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2011 International Symposium on Water Resource and Environmental Protection最新文献

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Calculating precipitation recharge to groundwater applying envieronmental chloride tracer method 应用环境氯化物示踪法计算降水补给量
Pub Date : 2011-06-16 DOI: 10.1109/ISWREP.2011.5892965
Q. Yong, Zhang Zhaoji, Fei Yuhong, Zhang Feng’e, C. Jingsheng
Precipitation infiltration recharge of groundwater has happened great change in North China Plain, caused by thick unsaturated zone going with groundwater level's drop, because of long-term sustainable mining. In this paper, rainfall infiltration recharge, in typical section of Piedmont Plain, was calculated applying environmental chloride tracer method, followed by objectivity analysis to the results. Rainfall infiltration coefficient, calculated by Chloride Accumulated Method, are 2.17%(K1) and 4.38%(K2), while infiltration quantity are 11.54mm/a(K1) and 23.29mm/a(K2) in current groundwater level (30m). Compared to the average value of this zone in 1985, 0.28, and the highest value, 0.37, and the lowest value, 0.18, the coefficient reduced significantly.
由于长期持续开采,华北平原地下水降水入渗补给量发生了较大的变化,这是由于地下水位下降而形成的厚非饱和带。本文采用环境氯离子示踪法对山前平原典型断面的降雨入渗补给量进行了计算,并对结果进行了客观分析。氯化物累积法计算的降雨入渗系数分别为2.17%(K1)和4.38%(K2),当前地下水位(30m)下的入渗量分别为11.54mm/a(K1)和23.29mm/a(K2)。与1985年的平均值0.28、最高值0.37和最低值0.18相比,该系数显著降低。
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引用次数: 2
Determination of vanadium(V) based on its ternary complex with 2-(8-quinolylazo)-4,5-diphenylimidazole and hydrogen peroxide by high performance liquid chromatography 高效液相色谱法测定2-(8-喹啉偶氮)-4,5-二苯咪唑和过氧化氢三元配合物中钒的含量
Pub Date : 2011-06-16 DOI: 10.1109/ISWREP.2011.5893600
Chengjie Zhang, Jing Liu, B. Yao, Luo-hong Zhang
A method based on reversed-phase high performance liquid chromatographic separation in combination with spectrophotometric detection was developed for the determination of trace amounts of vanadium(V) as its ternary complex with 2-(8-quinolylazo)-4,5-diphenylimidazole (QAI) and hydrogen peroxide. Spectral and chromatographic behaviors of the ternary complex were investigated. The complex was formed in weekly acidic medium (pH 2.5-4.0) and separated on a Cosmosil 5C8-MS column with 58% (m/m) aqueous acetonitrile mobile phase containing 5.0 × 10-3 mol kg-1 acetate buffer (pH 3.5), 1.0 × 10-4 mol kg-1 tetrabutylammonium bromide and 1.0 × 10-3 mol kg-1 ethylenediaminetetraacetic acid and detected at 595 nm. The calibration curve was linear up to 35 ng for vanadium(V) in 25.0 mL of test solution at 0.001 absorbance unit full scale. The detection limit was 2 pg for vanadium(V) with 100 L injection. The method showed good accuracy, selectivity and sensitivity for the determination of vanadium(V) in environmental samples.
建立了以2-(8-喹啉偶氮)-4,5-二苯基咪唑(QAI)和过氧化氢为溶剂的钒(V)三元配合物的反相高效液相色谱分离-分光光度法测定痕量钒的方法。研究了三元配合物的光谱和色谱行为。该配合物在周酸性培养基(pH 2.5-4.0)中形成,在Cosmosil 5C8-MS色谱柱上分离,色谱柱为58% (m/m)的乙腈水流动相,其中含有5.0 × 10-3 mol kg-1醋酸缓冲液(pH 3.5)、1.0 × 10-4 mol kg-1四丁基溴化铵和1.0 × 10-3 mol kg-1乙二胺四乙酸,在595 nm处检测。在0.001吸光度单位满量程下,在25.0 mL测试溶液中,钒(V)的校准曲线在35 ng以下呈线性。进样量为100 L时,钒(V)的检出限为2 pg。该方法对环境样品中钒的测定具有良好的准确度、选择性和灵敏度。
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引用次数: 3
Bioremediation of β-cypermethrin and 3-phenoxybenzoic acid in soils β-氯氰菊酯和3-苯氧苯甲酸在土壤中的生物修复作用
Pub Date : 2011-06-16 DOI: 10.1109/ISWREP.2011.5893579
Shaohua Chen, Yanbo Zhang, M. Hu, P. Geng, Yanan Li, Guodong An
β-cypermethrin (β-CP) is one of the most frequently and widely used kind of insecticides. Increasing use of β-CP has posed potential adverse effects on the environment; therefore, it is critically necessary to develop remediation strategies to remove β-CP from the environment. In this study, bioremediation efficiency of β-CP contaminated soils was assessed based on the results of laboratory experiment. The selected bacterium Achromobacter sp. strain P-01 was used to degrade β-CP and its major metabolite 3-phenoxybenzoic acid (3-PBA) in different soils. Studies on bioremediation in sterilized soil showed that strain P-01 exhibited efficient degradation of β-CP and 3-PBA (both 50 mg·kg-1) with a rate constant of 0.1857 and 0.1084 day-1, respectively. The degradation process followed the first-order kinetics and the half-life (T1/2) for β-CP and 3-PBA was 3.7 and 6.4 days, respectively. Studies on bioremediation in non-sterilized soil showed that degradation rates were 90.4% and 70.6% for β-CP and 3-PBA within 10 days after strain P-01 introduction, which was characterized by a constant of 0.3334 and 0.1341 day-1, respectively. Comparing with the control without inoculum, T1/2 for β-CP and 3-PBA reduced by 21.6-154.8 days. These results indicated that strain P-01 may have potential for use in bioremediation of β-CP contaminated environment.
β-氯氰菊酯(β-CP)是一种使用最频繁、应用最广泛的杀虫剂。越来越多地使用β-CP对环境造成了潜在的不利影响;因此,迫切需要开发修复策略来去除环境中的β-CP。本研究在室内试验的基础上,对β-CP污染土壤的生物修复效果进行了评价。选用无色杆菌P-01菌株降解不同土壤中β-CP及其主要代谢物3-苯氧苯甲酸(3-PBA)。无菌土壤生物修复研究表明,菌株P-01对β-CP和3-PBA(均为50 mg·kg-1)具有较好的降解效果,降解速率分别为0.1857和0.1084 d -1。降解过程符合一级动力学,β-CP和3-PBA的半衰期(T1/2)分别为3.7和6.4 d。对未灭菌土壤的生物修复研究表明,菌株P-01引入后10 d内,β-CP和3-PBA的降解率分别为90.4%和70.6%,降解常数分别为0.3334和0.1341 d -1。与未接种的对照相比,β-CP和3-PBA的T1/2缩短了21.6 ~ 154.8 d。这些结果表明,菌株P-01可能在β-CP污染环境的生物修复中具有潜在的应用价值。
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引用次数: 6
Isotopic and pollen evidence of paleo-vegetation changes in loess plateau of Luochuan, China 洛川黄土高原古植被变化的同位素和花粉证据
Pub Date : 2011-05-20 DOI: 10.1109/ISWREP.2011.5893428
Lu Yudong, Gu Jinyan, Sun Jianzhong, Ma Yuan, Han Mingchao, Li Yan, L. Hongjuan
Carbon isotopes in loess through S0 to S11 at Luochuan section in Shanxi province, China were studied. The curve of δ13C compares well to that of the oxygen isotope in deep sea sediments from Deep Sea Drilling Project Site 607 drill hole. There is a negative peak of δ13C within S5 paleosol where the content of δ13C is -16.6150/00, shows that the climatic of that period is optimum, and the vegetation is likely forest. Compared with the pollen analysis, we conclude that the vegetation type of palesol S0,S1,S4,S8,S9, whose δ13C content is -5.85--10.000/00, is forest-grass. The d13C content of paleosol S2, S3, S6, S7 is -8.72~-6.950/00, and their vegetation is grass. The loess layer L1, L2, L5, L6, L8, L9 represent the severe cold-dry glacial period with the δ13C content of -3.7- -2.270/00, and their vegetation belongs to steppe-desert. The research of paleo-vegetation type is significant to anti-soil erosion in the loess plateau of China.
对山西洛川剖面S0 ~ S11期黄土碳同位素进行了研究。δ13C曲线与深海钻探项目607钻孔的深海沉积物氧同位素曲线具有较好的一致性。S5古土壤δ13C呈负峰,δ13C含量为-16.6150/00,说明该时期气候适宜,植被可能为森林。与孢粉分析相比较,认为古土壤S0、S1、S4、S8、S9的δ13C含量为-5.85 ~ 10.000/00,植被类型为林草植被。古土壤S2、S3、S6、S7的d13C含量为-8.72~-6.950/00,植被为禾草。黄土L1、L2、L5、L6、L8、L9层为严重干冷冰期,δ13C含量为-3.7 ~ -2.270/00,植被类型为草原-荒漠。古植被类型的研究对黄土高原的土壤侵蚀防治具有重要意义。
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引用次数: 0
A study on the defluoridation thermodynamic and kinetics of the D401 version resin D401型树脂脱氟热力学和动力学研究
Pub Date : 2011-05-20 DOI: 10.1109/ISWREP.2011.5893284
Dong Sui-ming, Lin Chun-xiao, Wu Shu-feng
Adsorption model, dynamic mechanism and adsorption thermodynamic property of the version resin are discussed in this study. The results shows that Freundlich equation can favorably associate with the adsorption of fluoride ion on the D401 version resin. The adsorption process of fluorine for modified is carried out according to Freundlich adsorption model. The adsorption process is control by internal diffusion. The defluoridation material has good capability of defluoridation and the adsorption process is exothermal chemical adsorption. So rising temperature will go against the adsorption.
讨论了该树脂的吸附模型、动力学机理和吸附热力学性质。结果表明,Freundlich方程与D401型树脂对氟离子的吸附关系良好。根据Freundlich吸附模型进行了氟改性吸附过程。吸附过程由内扩散控制。该脱氟材料具有良好的脱氟性能,吸附过程为放热化学吸附。所以温度升高不利于吸附。
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引用次数: 0
Screening a novel high effective dioscorea zingiberensis degradation strain 一株高效薯蓣降解菌株的筛选
Pub Date : 2011-05-20 DOI: 10.1109/ISWREP.2011.5893294
Yanjun Lu, Jifeng Guo
12 strains of cellulolytic microorganism were isolated from the AB reactor of dioscorea zingiberensis wastewater treatment. A bacterial strain was obtained through the screening experiments of decomposition of dioscorea zingiberensis, which had high degradability for dioscorea zingiberensis and was named D-1. The gene sequence obtained from the DNA extraction and polymerase chain reaction (PCR) amplification was compared with NCBI Genbank of U.S.A., and the strain was preliminary identified to be Clostridium cellulosolvens. The optimum growth conditions were pH 5.0, 30°C, 100 r/min.
从盾叶薯蓣废水处理的AB反应器中分离出12株纤维素降解微生物。通过对盾叶薯蓣的分解筛选实验,获得了一株对盾叶薯蓣具有较高降解率的菌株,命名为D-1。通过DNA提取和聚合酶链反应(PCR)扩增获得的基因序列与美国NCBI Genbank进行比对,初步鉴定该菌株为Clostridium cellulosolvens。最佳生长条件为pH 5.0, 30℃,100 r/min。
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引用次数: 0
Characterization and bentonite amendment of oil contaminated soils 油污染土壤的表征及膨润土改性
Pub Date : 2011-05-20 DOI: 10.1109/ISWREP.2011.5893611
Wen-Ting Wang, Chen-Hong Wu, Yun‐Hai Wang, Jinglian Zhao
Bentonite has the advantages of strong hygroscopicity, expansibility, adsorptivity and adhesivity. It can ameliorate and reclaim soils. This research focused on the oil contaminated soils amendment by bentonite. The oil contaminated soils were characterized with different techniques and compared with the background soils to evaluate its contaminating level. The results indicated that the soils were heavily contaminated with oil and its ventilation, porosity and bioaccessibility were greatly affected. The addition of bentonite could affect the physical-chemical properties of soils and the possible mechanisms were discussed. It was demonstrated that bentonite addition could improve the soils water conservation, the air ventilation in soil and the sticky particles percentage. However, the pH increased a little by adding bentonite. The addition of bentonite could enhance the oil degradation.
膨润土具有较强的吸湿性、膨胀性、吸附性和粘附性等优点。它可以改良和开垦土壤。研究了膨润土对石油污染土壤的修复作用。采用不同的技术对油类污染土壤进行表征,并与本底土壤进行比较,评价其污染程度。结果表明,油类污染严重,土壤的通气性、孔隙度和生物可达性受到较大影响。膨润土的加入会影响土壤的理化性质,并对其可能的机理进行了探讨。结果表明,添加膨润土可以提高土壤的保水能力、土壤的通风性和粘粒率。添加膨润土后,pH值略有升高。膨润土的加入对油的降解有促进作用。
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引用次数: 0
Post-disaster assessment of northeastern coastal region for the 2011 Sendai Earthquake and tsunami 2011年仙台地震和海啸对东北沿海地区的灾后评估
Pub Date : 2011-05-20 DOI: 10.1109/ISWREP.2011.5893759
Ruopu Li, Shishi Liu, Qingfeng Guan, Yi Peng
The 2011 Sendai Earthquake has hit the north-east of Japan triggering a destructive tsunami that has caused extensive damage. A fast and effective post-disaster assessment is highly imperative for the recovery of this region. This study modeled the tsunami-affected areas of coastal Fukushima Prefecture using Landsat-7 ETM+ data and terrain analysis. The result shows that most of the coastal areas were significantly affected by the tsunami. The low-lying plains along the coast are particularly vulnerable to the tsunami.
2011年仙台地震袭击了日本东北部,引发了破坏性的海啸,造成了广泛的破坏。快速有效的灾后评估对该地区的恢复至关重要。本研究利用Landsat-7 ETM+数据和地形分析对福岛县沿海海啸灾区进行了模拟。结果表明,大部分沿海地区受海啸影响较大。沿海低洼的平原特别容易受到海啸的袭击。
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引用次数: 9
Application of Monte Carlo sampling and Latin Hypercube sampling methods in pumping schedule design during establishing surrogate model 建立代理模型时蒙特卡罗抽样和拉丁超立方抽样方法在抽油计划设计中的应用
Pub Date : 2011-05-20 DOI: 10.1109/ISWREP.2011.5892983
Yin Jinhang, Lu Wenxi, Xin Xin, Zhang Lei
For creating surrogate model of the groundwater numerical simulation model of Jinquan Industrial Park in Inner Mongolia, the application of Monte Carlo sampling method and Latin Hypercube Sampling method in pumping test design is studied. Firstly make sure the pumping load of each pumping wells obeys uniform distribution, then generate Monte Carlo samples and Latin Hypercube samples according to their own methods. Analyses these two results comparing with each other, it suggests that in small sample size, Monte Carlo sampling method has a low sampling efficiency, low coverage of the sampling value to population and needs a large amount of calculation, while Latin Hypercube Sampling method relatively improves the sampling efficiency, coverage of the sampling value to population, and reduce the workload. Latin Hypercube Sampling method has better practicability in this job.
为建立内蒙古金泉工业园区地下水数值模拟模型的代理模型,研究了蒙特卡罗采样法和拉丁超立方采样法在抽水试验设计中的应用。首先保证各抽井的抽载服从均匀分布,然后根据各自的方法生成蒙特卡罗样本和拉丁超立方样本。通过对两种结果的对比分析,表明在小样本量下,蒙特卡罗采样方法的采样效率低,采样值对总体的覆盖率低,需要大量的计算量,而拉丁超立方采样方法相对提高了采样效率,采样值对总体的覆盖率,减少了工作量。拉丁超立方抽样方法在该工作中具有较好的实用性。
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引用次数: 16
Alteration of inner-annual runoff distribution and attribution analysis of Longchuan station at Dongjiang River 东江龙川站年内径流分布变化及归因分析
Pub Date : 2011-05-20 DOI: 10.1109/ISWREP.2011.5893071
Xie Ping, Xu Bin, Huang Caixia, Chen Guangcai, Liu Xinyou, Tang Yasong
Due to the climate change, human activities and other factors, there are some inter-annual or inner-annual alterations happened in the hydrological series. Many important works had been affected severely, such as the planning and designation of hydraulic engineering, the sustainable utilization and optimal allocation of water resources etc. However, the studies about the features of inner-annual hydrologic elements distribution are mainly focused on the analysis of the inhomogeneity, with the disadvantage of unintuition and the poor comparability of the indicators from the view of methods that used nowadays, few of the studies considering the alteration of the inhomogeneity happened or not under the changing environment. Therefore, the Gini Coefficient with the advantage of well description of inhomogeneity is used to set up the analysis method of hydrological alteration of the inner-annual distribution. In this method, the series of homogeneity of inner-annual hydrological elements distribution will be calculated first of all, then the Hydrological Alteration Diagnosis System is used to analyze whether the alteration is happened in the series or not, finally, the mean difference method will be employed to analyze the attributions if the alteration is existing. At the end of this study, with the monthly runoff data from the year of 1954 to 2005 of Longchuan Station at Dongjiang River, the alterational characteristics of inner-annual runoff distribution is calculated and the attribution analysis is conducted in succession. The results show that: at the year of 1973, the increasing jump alteration happened in the series of inner-annual runoff distribution, which means the tendency of inner-annual runoff distribution becomes equalization. About 60% of the alteration is induced by the human activities, especially the construction and operation of Fengshuba Reservoir, and the factor of climate change only accounts for about 40%.
由于气候变化、人类活动等因素的影响,水文序列存在一定的年际或年内变化。许多重要的工程,如水利工程的规划设计、水资源的可持续利用和优化配置等都受到了严重的影响。然而,关于年内水文要素分布特征的研究主要集中在对非均匀性的分析上,从现有的方法来看,存在非直观性和指标可比性差的缺点,很少有研究考虑不均匀性的变化是否发生在变化的环境下。因此,利用具有较好描述非均匀性的基尼系数建立年内分布水文变化的分析方法。该方法首先计算年内水文要素分布的均匀性序列,然后利用水文变化诊断系统分析该序列中是否发生了变化,如果存在变化,则采用均差法分析归因。最后,利用东江龙川站1954 ~ 2005年的逐月径流资料,计算了东江龙川站年内径流分布的变化特征,并进行了归因分析。结果表明:在1973年,年内径流分布序列出现了越来越大的跃变,表明年内径流分布趋于均衡。人类活动,尤其是枫树坝水库的建设和运行,约占60%,气候变化因素仅占40%左右。
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引用次数: 4
期刊
2011 International Symposium on Water Resource and Environmental Protection
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