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Wafer-Scale Vertical 1D GaN Nanorods/2D MoS2/PEDOT:PSS for Piezophototronic Effect-Enhanced Self-Powered Flexible Photodetectors 晶圆级垂直 1D GaN 纳米棒/2D MoS2/PEDOT:PSS 用于压电光电效应增强型自供电柔性光电探测器。
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2024-11-05 DOI: 10.1007/s40820-024-01553-8
Xin Tang, Hongsheng Jiang, Zhengliang Lin, Xuan Wang, Wenliang Wang, Guoqiang Li

Highlights

  • Vertical 1D GaN nanorod arrays/2D MoS2/PEDOT:PSS heterostructures in wafer scale have been fabricated for flexible photodetection firstly.

  • Self-powered flexible photodetector at compressive strain reveals a significantly enhanced photoresponse with a responsivity of 2.47 A W−1 and response times of 40/45 µs, which are superior to the state-of-the-art flexible devices.

  • This work not only provides a valuable strategy for the design and construction of tunable van der Waals heterostructures, but also opens a new opportunity for flexible sensors.

由低维(0D、1D 和 2D)材料构建的范德华(vdW)异质结构正在成为下一代柔性光电探测中最具吸引力的系统之一。目前,手工堆叠的 vdW 型光电探测器与大面积阵列制造不兼容,而且在自供电模式下表现平平。本文首次提出了晶圆级垂直一维 GaN 纳米棒阵列(NRAs)/二维 MoS2/PEDOT:PSS 自供电柔性光电探测器阵列。得益于 GaN NRAs 的强光吸收和 II 型异质结中高效的光生载流子分离,该集成器件在弱紫外光照射下无需外部偏压,便可实现 1.47 A W-1 的高响应率和 1.2 × 1011 Jones 的高探测率,以及 54/71 µs 的快速响应速度。值得注意的是,该器件的应变可调光电探测性能已得到证实。令人印象深刻的是,该器件在-0.78%应变和零偏压条件下的光响应显著增强,响应率为2.47 A W-1,探测率为2.6 × 1011 Jones,响应时间为40/45 µs,优于最先进的自供电柔性光电探测器。这项工作为制备自供电柔性光电探测的可调 vdWs 异质结构提供了一条宝贵的途径,它在柔性传感器中表现出色。
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引用次数: 0
Defect Engineering with Rational Dopants Modulation for High-Temperature Energy Harvesting in Lead-Free Piezoceramics 利用合理掺杂调制缺陷工程实现无铅压电陶瓷的高温能量收集
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2024-11-04 DOI: 10.1007/s40820-024-01556-5
Kaibiao Xi, Jianzhe Guo, Mupeng Zheng, Mankang Zhu, Yudong Hou

Highlights

  • The solution limit of manganese ion in BiFeO3–BaTiO3 (BF–BT) was determined by combining multiple advanced characterization methods.

  • The defect engineering associated with fine doping can realize the co-modulation of polarization configuration, iron oxidation state and domain orientation.

  • The BF–BT–0.2Mn piezoelectric energy harvester shows excellent power generation capacity at 250 °C, which is an important breakthrough for lead-free piezoelectric devices.

高温压电能量收集器(HT-PEH)是替代化学电池实现高温无线传感器独立供电的重要解决方案。然而,无铅压电陶瓷必须同时具有优异的性能,包括高优点系数(FOM)、绝缘电阻率(ρ)和去极化温度(Td),但这很难实现,尤其是在 250 °C 下工作的无铅压电陶瓷更是如此。在这里,通过创新的缺陷工程和精细的锰掺杂,BiFeO3-BaTiO3 陶瓷实现了良好的平衡性能。由于极化构型优化提高了电致伸缩系数,高价锰离子调节了铁离子氧化态,缺陷偶极稳定了畴取向,这些协同作用在锰离子的固溶极限下实现了全面优异的电性能(Td = 340 ℃,ρ250 ℃ > 107 Ω cm,FOM250 ℃ = 4905 × 10-15 m2 N-1)。利用合理设计的压电陶瓷组装的 HT-PEH 可在 250 ℃ 下对商用电解电容器进行快速充电,并具有较高的能量转换效率(η = 11.43%)。这些特性表明,缺陷工程定制的 BF-BT 可以满足高端 HT-PEHs 的要求,为开发在高温环境下工作的自供电无线传感器铺平了新的道路。
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引用次数: 0
Smart Gas Sensors: Recent Developments and Future Prospective 智能气体传感器:最新发展与未来展望。
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2024-11-04 DOI: 10.1007/s40820-024-01543-w
Boyang Zong, Shufang Wu, Yuehong Yang, Qiuju Li, Tian Tao, Shun Mao

Highlights

  • Recent developments of advanced electronic and optoelectronic gas sensors are introduced.

  • Sensor array with artificial intelligence algorithms and smart gas sensors in “Internet of Things” paradigm are highlighted.

  • Applications of smart gas sensors in environmental monitoring, medical and healthcare applications, food quality control, and public safety are described.

气体传感器是现代社会不可或缺的一部分,在环境监测、医疗保健、食品工业、公共安全等领域有着广泛的应用。随着传感器技术、无线通信、智能监测终端、云存储/计算技术和人工智能的发展,智能气体传感器以其实时多功能监测、预警功能、智能化和自动化等优点,代表了气体传感的未来。为实现高性能的智能气体分析,人们开发了各种电子和光电气体传感器。随着智能终端的发展和集成技术的成熟,柔性可穿戴气体传感器在气体分析中发挥着越来越重要的作用。本综述重点介绍了智能气体传感器在不同应用领域的最新进展。文章介绍了电子和光电气体传感器的结构组成和基本原理,并重点介绍了柔性和可穿戴气体传感器设备。此外,还介绍了采用人工智能算法的传感器阵列和 "物联网 "范例中的智能气体传感器。最后,讨论了智能气体传感器面临的挑战和前景,以及未来智能城市和健康生活对气体传感器的需求。
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引用次数: 0
Multifunctional Nacre-Like Nanocomposite Papers for Electromagnetic Interference Shielding via Heterocyclic Aramid/MXene Template-Assisted In-Situ Polypyrrole Assembly 通过杂环芳纶/二甲苯模板辅助原位聚吡咯组装实现电磁干扰屏蔽的多功能珍珠母状纳米复合材料论文
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2024-10-31 DOI: 10.1007/s40820-024-01552-9
Jinhua Xiong, Xu Zhao, Zonglin Liu, He Chen, Qian Yan, Huanxin Lian, Yunxiang Chen, Qingyu Peng, Xiaodong He

Highlights

  • The large-scale, high-strength, super-tough, and multifunctional nacre-like heterocyclic aramid (HA)/MXene@polypyrrole (PPy) (HMP) nanocomposite papers were fabricated using the in-situ assembly of PPy onto the HA/MXene hydrogel template.

  • The "brick-and-mortar" layered structure and abundant hydrogen-bonding interactions among MXene, PPy, and HA respond cooperatively to external stress and effectively increase the mechanical properties of HMP nanocomposite papers.

  • The templating effect from HA/MXene was utilized to guide the assembly of conducting polymers, leading to high electrical conductivity and outstanding electromagnetic interference shielding performance.

通过在HA/MXene水凝胶模板上原位组装聚吡咯(PPy),制备了大尺度、高强、超韧、多功能珍珠状杂环芳纶(HA)/MXene@聚吡咯(PPy)(HMP)纳米复合纸。MXene、PPy和HA之间的 "砖墙式 "分层结构和丰富的氢键相互作用对外部应力产生了协同反应,有效地提高了HMP纳米复合纸的机械性能。利用HA/MXene的模板效应引导导电聚合物的组装,从而获得了高导电性和出色的电磁干扰屏蔽性能。
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引用次数: 0
Inter-Skeleton Conductive Routes Tuning Multifunctional Conductive Foam for Electromagnetic Interference Shielding, Sensing and Thermal Management 用于电磁干扰屏蔽、传感和热管理的骨架间导电路线调谐多功能导电泡沫。
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2024-10-28 DOI: 10.1007/s40820-024-01540-z
Xufeng Li, Chunyan Chen, Zhenyang Li, Peng Yi, Haihan Zou, Gao Deng, Ming Fang, Junzhe He, Xin Sun, Ronghai Yu, Jianglan Shui, Caofeng Pan, Xiaofang Liu

Highlights

  • Unique inter-skeleton conductive films are constructed in polymer foam.

  • The resistance change of the foam can reach four orders of magnitude under compression.

  • This foam exhibits strain-adaptive electromagnetic interference shielding performance, anti-interference pressure sensor with high sensitivity over a wide pressure range and compression-regulated Joule heating function.

导电聚合物泡沫(CPF)具有出色的可压缩性和可变电阻,在可穿戴电子设备的电磁干扰(EMI)屏蔽和其他集成功能方面具有广阔的应用前景。然而,其电阻随压缩应变的变化幅度不足通常会导致变形过程中屏蔽性能下降。本文提出了一种在聚合物泡沫上加载导电材料的创新策略,以显著提高导电元件在压缩条件下的接触概率和接触面积。通过在挂在泡沫骨架之间的聚甲基丙烯酸酯薄膜上加载藻酸盐装饰的磁性液态金属(称为 AMLM-PM 泡沫),构建了独特的骨架间导电薄膜。在压缩条件下,导电骨架之间的传统点接触升级为导电薄膜之间的平面接触。因此,AMLM-PM 在压缩时的电阻变化达到了四个数量级。此外,骨架间的导电膜还能提高泡沫的机械强度,防止液态金属泄漏,增加电磁波的散射面积。AMLM-PM 泡沫具有应变自适应电磁干扰屏蔽性能,并显示出压缩增强屏蔽效果,解决了传统 CPF 在压缩时的问题。电阻响应的升级还使泡沫能够在很宽的压力范围内实现灵敏的压力感应和压缩调节焦耳加热功能。
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引用次数: 0
Scalable Ir-Doped NiFe2O4/TiO2 Heterojunction Anode for Decentralized Saline Wastewater Treatment and H2 Production 可扩展的掺铱 NiFe2O4/TiO2 异质结阳极,用于分散式含盐废水处理和 H2 生产。
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2024-10-28 DOI: 10.1007/s40820-024-01542-x
Sukhwa Hong, Jiseon Kim, Jaebeom Park, Sunmi Im, Michael R. Hoffmann, Kangwoo Cho

Highlights

  • Ir-doped NiFe2O4 (NFI) spinel with TiO2 heterojunction overlayer brought about outstanding chlorine evolution reaction in circumneutral pH.

  • Electroanalyses including operando X-ray absorption spectroscopy uncovered the active role of TiO2 for Cl chemisorption.

  • NFI/TiO2 anode boosted both NH4+-to-N2 conversion and H2 generation in wastewater, and the practical applicability was confirmed with scaled-up anodes and real wastewater.

用于分散式废水处理/回用的废水电解槽(WECs)与 H2 生产相结合,可减少与水、废物和能源载体运输相关的碳足迹。本研究报告了掺铒镍铁氧体(NFI,约 5 at% Ir)尖晶石层和 TiO2 覆盖层(NFI/TiO2),作为一种可扩展的异质结阳极,用于在单室电池中直接电解周围 pH 值为中性的废水。在稀释(0.1 M)的氯化钠溶液中,NFI/TiO2 的活性和氯进化反应选择性均优于基准的 IrO2。在接近中性 pH 值的条件下,其稳健的运行也得到了证实。包括操作性 X 射线吸收光谱在内的电分析揭示了 TiO2 的关键作用,它既是 Cl- 化学吸附的主要场所,又是作为欧姆接触的 NFI 的保护层。对含有 NH4+ 的合成废水进行静电电解表明,NFI/二氧化钛不仅实现了 NH4+ 到 N2 的准均一转化,还提高了 H2 的生成效率,同时将溶解氧和活性氯的还原等竞争反应降至最低。使用 NFI/TiO2 的扩大型 WEC 已在电解厕所废水中得到验证。
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引用次数: 0
A Flexible Smart Healthcare Platform Conjugated with Artificial Epidermis Assembled by Three-Dimensionally Conductive MOF Network for Gas and Pressure Sensing 由三维导电 MOF 网络组装的与人工表皮共轭的柔性智能医疗保健平台,用于气体和压力传感
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2024-10-25 DOI: 10.1007/s40820-024-01548-5
Qingqing Zhou, Qihang Ding, Zixun Geng, Chencheng Hu, Long Yang, Zitong Kan, Biao Dong, Miae Won, Hongwei Song, Lin Xu, Jong Seung Kim

The rising flexible and intelligent electronics greatly facilitate the noninvasive and timely tracking of physiological information in telemedicine healthcare. Meticulously building bionic-sensitive moieties is vital for designing efficient electronic skin with advanced cognitive functionalities to pluralistically capture external stimuli. However, realistic mimesis, both in the skin’s three-dimensional interlocked hierarchical structures and synchronous encoding multistimuli information capacities, remains a challenging yet vital need for simplifying the design of flexible logic circuits. Herein, we construct an artificial epidermal device by in situ growing Cu3(HHTP)2 particles onto the hollow spherical Ti3C2Tx surface, aiming to concurrently emulate the spinous and granular layers of the skin’s epidermis. The bionic Ti3C2Tx@Cu3(HHTP)2 exhibits independent NO2 and pressure response, as well as novel functionalities such as acoustic signature perception and Morse code-encrypted message communication. Ultimately, a wearable alarming system with a mobile application terminal is self-developed by integrating the bimodular senor into flexible printed circuits. This system can assess risk factors related with asthmatic, such as stimulation of external NO2 gas, abnormal expiratory behavior and exertion degrees of fingers, achieving a recognition accuracy of 97.6% as assisted by a machine learning algorithm. Our work provides a feasible routine to develop intelligent multifunctional healthcare equipment for burgeoning transformative telemedicine diagnosis.

不断涌现的柔性智能电子产品极大地促进了远程医疗保健中对生理信息的无创和及时追踪。精心构建仿生敏感分子对于设计具有高级认知功能的高效电子皮肤以多元化捕捉外部刺激至关重要。然而,在皮肤的三维交错分层结构和同步编码多刺激信息能力两方面的逼真模拟,仍然是简化柔性逻辑电路设计的一项具有挑战性的重要需求。在此,我们通过在中空球形 Ti3C2Tx 表面原位生长 Cu3(HHTP)2 颗粒来构建人工表皮装置,旨在同时模拟皮肤表皮的棘层和颗粒层。仿生 Ti3C2Tx@Cu3(HHTP)2具有独立的二氧化氮和压力响应,以及声学特征感知和摩斯密码加密信息通信等新功能。最终,通过将双模传感器集成到柔性印刷电路中,自主开发出了带有移动应用终端的可穿戴报警系统。该系统可评估与哮喘有关的危险因素,如外部二氧化氮气体刺激、异常呼气行为和手指用力程度,在机器学习算法的辅助下,识别准确率达到 97.6%。我们的工作为开发智能化多功能医疗设备提供了可行的方法,从而促进远程医疗诊断的蓬勃发展。
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引用次数: 0
Dynamic Regulation of Hydrogen Bonding Networks and Solvation Structures for Synergistic Solar-Thermal Desalination of Seawater and Catalytic Degradation of Organic Pollutants 动态调节氢键网络和溶解结构,实现太阳能-热能协同海水淡化和有机污染物催化降解
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2024-10-23 DOI: 10.1007/s40820-024-01544-9
Ming-Yuan Yu, Jing Wu, Guang Yin, Fan-Zhen Jiao, Zhong-Zhen Yu, Jin Qu

Highlights

  • A flow-bed water purification system with an asymmetric solar-thermal and catalytic membrane is designed for synergistic solar-thermal desalination of seawater/brine and catalytic degradation of organic pollutants.

  • The hydrogen bonding networks can be regulated by the abundant surface –OH groups and the in situ generated ions and radicals during the degradation process for promoting solar-driven steam generation.

  • The de-solvation of solvated Na+ and subsequent nucleation/growth of NaCl are effectively inhibited by SO42−/HSO5 ions.

设计了一种具有非对称太阳能-热催化膜的流动床水净化系统,用于协同太阳能-热脱盐海水/盐水和催化降解有机污染物。在降解过程中,氢键网络可通过丰富的表面 -OH 基团和原位生成的离子和自由基进行调节,从而促进太阳能驱动的蒸汽生成。SO42-/HSO5- 离子可有效抑制溶解 Na+ 的脱溶和随后 NaCl 的成核/生长。
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引用次数: 0
Solution-Processed Thin Film Transparent Photovoltaics: Present Challenges and Future Development 溶液加工薄膜透明光伏技术:当前挑战与未来发展
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2024-10-23 DOI: 10.1007/s40820-024-01547-6
Tianle Liu, Munerah M. S. Almutairi, Jie Ma, Aisling Stewart, Zhaohui Xing, Mengxia Liu, Bo Hou, Yuljae Cho

Highlights

  • Recent advancement in solution-processed thin film transparent photovoltaics (TPVs) is summarized, including perovskites, organics, and colloidal quantum dots.

  • Pros and cons of the emerging TPVs are analyzed according to the materials characteristics and the application requirements on the aesthetics and energy generation.

  • Promising TPV applications are discussed with emphasis on agrivoltaics, smart windows and facades.

本文总结了溶液加工薄膜透明光伏技术(TPVs)的最新进展,包括过氧化物、有机物和胶体量子点,并根据材料特性以及应用对美观和发电的要求,分析了新兴 TPVs 的利弊。
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引用次数: 0
Graphene Aerogel Composites with Self-Organized Nanowires-Packed Honeycomb Structure for Highly Efficient Electromagnetic Wave Absorption 具有自组织纳米线填充蜂巢结构的石墨烯气凝胶复合材料可高效吸收电磁波
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2024-10-21 DOI: 10.1007/s40820-024-01541-y
Xiao You, Huiying Ouyang, Ruixiang Deng, Qiuqi Zhang, Zhenzhong Xing, Xiaowu Chen, Qingliang Shan, Jinshan Yang, Shaoming Dong

Highlights

  • A new strategy for elaborate regulation of microstructure was successfully introduced by the ice template‑assisted 3D printing and chemical vapor deposition strategy, including graphene nanoplate/silicon carbide nanowires hierarchical porous structure and graphene nanoplate/boron nitride composite heterogeneous interface.

  • The composite exhibits excellent electromagnetic wave absorption performance with an RLmin of -37.8 dB and an EABmax of 9.2 GHz (from 8.8 to 18.0 GHz) at 2.5 mm. And the high-temperature absorption stability makes it a promising absorber candidate under high temperature and oxidizing atmosphere.

通过冰模板辅助三维打印和化学气相沉积策略,成功引入了一种微观结构精细调节的新策略,包括石墨烯纳米板/碳化硅纳米线分层多孔结构和石墨烯纳米板/氮化硼复合异质界面。其高温吸收稳定性使其在高温和氧化气氛下成为一种很有前途的吸波材料。
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引用次数: 0
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Nano-Micro Letters
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