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Novel hybrid compounds containing 1,2,3-triazole and naphthalene subunits as xanthine oxidase inhibitors 作为黄嘌呤氧化酶抑制剂的含有 1,2,3-三唑和萘亚基的新型杂化化合物
IF 2.2 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-08-01 DOI: 10.1007/s13738-024-03061-3
Ayse Tan, Samir Abbas Ali Noma

In the present study, some hybrid compounds containing 1,2,3-triazole and naphthalene subunits 16(ag) and 17(af) were synthesized and characterized by 1H, 13C-NMR, FT-IR, and HR-MS analyses. The in vitro inhibitor activities on the xanthine oxidase (XO) enzyme of all the target compounds were investigated and compared with allopurinol, which is one of the most common gout drugs and inhibits the XO. The activity results show that all the target compounds have potential XO inhibitor activities. The compounds showed IC50 values in the range of 0.825–2.254 μM on the XO. IC50 value of allopurinol on the XO was determined to be 1.475 μM. 16e and 17e compounds among them exhibited the best inhibitions compared to other compounds and allopurinol. Additionally, molecular docking studies were carried out on the 3D crystallographic structure of the XO to investigate possible interactions with the active site of the XO of all compounds. According to the docking results, all the target compounds showed that the best binding energies vary in the between − 9.71 kcal.mol−1 and − 11.43 kcal.mol−1. Finally, in silico ADME and toxicity properties of the compounds were investigated using the Swiss ADME, ProTox-II, and Osiris Property Explorer websites and it has been predicted that the target compounds have low toxicity profiles. Consequently, the compounds can be considered new promising inhibitors for the XO.

本研究合成了一些含有 1,2,3-三唑和萘亚基 16(a-g) 和 17(a-f) 的杂化化合物,并通过 1H、13C-NMR、FT-IR 和 HR-MS 分析对其进行了表征。研究了所有目标化合物对黄嘌呤氧化酶(XO)的体外抑制活性,并与别嘌醇进行了比较。活性结果表明,所有目标化合物都具有潜在的 XO 抑制活性。这些化合物对 XO 的 IC50 值在 0.825-2.254 μM 之间。别嘌醇对 XO 的 IC50 值为 1.475 μM。与其他化合物和别嘌醇相比,16e 和 17e 化合物的抑制效果最好。此外,还对 XO 的三维晶体结构进行了分子对接研究,以探讨所有化合物与 XO 活性位点之间可能存在的相互作用。根据对接结果,所有目标化合物的最佳结合能介于 - 9.71 kcal.mol-1 和 - 11.43 kcal.mol-1 之间。最后,利用 Swiss ADME、ProTox-II 和 Osiris Property Explorer 网站对化合物的 ADME 和毒性特性进行了研究,结果表明目标化合物具有低毒性。因此,这些化合物可被视为新的有前途的 XO 抑制剂。
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引用次数: 0
Preparation of Mn3O4 nanoparticles on Al-substrate for degradation of Rhodamine B under solar light 在铝基底上制备用于在太阳光下降解罗丹明 B 的 Mn3O4 纳米粒子
IF 2.2 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-07-30 DOI: 10.1007/s13738-024-03054-2
A. Chaa, A. Haddad, G. Rekhila, S. Tria, M. Trari

The semiconducting properties of Mn3O4 thin films were assessed for the heterogeneous photocatalytic oxidation of Rhodamine B (Rh B). The films were grown on Al-substrate using a spray coating, and their physical and photoelectrochemical characteristics were studied. X-ray diffraction analysis showed a well-crystallized structure of the spinel Mn3O4. The atomic force microscopy revealed dense and irregular grains with a mean size of ~ 50 nm and a thickness of ~ 1 µm. The direct optical transition at 2.19 eV, in agreement with the brown color, is assigned to d–d transitions within the incomplete Mn-3d shell, which enables efficient photocatalytic conversion of the solar radiation. The photoelectrochemical measurements demonstrated p-type comportment, evidenced by a negative slope in the [capacitance−2–potential: C−2–E] graph with a flat band potential of + 0.35 VSCE and a hole density of 6.5 × 1018 cm−3. The electrochemical impedance spectroscopy (EIS) plot showed a semicircle due to a capacitive comportment of the bulk spinel (Rb = 70 kΩ cm2). The center positioned below the abscissa axis (− 23°) with a constant phase element (CPE). The conduction band (− 1.64 VSCE) is more cathodic than the ({text{O}}_{{2}} /{text{O}}_{{2}}^{ bullet - }) level, thus catalyzing the photocatalytic process by ({text{O}}_{{2}}^{ bullet - }) radicals. Under sunlight, 50% reduction of the Rh B concentration (10 ppm) was achieved within 1 h, the color removal, followed by spectrophotometry obeys a pseudo-first-order kinetic model with a rate constant of 9.9 × 10–3 min−1 (t1/2 = 70 min).

在罗丹明 B(Rh B)的异相光催化氧化过程中,对 Mn3O4 薄膜的半导体特性进行了评估。薄膜采用喷涂法在铝基底上生长,并对其物理和光电化学特性进行了研究。X 射线衍射分析表明尖晶石 Mn3O4 具有良好的晶体结构。原子力显微镜显示出致密而不规则的晶粒,平均尺寸约为 50 纳米,厚度约为 1 微米。2.19 eV 处的直接光学转变与棕色一致,是不完整的 Mn-3d 壳内的 d-d 转变,从而实现了太阳辐射的高效光催化转换。光电化学测量结果表明,该化合物具有 p 型特性,其[电容-2-电位:C-2-E]图的斜率为负值,平带电位为 + 0.35 VSCE,空穴密度为 6.5 × 1018 cm-3。电化学阻抗谱(EIS)图显示了一个半圆,这是由于块状尖晶石的电容性(Rb = 70 kΩ cm2)造成的。中心位置低于缺省轴(- 23°),具有恒定相位元素(CPE)。导带(- 1.64 VSCE)比 ({text{O}}_{{2}} /{text{O}}_{2}}^{ bullet - }) 电平更具阴极性,从而催化了 ({text{O}}_{2}}^{ bullet - }) 自由基的光催化过程。在阳光照射下,Rh B 浓度(10 ppm)在 1 小时内降低了 50%,颜色的去除以及随后的分光光度法遵循了一个伪一阶动力学模型,其速率常数为 9.9 × 10-3 min-1 (t1/2 = 70 分钟)。
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引用次数: 0
Synthesis and characterization of nanosize copper oxide by non-aqueous sol–gel process 利用非水溶胶-凝胶工艺合成纳米级氧化铜并确定其特性
IF 2.2 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-07-29 DOI: 10.1007/s13738-024-03065-z
Samreen Zahra, Tania Abbas, Asma Sheikh, Hamim Bukhari, Sarwat Zahra

Copper oxide nanoparticles calcined at temperatures varying from 500 to 900 °C were prepared through non-aqueous sol–gel route by using 2-ethyl hexanol as a modifying agent. Phase composition, presence of functional groups, thermal behavior, surface morphology and elemental composition of the prepared samples were identified by XRD, IR, TGA, FESEM and EDX. The results revealed the formation of single phase, i.e., monoclinic tenorite copper oxide with its entire transformation after calcination at 500 °C. Polyhedron shape nanoparticles of size below 100 nm were formed with a significant increase in the particle size and agglomeration due to nucleation growth of nanoparticles with the rise in calcination temperature. The synthesized samples showed a direct band gap of 4.08–4.14 eV. The study revealed that following the non-aqueous sol–gel process with 2-ethyl hexanol as a modifying agent inhibited agglomeration resulting in the formation of well-dispersed nanoparticles.

以 2- 乙基己醇为改性剂,通过非水溶胶-凝胶路线制备了在 500 至 900 °C 温度下煅烧的纳米氧化铜颗粒。通过 XRD、IR、TGA、FESEM 和 EDX 对所制备样品的相组成、官能团的存在、热行为、表面形貌和元素组成进行了鉴定。结果表明,在 500 °C 煅烧后,形成了单相,即单斜佃铜氧化物,并发生了完全转变。随着煅烧温度的升高,由于纳米粒子的成核生长,形成了粒径小于 100 纳米的多面体纳米粒子,且粒径和团聚度显著增加。合成样品的直接带隙为 4.08-4.14 eV。研究表明,以 2- 乙基己醇为改性剂的非水溶胶-凝胶工艺可抑制团聚,从而形成分散良好的纳米粒子。
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引用次数: 0
Synthesis of novel oxadiazole derivatives: DFT calculations, molecular docking studies, and in vitro, in vivo evaluation of antidiabetic activity using Drosophila melanogaster model 新型噁二唑衍生物的合成:DFT 计算、分子对接研究以及利用黑腹果蝇模型进行的体外和体内抗糖尿病活性评估
IF 2.2 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-07-26 DOI: 10.1007/s13738-024-03067-x
Govinda Anjanayya, Ramesh Gani, Avinash Kudva, Shrinivas Joshi, Murigendra Hiremath, Apsara Kavital, Karabasanagouda Timanagouda, Basavarajaiah Mathada, Mohammad Javeed, Raifa Aziz, Shamprasad Raghu

Current antidiabetic medications have a plethora of harmful side effects, and most of the drugs do not contain 1,3,4-oxadiazole moiety. Therefore, research into the development of novel drugs which contain 1,3,4-oxadiazole moiety with fewer side effects is necessary. Novel fluorine-incorporated 1,3,4-oxadiazole derivatives (1c–1n) were synthesized, characterized, and evaluated for α-amylase and α-glucosidase enzyme inhibitor activity. An in vivo Drosophila melanogaster model and an in vitro system were used to investigate its antidiabetic properties, further, which were characterized by 1HNMR, MASS, and FT-IR. Spectroscopic techniques and DFT are used to calculate more geometrically optimized molecule structures using the B3LYP technique. The compounds were tested against the α-glucosidase and α-amylase enzymes. Among different compounds tested, compounds 1i (IC50 = 54.83 µg/ml), 1k (IC50 = 64.95 µg/ml), 1m (IC50 = 64.78 µg/ml), and 1n (IC50 = 66.30 µg/ml) showed significant α-amylase inhibitor efficacy compared to the acarbose (IC50 = 35.17 µg/ml); compounds 1m (IC50 = 74.64 µg/ml) and 1i (IC50 = 60.35 µg/ml) exhibited significant α-glucosidase inhibitory action compared to acarbose (IC50 = 46.06 µg/ml). The docking study exhibited that compound 1i creates six hydrogen bonds and compound 1m forms three hydrogen bonding contacts at the active site of the enzyme (PDBID:4w93). The obtained results are demonstrated that compounds 1i, 1m, 1n, and 1k had greater antidiabetic activities and can be further taken into consideration for antidiabetic therapeutic interventions.

Graphical abstract

目前的抗糖尿病药物有许多有害的副作用,而且大多数药物都不含 1,3,4-恶二唑分子。因此,有必要研究开发含有 1,3,4-恶二唑分子且副作用较小的新型药物。研究人员合成了新型含氟 1,3,4-噁二唑衍生物(1c-1n),对其进行了表征,并评估了其对α-淀粉酶和α-葡萄糖苷酶的抑制活性。此外,还利用体内黑腹果蝇模型和体外系统研究了它的抗糖尿病特性,并通过 1HNMR、MASS 和 FT-IR 对其进行了表征。利用光谱技术和 DFT,采用 B3LYP 技术计算出了更优化的分子几何结构。对这些化合物进行了抗α-葡萄糖苷酶和α-淀粉酶测试。在测试的不同化合物中,化合物 1i(IC50 = 54.83 µg/ml)、1k(IC50 = 64.95 µg/ml)、1m(IC50 = 64.78 µg/ml)和 1n(IC50 = 66.30 µg/ml)与阿卡波糖(IC50 = 35.17 µg/ml)相比,化合物 1m(IC50 = 74.64 µg/ml)和 1i(IC50 = 60.35 µg/ml)表现出明显的α-葡萄糖苷酶抑制作用。对接研究表明,化合物 1i 在酶的活性位点上形成了六个氢键,化合物 1m 在活性位点上形成了三个氢键接触(PDBID:4w93)。研究结果表明,化合物 1i、1m、1n 和 1k 具有较强的抗糖尿病活性,可进一步考虑用于抗糖尿病治疗干预。
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引用次数: 0
Fabrication of a dye sensitized solar cell using TiO2 sensitized with a mono-carbonyl curcumin analog 利用单羰基姜黄素类似物敏化的二氧化钛制造染料敏化太阳能电池
IF 2.2 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-07-25 DOI: 10.1007/s13738-024-03072-0
Renan Fernando Rigueira, Gideã Taques Tractz, Daniela Aline Barancelli

Dye sensitized solar cell has been shown to be a promising technology for energy conversion. It presented in composition a scaffold material, an electrolyte, a counter electrode and a photosensiting molecule. Due to the costs of the most applied ruthenium-organic material, new compounds are synthesized with the aim of reducing costs. This work describes the synthesis and application of (E)-4-(4-hydroxy-3-methoxyphenyl) but-3-en-2-one (1), a monocarbonyl analog of curcumin, as a photosensiting material in a photovoltaic system. Devices were prepared using TiO2 as scaffold material sensitized with compound 1, graphene as a counter electrode, and I/I3 as an electrolyte. The results showed the possibility of using new organic materials, providing an efficient device in energy conversion, with parameters of Jsc = 0.31 mA cm−2; Voc = 0.54 V, FF = 0.47, PCE = 0.07% and (tau_{n}) = 0.637 s.

染料敏化太阳能电池已被证明是一种前景广阔的能源转换技术。它由支架材料、电解质、对电极和光敏分子组成。由于最常用的钌有机材料成本高昂,人们开始合成新的化合物以降低成本。本研究介绍了(E)-4-(4-羟基-3-甲氧基苯基)丁-3-烯-2-酮(1)的合成和应用,它是姜黄素的单羰基类似物,可用作光伏系统中的光敏材料。研究人员以化合物 1 增敏的二氧化钛为支架材料,以石墨烯为对电极,以 I-/I3- 为电解质制备了装置。结果表明,使用新型有机材料可以提供高效的能量转换装置,其参数为:Jsc = 0.31 mA cm-2;Voc = 0.54 V;FF = 0.47;PCE = 0.07%;(tau_{n}) = 0.637 s。
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引用次数: 0
Reduced graphene oxide with La@Co3O4 and La@CdO nanocomposite based sensors: synthesis, characterization and NO2 sensing properties 基于还原氧化石墨烯与 La@Co3O4 和 La@CdO 纳米复合材料的传感器:合成、表征和二氧化氮传感特性
IF 2.2 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-07-24 DOI: 10.1007/s13738-024-03075-x
Kiran Sabir Ali, Muhammad Sabir Zahoor, Muhammad Tariq, Hafiz Muhammad Asif, Shabbir Hussain, Jafir Hussain Shirazi

In the present study, we report fabrication of La@Co3O4 and La@CdO with rGO as new materials for NO2 sensing at a temperature range of 30–90 °C. The nanocomposites were characterized using various characterization tools like FTIR, Powder XRD and SEM to determine the composition and morphology of the nanocomposite sensors. The sensing properties such as sensor response, response time and recovery time were measured. The obtained results exhibited that rGO/La@Co3O4 showed a response of 2.9 while rGO /La@CdO is 2.4 at 50 °C. The sensor exhibited high selectivity to NO2, which is explained by a higher affinity for NO2 compared to other environmental pollutant gases like Cl2, NO, H2O and CO. The sensing mechanism was explained by the synergistic effect of reduced graphene with La@Co3O4 and La@CdO.

在本研究中,我们报告了用 rGO 制备 La@Co3O4 和 La@CdO 作为新材料在 30-90 °C 温度范围内进行二氧化氮传感的情况。利用傅立叶变换红外光谱、粉末 XRD 和扫描电镜等多种表征工具对纳米复合材料进行了表征,以确定纳米复合传感器的组成和形态。测量了传感器响应、响应时间和恢复时间等传感特性。结果表明,在 50 °C 时,rGO/La@Co3O4 的响应为 2.9,而 rGO /La@CdO 为 2.4。与 Cl2、NO、H2O 和 CO 等其他环境污染气体相比,该传感器对 NO2 具有更高的亲和力,因此对 NO2 具有高选择性。其传感机理可通过还原石墨烯与 La@Co3O4 和 La@CdO 的协同效应来解释。
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引用次数: 0
A new equation for determine the degradation temperature in energetic ionic liquid 确定高能离子液体降解温度的新方程
IF 2.2 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-07-23 DOI: 10.1007/s13738-024-03069-9
Dariush Fallah, Mohammad Ali Zarei, Masoud Faal, Rohollah Zarei

The degradation temperature in high-energy materials is vital, and by predicting, it is possible to prevent the dangers of the degradation of high-energy materials and increase their safety. In this study, the degradation temperature of 63 energetic ionic liquids was investigated based on imidazole cation, and a mathematical model was presented to predict the degradation temperature of this class of materials. In this model, 20% of the data were randomly used as test data, and the rest were used as training sets. Correlation prediction (R2) in training and test data was 0.946 and 0.909, respectively. Also, in the internal leave-many-out cross-validation method, the average correlation is 0.953. The average absolute deviation and the root mean square deviation were calculated for both training and test groups. The results showed that the presented model for predicting the degradation temperature in energetic ionic liquids is highly accurate.

高能材料的降解温度至关重要,通过预测可以防止高能材料降解带来的危险,提高其安全性。本研究以咪唑阳离子为基础,对 63 种高能离子液体的降解温度进行了研究,并提出了预测该类材料降解温度的数学模型。在该模型中,20% 的数据被随机用作测试数据,其余数据被用作训练集。训练数据和测试数据的相关预测值(R2)分别为 0.946 和 0.909。此外,在内部留空交叉验证法中,平均相关性为 0.953。计算了训练组和测试组的平均绝对偏差和均方根偏差。结果表明,所提出的预测高能离子液体降解温度的模型具有很高的准确性。
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引用次数: 0
Structural characterization, atomic Hirshfeld surface analysis, thermal behavior, electric and vibrational studies of the new tellurate conductor material 新型碲化镉导体材料的结构表征、原子希尔施菲尔德表面分析、热行为、电学和振动研究
IF 2.2 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-07-13 DOI: 10.1007/s13738-024-03018-6
Ismail Khlifi, Imen Gouti, Santiago García-Granda, Hejer Litaiem

In the current research work, we investigated the growth of the new potassium arsenate tellurate material formulated as K2(HAsO4).Te(OH)6 (KAsTe) through the use of the slow preparation method. The (KAsTe) compound crystallized in the monoclinic system with centrosymmetric space group  P21/c. Within this structure, two types of polyhedra (Te-O6 and HAsO4) were observed in the presence of K+ cations. The stability and the cohesion of the crystal structure were ensured by the linkage of different polyhedra via O‒H…O hydrogen bonds. To locate the closest contacts within this crystal structure, Hirshfeld surface analysis was performed. In fact, according to the fingerprint plots, we inferred that the hydrogen bonds constitute the dominant interactions present within this structure. The vibrational spectroscopy study at room temperature unveiled the occurrence and the independence of the ionic groups and provided detailed data on hydrogen bonds present in the crystal lattice. Thermal analyses (DSC, DTA, TG and MS) proved the presence of three phase transitions at 445, 514 and 555 K and indicated that no mass loss was recorded before 460 K. Furthermore, the σdc variation performed on (KAsTe) material suggested an important level of conductivity at high temperature, associated with the motion of H+ proton. This behavior goes in good agreement with the presence of the super‒ionic protonic phase transition at 445 K.

在当前的研究工作中,我们采用缓慢制备法研究了 K2(HAsO4).Te(OH)6(KAsTe)这一新型砷酸钾碲酸盐材料的生长情况。KAsTe)化合物在单斜体系中结晶,具有中心对称空间群 P21/c。在该结构中,观察到两种类型的多面体(Te-O6 和 HAsO4)存在于 K+ 阳离子中。不同多面体通过 O-H...O 氢键连接,确保了晶体结构的稳定性和内聚力。为了确定该晶体结构中最紧密接触点的位置,我们进行了 Hirshfeld 表面分析。事实上,根据指纹图,我们推断氢键是该结构中存在的主要相互作用。室温下的振动光谱研究揭示了离子基团的存在和独立性,并提供了晶格中氢键的详细数据。热分析(DSC、DTA、TG 和 MS)证明了在 445、514 和 555 K 时存在三个相变,并表明在 460 K 之前没有质量损失。这种行为与 445 K 时出现的超离子质子相变十分吻合。
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引用次数: 0
Design, synthesis, characterization, and docking studies of hiherto unkown chlorinated thiazolidine, thiophene, and 2-iminochromene derivatives as protein-like protease inhibitors 作为类蛋白酶抑制剂的未知氯化噻唑烷、噻吩和 2-亚氨基苯并吡喃衍生物的设计、合成、表征和对接研究
IF 2.2 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-07-11 DOI: 10.1007/s13738-024-03056-0
Mohamed A. M. Abdel Reheim, Gameel A. M. Elhagali, Khadija E. Saadon, Nadia M. H. Taha, N. A. Mahmoud, Mohamed. S. A. El-Gaby

The present work details the synthesis of several intriguing nitrogenous heterocycles utilizing a cyano-N-aryl-acetamide-reagent, notably chlorinated thiazolidine, thiophene and 2-iminochromene derivatives. Thus, the precursor 2-cyano-N-(2,4-dichlorophenyl) acetamide 1 underwent the reaction with phenyl isothiocyanate in DMF/KOH to afford the intermediate salt 3, which reacted in situ with several α-halogenated reagents 4a-c like ethylchloroacetate,α-bromoethylpropionate and α-bromo ethyl butaneoate and afforded the corresponding 4-thiazolidinnone derivatives (6a–c, yield%; 67–85), thiophene derivatives (11;yield 80%) and (15, yield 77%) obtained from the reaction of 3 with α- chloroacetyl acetone 9 and ethyl 2-chloro-3-oxobutanoate 12.Novel series of different 4-thiazolidinones(16a–e; yield%; 65–84) were obtained via condensation of 6a with different aldehydes. Finally, the reaction of compound with different bifunctional reagents, such as salicylaldehyde derivatives and 2-hydroxynaphthaldehyde, in ethanol furnished the iminochromenes (17a,b; yield %77,80) and (18; yield 85%). In addition, molecular docking studies of the prepared molecules were carried out against papain-like protease (PLpro) to identify novel promising inhibitors of Coronavirus Disease COVID-19. The binding affinity of the best docked compounds 16c and 16a toward the target enzyme was − 9.6 and − 8.9 kcal/mole, respectively. In silico-docking-Studies indicate, that compounds 16c and 16a have the potential as antiviral against COVID-19.

Graphical abstract

本研究详细介绍了利用氰基-N-芳基乙酰胺试剂合成的几种有趣的含氮杂环,特别是氯化噻唑烷、噻吩和 2-亚氨基苯并吡喃衍生物。因此,前体 2-氰基-N-(2,4-二氯苯基)乙酰胺 1 在 DMF/KOH 中与异硫氰酸苯酯反应生成中间盐 3,中间盐 3 与几种 α 卤化试剂 4a-c 如氯乙酸乙酯、α-溴乙基丙酸酯和α-溴乙基丁酸酯发生原位反应,生成相应的 4-噻唑烷酮衍生物(6a-c,产率%;67-85) 、噻吩衍生物 (11; 收率 80%) 和 (15, 收率 77%) 由 3 与 α-氯乙酰丙酮 9 和 2-氯-3-氧代丁酸乙酯 12 反应得到。通过 6a 与不同的醛缩合,得到了一系列不同的新型 4-噻唑烷酮(16a-e;收率%;65-84)。最后,化合物 1 与不同的双官能试剂(如水杨醛衍生物和 2-羟基萘甲醛)在乙醇中反应生成了亚氨基苯并吡喃(17a,b;收率 %77,80)和(18;收率 85%)。此外,还对所制备的分子进行了与木瓜蛋白酶(PLpro)的分子对接研究,以确定有希望的新型冠状病毒病 COVID-19 抑制剂。最佳对接化合物 16c 和 16a 与目标酶的结合亲和力分别为 - 9.6 和 - 8.9 千卡/摩尔。硅学对接研究表明,化合物 16c 和 16a 具有抗 COVID-19 病毒的潜力。
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引用次数: 0
Facile preparation of Ni-Hg-Fe amalgam for hydrogen evolution reaction in NaOH solution 在 NaOH 溶液中轻松制备用于氢进化反应的 Ni-Hg-Fe 汞齐
IF 2.2 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-07-10 DOI: 10.1007/s13738-024-03062-2
F. Hassanlou, S. Miandari, M. Jafarian

An alloy of Ni-Hg-Fe was synthesized on a graphite electrode using direct current electrodeposition to facilitate the hydrogen evolution reaction under alkaline circumstances. The alloy’s performance showcased outstanding catalytic properties, as demonstrated by the value of overpotential (324 mV at 10 mAcm−2), an exchange current density of 1.11 × 10–1 mAcm−2, and an activation energy of 4.419 J/mol. A comparison between Ni-Hg-Fe and Ni-Hg alloys revealed that the inclusion of iron notably improved catalytic efficacy, as evidenced by the turnover frequency (Ni-Hg-Fe: 0.8487 H2 s−1, Ni-Hg: 0.2408 H2 s−1), decreased charge transfer resistance (Ni-Hg-Fe: 49.96Ω, Ni-Hg: ~ 115Ω), and higher double-layer capacitance (Ni-Hg-Fe: 1.4 mF cm2−, Ni-Hg: 0.50 mFcm−2). The alloy’s effectiveness is ascribed to the synergistic effect of nickel and iron, as well as the enhanced surface area resulting from iron doping. X-ray diffraction was used to analyze the surface, along with the use of Energy-dispersive X-ray spectroscopy and scanning electron microscopy for surface characterization.

利用直流电沉积法在石墨电极上合成了一种镍-汞-铁合金,用于促进碱性条件下的氢进化反应。合金的过电位值(10 mAcm-2 时为 324 mV)、交换电流密度(1.11 × 10-1 mAcm-2)和活化能(4.419 J/mol)证明了其出色的催化性能。对 Ni-Hg-Fe 和 Ni-Hg 合金进行比较后发现,铁的加入显著提高了催化效率,具体表现在翻转频率(Ni-Hg-Fe:0.8487 H2 s-1,Ni-Hg:0.2408 H2 s-1)、电荷转移电阻减小(Ni-Hg-Fe:49.96Ω,Ni-Hg:~ 115Ω)和双层电容增大(Ni-Hg-Fe:1.4 mF cm2-,Ni-Hg:0.50 mF cm-2)。该合金的有效性归因于镍和铁的协同效应,以及铁掺杂导致的表面积增大。分析表面时使用了 X 射线衍射法,还使用了能量色散 X 射线光谱法和扫描电子显微镜进行表面表征。
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Journal of the Iranian Chemical Society
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