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Structural Evolution, Piezoelectric and Ferroelectric Properties of (1−x)Bi4Ti3O12-xCaBi2Nb2O9 High-Temperature Composite Ceramics (1−x)Bi4Ti3O12-xCaBi2Nb2O9高温复合陶瓷的结构演变、压电和铁电性能
IF 2.2 4区 工程技术 Q3 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-10-16 DOI: 10.1007/s11664-024-11527-6
Zhipeng Zhang, Zong-Yang Shen, Zhumei Wang, Tao Zeng, Wenqin Luo, Fusheng Song, Yueming Li

High leakage current density and relatively low piezoelectric activity have become one of the main obstacles to expanding the practical application of Bi4Ti3O12 (BIT) high-temperature piezoelectric ceramics. Although ion doping can improve electrical resistivity and piezoelectric response, it often lowers the Curie temperature. In this work, by introducing CaBi2Nb2O9 (CBN) with higher Curie temperature to BIT, a composite ceramic (1−x)BIT-xCBN was designed, and the effect of CBN content on the structure and electrical properties of the ceramics was investigated. With the increase in the x value, the intensity of the highest peak (117) gradually decreased until disappearing, while the intensity of peak (115) gradually increased, and the X-ray diffraction (XRD) refinement results showed that some non-stoichiometric compounds, Bi1.74Ti2O6.624 and Ca0.5Bi2.5Ti0.5Nb1.5O9, were produced. The sheet-like grains were effectively suppressed, while the granular grains became prominent with high CBN doping content, which should contribute to improving the electrical resistivity of ceramics. The optimal electrical properties were obtained in 0.8BIT-0.2CBN composite ceramics as follows: the piezoelectric coefficient d33 = 13.8 pC/N, the Curie temperature TC = 765°C, and the electrical resistivity ρdc = 8.52 × 105 Ω·cm (@ 500°C). In addition, the d33 maintained 89.1% of the initial value after annealing at 550°C, showing good thermal stability for high-temperature sensing applications.

高泄漏电流密度和相对较低的压电活度已成为Bi4Ti3O12 (BIT)高温压电陶瓷扩大实际应用的主要障碍之一。虽然离子掺杂可以改善电阻率和压电响应,但往往会降低居里温度。本文通过在BIT中引入具有较高居里温度的CaBi2Nb2O9 (CBN),设计了一种(1−x)BIT- xcbn复合陶瓷,并研究了CBN含量对陶瓷结构和电性能的影响。随着x值的增大,最高值(117)的强度逐渐减小直至消失,而峰值(115)的强度逐渐增大,x射线衍射(XRD)细化结果表明,生成了一些非化学计量化合物Bi1.74Ti2O6.624和Ca0.5Bi2.5Ti0.5Nb1.5O9。随着CBN掺杂量的增加,片状晶粒得到有效抑制,颗粒状晶粒突出,有利于提高陶瓷的电阻率。得到了0.8BIT-0.2CBN复合陶瓷的最佳电学性能:压电系数d33 = 13.8 pC/N,居里温度TC = 765℃,电阻率ρdc = 8.52 × 105 Ω·cm(@ 500℃)。此外,在550℃退火后,d33保持了初始值的89.1%,表现出良好的热稳定性,适用于高温传感应用。
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引用次数: 0
Correlation Between Structural, Electrical, and Optical Properties of ZnO:In for Ethanol Gas Sensing Application ZnO结构、电学和光学性质的相关性:在乙醇气体传感中的应用
IF 2.2 4区 工程技术 Q3 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-10-16 DOI: 10.1007/s11664-024-11508-9
Fatemeh Montazeri Davoodi, Seyed Mohammad Rozati, Sahar Soltani

Indium-doped zinc oxide (ZnO:In) thin films were prepared using the spray pyrolysis technique, and the effects of indium concentration on the structural, optical, electrical, and sensing properties of the ZnO:In films were investigated. The indium concentration was varied between 0 wt.% and 15 wt.%. The results show a polycrystalline structure for all layers using x-ray diffraction. The lowest sheet resistance of approximately 120 Ω/□ was achieved with an indium concentration of 5 wt.% in the starting solution. The morphological properties of the thin films were investigated using field-emission scanning electron microscopy. The results indicate that an increase in the indium concentration disrupts the nano-granular structure of the surface, the surface becomes wrinkled, and a snowflake-like pattern is formed on the surface of the thin film. The ethanol sensing properties of the samples were studied using an electric circuit. Sensing parameters including the dynamic response, sensitivity, and response/recovery times of the samples were investigated. For an ethanol concentration of 200 ppm, the gas response of the pure ZnO layer was about 1.05. An increase in the indium concentration to 15 wt.% was found to improve the gas response of the samples. For an ethanol concentration of 200 ppm, the gas response of the ZnO:In (15 wt.%) layer increased to 1.82.

利用喷雾热解技术制备了掺铟氧化锌(ZnO:In)薄膜,并研究了铟浓度对 ZnO:In 薄膜的结构、光学、电学和传感特性的影响。铟的浓度在 0 wt.% 到 15 wt.% 之间变化。X 射线衍射结果表明,所有层均为多晶结构。起始溶液中的铟浓度为 5 wt.%时,薄膜电阻最低,约为 120 Ω/□。使用场发射扫描电子显微镜研究了薄膜的形态特性。结果表明,铟浓度的增加会破坏薄膜表面的纳米粒状结构,使表面起皱,并在薄膜表面形成雪花状图案。利用电路研究了样品的乙醇传感特性。研究了样品的传感参数,包括动态响应、灵敏度和响应/恢复时间。乙醇浓度为 200 ppm 时,纯氧化锌层的气体响应约为 1.05。将铟的浓度提高到 15 wt.%后,发现样品的气体响应有所改善。乙醇浓度为 200 ppm 时,ZnO:In(15 wt.%)层的气体响应上升到 1.82。
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引用次数: 0
Unveiling the Potential of Zn-MOF/GO Nanoarchitectures for Highly Sensitive and Stable Ammonia Sensing at Ambient Conditions 揭示Zn-MOF/GO纳米结构在环境条件下高度敏感和稳定的氨传感的潜力
IF 2.2 4区 工程技术 Q3 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-10-15 DOI: 10.1007/s11664-024-11506-x
Zakaria M. Ali, Mohamed E. El Sayed, Ahmed Samir, Mohammad N. Murshed

This work reports the synthesis and characterization of a zinc-based metal–organic framework (Zn-MOF) and its nanocomposite with graphene oxide (GO) for room-temperature ammonia (NH3) sensing. The Zn-MOF/GO nanocomposite was prepared via an innovative solvothermal approach and comprehensively characterized using x-ray diffraction, UV–visible spectroscopy, Fourier transform infrared (FTIR) spectroscopy, Raman spectroscopy, and thermogravimetric analysis. The nanocomposite demonstrated exceptional NH3 sensing performance at ambient conditions, exhibiting a linear response from 20 ppm to 220 ppm, a significant 13.2% response towards 100 ppm NH3, and rapid response/recovery times of 102/127 s. Notably, the sensor maintained long-term stability, with 12.4% average sensitivity over 50 days. The synergistic effects between GO and Zn-MOF components, coupled with the high surface area and porous structure, contributed to the superior sensing characteristics. A strong linear correlation (R2 = 0.9906) between sensor response and NH3 concentration enabled precise quantitative detection. This study not only introduces a novel material for NH3 sensing but also provides crucial insights into the structure–property relationships governing nanocomposite gas sensors. The findings open new avenues for designing high-performance chemiresistive gas sensors operating at ambient conditions, with potential applications in environmental monitoring and industrial safety.

本研究报告了一种锌基金属有机框架(Zn-MOF)及其与氧化石墨烯(GO)的纳米复合材料的合成与表征,用于室温氨(NH3)传感。Zn-MOF/GO 纳米复合材料是通过创新的溶热法制备的,并利用 X 射线衍射、紫外可见光谱、傅立叶变换红外光谱、拉曼光谱和热重分析对其进行了全面表征。该纳米复合材料在环境条件下表现出卓越的 NH3 传感性能,在 20 ppm 到 220 ppm 的范围内表现出线性响应,对 100 ppm NH3 的响应为 13.2%,快速响应/恢复时间为 102/127 s。GO 和 Zn-MOF 成分之间的协同效应,再加上高表面积和多孔结构,造就了其卓越的传感特性。传感器响应与 NH3 浓度之间具有很强的线性相关性(R2 = 0.9906),从而实现了精确的定量检测。这项研究不仅介绍了一种新型的 NH3 传感材料,还对纳米复合气体传感器的结构-性能关系提供了重要的见解。这些发现为设计在环境条件下工作的高性能化学电阻式气体传感器开辟了新途径,有望应用于环境监测和工业安全领域。
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引用次数: 0
One-Step Electrochemical Modification of Pencil Graphite Electrode with Poly(DPASA-co-VP)-RuO2NPs and its Application for the Trace Analysis of Sumatriptan 聚(DPASA-co-VP)-RuO2NPs一步电化学修饰铅笔石墨电极及其在苏马曲坦痕量分析中的应用
IF 2.2 4区 工程技术 Q3 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-10-09 DOI: 10.1007/s11664-024-11509-8
Mansoureh Lalei, Kobra Zarei

A straightforward and one-step modification of the pencil graphite electrode was performed using co-polymerization of diphenyl amine-4-sulfonic acid (DPASA) sodium salt, and 4-vinylpyridine (VP), and also simultaneous formation of ruthenium dioxide nanoparticles (poly(DPASA-co-VP)-RuO2 NPs/PGE). The subsequent step involved the application of the altered electrode to examine the quantity of sumatriptan by employing a highly sensitive adsorptive differential pulse voltammetric method. The modified electrode was thoroughly characterized through the utilization of cyclic voltammetry (CV), field-emission scanning electron microscopy (FESEM), and electrochemical impedance spectroscopy (EIS). Under optimized conditions, the concentration of sumatriptan was determined within two linear ranges: 1.0–50.0 nM and 50.0–5000.0 nM, with a detection limit of 0.03 nM. Ultimately, the suggested approach was employed to gauge the sumatriptan content in tablet and urine samples, revealing that this method possesses the requisite levels of accuracy and precision.

用二苯胺-4-磺酸钠盐(DPASA)和4-乙烯基吡啶(VP)共聚合对铅笔石墨电极进行了直接的一步改性,并同时形成了二氧化钌纳米粒子(聚(DPASA-co-VP)-RuO2 NPs/PGE)。随后的步骤涉及应用改变电极,采用高灵敏度的吸附差分脉冲伏安法检查舒马曲坦的量。利用循环伏安法(CV)、场发射扫描电镜(FESEM)和电化学阻抗谱(EIS)对改性电极进行了全面表征。在优化条件下,舒马曲坦的浓度测定在1.0 ~ 50.0 nM和50.0 ~ 5000.0 nM两个线性范围内,检出限为0.03 nM。最后,该方法被用于测定片剂和尿样中的舒马曲坦含量,表明该方法具有必要的准确度和精密度。
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引用次数: 0
Preparation and Properties of High-Temperature Transient Thin-Film Thermopile Heat Flux Sensor 高温瞬态薄膜热电堆热流传感器的制备与性能研究
IF 2.2 4区 工程技术 Q3 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-10-09 DOI: 10.1007/s11664-024-11476-0
Shanghang Xie, Jin Zhu, Hongchuan Jiang, Xiaohui Zhao, Baorui Liu, Zhouxia Jia

The thermopile of the sensor consists of 192 pairs of Pt-PtRh10 thermocouples with length 1 mm and width 100 μm in serpentine series were deposited on Al2O3 ceramic substrates by a photolithography coating process. The thermal resistance layers with the proposed low thermal conductivity feature a meshed cavity structure, with four thermal resistance layers spaced over the thermopile contacts to enhance the sensitivity of the sensor. Calibration of the sensor’s sensitivity was performed by a flat-plate radiative heat flux device, while its response time was measured by a pulsed laser. Finally, the sensor’s performance in an actual application environment was simulated using a wind tunnel. The results showed that the thin-film heat flux sensor can operate in environments ranging from 200°C to 1500°C, with a sensitivity of 0.03067 m2 μV/W, the maximum relative error was 8.5% with an average response time of 12.7 μs. The sample exhibited stable performance during wind tunnel testing, responding quickly to changes in heat flux.

Graphical Abstract

该传感器的热电堆由192对长1 mm、宽100 μm的Pt-PtRh10热电偶组成,采用光刻镀膜工艺沉积在Al2O3陶瓷衬底上。所提出的低导热系数的热阻层具有网状腔结构,在热电堆触点上间隔有四个热阻层,以提高传感器的灵敏度。利用平板辐射热通量仪标定传感器的灵敏度,利用脉冲激光测量传感器的响应时间。最后,利用风洞模拟了传感器在实际应用环境中的性能。结果表明,薄膜式热流通量传感器可在200 ~ 1500℃的工作环境中工作,灵敏度为0.03067 m2 μV/W,最大相对误差为8.5%,平均响应时间为12.7 μs。在风洞测试中,样品表现出稳定的性能,对热通量的变化反应迅速。图形抽象
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引用次数: 0
Design and Optimization of a Piezoelectric Acoustic Sensor for Fluid Leak Detection Applications 用于流体泄漏检测的压电声传感器的设计与优化
IF 2.2 4区 工程技术 Q3 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-10-08 DOI: 10.1007/s11664-024-11504-z
Mohini Sawane, Mahanth Prasad, Rajesh Kumar

Pipeline leaks are known to frequently occur in chemical processing and urban gas pipes, which can lead to equipment damage, explosions, and potentially serious injuries. A design of a piezoelectric acoustic sensor for fluid leak detection is proposed in this work. The low-frequency acoustic leak signals that travel through the fluid in a pipeline can be detected using a piezoelectric acoustic sensor. The design and simulation of sensor is done using COMSOL Multiphysics software. The sensor specification is used to guide the choice of materials and optimization of geometry. The simulated results show the characteristics of transient response using a nondestructive detection approach at various leakage rates. The recommended detection method's ability to detect leak signals with tolerable accuracy is shown through simulated results. The designed sensor can be used for both long-term leak monitoring and short-term safety evaluations. The simulated sensitivity of 191 µV/m at 27.46 kHz resonance frequency is achieved by optimizing device design. The maximum deflection at the center is 2.37 nm. The total electric energy generated at 1 N of force and 5 Hz frequency is 8 nJ.

在化工和城市燃气管道中,管道泄漏是经常发生的事故,可能导致设备损坏、爆炸和潜在的严重伤害。本文提出了一种用于流体泄漏检测的压电声传感器的设计。通过使用压电声学传感器,可以检测到通过管道流体传播的低频声泄漏信号。利用COMSOL Multiphysics软件对传感器进行了设计和仿真。传感器规格用于指导材料的选择和几何结构的优化。仿真结果显示了不同泄漏率下无损检测方法的瞬态响应特性。通过模拟结果表明,所推荐的检测方法能够以可容忍的精度检测泄漏信号。所设计的传感器既可用于长期泄漏监测,也可用于短期安全评估。通过优化器件设计,在27.46 kHz谐振频率下实现了191µV/m的模拟灵敏度。中心的最大偏转为2.37 nm。在1n的力和5hz的频率下产生的总电能为8nj。
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引用次数: 0
Effect of Mn Doping on the Morphological and Optical Properties of Ba0.92Sr0.08Ti1-xMnxO3 Materials for Microwave Device Applications 掺杂锰对用于微波器件的 Ba0.92Sr0.08Ti1-xMnxO3 材料的形态和光学特性的影响
IF 2.2 4区 工程技术 Q3 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-10-07 DOI: 10.1007/s11664-024-11418-w
Mikanshi Chaudhary, Sheela Devi, Sukhdeep Kaur, Shilpi Jindal

In this work, we investigated the impact of Mn substitution on the morphological, structural, and optical properties of barium strontium titanate (BST) with the formula Ba0.92Sr0.08Ti1−xMnxO3 (x = 0.00, 0.10, 0.20) fabricated using the solid-state reaction technique. The morphological and structural properties were studied using scanning electron microscopy (SEM) and x-ray diffraction (XRD). The optical properties of the samples were analyzed using photoluminescence (PL), Fourier transform infrared (FTIR), and Raman spectroscopy. SEM micrographs displayed nearly spherical grains. The phase formation, lattice structure, crystallite size (D), strain (ε), and dislocation density (δ) of the Mn-doped BST ceramics were examined from the recorded XRD patterns using the Scherrer and Williamson–Hall (W–H) models, which showed that the crystallite size increased and the lattice strain and dislocation density decreased with increasing doping concentrations. FTIR results for the pristine sample of BST revealed that the absorption peak at a wavenumber of 470 cm−1 was shifted to 1250 cm−1 for Mn-doped BST concentrations. The Raman results indicated that the number of modes decreased with the increase in the Mn2+ concentrations. PL spectra showed an emission band centered at 60–659 nm, indicating redshift behavior. The analysis using XRD, SEM, FTIR, and Raman spectroscopy revealed that the concentration x = 0.20 is appropriate for use in microwave devices and other electro-optical applications.

在这项工作中,我们研究了锰取代对钛酸锶钡(BST)的形态、结构和光学性能的影响,该BST的分子式为Ba0.92Sr0.08Ti1−xMnxO3 (x = 0.00, 0.10, 0.20)。利用扫描电子显微镜(SEM)和x射线衍射仪(XRD)研究了材料的形貌和结构特性。利用光致发光(PL)、傅里叶变换红外(FTIR)和拉曼光谱分析了样品的光学性质。SEM显微图显示晶粒接近球形。采用Scherrer和Williamson-Hall (W-H)模型分析了mn掺杂BST陶瓷的相形成、晶格结构、晶粒尺寸(D)、应变(ε)和位错密度(δ),结果表明,随着掺杂浓度的增加,晶粒尺寸增大,晶格应变和位错密度减小。原始BST样品的FTIR结果显示,在掺杂mn的BST浓度下,波数为470 cm−1的吸收峰移到了1250 cm−1。拉曼结果表明,随着Mn2+浓度的增加,模式数量减少。PL光谱显示出以60 ~ 659 nm为中心的发射带,显示出红移行为。通过XRD, SEM, FTIR和Raman光谱分析表明,x = 0.20的浓度适合用于微波器件和其他电光应用。
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引用次数: 0
Investigation of Dielectric and Piezoelectric Properties of Polyvinylidene Fluoride Films Reinforced with Anatase Phase Titanium Dioxide for Pressure Sensing 锐钛矿相二氧化钛增强聚偏氟乙烯薄膜的介电和压电性能研究
IF 2.2 4区 工程技术 Q3 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-10-07 DOI: 10.1007/s11664-024-11499-7
Krishna Tewatia, Anuradha Sharma, Sohan Lal, Sridharbabu Yarramaneni, Tanuj Kumar, Arun Kumar

In the present study, anatase phase titanium dioxide (A-TiO2)-reinforced polyvinylidene fluoride (PVDF) nanocomposite films are synthesized by the solvent casting method. The electroactive phase, dielectric, and piezoelectric properties are studied for A-TiO2 nanoparticles at 0.8 wt.%, 1.6 wt.%, 2.4 wt.%, 3.2 wt.%, and 4.0 wt.% content in the PVDF matrix. X-ray diffraction (XRD) and Fourier transform infrared (FTIR) spectroscopy are used to assess the structural properties and the enhancement in the electroactive β phase, respectively. The β phase is found to improve up to 77%. Atomic force microscopy (AFM) shows that the roughness of the films increases with an increase in the amount of reinforcement. The dielectric constant (ε′) and dissipation factor are found to vary with filler weight percentage and frequency. The dielectric constant increases to 24.45 for 2.4 wt.% of A-TiO2 nanoparticles. The piezo-response increases significantly from 0.6 V to 1.3 V for the nanocomposite in comparison to pure PVDF films. The results of the current study show numerous potential applications in energy-harvesting pressure sensors.

本研究采用溶剂铸造法制备了锐钛矿相二氧化钛(A-TiO2)增强聚偏氟乙烯(PVDF)纳米复合薄膜。研究了A-TiO2纳米粒子在PVDF基体中含量为0.8 wt.%、1.6 wt.%、2.4 wt.%、3.2 wt.%和4.0 wt.%时的电活性相、介电和压电性能。利用x射线衍射(XRD)和傅里叶变换红外光谱(FTIR)分别评价了结构性能和电活性β相的增强。β相提高了77%。原子力显微镜(AFM)结果表明,膜的粗糙度随增强量的增加而增加。发现介电常数ε′和耗散系数随填料的重量百分比和频率而变化。当A-TiO2纳米粒子质量分数为2.4 wt.%时,介电常数增加到24.45。与纯PVDF膜相比,纳米复合材料的压电响应从0.6 V显著增加到1.3 V。目前的研究结果显示了能量收集压力传感器的许多潜在应用。
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引用次数: 0
Study of Di-/Ferro-/Piezoelectric Properties of Sm3+-Doped ZnO Nanoparticles Sm3+掺杂ZnO纳米颗粒的双/铁/压电性能研究
IF 2.2 4区 工程技术 Q3 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-10-07 DOI: 10.1007/s11664-024-11480-4
Radha Verma, Sahil Goel, Komal Verma, Krishan Kant, Rajesh Kumar, Maneesha Garg, Rashi Gupta

Pristine ZnO and Sm-doped ZnO nanoparticles were synthesized using a wet chemical co-precipitation technique. The morphological and structural characteristics of pristine and Sm-doped ZnO were studied by field-emission scanning electron microscopy (FESEM) and X-ray diffraction (XRD) techniques. Increases in lattice parameters, interplanar spacing, and volume was observed from the XRD patterns compared to its JCPDS card. Crystallite size, dislocation density, deformation stress, lattice strain, and energy density for both pristine and Sm-ZnO nanoparticles were calculated using Scherrer and Williamson–Hall (W–H) methods. An energy bandgap reduction was observed in the Sm-doped ZnO (Eg ~ 2.7 eV), which played a crucial role in explaining the increased leakage currents in Sm-ZnO. The Sm-doped ZnO nanoparticles exhibited a remnant polarization (Pr ~ 0.163 µC/cm2) and a coercive field (Ec ~ 25.33 kV/cm). Current–voltage (I–V) characteristics show maximum current generated on applying varying voltages (Vmax = 40 V, Imax =  ~600 μA). Frequency- and temperature-dependent dielectric studies were conducted to examine the change in the values of the dielectric constant and dielectric loss with the variation in frequency and temperature. The Sm-doped ZnO-based nanogenerator generated an output voltage ~ 400 mV at tapping force of ~ 0.02 kgf, which makes it a prominent candidate for self-powered devices.

Graphical Abstract

采用湿化学共沉淀法合成了原始氧化锌和sm掺杂氧化锌纳米颗粒。采用场发射扫描电镜(FESEM)和x射线衍射(XRD)技术研究了原始ZnO和sm掺杂ZnO的形貌和结构特征。与JCPDS卡相比,从XRD图中可以观察到晶格参数、面间距和体积的增加。采用Scherrer和Williamson-Hall (W-H)方法计算了原始和Sm-ZnO纳米颗粒的晶粒尺寸、位错密度、变形应力、晶格应变和能量密度。在sm掺杂的ZnO (Eg ~ 2.7 eV)中观察到能量带隙减小,这是Sm-ZnO中泄漏电流增加的关键原因。sm掺杂ZnO纳米粒子具有残余极化(Pr ~ 0.163µC/cm2)和矫顽力场(Ec ~ 25.33 kV/cm)。电流-电压(I-V)特性显示了施加不同电压时产生的最大电流(Vmax = 40 V, Imax = ~600 μA)。进行了频率和温度相关的介电研究,以检查介电常数和介电损耗值随频率和温度变化的变化。在攻丝力为~ 0.02 kgf的情况下,smo掺杂zno基纳米发电机的输出电压为~ 400 mV,是自供电器件的理想选择。图形抽象
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引用次数: 0
Study of Dielectric Properties of Binary Mixtures of n-Octanol and N,N-Dimethylformamide in Lower Microwave Radiation 正辛醇和N,N-二甲基甲酰胺二元混合物在低微波辐射下的介电性能研究
IF 2.2 4区 工程技术 Q3 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-10-07 DOI: 10.1007/s11664-024-11505-y
N. A. Chaudhary, S. P. Patel, C. R. Vaja, N. K. Acharya, V. A. Rana, A. N. Prajapati

The complex permittivity spectra of binary mixtures (0.0 → 1.0) of n-octanol and N,N-dimethylformamide (DMF) were obtained in the lower microwave radiation region using a vector network analyzer (VNA) at 293.15 K The complex permittivity spectra of n-octanol with DMF and binary mixtures were fitted in a dielectric relaxation model (Havriliak–Negami) to obtain the static dielectric constant (ε0) and relaxation time (τ). Complex nonlinear least-squares (CNLS) fitting was used to fit the complex dielectric spectra. The nonlinear variation in ε0 and τ against DMF concentration in binary mixtures of n-octanol + DMF indicated hetero-molecular interaction between participating molecular species. The variation in the dielectric constant and dielectric loss against concentration is discussed in light of their dependence on frequency. The microwave radiation heating parameters including power reflected (pr), power transmitted (pt), and penetration depth (dp) were investigated at general purpose and commercial microwave radiation of 2.45 GHz, respectively.

Graphical Abstract

利用矢量网络分析仪(VNA)在293.15 K下获得了正辛醇与N,N-二甲基甲酰胺(DMF)二元混合物(0.0→1.0)的复介电常数谱。将正辛醇与DMF及二元混合物的复介电常数谱拟合到介电弛豫模型(Havriliak-Negami)中,得到了其静态介电常数(ε0)和弛豫时间(τ)。采用复非线性最小二乘(CNLS)拟合方法拟合复介质谱。在正辛醇+ DMF二元混合物中,ε0和τ随DMF浓度的非线性变化表明参与分子种之间存在异分子相互作用。从介电常数和介电损耗与频率的关系出发,讨论了介电常数和介电损耗随浓度的变化。研究了微波辐射加热参数,包括反射功率(pr)、透射功率(pt)和穿透深度(dp),分别在普通微波和2.45 GHz商用微波辐射下进行。图形抽象
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引用次数: 0
期刊
Journal of Electronic Materials
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