fabricated from base metal and welded portions of Grade 91 steel for conducting tensile and creep tests in the temperature range of 575–675 °C and the stress range of 60–220 MPa, respectively. Understanding the creep deformation behaviour of Grade 91 steel up to rupture at different applied stresses is essential for ensuring reliable creep life and safe operation of the structural components of the power plants. The rupture times were obtained from 15 h to 5208 h for the samples of BM and WM. The stress dependence of minimum creep rate and rupture time is followed the Norton power law and the stress exponents were found in the range of 4.6–19.3 for the temperature range of 575–675 °C. The strain-hardening exponent is also substantially increased at 625 °C during tensile behaviour, which presence of MX precipitates. The higher stress exponent resulted at 575 °C and 625 °C, is mainly due to interaction of dislocations with the precipitates and grain boundaries. Furthermore, threshold stress analysis is performed for the base metal and weld joints to find the operating mechanism of creep. By considering threshold stresses, the true stress exponents are found to be approximately 4.6 and 5.1 within the temperature range of 575–675 °C, confirmed as dislocation climb is the rate-controlling mechanism of creep. The minimum creep rate and rupture time data followed Monkman-Grant relationship. The selected samples were taken for characterization using optical microscopy and scanning electron microscopy. The elemental compositions of the precipitates were analyzed using energy dispersive X-ray spectroscopy. This study gives an understanding of the role of microstructure on creep rupture behaviour of Grade 91 steel in the base metal and weld joints.
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