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Atomic layer deposition (ALD) of palladium: from processes to applications 钯原子层沉积(ALD):从工艺到应用
IF 10.8 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-11-15 DOI: 10.1080/10408436.2023.2273463
Clément Lausecker, David Muñoz-Rojas, Matthieu Weber
Atomic layer deposition (ALD) has been successfully used for the deposition of palladium (Pd) thin films and nanostructures, with a wide range of applications in fields such as microelectronics, en...
原子层沉积技术(ALD)已成功地应用于钯(Pd)薄膜和纳米结构的沉积,在微电子、光电等领域有着广泛的应用。
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引用次数: 0
The curious case of polyaniline-graphene nanocomposites: a review on their application as exceptionally conductive and gas sensitive materials 聚苯胺-石墨烯纳米复合材料的奇特案例:作为异常导电和气敏材料的应用综述
2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-11-14 DOI: 10.1080/10408436.2023.2274900
Abir Boublia, Zahir Guezzout, Nacerddine Haddaoui, Michael Badawi, Ahmad S Darwish, Tarek Lemaoui, Seif El Islam Lebouachera, Krishna Kumar Yadav, Maha Awjan Alreshidi, Jari S. Algethami, Mohamed Abbas, Fawzi Banat, Inas M AlNashef, Byong-Hun Jeon, Yacine Benguerba
AbstractThis review presents a brief overview of the electrical and gas-sensor properties of polyaniline (PANI) and graphene-based nanocomposites, their application as gas detection materials, and their underlying sensing mechanisms. Several studies have shown that graphene-based PANI gas sensors perform remarkably well at ambient temperatures, are energy efficient, and are inexpensive. The electrical and gas sensing properties of PANI/graphene nanocomposites offer improved responsiveness, durability, and other detection capabilities in sensor-based devices at room temperature. Moreover, the electrical conductivity and gas sensor properties may be controlled by the synthesis methods and the form and type of graphene. This review provides a new framework for the development of new nanomaterials based on PANI/graphene, which will advance their development and industrialization in the environment.Keywords: PANI/graphene nanocompositesgrapheneelectrical propertiesgas sensing properties Disclosure statementNo potential conflict of interest was reported by the author(s).Additional informationFundingThe authors extend their appreciation to the Deanship of Scientific Research at King Khalid University (KKU) for funding this research through the Research Group Program Under the Grant Number: (R.G.P.2/588/44). The authors are thankful to the Deanship of Scientific Research at Najran University for funding this work, under the Research Groups Funding program grant code [NU/RG/SERC/12/45].
摘要本文综述了聚苯胺(PANI)和石墨烯基纳米复合材料的电和气敏性能、作为气体检测材料的应用及其潜在的传感机制。几项研究表明,基于石墨烯的聚苯胺气体传感器在环境温度下表现非常好,节能且价格低廉。聚苯胺/石墨烯纳米复合材料的电和气敏特性为室温下基于传感器的设备提供了更好的响应性、耐用性和其他检测能力。此外,石墨烯的电导率和气体传感器性能可以通过合成方法和石墨烯的形式和类型来控制。本文综述为基于聚苯胺/石墨烯的新型纳米材料的开发提供了一个新的框架,将推动其在环境中的开发和产业化。关键词:聚苯胺/石墨烯纳米复合材料石墨烯电特性气敏特性公开声明作者未报告潜在利益冲突。作者感谢哈立德国王大学(KKU)的科学研究主任通过研究小组计划资助本研究,资助编号:(R.G.P.2/588/44)。作者感谢Najran大学科学研究主任根据研究小组资助计划资助代码[NU/RG/SERC/12/45]资助这项工作。
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引用次数: 0
Ferrites and ferrite-based composites for energy conversion and storage applications 用于能量转换和存储的铁氧体和铁氧体基复合材料
2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-11-06 DOI: 10.1080/10408436.2023.2272963
Khadijat Olabisi Abdulwahab, Mohammad Mansoob Khan, James Robert Jennings
AbstractFerrites and ferrite-based composites are known for their fascinating magnetic properties, varied redox chemistry, good stability, and excellent catalytic properties, all of which make them useful for a growing range of energy-related applications. The present review provides a concise summary of the basic properties of ferrites, an overview of the applicable synthetic methods, and recent advances related to the application of ferrites and ferrite-based composites in photoelectrochemical cells, photocatalytic CO2 reduction, batteries, supercapacitors, and microbial fuel cells. Special emphasis is placed on materials prepared by modern techniques, including microwave-assisted synthesis, ultrasound-assisted and sonochemical methods, synthesis employing metal-organic framework precursors, and electrospinning methods. The effects of intrinsic magnetism and external magnetic fields on the efficiency of ferrites in selected energy applications are also highlighted. The review concludes with a future outlook for the field that proffers solutions to issues currently hindering the effective utilization of ferrites and ferrite-based composites in energy conversion and storage applications.HighlightsOverview of the preparation and electrochemical energy applications of ferrites and ferrite-based compositesRecent applications of ferrites in photoelectrochemical cells, photocatalytic CO2 reduction, batteries, supercapacitors, and microbial fuel cellsEffect of magnetism and external magnetic fields on the synthesis and electrochemical applications of ferritesKeywords: Ferritesbatteriessupercapacitorsphotoelectrochemical cellsmicrobial fuel cells Disclosure statementThe authors declare that there are no conflicts of interest.Additional informationFundingThis research was funded by Universiti Brunei Darussalam through grants UBD/RSCH/1.4/FICBF(b)/2021/035 and UBD/RSCH/URC/NIG/8.0/2021/001, and by the Islamic Development Bank (IsDB) through provision of a post-doctoral scholarship to Dr Khadijat Abdulwahab (IsDB reference no. SCHD-277).
摘要铁氧体和铁氧体基复合材料以其迷人的磁性、多样的氧化还原化学、良好的稳定性和优异的催化性能而闻名,这些都使它们在越来越多的能源相关应用中发挥着重要作用。本文简要介绍了铁氧体的基本性质、适用的合成方法,以及铁氧体和铁氧体基复合材料在光电化学电池、光催化CO2还原、电池、超级电容器和微生物燃料电池等方面的应用进展。特别强调了用现代技术制备的材料,包括微波辅助合成、超声辅助和声化学方法、金属有机框架前体合成和静电纺丝方法。本文还重点讨论了本征磁场和外加磁场对铁氧体在特定能量应用中效率的影响。最后,对该领域的未来前景进行了展望,提出了目前阻碍铁氧体和铁氧体基复合材料在能量转换和存储应用中有效利用的问题的解决方案。重点:铁氧体及铁氧体基复合材料的制备及电化学能源应用综述铁氧体在光电化学电池、光催化CO2还原、电池、超级电容器、微生物燃料电池等领域的研究进展磁性和外磁场对铁氧体合成及电化学应用的影响铁氧体电池超级电容器光电化学电池微生物燃料电池公开声明作者声明不存在利益冲突。本研究由文莱达鲁萨兰国大学通过赠款UBD/RSCH/1.4/FICBF(b)/2021/035和UBD/RSCH/URC/NIG/8.0/2021/001资助,并由伊斯兰开发银行(IsDB)通过向Khadijat Abdulwahab博士提供博士后奖学金(IsDB参考号:schd - 277)。
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引用次数: 0
Recent advances in 2D anode materials for Na-ion batteries from a theoretical perspective 钠离子电池二维负极材料的理论研究进展
2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-11-01 DOI: 10.1080/10408436.2023.2273465
Nidhi Verma, Pooja Jamdagni, Ashok Kumar, Sunita Srivastava, K Tankeshwar
AbstractNa-ion batteries (SIBs) are a promising replacement for lithium-ion batteries (LIBs) for low-cost and large-scale energy storage systems in the forthcoming years after additional in-depth examination and investigation. A significant part of the development of innovative anode materials and their in-depth understanding has come through simulations. Ab initio simulations based on density functional theory (DFT) have been proven to be a reliable, efficient, and cost-effective way to design new anode materials for SIBs. As a result of the identification of graphene, researchers and scientists were influenced to create new two-dimensional (2D) materials. On account of their distinctive physical and chemical properties, the broad expanse of surface, innovative electronic features, and charging ability of 2D materials attract much attention. Many of these characteristics are significant prerequisites for using anodes in batteries. Herein, based on recent research progress, we have reviewed the structures and electrochemical properties of 2D materials as anode for Na-ion batteries from a theoretical perspective. The effective methodologies for high-performance anode materials are provided based on the substantial literature and theoretical studies. Added to that, we have also explored the various techniques such as heterostructure, doping, defect- and strain-engineering of 2D materials for the improvement of the performance of these materials as anodes for SIBs.Keywords: 2D Materialsdensity functional theoryenergy storagespecific capacityanode materials AcknowledgementsNV thanks the CSIR for providing financial support in the form of a junior research fellowship (JRF). PJ gratefully acknowledges the UGC for D. S. Kothari Post-Doctoral Fellowship. The helpful discussions with Jaspreet Singh and Poonam Chauhan are highly acknowledged.Disclosure statementNo potential conflict of interest was reported by the author(s).
经过进一步深入的研究和研究,钠离子电池(SIBs)有望在未来几年替代锂离子电池(lib)用于低成本和大规模的储能系统。创新阳极材料的发展及其深入理解的一个重要部分是通过模拟。基于密度泛函理论(DFT)的从头算模拟已被证明是设计sib负极材料的一种可靠、高效和经济的方法。由于石墨烯的发现,研究人员和科学家们受到了创造新的二维(2D)材料的影响。二维材料由于其独特的物理和化学性质,其广阔的表面、创新的电子特性和充电能力备受关注。这些特性中的许多都是在电池中使用阳极的重要先决条件。本文基于近年来的研究进展,从理论角度综述了作为钠离子电池负极材料的二维材料的结构和电化学性能。在大量文献和理论研究的基础上,提出了高性能阳极材料的有效方法。此外,我们还探索了各种技术,如异质结构、掺杂、二维材料的缺陷和应变工程,以提高这些材料作为sib阳极的性能。关键词:二维材料密度泛函理论能量存储特定容量阳极材料感谢CSIR以初级研究奖学金(JRF)的形式提供资金支持。PJ感谢教资会为Kothari博士提供博士后奖学金。与Jaspreet Singh和Poonam Chauhan的有益讨论得到了高度认可。披露声明作者未报告潜在的利益冲突。
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引用次数: 1
Synthesis approaches of MXene based polymeric nano system for electromagnetic shielding Application- A review 电磁屏蔽用MXene基聚合物纳米体系的合成方法综述
2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-10-07 DOI: 10.1080/10408436.2023.2263485
Mayank Pandey, Kaili Gong, Deepthi Jayan K, Keqing Zhou
AbstractTwo dimensional (2D) nanomaterials brought an advancement in material world with respect to its excellent and unique properties. Recently the modification to form polymer nanocomposites by using 2D nanomaterials for many applications have grabbed attention of researchers. Among many 2D nanomaterials, MXenes is an excellent and fastest growing nanomaterial which is certainly a combination of transition metal carbides, nitrides and carbonitrides. Because of its excellent intrinsic properties, electrical conductivity, flexible and lightweight property and easy processability, MXene have attracted an attention of researchers. Polymer with the insertion of MXens, forms the polymer nanocomposites with enhanced and improved thermal, mechanical, electrical and morphological properties. The focus of this article is to bring the recent literature persistent to the general fabrication of MXene polymer System which includes different etching process. The present review report also provides the broad literature and recent research works to understand different synthesis approaches, structure and properties of MXene based polymer nanocomposites for electromagnetic interface (EMI) shielding applications including intrinsic and modified extrinsic properties. This review will be extensively helpful for the researchers to understand the basic properties and usage of MXene based polymer nanocomposites for EMI Shielding applications. The results of these review articles will serve as a storage for knowledge, facilitating the growth of research and advancement in the field of electromagnetic interface (EMI) shielding applications.Keywords: Multifunctional compositesNanocompositesEMI shieldingLayered structures Disclosure statementNo potential conflict of interest was reported by the authors.
摘要二维纳米材料以其优异而独特的性能引领了材料领域的发展。近年来,利用二维纳米材料进行改性制备聚合物纳米复合材料的研究受到了广泛的关注。在众多二维纳米材料中,MXenes是一种生长速度最快的优秀纳米材料,它是过渡金属碳化物、氮化物和碳氮化物的结合体。MXene由于其优异的固有性能、导电性、柔韧性和轻质性以及易加工性而受到了研究人员的关注。聚合物与MXens的插入,形成聚合物纳米复合材料具有增强和改善的热,机械,电学和形态性能。本文的重点是把最近的文献持续到MXene聚合物体系的一般制备,包括不同的蚀刻工艺。本文还介绍了MXene基聚合物纳米复合材料的合成方法、结构和性能,包括其内在和修饰的外在性能。本文综述将有助于研究人员了解MXene基聚合物纳米复合材料的基本特性和应用。这些综述文章的结果将作为知识的存储,促进电磁接口(EMI)屏蔽应用领域的研究和进步。关键词:多功能复合材料纳米复合材料电磁屏蔽层状结构公开声明作者未报告潜在利益冲突。
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引用次数: 0
Process-microstructure-corrosion of additively manufactured steels: a review 增材制造钢的工艺-显微组织-腐蚀研究进展
2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-09-23 DOI: 10.1080/10408436.2023.2255616
M.H Ghoncheh, A. Shahriari, N. Birbilis, M. Mohammadi
Among the alloy systems for the fabrication of metallic components using additive manufacturing (AM), steels as a broad family of alloys attract significant attention owing to their established mechanical and corrosion properties under various loading and environmental conditions. In an erosive/corrosive environment, the possible failure mechanisms necessitate consideration in materials selection and design. Although functional alloying elements are deliberately added to steels to improve corrosion resistance, the crucial role of initial microstructure and post-process heat treatments are equally critical and cannot be neglected. Specifically, the proper selection and optimization of AM process parameters are essential steps in minimizing microstructural defects. This comprehensive review provides a consolidated treatise of powder atomization techniques, AM process parameter control, rapid solidification principles, their roles on the as-built microstructure. The role of different phases and microstructures formed during post-process heat treatments, and corrosion behavior of various grades of AM steels are also presented. The review presents the interplay between process-microstructure-corrosion properties of the AM steels through the entire fabrication process - from powder feedstock to final AM product exposed to harsh environments. In the first section of this review paper, the authors comprehensively explain the important factors, which affect the processability and quality of AM steel components. In the second section, the authors focus on the microstructure of both as-printed and heat-treated AM steel products, the parameters which determine variations of the microstructure, the effect of microstructural features such as the grain size and the dendrite arm spacing on the mechanical properties, and the detrimental effect of inclusions embedded into the matrix. Finally, the third part of the paper is a comprehensive review of the corrosion of different types of stainless steels (316 L austenitic stainless steel, 420 martensitic stainless steel, martensitic precipitation-hardened stainless steels of 15-5 PH, 17-4 PH, and Corrax) fabricated by AM techniques.
在使用增材制造(AM)制造金属部件的合金系统中,钢作为一个广泛的合金家族,由于其在各种载荷和环境条件下的机械和腐蚀性能而引起了极大的关注。在侵蚀/腐蚀环境中,材料选择和设计时必须考虑可能的失效机制。虽然在钢中故意添加功能合金元素以提高耐腐蚀性,但初始组织和后处理的关键作用同样至关重要,不可忽视。具体而言,正确选择和优化增材制造工艺参数是减少微结构缺陷的必要步骤。本文综合评述了粉末雾化技术、增材制造工艺参数控制、快速凝固原理及其对成形组织的影响。本文还介绍了不同相的作用和加工后热处理过程中形成的显微组织,以及不同牌号AM钢的腐蚀行为。回顾了AM钢在整个制造过程中的工艺-微观结构-腐蚀性能之间的相互作用-从粉末原料到暴露于恶劣环境的最终AM产品。在本文的第一部分中,作者全面阐述了影响增材制造钢零件可加工性和质量的重要因素。在第二部分中,作者重点研究了打印和热处理AM钢产品的显微组织,决定显微组织变化的参数,显微组织特征(如晶粒尺寸和枝晶臂间距)对力学性能的影响,以及嵌入基体的夹杂物的有害影响。最后,论文的第三部分是对不同类型的不锈钢(316l奥氏体不锈钢、420马氏体不锈钢、15-5 PH、17-4 PH和Corrax的马氏体沉淀硬化不锈钢)用增材制造技术的腐蚀进行了全面的综述。
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引用次数: 0
The measurement and impact of negative oxygen ions during reactive sputter deposition 反应溅射沉积过程中负氧离子的测量及其影响
2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-09-21 DOI: 10.1080/10408436.2023.2258159
D. Depla
AbstractMany thin film applications are based on oxides. The optimization of the oxide properties is an on-going process and requires a deep understanding of the deposition process. A typical feature of reactive (magnetron) sputter deposition is the presence of negative oxygen ions. Two groups of ions can be identified based on their energy. Low energy ions are generated in the bulk of the discharge. The high energy ions are emitted from the oxide or oxidized target surface. As these ions are generated at the cathode, they are accelerated by the electric field toward the growing film. Depending on the discharge voltage and the powering method, their energy is typically several tenths to hundreds electron volt. As such the ions can have a strong impact on the film properties. In the case of magnetron sputtering, this will lead to inhomogenous film properties over the substrate facing the locally eroded target. Due to their high energy, the trajectory of negative ions can be easily predicted which has led to several strategies to avoid negative ion bombardment such as facing target sputtering and off-axis sputtering. This paper reviews several facets of the production, the measurements and the impact on the film properties of negative ions during reactive sputtering. Despite the many illustrative studies on the impact of negative oxygen ions, quantification is often lacking as the negative ion yield is only known for a few oxides. The compilation of several literature sources allows the discussed trends to be placed in a quantitative framework.Keywords: Negative ion yieldmagnetron sputteringion assisted deposition AcknowledgementsThis work is dedicated to two researchers who have passed away recently and had a major impact on the scientific career of the author. The first researcher is Professor Johan (Jo) Haemers, a member of the same department, who assisted the research of the author in the development of special measuring set-ups, and in long discussions on science and other important things in life. The second researcher is Professor Joseph (Joe) Greene. His research approach, presentation style, and his interest in old and recent scientific literature was an example to many and to the author in particular.Disclosure statementThe author declares that there are no relevant financial or non-financial competing interests to report.
许多薄膜的应用都是基于氧化物。氧化物性能的优化是一个持续的过程,需要对沉积过程有深入的了解。反应性(磁控)溅射沉积的一个典型特征是负氧离子的存在。根据它们的能量可以识别出两组离子。低能离子在大部分放电中产生。高能离子从氧化物或被氧化的目标表面发射出来。当这些离子在阴极产生时,它们在电场的作用下向生长的薄膜加速。根据放电电压和供电方法的不同,它们的能量通常为几十到几百电子伏特。因此,离子对薄膜的性能有很大的影响。在磁控溅射的情况下,这将导致面向局部侵蚀目标的衬底上的薄膜性质不均匀。由于负离子的高能量,其运动轨迹可以很容易地预测,这导致了几种避免负离子轰击的策略,如面对目标溅射和离轴溅射。本文综述了反应溅射过程中负离子的产生、测量及其对薄膜性能的影响。尽管有许多关于负氧离子影响的说明性研究,但由于只知道少数氧化物的负离子产率,因此往往缺乏量化。若干文献资料的汇编使所讨论的趋势可以放在一个定量的框架内。关键词:负离子屈服磁控溅射辅助沉积致谢本作品献给两位最近去世的研究人员,他们对作者的科学生涯产生了重大影响。第一位研究人员是约翰·海默斯教授,他是同一系的成员,他协助作者研究开发特殊测量装置,并就科学和生活中其他重要事情进行长时间的讨论。第二位研究员是约瑟夫·格林教授。他的研究方法,演讲风格,以及他对新旧科学文献的兴趣是许多人的榜样,尤其是作者。作者声明,没有相关的财务或非财务竞争利益需要报告。
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引用次数: 0
The emergence of reflective thermal barrier coatings 反光热障涂层的出现
IF 10.8 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-09-06 DOI: 10.1080/10408436.2023.2245599
Jaasim Mulla, Fiyanshu Kaka, RK Satapathy
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引用次数: 0
A historical, statistical and electrochemical approach on the effect of microstructure in the anodizing of Al alloys: a review 铝合金阳极氧化过程中微观组织影响的历史、统计和电化学方法综述
IF 10.8 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-07-09 DOI: 10.1080/10408436.2023.2230250
João V. de S. Araujo, M. Milagre, I. Costa
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引用次数: 0
A critique on boron nitride nanotube reinforced metal matrix composites 氮化硼纳米管增强金属基复合材料研究进展
IF 10.8 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-07-04 DOI: 10.1080/10408436.2023.2229867
Sohail Mohammed, Pranjal Nautiyal, Tanaji Paul, Cheng Zhang, Arvind Agarwal
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引用次数: 0
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