Pub Date : 2024-11-18DOI: 10.1007/s11664-024-11562-3
J. Salamon, A. Simi, H. Joy Prabu, A. Felix Sahayaraj, A. Joseph Sagaya Kennedy, J. Beny, V. Snowlin, R. R. Gopi, I. Johnson, Amanullah Fatehmulla
Supercapacitors have been given significant consideration as advanced energy storage devices owing to their rapid charging capabilities, exceptional stability, and high retention performance, aligning with the demands of modern technologies. In the current investigation, a hybrid nanocomposite containing MnO2 nanorods anchored onto reduced graphene oxide (rGO) was made via a hydrothermal route, demonstrating superior supercapacitive behavior. The nanocomposite was extensively characterized through functional, structural, morphological, and electrochemical analyses, and subsequently utilized as supercapacitor electrode material. Electrochemical evaluations were conducted in a 3-electrode system using the electrolyte of 1 M Na2SO4, revealing an impressive specific capacitance of about 398 F g-1. Notably, the electrode exhibited remarkable long-term stability, with a retention value of 94% after 5000 charge–discharge cycles. These results position the rGO-MnO2 hybrid as an auspicious candidate for future supercapacitor applications.
超级电容器具有快速充电能力、优异的稳定性和高保持性能,符合现代技术的要求,因此被视为先进的储能设备。在目前的研究中,通过水热法制备了一种包含锚定在还原氧化石墨烯(rGO)上的 MnO2 纳米棒的混合纳米复合材料,显示出卓越的超级电容器性能。该纳米复合材料通过功能、结构、形态和电化学分析进行了广泛表征,随后被用作超级电容器电极材料。在使用 1 M Na2SO4 电解质的 3 电极系统中进行了电化学评估,结果显示其比电容高达 398 F g-1。值得注意的是,该电极表现出显著的长期稳定性,在经过 5000 次充放电循环后,保持值达到 94%。这些结果使 rGO-MnO2 杂化物成为未来超级电容器应用的理想候选材料。
{"title":"Synthesis and Characterization of rGO-Anchored MnO2 Nanorods and their Application in Supercapacitors as Electrode Material","authors":"J. Salamon, A. Simi, H. Joy Prabu, A. Felix Sahayaraj, A. Joseph Sagaya Kennedy, J. Beny, V. Snowlin, R. R. Gopi, I. Johnson, Amanullah Fatehmulla","doi":"10.1007/s11664-024-11562-3","DOIUrl":"10.1007/s11664-024-11562-3","url":null,"abstract":"<div><p>Supercapacitors have been given significant consideration as advanced energy storage devices owing to their rapid charging capabilities, exceptional stability, and high retention performance, aligning with the demands of modern technologies. In the current investigation, a hybrid nanocomposite containing MnO<sub>2</sub> nanorods anchored onto reduced graphene oxide (rGO) was made via a hydrothermal route, demonstrating superior supercapacitive behavior. The nanocomposite was extensively characterized through functional, structural, morphological, and electrochemical analyses, and subsequently utilized as supercapacitor electrode material. Electrochemical evaluations were conducted in a 3-electrode system using the electrolyte of 1 M Na<sub>2</sub>SO<sub>4</sub>, revealing an impressive specific capacitance of about 398 F g<sup>-1</sup>. Notably, the electrode exhibited remarkable long-term stability, with a retention value of 94% after 5000 charge–discharge cycles. These results position the rGO-MnO<sub>2</sub> hybrid as an auspicious candidate for future supercapacitor applications.</p></div>","PeriodicalId":626,"journal":{"name":"Journal of Electronic Materials","volume":"54 1","pages":"510 - 522"},"PeriodicalIF":2.2,"publicationDate":"2024-11-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11664-024-11562-3.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142859682","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-11-18DOI: 10.1007/s11664-024-11585-w
Ali Hajjiah, Nima E. Gorji
This study utilizes an image processing method to analyse the grain size of perovskite, CZTS kesterite and antimony chalcogenide (Sb2Se3) thin films at various temperatures using SEM and TEM images. Empirical equations (exponential, Gaussian, power law) were derived from the data, revealing distinct temperature-dependent trends in grain size. Perovskite films exhibit a Gaussian trend, showing extreme sensitivity to temperature. CZTS films follow a double exponential function, with optimal grain size at 300°C. Sb2Se3 films adhere to a power law (~T6), with grain size rapidly increasing at higher temperatures. These temperature-dependent behaviours offer insights into optimizing fabrication processes and enhancing the efficiency of these materials in photovoltaic applications.
本研究采用一种图像处理方法,利用 SEM 和 TEM 图像分析了不同温度下的包晶、CZTS kesterite 和锑瑀 (Sb2Se3) 薄膜的晶粒尺寸。根据数据推导出经验方程(指数、高斯、幂律),揭示了晶粒尺寸随温度变化的明显趋势。Perovskite 薄膜呈现出高斯趋势,显示出对温度的极端敏感性。CZTS 薄膜呈现双指数函数,最佳晶粒大小出现在 300°C 时。Sb2Se3 薄膜遵循幂律(~T6),晶粒大小在较高温度下迅速增大。这些随温度变化的行为为优化制造工艺和提高这些材料在光伏应用中的效率提供了启示。
{"title":"SEM and TEM Image Analysis for Morphology and Phase Transition of CZTS, Sb2Se3 and Perovskite Thin Films under Thermal Stress","authors":"Ali Hajjiah, Nima E. Gorji","doi":"10.1007/s11664-024-11585-w","DOIUrl":"10.1007/s11664-024-11585-w","url":null,"abstract":"<div><p>This study utilizes an image processing method to analyse the grain size of perovskite, CZTS kesterite and antimony chalcogenide (Sb<sub>2</sub>Se<sub>3</sub>) thin films at various temperatures using SEM and TEM images. Empirical equations (exponential, Gaussian, power law) were derived from the data, revealing distinct temperature-dependent trends in grain size. Perovskite films exhibit a Gaussian trend, showing extreme sensitivity to temperature. CZTS films follow a double exponential function, with optimal grain size at 300°C. Sb<sub>2</sub>Se<sub>3</sub> films adhere to a power law (~T<sup>6</sup>), with grain size rapidly increasing at higher temperatures. These temperature-dependent behaviours offer insights into optimizing fabrication processes and enhancing the efficiency of these materials in photovoltaic applications.</p></div>","PeriodicalId":626,"journal":{"name":"Journal of Electronic Materials","volume":"54 1","pages":"523 - 530"},"PeriodicalIF":2.2,"publicationDate":"2024-11-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142859683","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-11-15DOI: 10.1007/s11664-024-11571-2
Punit Tomar, Sarvendra Kumar, Megha Gupta Chaudhary, Jitendra Kumar, Komal Jain, R. P. Pant
This study investigates the effect of particle concentration on tuneable magneto-optical transmittance and optically induced refractive index coefficients in Fe3O4-based nanomagnetic fluid (NMF) at room temperature. A static magneto-optical experimental setup was devised to investigate the magneto-optical effects arising from variations in particle concentration and dipolar interactions, under varying magnetic fields. In this work, Fe3O4-based nanomagnetic fluid was synthesized using a chemical co-precipitation method. The structural, morphological, and magnetic properties of the fluid were investigated using sophisticated characterization techniques including x-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM), and vibrating-sample magnetometry (VSM). Our investigation focused on the tunability of magneto-optical transmittance as a function of the varying magnetic field at different particle concentrations. Further, we observed variations in diffraction fringes in the nanomagnetic fluid, correlating with particle concentration, by passing a high-power laser through the diluted fluid system. Light–matter interaction in the presence of a varying magnetic field induces optical anisotropy in the fluid, whereas dipole–moment interaction and magnetic particle alignment in the presence of a magnetic field are the main supporting phenomenon of magneto-optical tunability in our experiment. Experimental modulation of the transmittance profile and field-induced refractive index coefficients in NMF, elucidated through fringe diffraction, has potential for applications such as tuneable magneto-optical devices, optical filters, and optical limiters.
{"title":"Magneto-Optical Studies of Fe3O4-Based Nanomagnetic Fluid","authors":"Punit Tomar, Sarvendra Kumar, Megha Gupta Chaudhary, Jitendra Kumar, Komal Jain, R. P. Pant","doi":"10.1007/s11664-024-11571-2","DOIUrl":"10.1007/s11664-024-11571-2","url":null,"abstract":"<div><p>This study investigates the effect of particle concentration on tuneable magneto-optical transmittance and optically induced refractive index coefficients in Fe<sub>3</sub>O<sub>4</sub>-based nanomagnetic fluid (NMF) at room temperature. A static magneto-optical experimental setup was devised to investigate the magneto-optical effects arising from variations in particle concentration and dipolar interactions, under varying magnetic fields. In this work, Fe<sub>3</sub>O<sub>4</sub>-based nanomagnetic fluid was synthesized using a chemical co-precipitation method. The structural, morphological, and magnetic properties of the fluid were investigated using sophisticated characterization techniques including x-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM), and vibrating-sample magnetometry (VSM). Our investigation focused on the tunability of magneto-optical transmittance as a function of the varying magnetic field at different particle concentrations. Further, we observed variations in diffraction fringes in the nanomagnetic fluid, correlating with particle concentration, by passing a high-power laser through the diluted fluid system. Light–matter interaction in the presence of a varying magnetic field induces optical anisotropy in the fluid, whereas dipole–moment interaction and magnetic particle alignment in the presence of a magnetic field are the main supporting phenomenon of magneto-optical tunability in our experiment. Experimental modulation of the transmittance profile and field-induced refractive index coefficients in NMF, elucidated through fringe diffraction, has potential for applications such as tuneable magneto-optical devices, optical filters, and optical limiters.</p></div>","PeriodicalId":626,"journal":{"name":"Journal of Electronic Materials","volume":"54 1","pages":"232 - 240"},"PeriodicalIF":2.2,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142859574","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-11-15DOI: 10.1007/s11664-024-11560-5
Gourav Rana, Chandan Bera
A theoretical investigation is conducted on semiconducting MXenes (hbox {M}_{2})COS (M = Zr, Hf) using both density functional theory and the Boltzmann transport equation. The findings suggest that optimization of thermoelectric properties is more effective through n-type doping than p-type doping. At 300 K, n-type doping yields a power factor of 4.3(times ) 10(^{3})(mu )W/(hbox {mK}^{2}) for Zr({_2})COS and 4.5(times ) 10(^{3})(mu )W/(hbox {mK}^{2}) for Hf({_2})COS. Furthermore, lattice thermal conductivity ((kappa _{l})) values of 21.8 W/m K and 27 W/m K are obtained for Zr({_2})COS and Hf({_2})COS, respectively, at 300 K. These values are lower than the lattice thermal conductivity of oxygen-functionalized MXenes (hbox {Zr}_2hbox {CO}_2) (61.9 W/m K) and (hbox {Hf}_2hbox {CO}_2) (86.3 W/m K). The projected thermoelectric figure of merit value can potentially reach 0.27 and 0.23 at 700 K for n-type Zr({_2})COS and Hf({_2})COS, respectively. These findings reveal the promising application prospects for n-type Zr({_2})COS and Hf({_2})COS in the field of thermoelectric materials.
利用密度泛函理论和玻尔兹曼输运方程对半导体 MXenes (hbox {M}_{2})COS (M = Zr、Hf)进行了理论研究。研究结果表明,通过 n 型掺杂比 p 型掺杂能更有效地优化热电性能。在300 K时,Zr({_2})COS的n型掺杂产生的功率因数为4.3(times )10(^{3})(mu )W/(hbox {mK}^{2}),而Hf({_2})COS的功率因数为4.5(times )10(^{3})(mu )W/(hbox {mK}^{2})。此外,Zr({_2})COS 和 Hf({_2})COS 在 300 K 时的晶格热导率((kappa _{l}))值分别为 21.8 W/m K 和 27 W/m K。这些值低于氧官能化 MXenes 的晶格热导率(61.9 W/m K)和(86.3 W/m K)。在 700 K 时,n 型 Zr({_2})COS 和 Hf({_2})COS 的预计热电功勋值可能分别达到 0.27 和 0.23。这些发现揭示了 n 型 Zr({_2})COS 和 Hf({_2})COS 在热电材料领域的广阔应用前景。
{"title":"Theoretical Investigation of Thermoelectric Properties of Semiconducting Janus (hbox {M}_{2})COS (M = Zr, Hf) MXenes","authors":"Gourav Rana, Chandan Bera","doi":"10.1007/s11664-024-11560-5","DOIUrl":"10.1007/s11664-024-11560-5","url":null,"abstract":"<div><p>A theoretical investigation is conducted on semiconducting MXenes <span>(hbox {M}_{2})</span>COS (M = Zr, Hf) using both density functional theory and the Boltzmann transport equation. The findings suggest that optimization of thermoelectric properties is more effective through <i>n</i>-type doping than <i>p</i>-type doping. At 300 K, <i>n</i>-type doping yields a power factor of 4.3<span>(times )</span> 10<span>(^{3})</span> <span>(mu )</span>W/<span>(hbox {mK}^{2})</span> for Zr<span>({_2})</span>COS and 4.5<span>(times )</span> 10<span>(^{3})</span> <span>(mu )</span>W/<span>(hbox {mK}^{2})</span> for Hf<span>({_2})</span>COS. Furthermore, lattice thermal conductivity (<span>(kappa _{l})</span>) values of 21.8 W/m K and 27 W/m K are obtained for Zr<span>({_2})</span>COS and Hf<span>({_2})</span>COS, respectively, at 300 K. These values are lower than the lattice thermal conductivity of oxygen-functionalized MXenes <span>(hbox {Zr}_2hbox {CO}_2)</span> (61.9 W/m K) and <span>(hbox {Hf}_2hbox {CO}_2)</span> (86.3 W/m K). The projected thermoelectric figure of merit value can potentially reach 0.27 and 0.23 at 700 K for <i>n</i>-type Zr<span>({_2})</span>COS and Hf<span>({_2})</span>COS, respectively. These findings reveal the promising application prospects for <i>n</i>-type Zr<span>({_2})</span>COS and Hf<span>({_2})</span>COS in the field of thermoelectric materials.</p></div>","PeriodicalId":626,"journal":{"name":"Journal of Electronic Materials","volume":"54 1","pages":"432 - 439"},"PeriodicalIF":2.2,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142859577","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-11-14DOI: 10.1007/s11664-024-11552-5
Punam Tiwary, Amit K. Chakraborty, Holly J. Edwards, Vinod R. Dhanak, Rajat Mahapatra
A graphene oxide (GO)-based humidity sensor is reported in this work wherein the influence of the substrate on its humidity-sensing properties is compared by depositing a GO film on two different substrates: glass and wearable fabric. While the GO film exhibits sensitivity to humidity for both substrates, its response varies from 35% for the glass substrate to 74% for wearable fabric at 60% relative humidity (RH), clearly indicating the superiority of the wearable fabric over glass. The sensors (on both substrates) show almost no sensitivity to several common volatile organic compounds (VOCs) and gases, suggesting their high selectivity towards humidity. In both cases, the sensor can detect humidity with high repeatability over several cycles and exhibits fast response and recovery times of 6 s/10 s and 7 s/12 s for glass and wearable fabric, respectively. The sensing mechanism is explained in terms of pre-adsorbed surface oxygen ions, as measured by the change in water signal upon exposure of the GO film to humidity using Fourier transform infrared (FTIR) spectroscopy. Thus, we demonstrate that the developed GO film on wearable fabric can act as a low-cost, flexible, and wearable humidity sensor with good sensitivity, reproducibility, and selectivity.