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Strategies for Biomethane Purification: A Critical Review and New Approaches 生物甲烷净化策略:综述与新途径
IF 5.9 3区 工程技术 Q1 AGRONOMY Pub Date : 2025-04-26 DOI: 10.1111/gcbb.70040
Lolo Errol Molatudi, Thokozani Justin Kunene, Tebogo Mashifana

The global shift towards clean energy emphasizes waste valorization as a key to achieving sustainable development goals. Biomethane production from organic waste not only converts waste to energy but also reduces greenhouse gas emissions. The growth trajectory of sustainability and environmental protection highlights the significance of energy valorization in anaerobic digestion to produce biomethane and digestate. A 2019 UN report noted that 17% of global food production, equating to 1.0 billion tons, became waste, with major contributions from food waste (61%), households (26%), and food services (13%). The value derived from biomethane, carbon dioxide, nitrogen, ammonia, and manure underscores the need for economically sustainable valorization pathways to attract investment and ensure market viability. Research into purifying biogas for diverse applications has advanced, with technologies such as membranes, genetic manipulation, and metabolic engineering showing potential for improving biogas conversion. Enhanced membrane technologies promise improved biogas quality and efficiency. This review focuses on developing a microscale biogas purification plant and examining processes such as amine scrubbing, absorption, adsorption, and membrane separation as promising methods.

全球向清洁能源的转变强调废物增值是实现可持续发展目标的关键。从有机废物中生产生物甲烷不仅可以将废物转化为能源,还可以减少温室气体排放。可持续发展和环境保护的增长轨迹凸显了厌氧消化生产生物甲烷和消化物的能量增值的重要性。2019年联合国的一份报告指出,全球粮食产量的17%,相当于10亿吨,成为废物,主要来自食物垃圾(61%)、家庭(26%)和食品服务(13%)。从生物甲烷、二氧化碳、氮、氨和粪便中获得的价值强调了经济上可持续的价值增值途径的必要性,以吸引投资并确保市场可行性。随着膜、基因操作和代谢工程等技术显示出改善沼气转化的潜力,对各种应用的沼气净化研究取得了进展。增强膜技术有望改善沼气质量和效率。本文重点介绍了微型沼气净化装置的开发,并对氨洗涤、吸收、吸附和膜分离等方法进行了研究。
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引用次数: 0
Strategy for Sustainable Bio-Value Chain Development: Algal Biomass Utilization Without Inhibitory Effects on Lactic Acid Production via Efficient Diluted Acid Hydrolysis of Brown Macroalga 可持续生物价值链发展战略:褐藻高效稀酸水解对乳酸生产无抑制作用的藻类生物质利用
IF 5.9 3区 工程技术 Q1 AGRONOMY Pub Date : 2025-04-25 DOI: 10.1111/gcbb.70038
Jihyun Bae, Jeongho Lee, Hyeok Ki Kwon, Giwon Lee, Taek Lee, Hyun Gyu Lim, Sang Woo Seo, Gyoo Yeol Jung, Hah Young Yoo, Chulhwan Park

Saccharina japonica, one of the most widely cultivated brown algae species, is considered a promising biorefinery feedstock due to its high carbohydrate content. Dilute acid hydrolysis can be performed to recover sugars from S. japonica; however, the impact of sugar derivatives (potential inhibitors) generated during the hydrolysis process on lactic acid production remains unexplored. In this study, the inhibitory effects of sugar derivatives on the fermentation performance of Lacticaseibacillus rhamnosus were systematically examined to enhance the bioconversion efficiency of S. japonica. Firstly, the sugar derivatives present in S. japonica hydrolysate were identified, revealing the presence of acetic acid, formic acid, and furfural. Subsequently, their inhibitory effects on lactic acid production were assessed, demonstrating significant inhibition (p < 0.05) at the following concentrations: > 2 g/L acetic acid, > 0.5 g/L formic acid, and > 1 g/L furfural. Based on the information, 5% H2SO4 was determined to be the optimal solvent for S. japonica hydrolysis, enabling the production of hydrolysate with high fermentable sugar content and minimal sugar derivatives: 23.23 g/L mannitol, 0.86 g/L glucose, 0.21 g/L acetic acid, 0.14 g/L formic acid, and no detectable furfural. The resulting S. japonica hydrolysate contained sugar derivatives at non-inhibitory levels, allowing for direct application to fermentation without detoxification. As a result, lactic acid production and yield were determined to be 18.26 g/L and 92.3%, respectively, comparable to the control group (17.32 g/L and 87.6%). This study addresses a critical knowledge gap in the bioconversion of macroalgae to lactic acid by elucidating the effects of sugar derivatives on fermentation performance.

糖藻(Saccharina japonica)是种植最广泛的褐藻之一,由于其碳水化合物含量高,被认为是一种有前途的生物炼制原料。用稀酸水解法可回收粳稻中的糖;然而,在水解过程中产生的糖衍生物(潜在抑制剂)对乳酸生产的影响仍未被探索。本研究系统研究了糖衍生物对鼠李糖乳杆菌发酵性能的抑制作用,以提高稻瘟病菌的生物转化效率。首先,鉴定了粳稻水解液中存在的糖衍生物,揭示了乙酸、甲酸和糠醛的存在。随后,评估了它们对乳酸生成的抑制作用,在以下浓度下显示出显著的抑制作用(p < 0.05): 2 g/L乙酸,0.5 g/L甲酸和1 g/L糠醛。结果表明,以5% H2SO4为最佳水解溶剂,可得到高糖水解产物,糖衍生物最低,甘露醇23.23 g/L,葡萄糖0.86 g/L,乙酸0.21 g/L,甲酸0.14 g/L,糠醛无检出。由此产生的粳稻水解液含有无抑制水平的糖衍生物,允许直接应用于发酵而不解毒。结果表明,乳酸产量和产率分别为18.26 g/L和92.3%,与对照组(17.32 g/L和87.6%)相当。本研究通过阐明糖衍生物对发酵性能的影响,解决了大型藻类生物转化为乳酸的关键知识缺口。
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引用次数: 0
Assessing Feedstock Availability and Economic Feasibility of Utilizing Forest Biomass for Biochar Production in Stationary and Portable Systems in Michigan 评估密歇根州固定式和便携式系统中利用森林生物质生产生物炭的原料有效性和经济可行性
IF 5.9 3区 工程技术 Q1 AGRONOMY Pub Date : 2025-04-25 DOI: 10.1111/gcbb.70030
Nafisa N. Ahmed, Raju Pokharel, Jessica Miesel, Christopher M. Saffron

The accumulation of small-diameter and low-value trees and logging residues can negatively impact forest health by increasing the risks of pests, diseases, and wildfires. Biochar production presents a potential solution by creating markets for these underutilized resources. However, there is limited information on market dynamics and the influence of subregional conditions on the use of forest biomass for biochar. The study identified potential locations for biochar production and developed procurement zones using delivered wood prices to evaluate biomass availability and biochar application. The minimum selling prices (MSP) for biochar were calculated for local applications to assess the cost savings. Under a baseline scenario with an average delivered biomass price of $23.25 per green ton, stationary facilities produced 71% more biochar than the estimated requirements in the Upper Peninsula (UP) but only 10% more in the Lower Peninsula (LP). Portable units, however, produced less biochar than the required application in both regions, with deficits of 4% in the UP and 50% in the LP. While stationary facilities are more cost-effective and scalable, portable units can procure more biomass and offer greater opportunities for land application of biochar. Despite a lower MSP for stationary facilities, portable units could provide a more economical option by reducing investment costs and risks. The study recommends establishing portable units in the UP and stationary facilities in the LP to optimize forest biomass procurement and biochar production in Michigan. This analysis contributes to understanding resource availability and the potential utilization of forest biomass for biochar in Michigan.

小直径和低价值树木的积累以及伐木残留物会增加虫害、疾病和野火的风险,从而对森林健康产生负面影响。通过为这些未充分利用的资源创造市场,生物炭生产提供了一个潜在的解决方案。但是,关于市场动态和分区域条件对利用森林生物量生产生物炭的影响的资料有限。该研究确定了生物炭生产的潜在地点,并利用交付的木材价格开发了采购区,以评估生物质的可用性和生物炭的应用。计算了生物炭的最低销售价格(MSP),以评估当地应用的成本节约。在平均生物质交付价格为每绿色吨23.25美元的基线情景下,固定设施产生的生物炭比上半岛(UP)的估计需求多71%,但在下半岛(LP)只多10%。然而,在这两个地区,便携式装置产生的生物炭比所需的施用要少,在上游和下游分别减少了4%和50%。虽然固定式设施更具成本效益和可扩展性,但便携式装置可以获得更多的生物质,并为生物炭的土地应用提供更大的机会。尽管固定设备的MSP较低,但便携式设备可以通过降低投资成本和风险提供更经济的选择。该研究建议在上游建立便携式装置,在下游建立固定设施,以优化密歇根州的森林生物质获取和生物炭生产。这一分析有助于了解密歇根州森林生物量的可利用性和潜在的生物炭利用潜力。
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引用次数: 0
Incorporating Biochar Into Biogeochemical Models: Achievements and Challenges 将生物炭纳入生物地球化学模型:成就与挑战
IF 5.9 3区 工程技术 Q1 AGRONOMY Pub Date : 2025-04-25 DOI: 10.1111/gcbb.70037
Amanda Ronix, Eduardo Carvalho da Silva Neto, Carlos Eduardo Pellegrino Cerri, Agnieszka Ewa Latawiec, João Luís Nunes Carvalho

In the last two decades, several studies have utilized biogeochemical models to evaluate the impact of different edaphoclimatic conditions on soil carbon storage and the dynamics of soil organic carbon. At the same time, biochar, a carbon-rich material obtained from the pyrolysis of biomass residues, has been identified as a promising carbon sequestration material. However, current models do not adequately incorporate the role of biochar in soil management. In this context, the current state of research on biogeochemical models that include the entry of biochar into soil has been characterized. The research indicated that the development of studies on the topic “biochar” is widely explored, with 4259 papers being identified using the first search filter. Specifically, searching for studies that mentioned terms related to biogeochemical models for estimating soil carbon stock, it was observed that a small number of the studies (N = 46) considered the entry of biochar into the models. Although most studies have used the RothC model to simulate biochar within biogeochemical models, biochar inputs have also been implemented in APSIM, EPIC, Century, DNDC, and other models, including those not primarily focused on soil carbon stock estimation. Among these studies, the minority included the results of calibration and validation of the models, which are paramount for the model's credibility. Therefore, efforts must be concentrated on solving the lack of valuable data to validate the models. Data from long-term field experiments that consider interactions between crop and climate conditions are highly desirable. The possibility of increasing carbon stocks by incorporating biochar into the soil could promote environmental and financial gains, and biogeochemical models that consider the incorporation of biochar are valuable tools for decision-makers.

近二十年来,利用生物地球化学模型研究了不同土壤气候条件对土壤碳储量和土壤有机碳动态的影响。与此同时,生物炭作为一种由生物质残渣热解得到的富碳物质,被认为是一种很有前途的固碳材料。然而,目前的模型没有充分考虑生物炭在土壤管理中的作用。在此背景下,对包括生物炭进入土壤在内的生物地球化学模型的研究现状进行了评述。研究表明,“生物炭”这一主题的研究得到了广泛的探索,使用第一种搜索过滤器识别出4259篇论文。具体来说,在搜索涉及生物地球化学模型估算土壤碳储量相关术语的研究时,发现少数研究(N = 46)考虑将生物炭纳入模型。虽然大多数研究在生物地球化学模型中使用RothC模型来模拟生物炭,但在APSIM、EPIC、Century、DNDC和其他模型中也实现了生物炭输入,包括那些不主要关注土壤碳储量估算的模型。在这些研究中,少数包括模型的校准和验证结果,这对模型的可信度至关重要。因此,必须集中精力解决缺乏有价值的数据来验证模型的问题。考虑作物与气候条件之间相互作用的长期田间试验数据是非常可取的。通过将生物炭纳入土壤增加碳储量的可能性可以促进环境和经济收益,考虑将生物炭纳入土壤的生物地球化学模型对决策者来说是有价值的工具。
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引用次数: 0
Burning Up the Carbon Sink: How the EU's Forest Biomass Policy Undermines Climate Mitigation 烧毁碳汇:欧盟的森林生物质政策如何削弱气候减缓效果
IF 5.9 3区 工程技术 Q1 AGRONOMY Pub Date : 2025-04-19 DOI: 10.1111/gcbb.70035
M. S. Booth, J. Giuntoli

While burning wood for heat and electricity constitutes the largest source of renewable energy in the EU, forest biomass harvesting is weakening the EU's forest carbon sink, and some Member States have lost their net forest sink completely, including heavily forested countries like Estonia and Finland. A European Commission 2016 impact assessment for bioenergy under the EU's Renewable Energy Directive predicted the forest sink would shrink as biomass use increased, even if sustainability criteria were required. Nonetheless, the EU adopted criteria that consider “sustainable” forest biomass to have zero carbon emissions, rendering EU and UK treatment of biomass inconsistent with IPCC's Guidance for National Greenhouse Gas Inventories. Renewable energy incentives have increased biomass use for electricity generation 1100% since 1990, but residential heating, which is ungoverned by any criteria, still represents the largest use of wood for energy in the EU. Incentives for bioenergy with carbon capture and storage (BECCS), which is intended to deliver “negative emissions,” will likely increase pressure on forests. Although IPCC Guidance is clear that BECCS fueled with forest biomass does not remove net CO2 from the atmosphere just because carbon has been stored belowground, EU and UK climate policies rely on large-scale deployment of BECCS to meet climate targets. Bioenergy use cuts across environmental, energy, and climate policy domains; thus, reversing the accelerating decline of the forest carbon sink will require significantly better integration of renewable energy policies with climate targets and ensuring that biomass policies are aligned with international emissions reporting. Policymakers can reduce pressure on forests by disqualifying forest biomass from counting toward renewable energy targets, reducing subsidies for wood-burning, and adopting forest management policies that prioritize carbon sequestration and biodiversity. Reducing biomass harvesting and reallocating the billions currently spent on bioenergy subsidies to solar, wind, and geothermal energy is essential for restoring forests and achieving climate targets.

虽然燃烧木材供热和发电是欧盟最大的可再生能源来源,但森林生物质的采伐正在削弱欧盟的森林碳汇,一些成员国已经完全失去了森林净汇,包括爱沙尼亚和芬兰等森林茂密的国家。欧盟委员会 2016 年根据欧盟《可再生能源指令》对生物能源进行的影响评估预测,随着生物质使用量的增加,即使要求制定可持续性标准,森林碳汇也会减少。然而,欧盟采用的标准认为 "可持续 "森林生物质的碳排放量为零,这使得欧盟和英国对生物质的处理不符合 IPCC 的《国家温室气体清单指南》。自 1990 年以来,可再生能源激励措施已使生物质发电的使用量增加了 1100%,但不受任何标准约束的住宅供暖仍是欧盟最大的木材能源使用量。旨在实现 "负排放 "的碳捕集与封存(BECCS)生物能源激励措施可能会增加对森林的压力。尽管 IPCC 指南明确指出,以森林生物质为燃料的 BECCS 并不会因为碳已被储存在地下而从大气中清除净二氧化碳,但欧盟和英国的气候政策依赖大规模部署 BECCS 来实现气候目标。生物能源的使用涉及环境、能源和气候政策领域;因此,要扭转森林碳汇加速减少的趋势,就必须更好地将可再生能源政策与气候目标相结合,并确保生物质政策与国际排放报告相一致。政策制定者可以通过取消将森林生物质计入可再生能源目标的资格、减少对木材燃烧的补贴,以及采取优先考虑碳固存和生物多样性的森林管理政策来减少对森林的压力。减少生物质采伐,将目前用于生物能源补贴的数十亿资金重新分配给太阳能、风能和地热能,对于恢复森林和实现气候目标至关重要。
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引用次数: 0
Developing Marginal-Land-Based Bioeconomy Systems—A Design and Development Approach for Bio-Based Value Chains and Webs 发展边缘土地生物经济系统——基于生物价值链和网络的设计与开发方法
IF 5.9 3区 工程技术 Q1 AGRONOMY Pub Date : 2025-04-10 DOI: 10.1111/gcbb.70034
Valentin Schlecht, Ricardo Vargas-Carpintero, Moritz von Cossel, Iris Lewandowski

Industrial crops grown on marginal lands offer a potential source of low-iLUC feedstock for bio-based industries, supporting sustainable bioeconomic development. However, marginal-land-based bioeconomy systems face significant uncertainties at early stages, such as limited data, farmers' hesitancy to adopt novel crops, undeveloped markets and immature technologies. This study implements an integrated multi-criteria framework as a structured, multi-step approach to connect bio-based value chain components and stakeholders in marginal-land-based bioeconomy systems at the research level. The framework was applied within the EU Horizon project MIDAS to identify, evaluate and combine bio-based value chain components, with a case study in the Swabian Alb (southern Germany) demonstrating its potential for designing scalable bio-based value chains tailored to regional conditions. Key findings emphasise the importance of stakeholder collaboration, iterative design processes and context-specific criteria that address technical, economic, social and regulatory aspects. The approach, based on qualitative data and stakeholder input, offers critical insights into the feasibility of biomass-to-product pathways and serves as a foundation for advanced research. Future research needs to focus on expanding data availability, incorporating quantitative methods, and addressing economic and market factors, such as stakeholder willingness to produce feedstocks, to enhance the scalability and robustness of the findings and facilitate the establishment of sustainable bioeconomy systems on marginal lands.

在边际土地上种植的工业作物为生物基工业提供了低iluc原料的潜在来源,支持可持续的生物经济发展。然而,边缘土地生物经济系统在早期阶段面临着重大的不确定性,例如有限的数据、农民对采用新作物的犹豫、不发达的市场和不成熟的技术。本研究实施了一个集成的多标准框架,作为一个结构化的、多步骤的方法,在研究层面上连接边缘土地生物经济系统中基于生物的价值链组成部分和利益相关者。该框架在欧盟地平线项目MIDAS中得到应用,用于识别、评估和组合生物基价值链组件,并在斯瓦本Alb(德国南部)进行了案例研究,展示了其设计适合区域条件的可扩展生物基价值链的潜力。主要研究结果强调了利益相关者合作、迭代设计过程和解决技术、经济、社会和监管方面的具体环境标准的重要性。该方法基于定性数据和利益相关者的意见,提供了对生物质到产品途径可行性的关键见解,并为高级研究奠定了基础。未来的研究需要侧重于扩大数据的可用性,结合定量方法,并解决经济和市场因素,如利益相关者生产原料的意愿,以增强研究结果的可扩展性和稳健性,并促进在边缘土地上建立可持续的生物经济系统。
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引用次数: 0
Bioenergy Production From Sugarcane Straw: Implications for Soil-Related Ecosystem Services 利用甘蔗秸秆生产生物能源:对土壤相关生态系统服务的影响
IF 5.9 3区 工程技术 Q1 AGRONOMY Pub Date : 2025-04-08 DOI: 10.1111/gcbb.70032
Carlos Roberto Pinheiro Junior, João Luís Nunes Carvalho, Lucas Pecci Canisares, Ricardo de Oliveira Bordonal, Carlos Eduardo Pellegrino Cerri, Maurício Roberto Cherubin

Sugarcane straw removal for bioenergy production—especially second-generation ethanol—is shown to be a promising pathway for decarbonization. However, indiscriminate straw removal can negatively affect soil-related ecosystem services (SES), compromising the sustainability of the associated bioenergy production. Here, a comprehensive literature review was conducted to select and quantify the changes in agronomic and environmental indicators affected by low (≤ 1/3), moderate (> 1/3 to ≤ 2/3), and high (> 2/3) straw removal levels and the consequential impacts on eight SES. A quali-quantitative approach was developed to generate an impact matrix that provides the direction of the effects (negative, neutral, or positive) and the associated confidence levels. Overall, the lowest impact on SES occurs under low straw removal with a neutral effect on C storage, nutrient cycling, weed control, greenhouse gas (GHG) mitigation, and provision of food and bioenergy. Water regulation, erosion control, and maintenance of soil biodiversity were the SES most negatively affected by straw removal. Moderate and high levels of straw removal negatively impact the maintenance of SES and compromise the sustainability of sugarcane cultivation areas, except for pest control and soil GHG emission mitigation. Finally, it was also discussed how the negative impacts of straw removal on SES could be mitigated or even reversed through the adoption of best management practices, such as cover crops, organic amendments, biological products (e.g., use of phosphate-solubilizing bacteria and mycorrhizal fungi), reduced tillage, and machinery traffic control. Ultimately, the results of this study can be useful to guide decision-making by farmers, investors, stakeholders, and policymakers toward sustainable bioenergy production that contributes to a low-carbon economy and climate change mitigation.

去除甘蔗秸秆用于生物能源生产——尤其是第二代乙醇——被证明是一种很有前途的脱碳途径。然而,不加选择地去除秸秆会对与土壤相关的生态系统服务(SES)产生负面影响,损害相关生物能源生产的可持续性。本文通过文献综述,选取并量化低(≤1/3)、中(>; 1/3至≤2/3)、高(> 2/3)秸秆去除水平对8种SES农艺和环境指标的影响及其对SES的影响。开发了一种质量定量方法,以产生一个影响矩阵,提供影响的方向(消极、中性或积极)和相关的置信水平。总体而言,低秸秆去除对SES的影响最小,对碳储存、养分循环、杂草控制、温室气体(GHG)缓解以及粮食和生物能源供应的影响为中性。秸秆去除对土壤水分调节、侵蚀控制和生物多样性维持的负面影响最大。除虫害防治和减少土壤温室气体排放外,中等和高水平的秸秆清除会对SES的维持产生负面影响,并损害甘蔗种植区的可持续性。最后,还讨论了如何通过采用最佳管理做法,如覆盖作物、有机改良剂、生物制品(如使用磷肥增溶菌和菌根真菌)、减少耕作和机械交通管制,减轻或甚至扭转秸秆去除对SES的负面影响。最终,本研究的结果可用于指导农民、投资者、利益相关者和决策者的决策,以实现可持续的生物能源生产,从而有助于低碳经济和减缓气候变化。
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引用次数: 0
Enhancing Methane Production Through Co-Digestion of Sewage Sludge, Citrus Waste and Brewery Spend Grain With Natural Zeolite: Mechanisms and Microbiome Analysis 天然沸石共消化污泥、柑橘废弃物和啤酒厂废粮提高甲烷产量:机理和微生物组分析
IF 5.9 3区 工程技术 Q1 AGRONOMY Pub Date : 2025-04-07 DOI: 10.1111/gcbb.70029
Aleksandra Szaja, Agnieszka Montusiewicz, Agnieszka Cydzik-Kwiatkowska, Sylwia Pasieczna-Patkowska, Magdalena Lebiocka

The presented research is focused on evaluating the influence of adding clinoptilolite (Z) on the multi-component co-digestion (AcoD) of sewage sludge (SS), citrus waste represented by orange peel (OP) and brewery spent grain (BSG). The experiments were conducted under mesophilic conditions at 37°C in batch mode; 7 series with differing feedstock configurations were performed. The positive effect of Z was shown in each configuration, most strongly with SS:OP:BSG:Z. The production of methane was enhanced by 81%, in comparison to the co-digestion of SS:OP:BSG without Z, reaching 362.4 mL CH4/g volatile solids (VS). The kinetics was also improved as the methane production rate increased to a similar extent, amounting to 17.3 mL CH4/g VS d. Moreover, it was observed that the lag phase was shortened and the contents of both limonene and phenols were reduced. The composition of the microbial communities was significantly altered by the addition of Z in AcoD of SS:OP and SS:OP:BSG. Therein, a unique microbiome structure with the highest percentage of unidentified sequences was found. The beneficial effect of Z was multifaceted and related to the reduction of the stress caused by the presence of limonene and phenols as well as the syntrophic relation between the microorganisms.

研究了投加斜沸石(Z)对污水污泥(SS)、柑桔废弃物(OP)和啤酒废粮(BSG)多组分共消化(AcoD)的影响。实验在37℃的中温条件下分批进行;采用不同的原料配置进行了7个系列的试验。Z的积极作用在每种构型中都表现出来,其中SS:OP:BSG:Z的作用最强。与不加Z的SS:OP:BSG共消化相比,甲烷产量提高了81%,达到362.4 mL CH4/g挥发性固体(VS)。甲烷产率达到17.3 mL CH4/g VS d,反应动力学也有所改善,滞后期缩短,柠檬烯和酚类物质含量均有所降低。SS:OP和SS:OP:BSG的AcoD中添加Z显著改变了微生物群落的组成。其中,发现了具有最高百分比未识别序列的独特微生物组结构。Z的有益作用是多方面的,与减少柠檬烯和酚类物质引起的胁迫以及微生物之间的共生关系有关。
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引用次数: 0
Biochar Production From Vineyard Pruning Waste by Oxidative Torrefaction 用氧化焙烧法从葡萄园修剪废弃物中生产生物炭
IF 5.9 3区 工程技术 Q1 AGRONOMY Pub Date : 2025-04-01 DOI: 10.1111/gcbb.70031
Gizem Özer, Neslihan Duranay

The torrefaction process for producing biochar from waste biomass has garnered significant attention in recent years. However, economic constraints hinder the broader adoption of this process. One such constraint is the requirement for an inert atmosphere during torrefaction. This study aimed to evaluate the feasibility of torrefying vineyard pruning waste in an oxygen-rich environment. Torrefaction of waste vine shoots was conducted in a fixed-bed reactor, utilizing a carrier gas medium with varying O2 concentrations (0% to 21%) at process temperatures of 220°C, 250°C, and 280°C. Proximate and elemental analyses revealed that the torrefaction temperature is the key variable influencing biochar yield. Moreover, under mild torrefaction conditions, an increase in the carrier gas O2 concentration had a lesser impact on product yield compared with process temperature. Thus, it can be inferred that combustion gases and gases generated under mild torrefaction conditions could serve as carrier gases for a more cost-effective torrefaction process. Under oxidative conditions, the total biomass energy recovery was measured at 87.3% ± 1.7% for low temperatures and short torrefaction durations.

近年来,从废弃生物质中生产生物炭的焙烧过程引起了人们的极大关注。然而,经济限制阻碍了这一进程的广泛采用。其中一个限制条件是在焙烧过程中对惰性气氛的要求。本研究旨在评价在富氧环境下提纯葡萄园修剪废弃物的可行性。在固定床反应器中,利用不同O2浓度(0%至21%)的载气介质,在220°C、250°C和280°C的工艺温度下对废弃藤苗进行焙烧。比邻分析和元素分析表明,热解温度是影响生物炭产率的关键变量。此外,在轻度焙烧条件下,与工艺温度相比,载体气O2浓度的增加对产品收率的影响较小。因此,可以推断,燃烧气体和在温和焙烧条件下产生的气体可以作为载气,以实现更具成本效益的焙烧过程。在低温短发酵条件下,总生物质能量回收率为87.3%±1.7%。
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引用次数: 0
Harvest Time Optimization for Biomass Productivity and Combustion Quality of Tall Wheatgrass in a Semi-Arid Mediterranean Environment 在半干旱地中海环境中优化收割时间,提高高麦草的生物质生产率和燃烧质量
IF 5.9 3区 工程技术 Q1 AGRONOMY Pub Date : 2025-03-24 DOI: 10.1111/gcbb.70028
Recep Irfan Nazli, Mihrab Polat, Asiye Sena Cavdar, Veyis Tansi

Optimizing harvest time has a significant impact on biomass productivity and combustion quality, making it essential to produce sustainable solid biofuel from perennial grasses. This study was conducted to determine the optimum harvest time in tall wheatgrass for the production of solid biofuel in a semi-arid Mediterranean environment by evaluating the effects of six different harvest times (November, January, March, May, July, and September) on biomass yield and combustion quality parameters over two growing seasons. Dry matter yield of the crop steadily increased from the November to May harvest, which approximately coincided with the end of the growing season, but then it was significantly reduced by both the July and September harvests. Additionally, the content of cell wall components (lignin, cellulose, and hemicellulose) and the lignin/holocellulose ratio gradually increased with the progression of maturity and senescence. In contrast, ash, moisture, and mineral (N, P, K, Ca, Mg, S, Si, Cl, Na, and Zn) contents tended to decrease from the May to September harvest. In this regard, the September harvest significantly improved combustion quality by reducing the contents of ash, mineral, and moisture, the risks of slagging, aerosol formation, and corrosion, and increasing the lignin content and lignin/holocellulose ratio, despite causing a 22% yield loss in comparison to the May harvest. These results suggest that the September harvest may be primarily preferred for the sustainable solid biofuel production from tall wheatgrass in the dry marginal lands of the Mediterranean region.

优化收获时间对生物质生产力和燃烧质量有重大影响,因此从多年生草中生产可持续的固体生物燃料至关重要。本研究通过评估6个不同的收获时间(11月、1月、3月、5月、7月和9月)对两个生长季节的生物质产量和燃烧质量参数的影响,确定了半干旱地中海环境中用于生产固体生物燃料的高小麦草的最佳收获时间。干物质产量在11月至5月收获期间稳步增长,与生长季结束时间基本一致,但随后在7月和9月收获期间显著下降。随着成熟和衰老,细胞壁组分(木质素、纤维素和半纤维素)含量和木质素/全纤维素比逐渐升高。灰分、水分和矿物(N、P、K、Ca、Mg、S、Si、Cl、Na、Zn)含量在5 ~ 9月间呈下降趋势。在这方面,9月份的收获显著改善了燃烧质量,减少了灰分、矿物和水分的含量,降低了结渣、气溶胶形成和腐蚀的风险,增加了木质素含量和木质素/全纤维素比,尽管与5月份的收获相比,产量损失了22%。这些结果表明,9月份的收获可能是地中海地区干旱边缘土地上高小麦草可持续固体生物燃料生产的首选。
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引用次数: 0
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Global Change Biology Bioenergy
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