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Calcium Phosphate Brushite Cements Made of Substituted Tricalcium Phosphate Ca3(PO4)2 and Reinforced with Silicate Glass Fiber 由取代的磷酸三钙 Ca3(PO4)2 制成并用硅酸盐玻璃纤维增强的磷酸钙刷状水泥
IF 0.75 Q4 Engineering Pub Date : 2024-05-23 DOI: 10.1134/s2075113324010179
Sh. A. Musoev, A. V. Knotko, Ya. Yu. Filippov

Abstract

This work examines the reinforcement of reaction-hardening phosphate materials (phosphate cements) for bone implants based on isomorphically cation-(Na+, K+) and anion-(({text{SiO}}_{4}^{{4 - }}), ({text{SO}}_{4}^{2})) substituted tricalcium phosphate (β and α-TCP, Ca3(PO4)2), which are reinforced with silicate (basalt-based) fiberglass. The resulting materials were characterized by XRD and SEM methods, mechanical compression tests were carried out, the setting times of cements were determined, and changes in the pH of aqueous medium in contact with the cements under study were measured. Analysis of microstructure showed that the reinforcing fiber surface, upon contact with the matrix of hardening cement, is partially corroded with the formation of phosphate microparticles on it. Using the pH-metry method, it was found that samples with prolonged contact to water do not significantly change the value of the pH of the aqueous environment, which remains close to the neutral range from 5 to 7.5, favorable for further biological tests.

Abstract This work examines the reinforcement of reaction-hardening phosphate materials (phosphate cements) for bone implants based on isomorphically cation-(Na+. K+) and anion-({text{SiO}}_{4}^{4 - }})、K+)和阴离子({text{SiO}}_{4}^{4 - }}), ({text{SO}}_{4}^{2}))取代的磷酸三钙(β 和 α-TCP,Ca3(PO4)2),并用硅酸盐(玄武岩基)玻璃纤维对其进行加固。通过 XRD 和 SEM 方法对所得材料进行了表征,进行了机械压缩试验,测定了水泥的凝结时间,并测量了与所研究水泥接触的水介质 pH 值的变化。微观结构分析表明,在与硬化水泥基质接触时,增强纤维表面会被部分腐蚀,并在其上形成磷酸盐微粒。使用 pH 值测定法发现,长期与水接触的样品不会明显改变水环境的 pH 值,其值仍接近 5 至 7.5 的中性范围,有利于进一步的生物测试。
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引用次数: 0
Investigation of Properties of Polytetrafluoroethylene-Based Composites and Carbon Fibers Depending on the Production Technology 不同生产技术下的聚四氟乙烯基复合材料和碳纤维性能研究
IF 0.75 Q4 Engineering Pub Date : 2024-05-23 DOI: 10.1134/s2075113324010258
P. N. Petrova, M. A. Markova, V. D. Chernykh

Abstract

This paper presents the results of research on the development of technologies for production of wear-resistant polymer materials based on polytetrafluoroethylene (PTFE) and carbon fibers of the UVIS-AK-P brand. Physical, mechanical, and tribological characteristics of polymer composites have been studied depending on the technology for their production. To predict the performance of the developed composites under various operating conditions, the joint influence of the load applied during the friction process and the sliding speed on the mass wear rate and the friction coefficient of the developed materials has been studied.

摘要 本文介绍了基于聚四氟乙烯(PTFE)和 UVIS-AK-P 品牌碳纤维的耐磨聚合物材料生产技术的研发成果。根据不同的生产技术,对聚合物复合材料的物理、机械和摩擦学特性进行了研究。为了预测所开发的复合材料在各种工作条件下的性能,研究了摩擦过程中施加的载荷和滑动速度对所开发材料的大量磨损率和摩擦系数的共同影响。
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引用次数: 0
Mechanical and Thermomechanical Characteristics of the Ni50Ti47.5Hf2.5 Alloy with a High-Temperature Shape Memory Effect 具有高温形状记忆效应的 Ni50Ti47.5Hf2.5 合金的机械和热机械特性
IF 0.75 Q4 Engineering Pub Date : 2024-05-23 DOI: 10.1134/s207511332401026x
N. N. Popov, D. V. Presnyakov, E. N. Grishin, T. I. Sysoeva, T. A. Morozova, S. V. Glukhareva, A. A. Kostyleva

Abstract

The properties of the Ni50Ti47.5Hf2.5 alloy with a high-temperature shape memory effect have been comprehensively studied on samples made from a 2.34-mm-thick strip in the initial state and after high-temperature annealing in vacuum. Data on the elemental and phase compositions and structural state have been obtained. The results of investigations of the phase transformation temperatures and the mechanical and thermomechanical characteristics of the alloy are reported. Using annealing and selecting the strain-inducing conditions, the shape recovery temperatures As SME = 137°C and Af SME = 150°C have been determined. These values are acceptable for creating the required depressurization device. The maximum εSME and ηSME values have been found to be 3.4 and 43%, respectively. These are not very large values for creating an efficient depressurization device for nuclear power plants. The desired displacement values in such a device can be obtained by optimizing the geometry of a thermosensitive element.

摘要 对具有高温形状记忆效应的 Ni50Ti47.5Hf2.5 合金的初始状态和真空高温退火后的 2.34 毫米厚带材样品的性能进行了全面研究。获得了有关元素和相组成以及结构状态的数据。报告了对合金相变温度以及机械和热机械特性的研究结果。通过退火和选择应变诱导条件,确定了形状恢复温度 As SME = 137°C 和 Af SME = 150°C。这些值对于制造所需的减压装置是可以接受的。最大 εSME 和 ηSME 值分别为 3.4% 和 43%。对于为核电站制造高效减压装置来说,这些数值并不算大。通过优化热敏元件的几何形状,可以在这种装置中获得所需的位移值。
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引用次数: 0
Stabilization of Polybutylene Terephthalate by Various Antioxidants 各种抗氧化剂对聚对苯二甲酸丁二醇酯的稳定作用
IF 0.75 Q4 Engineering Pub Date : 2024-05-23 DOI: 10.1134/s2075113324010052
T. A. Borukaev, L. I. Kitieva, A. Kh. Malamatov

Abstract

Stabilization of polybutylene terephthalate by various antioxidants is performed. The optimum concentrations of antioxidants are determined at which substantial values of heat resistance and thermal stability are achieved. It is shown that the use of mixed systems of different stabilizers makes it possible to effectively inhibit the thermo-oxidative destruction of polybutylene terephthalate.

摘要 采用各种抗氧化剂稳定聚对苯二甲酸丁二醇酯。研究确定了抗氧化剂的最佳浓度,在该浓度下,聚对苯二甲酸丁二醇酯的耐热性和热稳定性都能达到相当高的数值。研究表明,使用不同稳定剂的混合体系可以有效抑制聚对苯二甲酸丁二醇酯的热氧化破坏。
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引用次数: 0
MgAl-Layered Double Hydroxides: Synthesis, Characteristics, and Their Effects on Flame Retardant and Mechanical Properties of Casting Polyurethane 镁铝层双氢氧化物:合成、特性及其对浇注聚氨酯阻燃性和机械性能的影响
IF 0.75 Q4 Engineering Pub Date : 2024-05-23 DOI: 10.1134/s2075113324010209
T. V. A. Nguyen, B. P. Tolochko, F. K. Gorbunov, A. A. Fadina

Abstract

MgAl–layered double hydroxides with different molar ratios of cations were synthesized. The compound with a ratio of 2 : 1 was shown to exhibit better characteristics of thermal stability. The modification of polyurethane by using these hydroxides led to the improvement in the properties of composites: decrease by 47% in flame retardancy, and increase by 24.8 and 54.1% in tensile strength and Young’s modulus, respectively.

摘要 合成了不同阳离子摩尔比的镁铝层双氢氧化物。结果表明,比例为 2 : 1 的化合物具有更好的热稳定性。使用这些氢氧化物对聚氨酯进行改性可改善复合材料的性能:阻燃性降低 47%,拉伸强度和杨氏模量分别提高 24.8% 和 54.1%。
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引用次数: 0
Heat-Resistant Diamond–Silicon Carbide Composite Materials Modified with Hafnium 用铪改性的耐热金刚石-碳化硅复合材料
IF 0.75 Q4 Engineering Pub Date : 2024-05-23 DOI: 10.1134/s2075113324010210
A. N. Nikolaev, E. S. Stepichev, S. N. Perevislov

Abstract

In this work, diamond–SiC composite materials modified with hafnium have been obtained, and their thermal stability at 1200°C in air has been studied. The phase composition, microstructure, and physical and mechanical characteristics have been determined. A higher thermal stability of sintered Hf-modified materials has been demonstrated compared to a diamond–silicon carbide composite materials with no additives.

摘要 在这项工作中,获得了用铪改性的金刚石-碳化硅复合材料,并对其在 1200°C 空气中的热稳定性进行了研究。研究确定了相组成、微观结构以及物理和机械特性。与未添加任何添加剂的金刚石-碳化硅复合材料相比,烧结铪改性材料具有更高的热稳定性。
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引用次数: 0
Studies on Microhardness of Composition Materials of High-Temperature Superconductor YBCO–MoO3 Nanofibers 高温超导体 YBCO-MoO3 纳米纤维组成材料的显微硬度研究
IF 0.75 Q4 Engineering Pub Date : 2024-05-23 DOI: 10.1134/s207511332401012x
L. Yu. Fedorov, A. V. Ushakov, I. V. Karpov, E. A. Goncharova, M. V. Brungardt

Abstract

Superconducting polycrystalline composites YBa2Cu3O7–x + MoO3 with MoO3 nanofiber content of 1, 5, 10, and 15 wt % have been studied in the work. The temperature and width of transition into the superconducting state of samples with description of possible mechanisms for observable changes have been determined from measurements of electrical resistance. The elastic modulus, yield strength, fracture toughness, and fragility index have been determined from measurements of the Vickers microhardness. Five different models have been used during studies on the physical and mechanical properties of the MoO3-containing bulk HTSC samples to interpret microindentation data and explain the results with consideration of the indentation size effect.

摘要 研究了纳米 MoO3 纤维含量为 1、5、10 和 15 wt % 的超导多晶复合材料 YBa2Cu3O7-x + MoO3。通过测量电阻,确定了样品过渡到超导状态的温度和宽度,并描述了可观察到的变化的可能机制。通过测量维氏硬度,确定了弹性模量、屈服强度、断裂韧性和脆性指数。在对含氧化钼的块状 HTSC 样品的物理和机械性能进行研究期间,使用了五种不同的模型来解释微压痕数据,并在考虑压痕尺寸效应的情况下解释结果。
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引用次数: 0
Computer Models of Biomaterials Used for the Manufacture of the Leaflet Apparatus of Heart Valve Prostheses 用于制造心脏瓣膜假体瓣叶装置的生物材料计算机模型
IF 0.75 Q4 Engineering Pub Date : 2024-05-23 DOI: 10.1134/s2075113324010222
P. S. Onishchenko, T. V. Glushkova, A. E. Kostyunin, M. A. Rezvova, T. N. Akentyeva, L. S. Barbarash

Abstract

The physical and mechanical characteristics of the component materials of bioprosthetic heart valves presented in clinical practice in Russia were obtained and generalized for subsequent adaptation of the properties for numerical modeling problems. It was shown that all materials studied have pronounced nonlinearity and can be represented only in the form of polynomial models. A comparison of the results of computer modeling based on the obtained material coefficients did not demonstrate any differences with the data of full-scale bench tests, which made it possible to verify the computer models.

摘要 研究人员获得了俄罗斯临床实践中生物人工心脏瓣膜组件材料的物理和机械特性,并对其进行了归纳,以便随后将这些特性用于数值建模问题。研究表明,所研究的所有材料都具有明显的非线性,只能以多项式模型的形式表示。根据获得的材料系数对计算机建模结果进行比较后发现,与全尺寸台架试验的数据没有任何差异,因此可以对计算机模型进行验证。
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引用次数: 0
Mineral Powders: Activity and Specific Surface Area 矿物粉末:活性和比表面积
IF 0.75 Q4 Engineering Pub Date : 2024-05-23 DOI: 10.1134/s2075113324010131
M. A. Frolova, A. M. Ayzenshtadt, V. E. Danilov, T. A. Makhova

Abstract

A thermodynamic criterion—surface activity—has been proposed to characterize the reactivity of powder materials obtained by the method of mechanical grinding. The work shows that, between the surface activity calculated taking into account values of the specific surface area of powder materials determined by the method of gas sorption and this criterion calculated from the specific surface area determined by the method of gas permeability, there is a functional interrelation that allows one to draw a conclusion about the effectiveness of mechanical activation of mineral raw material systems.

摘要 有人提出了一种热力学标准--表面活性--来描述用机械研磨方法获得的粉末材料的反应性。研究结果表明,根据气体吸附法确定的粉末材料比表面积值计算出的表面活性与根据气体渗透法确定的比表面积计算出的这一标准之间,存在着一种功能上的相互关系,使人们能够就矿物原料系统的机械活化效果得出结论。
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引用次数: 0
Influence of Cooling Modes during Quenching on Structure and Corrosion Resistance of Alloy V-1341T1 淬火时的冷却模式对 V-1341T1 合金结构和耐腐蚀性的影响
IF 0.75 Q4 Engineering Pub Date : 2024-05-23 DOI: 10.1134/s2075113324010283
Yu. A. Puchkov, I. Benarieb

Abstract

This article presents the results of a study of the influence of cooling modes during quenching on the structure and corrosion resistance in NaCl aqueous solutions of a high-tech deformable corrosion-resistant alloy V-1341 in a state after artificial aging. The structure and corrosion resistance of this alloy in the annealed state were also studied. Studies were carried out using the potentiodynamic method, electrochemical impedance spectroscopy, and transmission electron microscopy. The results obtained can be used when choosing the quenching cooling modes for products made of alloy V-1341 and predicting their corrosion resistance.

摘要 本文介绍了一项研究结果,即淬火时的冷却模式对人工时效后的高科技可变形耐腐蚀合金 V-1341 在氯化钠水溶液中的结构和耐腐蚀性的影响。此外,还研究了该合金在退火状态下的结构和耐腐蚀性。研究使用了电位法、电化学阻抗光谱法和透射电子显微镜。所得结果可用于选择 V-1341 合金产品的淬火冷却模式和预测其耐腐蚀性。
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引用次数: 0
期刊
Inorganic Materials: Applied Research
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