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Synthesis of MnO2/ZIF-8 for the construction of Pt-free counter electrode for dye-sensitized solar cell applications 合成用于构建染料敏化太阳能电池无铂对电极的 MnO2/ZIF-8
IF 2.6 4区 化学 Q3 ELECTROCHEMISTRY Pub Date : 2024-07-23 DOI: 10.1007/s10008-024-06021-2
Khursheed Ahmad, Praveen Kumar, Rais Ahmad Khan, Dieudonne Tanue Nde, Waseem Raza

Herein, we reported the synthesis of MnO2/ZIF-8 composite by employing two-step synthetic procedure. The synthesized samples have been characterized by utilizing various sophisticated physicochemical technique such as X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and energy-dispersive X-ray (EDX) spectroscopy. The synthesized MnO2/ZIF-8 has been used as counter electrode (CE) for the fabrication of dye-sensitized solar cells (DSSCs). The effect of annealing temperature was studied, and the highest efficiency of 7.2% with a decent open-circuit voltage (Voc) of 0.77 V was achieved at 200 °C. The obtained efficiency of 7.2% is reasonable in comparison to the platinum (Pt)-based DSSCs (7.4%). This work proposed the construction of Pt-free CE for the development of cost-effective DSSCs with reasonable performance in terms of efficiency.

在此,我们采用两步合成法合成了 MnO2/ZIF-8 复合材料。我们利用各种复杂的物理化学技术,如 X 射线衍射 (XRD)、扫描电子显微镜 (SEM)、X 射线光电子能谱 (XPS) 和能量色散 X 射线 (EDX) 光谱,对合成样品进行了表征。合成的 MnO2/ZIF-8 被用作制造染料敏化太阳能电池(DSSC)的对电极(CE)。对退火温度的影响进行了研究,结果表明,在 200 ℃ 时效率最高,达到 7.2%,开路电压(Voc)为 0.77 V。与铂(Pt)基 DSSC(7.4%)相比,7.2% 的效率是合理的。这项工作提出了构建无铂 CE 的建议,以开发具有合理效率性能的高性价比 DSSC。
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引用次数: 0
Eco-friendly synthesis of gold nanoparticles onto glassy carbon electrode and its application to DNA biosensor 在玻璃碳电极上以环保方式合成金纳米粒子并将其应用于 DNA 生物传感器
IF 2.6 4区 化学 Q3 ELECTROCHEMISTRY Pub Date : 2024-07-23 DOI: 10.1007/s10008-024-06014-1
Phuong Thao Dao Vu, Dien Nguyen Dac, Tam Phuong Dinh

This work studies gold nanoparticle (AuNP) nucleation and growth mechanism from deep eutectic solvent (DES)-based choline chloride and glycerol (glyceline) onto glassy carbon electrode (GCE) and its application for DNA biosensor. Investigation of the current density transients indicated that the AuNPs were formed by the simultaneous presence of Au diffusion-controlled 3D nucleation and growth and residual water reaction over the Au nuclei growing surfaces. The AuNP structure was characterized by the field emission scanning electron microscopy, energy dispersive X-ray spectroscopy, and X-ray diffraction. AuNPs were used to fabricate electrochemical DNA sensor. The hybridization was monitored by cyclic voltammetry and electrochemical impedance spectroscopy measurement using potassium ferri/ferrocyanide redox probes ({left[Fe{(CN)}_{6}right]}^{3-/4-}) as the indicator probe. Results show that the biosensor exhibited a linear correlation to the logarithm of the target DNA concentration ranged from 1.10−14 M to 1.10−9 M, and the limit of detection was 1.10−14 M. Furthermore, the findings indicate that the prepared electrode exhibited excellent reproducibility and long-term stability when applied for determining M. tuberculosis samples.

这项工作研究了基于深共晶溶剂(DES)的氯化胆碱和甘油(甘氨酸)在玻璃碳电极(GCE)上的金纳米粒子(AuNP)成核和生长机制及其在 DNA 生物传感器中的应用。对电流密度瞬态的研究表明,AuNPs 是由金扩散控制的三维成核和生长以及金核生长表面的残余水反应同时存在而形成的。场发射扫描电子显微镜、能量色散 X 射线光谱和 X 射线衍射对 AuNP 结构进行了表征。利用 AuNPs 制作了电化学 DNA 传感器。使用铁/铁氰化钾氧化还原探针({left[Fe{(CN)}_{6}right]}^{3-/4-})作为指示探针,通过循环伏安法和电化学阻抗谱测量来监测杂交。结果表明,该生物传感器与目标 DNA 浓度的对数在 1.10-14 M 到 1.10-9 M 之间呈现线性相关,检测限为 1.10-14 M。
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引用次数: 0
3D carbonaceous substrates synthesized from melamine sponges for energy storage: Influence of pyrolysis temperature in physicochemical and electrochemical properties 由三聚氰胺海绵合成的三维碳质基底用于能量存储:热解温度对物理化学和电化学性质的影响
IF 2.6 4区 化学 Q3 ELECTROCHEMISTRY Pub Date : 2024-07-23 DOI: 10.1007/s10008-024-05971-x
Natalia Patricia Páez-Sánchez, E. Córdoba-Tuta, J. Vazquez-Samperio, P. Acevedo-Peña, E. Reguera

High-energy global requirements have caused a renewed interest in studying and developing new and improved energy storage devices and, precisely, the electrode materials that compose them, which play a fundamental role in determining the device’s performance. Carbon materials are first-class candidates due to their high electrical conductivity, chemical stability, and surface area. Although several carbon materials and their precursors have been studied, melamine sponges stand out for their nitrogen content, allowing them to act as a template and precursor for N-doped, ultralight carbon materials with good mechanical properties and a controlled pore size distribution. This work reports a simple and quick methodology to form ultralight and flexible carbon foam, along with the influence of the pyrolysis temperature on the physicochemical and electrochemical properties of 3D carbonaceous substrates used for energy storage and synthesized from melamine sponges. The substrates exhibit higher 3D porous structure than previously reported materials, with an average pore diameter of 80–90 µm. This morphology, added to the N content, promotes the remarkable electrochemical behavior (MS–950 °C) and cycling stability (MS–1000 °C) of almost 100% of capacitance retention after 10,000 cycles (≈ 60 F/g @1 A/g).

全球对高能量的需求再次激发了人们对研究和开发新型、改良型储能设备的兴趣,确切地说,是对设备性能起决定性作用的电极材料的兴趣。碳材料因其高导电性、化学稳定性和表面积而成为一流的候选材料。虽然已经对多种碳材料及其前驱体进行了研究,但三聚氰胺海绵因其含氮量高而脱颖而出,可作为掺氮超轻碳材料的模板和前驱体,具有良好的机械性能和可控的孔径分布。这项研究报告了一种形成超轻柔性泡沫碳材料的简单快速方法,以及热解温度对三聚氰胺海绵合成的用于储能的三维碳质基底的物理化学和电化学性质的影响。与之前报道的材料相比,这些基底呈现出更高的三维多孔结构,平均孔径为 80-90 微米。这种形态加上氮含量,促进了显著的电化学行为(MS-950 °C)和循环稳定性(MS-1000 °C),10000 次循环后电容保持率几乎达到 100%(≈ 60 F/g @1 A/g)。
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引用次数: 0
Modeling solid-state reaction processes: application for the archaeometric study of potteries from Venus Fisica Temple in Pompeii (Italy) 固态反应过程建模:应用于庞贝(意大利)维纳斯菲西卡神庙陶器的考古研究
IF 2.5 4区 化学 Q3 ELECTROCHEMISTRY Pub Date : 2024-07-22 DOI: 10.1007/s10008-024-06011-4
Francesca Di Turo, Caterina De Vito, Fulvio Coletti, Antonio Doménech-Carbó

This research employs the voltammetry of immobilized microparticles (VIMP) methodology to analyze a collection of ceramic samples from the temple of Venus Fisica in the archaeological site of Pompeii. The primary objective is to discern their origins and manufacturing processes by the solid-state analysis of the electroactive properties of iron minerals, particularly hematite, extensively investigated for its electrochemical and catalytic characteristics. In our study, we propose a model to elucidate the electrochemical processes involved, building upon prior logistic and nucleation formulations. In this model, we consider the possibility of two superimposed pathways. This approach provides a nuanced understanding of composition changes and mineral crystallinity, factors that can induce significant variations in the voltammetric signal. Consequently, it becomes an effective means to discriminate between different provenances and manufacturing techniques of different potteries. The outcomes of this research contribute valuable insights into the intricate realm of ancient ceramic materials, casting light on their origins and production processes within the historical context of Pompeii.

这项研究采用固定微粒伏安法(VIMP)分析庞贝考古遗址维纳斯菲西卡神庙中的陶瓷样品。主要目的是通过对铁矿物,特别是赤铁矿(因其电化学和催化特性而被广泛研究)的电活性特性进行固态分析,来确定它们的来源和制造工艺。在我们的研究中,我们在先前的逻辑和成核公式的基础上,提出了一个模型来阐明所涉及的电化学过程。在该模型中,我们考虑了两种叠加途径的可能性。通过这种方法,我们可以对成分变化和矿物结晶度有一个细致入微的了解,因为这些因素会导致伏安信号的显著变化。因此,它成为区分不同产地和不同陶器制造技术的有效手段。这项研究成果有助于深入了解古代陶瓷材料的复杂领域,揭示其在庞贝历史背景下的起源和生产工艺。
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引用次数: 0
Sensing reaching the stars: mild condition ZnO defect development for vitamin detection 感知星空:用于维生素检测的温和条件氧化锌缺陷开发
IF 2.5 4区 化学 Q3 ELECTROCHEMISTRY Pub Date : 2024-07-22 DOI: 10.1007/s10008-024-06020-3
Anton Abramyan, Mikhail Golovin, Valeriya Zakharchenkova, Andrey Lalov, Dalibor Stanković, Oleg Bol’shakov

Here, we present the preparation and electrochemical evaluation of a vitamin B2-riboflavin (RF) sensor based on hierarchically structured zinc oxide (ZnO) of the wurtzite type. The highly crystalline ZnO obtained under hydrothermal conditions from a zinc peroxocomplex has the appearance of “micro-stars,” with an average size of 10 μm. Development of unusual morphology was accompanied by significant lattice defect introduction. Zinc oxide as an electroactive additive for carbon paste electrode was studied with electrochemical impedance spectroscopy (EIS), cyclic voltammetry (CV), and differential pulse voltammetry (DPV), which revealed excellent charge mobility and low resistivity. Electrochemical properties of the semiconductor allowed for development of riboflavin (RF) electrochemical sensor with an improved linearity range and a low limit of detection. The repeatability and stability of the sensor were at a satisfactory level for real-time measurements.

Graphical abstract

Conventional hydrothermal treatment of zinc peroxocomplex provided star-shaped zinc oxide microparticles with metal-deficient lattice. Increased defect concentration facilitated charge mobility, which helped in developing of sensor for relevant vitamin.

在此,我们介绍了一种基于层状结构沃特兹型氧化锌(ZnO)的维生素 B2-核黄素(RF)传感器的制备和电化学评估。在水热条件下从锌过氧化物复合物中获得的高结晶氧化锌具有 "微星 "外观,平均尺寸为 10 μm。异常形态的形成伴随着晶格缺陷的显著引入。利用电化学阻抗谱(EIS)、循环伏安法(CV)和微分脉冲伏安法(DPV)研究了氧化锌作为碳浆电极电活性添加剂的情况,结果表明其具有出色的电荷迁移率和低电阻率。半导体的电化学特性使得核黄素(RF)电化学传感器的线性范围更宽,检测限更低。该传感器的重复性和稳定性达到了令人满意的实时测量水平。缺陷浓度的增加促进了电荷的迁移,有助于开发相关维生素的传感器。
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引用次数: 0
Low-cost and stable Li1.5Al0.3Ti1.7Si0.2P2.8O12 glass–ceramics for lithium extraction from seawater 用于从海水中提取锂的低成本、稳定的 Li1.5Al0.3Ti1.7Si0.2P2.8O12 玻璃陶瓷
IF 2.6 4区 化学 Q3 ELECTROCHEMISTRY Pub Date : 2024-07-22 DOI: 10.1007/s10008-024-06015-0
Bo Chang, Yigang Wang, Yue Dai, Mingjie Du, Haoshen Zhou, Ping He

Rapid development of electronic and grid storage technologies based on lithium-ion batteries are leading to tight supply of lithium resources in the future. Extracting lithium from seawater can completely solve the problem of lithium resource shortage. An electro-deposition method based on a lithium superionic conductive solid-state electrolyte, Li1.5Al0.5Ge1.5(PO4)3 (LAGP), has been reported to obtain metallic lithium from seawater. However, expensive LAGP increases the cost of lithium extraction, while Li1.3Al0.3Ti1.7(PO4)3 (LATP) with relatively lower prices cannot meet the stable requirements. Herein, a low-cost, stable glass–ceramics, Li1.5Al0.3Ti1.7Si0.2P2.8O12 (LATSP), has been prepared for lithium extraction from seawater. The LATSP glass–ceramics show good selectivity towards Li+ and exhibit a high ionic conductivity of 3.98 × 10−4 S cm−1 at 22 °C. After soaking in simulated seawater, LATSP showed much better stability than LATP, comparable to LAGP. The resultant LATSP glass–ceramics was successfully employed in a seawater lithium extraction device, with a high lithium extraction Coulombic efficiency of 94.0%. Moreover, the LATSP exhibits an ionic conductivity of 2.80 × 10−4 S cm−1 and maintains a complete structure after 45 h of lithium extraction. This work presents an effective and practical Li-ion conducting membrane for lithium extraction from seawater.

Graphical Abstract

以锂离子电池为基础的电子和电网存储技术的快速发展导致未来锂资源供应紧张。从海水中提取锂可以彻底解决锂资源短缺的问题。据报道,一种基于锂超离子导电固态电解质 Li1.5Al0.5Ge1.5(PO4)3 (LAGP) 的电沉积方法可从海水中提取金属锂。然而,昂贵的 LAGP 增加了锂提取的成本,而价格相对较低的 Li1.3Al0.3Ti1.7(PO4)3 (LATP) 则无法满足稳定的要求。本文制备了一种低成本、稳定的玻璃陶瓷 Li1.5Al0.3Ti1.7Si0.2P2.8O12 (LATSP),用于从海水中提取锂。LATSP 玻璃陶瓷对 Li+ 具有良好的选择性,在 22 °C 时离子电导率高达 3.98 × 10-4 S cm-1。在模拟海水中浸泡后,LATSP 显示出比 LATP 更好的稳定性,可与 LAGP 相媲美。制备出的 LATSP 玻璃陶瓷被成功应用于海水锂萃取装置,锂萃取库仑效率高达 94.0%。此外,LATSP 的离子电导率为 2.80 × 10-4 S cm-1,并且在锂萃取 45 小时后仍能保持完整的结构。这项研究为从海水中提取锂提供了一种有效而实用的锂离子传导膜。
{"title":"Low-cost and stable Li1.5Al0.3Ti1.7Si0.2P2.8O12 glass–ceramics for lithium extraction from seawater","authors":"Bo Chang,&nbsp;Yigang Wang,&nbsp;Yue Dai,&nbsp;Mingjie Du,&nbsp;Haoshen Zhou,&nbsp;Ping He","doi":"10.1007/s10008-024-06015-0","DOIUrl":"10.1007/s10008-024-06015-0","url":null,"abstract":"<div><p>Rapid development of electronic and grid storage technologies based on lithium-ion batteries are leading to tight supply of lithium resources in the future. Extracting lithium from seawater can completely solve the problem of lithium resource shortage. An electro-deposition method based on a lithium superionic conductive solid-state electrolyte, Li<sub>1.5</sub>Al<sub>0.5</sub>Ge<sub>1.5</sub>(PO<sub>4</sub>)<sub>3</sub> (LAGP), has been reported to obtain metallic lithium from seawater. However, expensive LAGP increases the cost of lithium extraction, while Li<sub>1.3</sub>Al<sub>0.3</sub>Ti<sub>1.7</sub>(PO<sub>4</sub>)<sub>3</sub> (LATP) with relatively lower prices cannot meet the stable requirements. Herein, a low-cost, stable glass–ceramics, Li<sub>1.5</sub>Al<sub>0.3</sub>Ti<sub>1.7</sub>Si<sub>0.2</sub>P<sub>2.8</sub>O<sub>12</sub> (LATSP), has been prepared for lithium extraction from seawater. The LATSP glass–ceramics show good selectivity towards Li<sup>+</sup> and exhibit a high ionic conductivity of 3.98 × 10<sup>−4</sup> S cm<sup>−1</sup> at 22 °C. After soaking in simulated seawater, LATSP showed much better stability than LATP, comparable to LAGP. The resultant LATSP glass–ceramics was successfully employed in a seawater lithium extraction device, with a high lithium extraction Coulombic efficiency of 94.0%. Moreover, the LATSP exhibits an ionic conductivity of 2.80 × 10<sup>−4</sup> S cm<sup>−1</sup> and maintains a complete structure after 45 h of lithium extraction. This work presents an effective and practical Li-ion conducting membrane for lithium extraction from seawater.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":null,"pages":null},"PeriodicalIF":2.6,"publicationDate":"2024-07-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141738585","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electrochemical properties of polythiophene/iron dust composites synthesized using chemical oxidative polymerization 利用化学氧化聚合法合成的聚噻吩/铁粉复合材料的电化学特性
IF 2.6 4区 化学 Q3 ELECTROCHEMISTRY Pub Date : 2024-07-19 DOI: 10.1007/s10008-024-06008-z
Rizwan Ullah, Misbah Ullah, Nadia Khan, Maheen Rahim

The supercapacitive properties of the polythiophene (PTh) and its composites with iron dust synthesized by chemical oxidative polymerization are investigated. The UV–Vis, FTIR, TGA, XRD, SEM, and EDX were used to characterize the composites. Iron (Fe) dust is inserted into PTh matrix as confirmed by FTIR, UV–Vis, EDX, and XRD analysis. The TGA shows that composites have higher thermal stability than pure PTh. The SEM reveals highly porous and packed morphology of the composites as compared to pure PTh. Cyclic voltammetry (CV), galvanostatic charge–discharge (GCD), and electrochemical impedance spectroscopy (EIS) show that a 1:1 ratio by mass of PTh and Fe composite displayed greater specific capacitance than pure PTh. The high specific capacitance of the composite material (428.46 F/g at 1 A/g) suggested that the material is suitable for supercapacitor electrode. Cyclic stability is also tested for 1000 cycles at a current density of 1 A/g with excellent retention of 88.89%.

Graphical Abstract

研究了通过化学氧化聚合法合成的聚噻吩(PTH)及其与铁粉的复合材料的超级电容特性。复合材料的表征采用了紫外可见光、傅立叶变换红外光谱、热重分析、X射线衍射、扫描电镜和电离辐射显微镜。傅立叶变换红外光谱(FTIR)、紫外可见光光谱(UV-Vis)、电离辐射 X 射线衍射(EDX)和 X 射线衍射(XRD)分析证实,铁(Fe)粉尘被加入到 PTh 基体中。热重分析表明,与纯 PTh 相比,复合材料具有更高的热稳定性。扫描电子显微镜(SEM)显示,与纯 PTh 相比,复合材料具有高多孔性和填充形态。循环伏安法(CV)、电静态充放电法(GCD)和电化学阻抗光谱法(EIS)显示,按质量比为 1:1 的 PTh 和铁复合材料比纯 PTh 显示出更大的比电容。复合材料的高比电容(1 A/g 时为 428.46 F/g)表明该材料适用于超级电容器电极。此外,在电流密度为 1 A/g 的条件下,还进行了 1000 次循环稳定性测试,结果表明其保持率达到 88.89%。
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引用次数: 0
Electrical conductivity of pectin-based biopolymer electrolytes: search for a theoretical framework 果胶基生物聚合物电解质的导电性:寻找理论框架
IF 2.5 4区 化学 Q3 ELECTROCHEMISTRY Pub Date : 2024-07-19 DOI: 10.1007/s10008-024-06018-x
Kailash Kumar, Ikhwan Syafiq Mohd Noor, Shri Prakash Pandey, Bhaskar Bhattacharya, Amit Saxena

This paper reports the successful fabrications of polymer electrolytes using biopolymer pectin in conjunction with ammonium azide (NaN3) salt by solution casting method. The ionic conductivity of these electrolytes was evaluated using EIS at room temperature. Among the compositions tested, the highest conductivity of 2.3 × 10−3 S cm−1 was observed to sample of 5 wt.% of NaN3. The charge carriers' concentration (n) and mobility (µ) were calculated to understand the conductivity behavior attributed to dispersoids. For the calculation of n and μ, two theoretical models were used, namely the Trukhan and the S&G Model. The correlations between conductivity, n and μ are discussed.

本文报告了利用生物聚合物果胶和叠氮化铵(NaN3)盐通过溶液浇铸法成功制备聚合物电解质的情况。这些电解质的离子电导率在室温下通过 EIS 进行了评估。在测试的成分中,NaN3 含量为 5 wt.% 的样品电导率最高,达到 2.3 × 10-3 S cm-1。通过计算电荷载流子浓度(n)和迁移率(μ),可以了解分散体的导电行为。在计算 n 和 μ 时,使用了两种理论模型,即 Trukhan 模型和 S&G 模型。讨论了电导率、n 和 μ 之间的相关性。
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引用次数: 0
The effect of coprecipitation and heating temperature on structural evolution and electrochemical performance of iron-based prussian blue analogs 共沉淀和加热温度对铁基普鲁士蓝类似物结构演变和电化学性能的影响
IF 2.6 4区 化学 Q3 ELECTROCHEMISTRY Pub Date : 2024-07-17 DOI: 10.1007/s10008-024-06005-2
Yuqing Liu, Wencheng Chu, Yaozu Xu, Zijian Yuan, Jiarui Liu, Haitao Zhao, Quan Liu, Wu Zhang

Iron-based Prussian blue analogs (PBAs) are synthesized using a modified coprecipitation approach at different temperatures to study the effect of coprecipitation reaction temperature on structural and electrochemical performance. The experimental results showed that the iron-based PBAs transferred from the cubic structure to the monoclinic phase as the temperature increased from 5 °C to 60 °C, with the former exhibiting rich-in-boundary morphology and the latter showing a well-defined cubic shape. The electrochemical performance of the samples is closely related to the structure: the PBAs with monoclinic structures exhibit a higher charge/discharge specific capacity than those of PBAs with cubic structures. In addition, the samples are further treated at 270 °C, new phases are probed, and the charge/discharge specific capacity for the HT-PB-60 sample is significantly improved by more than 36.15%.

采用改良共沉淀方法,在不同温度下合成了铁基普鲁士蓝类似物(PBAs),以研究共沉淀反应温度对结构和电化学性能的影响。实验结果表明,随着温度从 5 ℃升高到 60 ℃,铁基 PBA 从立方结构转变为单斜相,前者表现出丰富的边界形貌,后者则呈现出清晰的立方体形状。样品的电化学性能与结构密切相关:单斜结构的 PBA 比立方结构的 PBA 具有更高的充放电比容量。此外,样品在 270 ℃ 下进一步处理后,探究出了新的相,HT-PB-60 样品的充放电比容量显著提高了 36.15% 以上。
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引用次数: 0
Passivity breakdown of high-strength 7068 aluminum alloy in borate buffer solutions containing chlorides 高强度 7068 铝合金在含氯化物的硼酸盐缓冲溶液中的钝性破坏
IF 2.6 4区 化学 Q3 ELECTROCHEMISTRY Pub Date : 2024-07-17 DOI: 10.1007/s10008-024-06010-5
Ankur Kumar, Gajanan P. Chaudhari

Passivity breakdown mechanism of high-strength 7068 alloy is studied. Breakdown potential varied linearly with log aCl, pH, and square root of scan rate in potentiodynamic polarization tests. Mott-Schottky analysis showed that the dominant defect is cation vacancy. Passive layer characteristics like cation vacancy density and defect annihilation rate are determined. Critical cation vacancy density for pitting obtained from point defect model and the theoretical values are somewhat compatible. Chloride concentration of 0.01 M is too dilute to cause severe localized corrosion, whereas beyond 0.5 M, saturation is achieved in terms of breakdown potential and the cation vacancy density.

研究了高强度 7068 合金的钝化击穿机理。在电位极化测试中,击穿电位与对数 aCl-、pH 值和扫描速率的平方根呈线性变化。莫特-肖特基分析表明,主要缺陷是阳离子空位。确定了阳离子空位密度和缺陷湮灭率等被动层特征。根据点缺陷模型得出的点蚀临界阳离子空位密度与理论值基本吻合。氯化物浓度为 0.01 M 时,由于过于稀释而导致严重的局部腐蚀,而超过 0.5 M 时,就击穿电位和阳离子空位密度而言,则达到了饱和状态。
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引用次数: 0
期刊
Journal of Solid State Electrochemistry
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