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Skin-Friendly Large Matrix Iontronic Sensing Meta-Fabric for Spasticity Visualization and Rehabilitation Training via Piezo-Ionic Dynamics
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2024-12-19 DOI: 10.1007/s40820-024-01566-3
Ruidong Xu, Tong Xu, Minghua She, Xinran Ji, Ganghua Li, Shijin Zhang, Xinwei Zhang, Hong Liu, Bin Sun, Guozhen Shen, Mingwei Tian

Highlights

  • The iontronic meta-fabric exhibits a “hitting three birds with one stone” property, breaking through the bottleneck that traditional film materials (PDMS) cannot balance comfort and durability.

  • The meta-fabrics can be integrated with garments and advanced data analysis systems to manufacture a series of large matrix structure (> 40 × 40, 1600 sensing units) rehabilitation training devices, overcoming the bottleneck of low matrix integration of traditional iontronic devices (< 10 × 10, 100 sensing units).

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引用次数: 0
Correction: Defects-Rich Heterostructures Trigger Strong Polarization Coupling in Sulfides/Carbon Composites with Robust Electromagnetic Wave Absorption 更正:富缺陷异质结构触发硫化物/碳复合材料中的强极化耦合,具有强大的电磁波吸收能力
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2024-12-16 DOI: 10.1007/s40820-024-01608-w
Jiaolong Liu, Siyu Zhang, Dan Qu, Xuejiao Zhou, Moxuan Yin, Chenxuan Wang, Xuelin Zhang, Sichen Li, Peijun Zhang, Yuqi Zhou, Kai Tao, Mengyang Li, Bing Wei, Hongjing Wu
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引用次数: 0
Concurrently Boosting Activity and Stability of Oxygen Reduction Reaction Catalysts via Judiciously Crafting Fe–Mn Dual Atoms for Fuel Cells
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2024-12-16 DOI: 10.1007/s40820-024-01580-5
Lei Zhang, Yuchen Dong, Lubing Li, Yuchuan Shi, Yan Zhang, Liting Wei, Chung-Li Dong, Zhiqun Lin, Jinzhan Su

Highlights

  • Fe–Mn dual-atom catalysts exhibit superior oxygen reduction reaction (ORR) activity and stability, with high half-wave potentials in both alkaline and acidic conditions.

  • Synergistic Mn incorporation effectively anchors Fe atoms, mitigates the Fenton reaction, and enhances the durability of ORR catalysts.

  • Advanced characterization and density-functional theory calculations reveal Mn-induced electronic structure modifications, promoting superior ORR kinetics and active site performance.

  • (FeMn-DA)-N-C catalysts show remarkable potential for practical fuel cell applications.

先进的表征和密度泛函理论计算揭示了锰诱导的电子结构修饰,促进了卓越的 ORR 动力学和活性位点性能。
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引用次数: 0
Precision-Engineered Construction of Proton-Conducting Metal–Organic Frameworks
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2024-12-11 DOI: 10.1007/s40820-024-01558-3
Liyu Zhu, Hongbin Yang, Ting Xu, Feng Shen, Chuanling Si

Highlights

  • The effects of the size structure and stability of metal–organic frameworks (MOFs) on proton conduction are comprehensively summarized.

  • Advanced strategies for constructing proton conduction MOFs are critically discussed.

  • Challenges and opportunities for the development of novel proton-conducting MOFs are further outlined.

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引用次数: 0
Unlocking Novel Functionality: Pseudocapacitive Sensing in MXene-Based Flexible Supercapacitors
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2024-12-09 DOI: 10.1007/s40820-024-01567-2
Eunji Kim, Seongbeen Kim, Hyeong Min Jin, Gyungtae Kim, Hwi-Heon Ha, Yunhui Choi, Kyoungha Min, Su-Ho Cho, Hee Han, Chi Won Ahn, Jaewoo Roh, Il-Kwon Oh, Jinwoo Lee, Yonghee Lee

Highlights

  • We have discovered a novel phenomenon where the pseudocapacitance of flexible MXene supercapacitors changes sensitively in response to bending, leading to the development of Pseudocapacitive Sensors.

  • Pseudocapacitive Sensors repurpose supercapacitors as strain sensors, detecting capacitance changes from shifts between pseudocapacitance and electrical double layer capacitor. These highly sensitive sensors have a gauge factor of about 1200, far exceeding that of conventional strain sensors.

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引用次数: 0
Tailoring Cathode–Electrolyte Interface for High-Power and Stable Lithium–Sulfur Batteries
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2024-12-04 DOI: 10.1007/s40820-024-01573-4
Mengting Liu, Ling-Jiao Hu, Zhao-Kun Guan, Tian-Ling Chen, Xin-Yu Zhang, Shuai Sun, Ruoli Shi, Panpan Jing, Peng-Fei Wang

Highlights

  • This review delves into the mechanism of the state-of-the-art lithium–sulfur batteries from a novel perspective of cathode–electrolyte interface.

  • It provides extensive strategies to construct a stable cathode–electrolyte interphase layer and improve the uneven deposition of Li2S, enhancing the stability of the interface structure.

  • It proposes an in-depth and comprehensive research on how to inhibit the shuttle effect at the cathode–electrolyte interface with regard to distinct reaction pathways.

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引用次数: 0
Hierarchical Polyimide Nonwoven Fabric with Ultralow-Reflectivity Electromagnetic Interference Shielding and High-Temperature Resistant Infrared Stealth Performance
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2024-12-03 DOI: 10.1007/s40820-024-01590-3
Xinwei Tang, Yezi Lu, Shuangshuang Li, Mingyang Zhu, Zixuan Wang, Yan Li, Zaiyin Hu, Penglun Zheng, Zicheng Wang, Tianxi Liu

Highlights

  • Hierarchical polyimide (PI) nonwoven fabric is fabricated by alkali treatment, in-situ growth of magnetic particles, and "self-activated" electroless Ag plating process.

  • Impedance matching structure by assembling Fe3O4/Ag-loaded PI nonwoven fabric (PFA) and pure Ag-coated PI nonwoven fabric (PA) induces more electromagnetic waves enter PFA/PA and be dissipated.

  • The fluffy 3D space structure of PFA with strong adhesion interaction and low infrared emissivity of PA endow PFA/PA with excellent thermal stability in electromagnetic interference shielding and high-temperature resistant infrared stealth performance.

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引用次数: 0
Atomically Precise Cu Nanoclusters: Recent Advances, Challenges, and Perspectives in Synthesis and Catalytic Applications
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2024-12-03 DOI: 10.1007/s40820-024-01555-6
Mengyao Chen, Chengyu Guo, Lubing Qin, Lei Wang, Liang Qiao, Kebin Chi, Zhenghua Tang

Atomically precise metal nanoclusters are an emerging type of nanomaterial which has diverse interfacial metal–ligand coordination motifs that can significantly affect their physicochemical properties and functionalities. Among that, Cu nanoclusters have been gaining continuous increasing research attentions, thanks to the low cost, diversified structures, and superior catalytic performance for various reactions. In this review, we first summarize the recent progress regarding the synthetic methods of atomically precise Cu nanoclusters and the coordination modes between Cu and several typical ligands and then discuss the catalytic applications of these Cu nanoclusters with some explicit examples to explain the atomical-level structure–performance relationship. Finally, the current challenges and future research perspectives with some critical thoughts are elaborated. We hope this review can not only provide a whole picture of the current advances regarding the synthesis and catalytic applications of atomically precise Cu nanoclusters, but also points out some future research visions in this rapidly booming field.

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引用次数: 0
Anti-Swelling Polyelectrolyte Hydrogel with Submillimeter Lateral Confinement for Osmotic Energy Conversion
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2024-12-03 DOI: 10.1007/s40820-024-01577-0
Yongxu Liu, Jiangnan Song, Zhen Liu, Jialin Chen, Dejuan Wang, Hui Zhi, Jiebin Tang, Yafang Zhang, Ningbo Li, Weijia Zhou, Meng An, Hong Liu, Guobin Xue

Highlights

  • Ionic polymers can directly serve as high-performance ion-selective membranes when it was physically confined within submillimeter-sized cylindrical pore.

  • The universality of this strategy is demonstrated in preparing cation/anion-selective membrane.

  • With real seawater and river water, the output power density of a three-chamber cell on behalf of repeat unit of reverse electrodialysis system can reach up to 8.99 W m−2.

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引用次数: 0
Revealing the Role of Hydrogen in Highly Efficient Ag-Substituted CZTSSe Photovoltaic Devices: Photoelectric Properties Modulation and Defect Passivation
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2024-12-03 DOI: 10.1007/s40820-024-01574-3
Xiaoyue Zhao, Jingru Li, Chenyang Hu, Yafang Qi, Zhengji Zhou, Dongxing Kou, Wenhui Zhou, Shengjie Yuan, Sixin Wu

The presence of SnZn-related defects in Cu2ZnSn(S,Se)4 (CZTSSe) absorber results in large irreversible energy loss and extra irreversible electron–hole non-radiative recombination, thus hindering the efficiency enhancement of CZTSSe devices. Although the incorporation of Ag in CZTSSe can effectively suppress the SnZn-related defects and significantly improve the resulting cell performance, an excellent efficiency has not been achieved to date primarily owing to the poor electrical-conductivity and the low carrier density of the CZTSSe film induced by Ag substitution. Herein, this study exquisitely devises an Ag/H co-doping strategy in CZTSSe absorber via Ag substitution programs followed by hydrogen-plasma treatment procedure to suppress SnZn defects for achieving efficient CZTSSe devices. In-depth investigation results demonstrate that the incorporation of H in Ag-based CZTSSe absorber is expected to improve the poor electrical-conductivity and the low carrier density caused by Ag substitution. Importantly, the C=O and O–H functional groups induced by hydrogen incorporation, serving as an electron donor, can interact with under-coordinated cations in CZTSSe material, effectively passivating the SnZn-related defects. Consequently, the incorporation of an appropriate amount of Ag/H in CZTSSe mitigates carrier non-radiative recombination, prolongs minority carrier lifetime, and thus yields a champion efficiency of 14.74%, showing its promising application in kesterite-based CZTSSe devices.

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Nano-Micro Letters
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