Pub Date : 2017-02-28DOI: 10.17265/1934-7375/2017.02.008
O. Dogan, R. Dag
Liquid SiO2 solutions produced by silicon-based nanopowder are covered on the fabric surface by using spray method. Fabric surfaces were coated at the room temperature in air with the different spray nozzles. Surface analysis of the coated fabric was performed by using Contact Angle and SEM pictures. According to the Contact Angles measurements, the coated fabric surfaces showed hydrophobic character between 126 and 146 degrees, and the SiO2 particles sticked to the fabric fibers as seen from SEM picture.
{"title":"Application of Nano Coating (SiO2) on Textile Products","authors":"O. Dogan, R. Dag","doi":"10.17265/1934-7375/2017.02.008","DOIUrl":"https://doi.org/10.17265/1934-7375/2017.02.008","url":null,"abstract":"Liquid SiO2 solutions produced by silicon-based nanopowder are covered on the fabric surface by using spray method. Fabric surfaces were coated at the room temperature in air with the different spray nozzles. Surface analysis of the coated fabric was performed by using Contact Angle and SEM pictures. According to the Contact Angles measurements, the coated fabric surfaces showed hydrophobic character between 126 and 146 degrees, and the SiO2 particles sticked to the fabric fibers as seen from SEM picture.","PeriodicalId":67212,"journal":{"name":"化学与化工:英文版","volume":" ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2017-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42209381","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2017-02-28DOI: 10.17265/1934-7375/2017.02.006
A. Yerkin, Yemelyanova Valentina, S. Tatyana, Bulenbaev Maxat, Blagikh Evgeniy
The authors have studied the effect of a magnetic field on Baldwin’s rules. The authors have proposed a new mechanism that takes into account the effect of the angle and energy endoor exo-cyclization. The authors propose to extend the rule Bouldwin not only for sp-, spand sporbits, but and for d d and f f elements of I-VIII of the Periodic table.
{"title":"The New Approach of Expansion Baldwin-Aibassov’s Rules for Ring-Closing Reaction for d- and f-elements Periodic Table of Elements","authors":"A. Yerkin, Yemelyanova Valentina, S. Tatyana, Bulenbaev Maxat, Blagikh Evgeniy","doi":"10.17265/1934-7375/2017.02.006","DOIUrl":"https://doi.org/10.17265/1934-7375/2017.02.006","url":null,"abstract":"The authors have studied the effect of a magnetic field on Baldwin’s rules. The authors have proposed a new mechanism that takes into account the effect of the angle and energy endoor exo-cyclization. The authors propose to extend the rule Bouldwin not only for sp-, spand sporbits, but and for d d and f f elements of I-VIII of the Periodic table.","PeriodicalId":67212,"journal":{"name":"化学与化工:英文版","volume":" ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2017-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49438382","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2017-01-28DOI: 10.17265/1934-7375/2017.01.002
Shih-Kun Lo, W. Hong, Hsueh-I Tan, Hua Ting, Ting-Wei Liu, Ruey‐yi Lee
This research presents the results of system validation tests for an SOFC power system. In the study, the system was heated up without electric device, i.e., the fuel providing the required thermal energy through an integrated BOP (balance of plant). The ex-situ experiments, without an SOFC stack installed in the system, were first conducted to investigate the operability of a BOP apparatus. It was found that the BOP possessed high conversion rates for both steam reforming and water gas shift reactions. The total fuel concentration of hydrogen and carbon monoxide from the reformer was around 91.2%. The system validation tests showed that, with the natural gas as fuel, the output power from the stack reached to 1,060 W, while the fuel utilization efficiency and electrical efficiency were 67.16% and 45.0%, respectively. A steady 600-hour system operation test was carried out at an average system temperature of 694 C. Of which, a 36-cell stack was employed for the test. Meanwhile, the current, voltage and output power were 26 A, 32.3 V and 840 W, respectively, and its electrical efficiency was around 33.4%.
{"title":"System Validation Tests for an SOFC Power System at INER","authors":"Shih-Kun Lo, W. Hong, Hsueh-I Tan, Hua Ting, Ting-Wei Liu, Ruey‐yi Lee","doi":"10.17265/1934-7375/2017.01.002","DOIUrl":"https://doi.org/10.17265/1934-7375/2017.01.002","url":null,"abstract":"This research presents the results of system validation tests for an SOFC power system. In the study, the system was heated up without electric device, i.e., the fuel providing the required thermal energy through an integrated BOP (balance of plant). The ex-situ experiments, without an SOFC stack installed in the system, were first conducted to investigate the operability of a BOP apparatus. It was found that the BOP possessed high conversion rates for both steam reforming and water gas shift reactions. The total fuel concentration of hydrogen and carbon monoxide from the reformer was around 91.2%. The system validation tests showed that, with the natural gas as fuel, the output power from the stack reached to 1,060 W, while the fuel utilization efficiency and electrical efficiency were 67.16% and 45.0%, respectively. A steady 600-hour system operation test was carried out at an average system temperature of 694 C. Of which, a 36-cell stack was employed for the test. Meanwhile, the current, voltage and output power were 26 A, 32.3 V and 840 W, respectively, and its electrical efficiency was around 33.4%.","PeriodicalId":67212,"journal":{"name":"化学与化工:英文版","volume":" ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2017-01-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44662031","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2017-01-28DOI: 10.17265/1934-7375/2017.01.001
Darlan Ferreira da Silva, M. Landgraf, M. O. Rezende
An alternative and fast method for the analysis of a mixture of nine triazines herbicides in soil is presented. The method is based on MAE (microwave-assisted extraction) of herbicides using ethyl acetate as extractant. The economy in the use of solvents coupled with the decrease in extraction time and lower power consumption make MAE a technique that meets the principles of green chemistry. MAE operational parameters, extraction time, mass of the sample and extraction temperature, were optimized by RSM (response surface methodology). Determination of analytes was completed using gas chromatograph coupled to mass spectrometry detection. The selected triazines could be efficiently extracted by the solvent at 80 °C for 10 min, with 80% output of maximum power. When the optimized method was applied to analysis samples, the recoveries of analytes ranged from 81.8 to 106.0% and relative standard deviations were lower than 8.41%. The method is stable and reasonable, which can be used for the determination of ninetriazine herbicides residues in soil.
{"title":"Assessment of Triazine Herbicides in Soil by Microwave-assisted Extraction Followed by Gas Chromatography Coupled to Mass Spectrometry Detection","authors":"Darlan Ferreira da Silva, M. Landgraf, M. O. Rezende","doi":"10.17265/1934-7375/2017.01.001","DOIUrl":"https://doi.org/10.17265/1934-7375/2017.01.001","url":null,"abstract":"An alternative and fast method for the analysis of a mixture of nine triazines herbicides in soil is presented. The method is based on MAE (microwave-assisted extraction) of herbicides using ethyl acetate as extractant. The economy in the use of solvents coupled with the decrease in extraction time and lower power consumption make MAE a technique that meets the principles of green chemistry. MAE operational parameters, extraction time, mass of the sample and extraction temperature, were optimized by RSM (response surface methodology). Determination of analytes was completed using gas chromatograph coupled to mass spectrometry detection. The selected triazines could be efficiently extracted by the solvent at 80 °C for 10 min, with 80% output of maximum power. When the optimized method was applied to analysis samples, the recoveries of analytes ranged from 81.8 to 106.0% and relative standard deviations were lower than 8.41%. The method is stable and reasonable, which can be used for the determination of ninetriazine herbicides residues in soil.","PeriodicalId":67212,"journal":{"name":"化学与化工:英文版","volume":" ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2017-01-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43486400","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2017-01-28DOI: 10.17265/1934-7375/2017.01.006
U. Osonwa, S. Majekodunmi, Emmanuella OnyechiN, Harrison Thaddeus Gugu
Solid lipid microparticles of erythromycin ethyl succinate were prepared using solvent evaporation method to improve its bioavailability and efficacy. The solvent was allowed to evaporate after which the various entrapments were determined; the best entrapment was used in the in vivo studies to determine the bioavailability and efficacy. This study was done with albino mice. The best entrapment obtained was 83% with a loading capacity of 2.9% (Batch D) and was used in comparison with the unformulated drug to check for the in vivo efficacy. The results show higher efficacy with the formulated drug than with the pure drug both in vitro and in vivo. The in vitro test results were better despite that some enzymes which need to act on the solid lipid microparticles were not present in the in vitro assay and could lead to a reduction in the release of the drugs. In conclusion, there was improvement in efficacy, and hence bioavailability.
{"title":"Bioavailability Improvement of SLMs Based Erythromycin Ethyl Succinate using Stearic Acid-Myrj-52-based SLM’s","authors":"U. Osonwa, S. Majekodunmi, Emmanuella OnyechiN, Harrison Thaddeus Gugu","doi":"10.17265/1934-7375/2017.01.006","DOIUrl":"https://doi.org/10.17265/1934-7375/2017.01.006","url":null,"abstract":"Solid lipid microparticles of erythromycin ethyl succinate were prepared using solvent evaporation method to improve its bioavailability and efficacy. The solvent was allowed to evaporate after which the various entrapments were determined; the best entrapment was used in the in vivo studies to determine the bioavailability and efficacy. This study was done with albino mice. The best entrapment obtained was 83% with a loading capacity of 2.9% (Batch D) and was used in comparison with the unformulated drug to check for the in vivo efficacy. The results show higher efficacy with the formulated drug than with the pure drug both in vitro and in vivo. The in vitro test results were better despite that some enzymes which need to act on the solid lipid microparticles were not present in the in vitro assay and could lead to a reduction in the release of the drugs. In conclusion, there was improvement in efficacy, and hence bioavailability.","PeriodicalId":67212,"journal":{"name":"化学与化工:英文版","volume":" ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2017-01-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46817880","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2017-01-28DOI: 10.17265/1934-7375/2017.01.004
E. Brandaleze, M. Ramírez, M. Ávalos
In low carbon microalloyed steels (C 0.1%), the content of V, Nb and Ti affects the phases transformation kinetic during cooling in the rolling process. The final microstructure determines the required mechanical properties such as high formability, high toughness and adequate strength. For this reason it is relevant to identify and determine the volume fraction of the ferrite, bainite and martensite present in the structure. The microalloying elements: V, Nb and Ti promote carbides precipitation during cooling. The precipitates control the grain size refinement during hot rolling process and the mechanical properties of the steel. In this sense it is necessary to increase the knowledge on the microstructure evolution at different cooling rates. In this paper, the results obtained on two low carbon microalloyed steels (with C contents between 0.11%-0.06%) are reported. An integrated methodology including dilatometry in combination with microscopy techniques was applied. By EBSD (Electron Backscatter Diffraction) technique and microhardness measurements, the structural study was completed. Through a thermodynamic simulation using Fact Sage the type of precipitates in the studied steels structure at the temperature range between 950 °C and 450 °C, were predicted. The information on the evolution of the steel structure at rolling process conditions is relevant to consider changes in processing conditions.
{"title":"Microstructure Evolution at Different Cooling Rates of Low Carbon Microalloyed Steels","authors":"E. Brandaleze, M. Ramírez, M. Ávalos","doi":"10.17265/1934-7375/2017.01.004","DOIUrl":"https://doi.org/10.17265/1934-7375/2017.01.004","url":null,"abstract":"In low carbon microalloyed steels (C 0.1%), the content of V, Nb and Ti affects the phases transformation kinetic during cooling in the rolling process. The final microstructure determines the required mechanical properties such as high formability, high toughness and adequate strength. For this reason it is relevant to identify and determine the volume fraction of the ferrite, bainite and martensite present in the structure. The microalloying elements: V, Nb and Ti promote carbides precipitation during cooling. The precipitates control the grain size refinement during hot rolling process and the mechanical properties of the steel. In this sense it is necessary to increase the knowledge on the microstructure evolution at different cooling rates. In this paper, the results obtained on two low carbon microalloyed steels (with C contents between 0.11%-0.06%) are reported. An integrated methodology including dilatometry in combination with microscopy techniques was applied. By EBSD (Electron Backscatter Diffraction) technique and microhardness measurements, the structural study was completed. Through a thermodynamic simulation using Fact Sage the type of precipitates in the studied steels structure at the temperature range between 950 °C and 450 °C, were predicted. The information on the evolution of the steel structure at rolling process conditions is relevant to consider changes in processing conditions.","PeriodicalId":67212,"journal":{"name":"化学与化工:英文版","volume":" ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2017-01-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47658245","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2017-01-28DOI: 10.17265/1934-7375/2017.01.005
F. Naderi, V. Veryazov
Multiconfigurational second order perturbation theory was employed in order to describe the ground and excited states of C_60^(-n). Different choices of the active spaces are discussed and the possibility to apply multiconfigurational theory to study C_120 is investigated. The calculations were performed for all possible spin states (for selected charge) and show the preference of low spin state. The energy difference between two C_60^(-3) and pairs C_60^(-1)- C_60^(-5) and C_60^(-2)- C_60^(-4) shows that the probability to create a charge alternation in fullerides is small.
{"title":"Multiconfigurational Study of the Electronic Structure of Negatively Charged Fullerens","authors":"F. Naderi, V. Veryazov","doi":"10.17265/1934-7375/2017.01.005","DOIUrl":"https://doi.org/10.17265/1934-7375/2017.01.005","url":null,"abstract":"Multiconfigurational second order perturbation theory was employed in order to describe the ground and excited states of C_60^(-n). Different choices of the active spaces are discussed and the possibility to apply multiconfigurational theory to study C_120 is investigated. The calculations were performed for all possible spin states (for selected charge) and show the preference of low spin state. The energy difference between two C_60^(-3) and pairs C_60^(-1)- C_60^(-5) and C_60^(-2)- C_60^(-4) shows that the probability to create a charge alternation in fullerides is small.","PeriodicalId":67212,"journal":{"name":"化学与化工:英文版","volume":"11 1","pages":"30-30"},"PeriodicalIF":0.0,"publicationDate":"2017-01-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46406042","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2017-01-28DOI: 10.17265/1934-7375/2017.01.003
Ganchimeg Yunden, Burmaa Gunchin, N. Kano, Hee-Joon Kim
The silicon organic polymer containing PSOT-3 (dioxothiocarbamide groups) has been synthesized and characterized, and the adsorption of Au(III) on PSOT-3 was investigated. The results showed that PSOT-3 had good adsorption capacity for Au(III), and the adsorption of Au(III) was found to be the most effective in 0.1~0.3 mol/dm hydrochloric acid solution. The adsorption is physical and the process is endothermic, and Freundlich isotherm fits the data better than the Langmuir isotherm. The adsorption can be generally described by electrostatic interaction (Coulomb’s force) between the adsorbent and the adsorbate. The high adsorption capacity of this sorbent has significant potential for gold recovery from aqueous solutions.
{"title":"Recovery of Gold from Aqueous Solution Containing Au(III) by Silicon Organic Polymer","authors":"Ganchimeg Yunden, Burmaa Gunchin, N. Kano, Hee-Joon Kim","doi":"10.17265/1934-7375/2017.01.003","DOIUrl":"https://doi.org/10.17265/1934-7375/2017.01.003","url":null,"abstract":"The silicon organic polymer containing PSOT-3 (dioxothiocarbamide groups) has been synthesized and characterized, and the adsorption of Au(III) on PSOT-3 was investigated. The results showed that PSOT-3 had good adsorption capacity for Au(III), and the adsorption of Au(III) was found to be the most effective in 0.1~0.3 mol/dm hydrochloric acid solution. The adsorption is physical and the process is endothermic, and Freundlich isotherm fits the data better than the Langmuir isotherm. The adsorption can be generally described by electrostatic interaction (Coulomb’s force) between the adsorbent and the adsorbate. The high adsorption capacity of this sorbent has significant potential for gold recovery from aqueous solutions.","PeriodicalId":67212,"journal":{"name":"化学与化工:英文版","volume":" ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2017-01-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44943152","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2016-07-28DOI: 10.17265/1934-7375/2016.07.004
Hairui Zhang, Guofu Zhang, Li Zhang
Access database technology and Visual Basic programming language are used to develop a set of chemical reagents quality analysis and inspection of intelligent management application software, and its stability was investigated. The results show that the software is used to manage intelligently the quality analysis of chemical reagents test each linkage, to upload and save the analysis of test data and results in the network in time for users, to build a network of information sharing platform for enterprises and quality management departments, and its quality of chemical reagents test results is used to manage by the computer with practical application value. The software is simple, convenient, fast, friendly interface, stable operation, accurate and reliable results, with a high value to promote the application.
{"title":"Intelligent Management Based on Chemical Reagent Quality Analysis","authors":"Hairui Zhang, Guofu Zhang, Li Zhang","doi":"10.17265/1934-7375/2016.07.004","DOIUrl":"https://doi.org/10.17265/1934-7375/2016.07.004","url":null,"abstract":"Access database technology and Visual Basic programming language are used to develop a set of chemical reagents quality analysis and inspection of intelligent management application software, and its stability was investigated. The results show that the software is used to manage intelligently the quality analysis of chemical reagents test each linkage, to upload and save the analysis of test data and results in the network in time for users, to build a network of information sharing platform for enterprises and quality management departments, and its quality of chemical reagents test results is used to manage by the computer with practical application value. The software is simple, convenient, fast, friendly interface, stable operation, accurate and reliable results, with a high value to promote the application.","PeriodicalId":67212,"journal":{"name":"化学与化工:英文版","volume":"22 1","pages":"336-340"},"PeriodicalIF":0.0,"publicationDate":"2016-07-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"67524388","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2016-07-28DOI: 10.17265/1934-7375/2016.07.001
Alexander, Vasil'evich, Udal'tsov
Et3N (Mn-triethylamine) complex conjugated with binuclear Mn-hydroxide, Mn2(OH)3Cl and similar manganese complex with Et2NH (diethylamine) self-assembled in aqueous solutions have been investigated by simultaneous AFM (atomic force microscopy) and SNOM (scanning near-field optical microscopy) in thin layers prepared on mica and PET (polyethylene terephthalate). The size of the particles after crystallization of the precipitated former conjugate was controlled with XRD (X-ray diffraction). It is found that the conjugate self-assembling produces the smallest grains with the diameter of 65 ± 7.5 nm measured at contact with the support. This particle size matches the crystallite size of 44.2 nm found by XRD for the conjugate taking into account the particles deformation under the contact with the support. The self-assembly of the smallest particles in solution has produced non-transparent for light core observed on mica with the size varied between 300 to 400 nm. The latter occurs due to hydrophobic interactions since no core of the former conjugate has been found on hydrophobic PET surface. No submicroscopic core is also found in the case of similar conjugate with Mn-Et2NH complex on PET film and mica both.
{"title":"Behavior of Self-assembled Mn(III)/Mn(II)-NEt3 Conjugate on Different Support Observed by AFM-SNOM","authors":"Alexander, Vasil'evich, Udal'tsov","doi":"10.17265/1934-7375/2016.07.001","DOIUrl":"https://doi.org/10.17265/1934-7375/2016.07.001","url":null,"abstract":"Et3N (Mn-triethylamine) complex conjugated with binuclear Mn-hydroxide, Mn2(OH)3Cl and similar manganese complex with Et2NH (diethylamine) self-assembled in aqueous solutions have been investigated by simultaneous AFM (atomic force microscopy) and SNOM (scanning near-field optical microscopy) in thin layers prepared on mica and PET (polyethylene terephthalate). The size of the particles after crystallization of the precipitated former conjugate was controlled with XRD (X-ray diffraction). It is found that the conjugate self-assembling produces the smallest grains with the diameter of 65 ± 7.5 nm measured at contact with the support. This particle size matches the crystallite size of 44.2 nm found by XRD for the conjugate taking into account the particles deformation under the contact with the support. The self-assembly of the smallest particles in solution has produced non-transparent for light core observed on mica with the size varied between 300 to 400 nm. The latter occurs due to hydrophobic interactions since no core of the former conjugate has been found on hydrophobic PET surface. No submicroscopic core is also found in the case of similar conjugate with Mn-Et2NH complex on PET film and mica both.","PeriodicalId":67212,"journal":{"name":"化学与化工:英文版","volume":"10 1","pages":"305-314"},"PeriodicalIF":0.0,"publicationDate":"2016-07-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"67524027","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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