Methods allowing passive daytime radiative cooling (PDRC) to be carried out in an energy-efficient and scalable way are potentially important for various disciplines. Here, we report a sustainable strategy for scalable-designed and color-regulating PDRC coating based on high-crystallinity photonic metamaterial (crystallinity: 71.5%; enhanced assembly efficiency: 72%), that is derived from the as-prepared 55 wt% solid content poly(methyl methacrylate-butyl acrylate-methacrylic acid) P(MMA-BA-MAA) monodispersed latexes (approaching theoretical limit: 59 wt%). Robust meter-scale PDRC coatings are constructed by various industrial modes onto diverse surfaces, addressing bottlenecks like dull appearance, high cost, low efficiency, and hard construction. Notably, the solar reflectance, long-wave infrared emittance, and calculated theoretical cooling power of the designed PDRC coating, respectively, reach ~ 0.94, ~ 0.97, and ~ 95.5 W m-2 under solar radiation, which can achieve an average 5.3 °C sub-ambient daytime temperature drop in the summer in Nanjing. The cooling performance, scale preparation, and cost-effectiveness of the PDRC coating have extended into leading position compared with those of state-of-the-art designs. This work provides promising route to reduce carbon emissions and energy consumption for global sustainability.
以节能和可扩展的方式进行被动日间辐射冷却（PDRC）的方法对各个学科都具有潜在的重要意义。在这里，我们报告了一种基于高结晶度光子超材料（结晶度：71.5%；提高组装效率：72%）的可扩展设计和调色PDRC涂层的可持续策略，该材料来自于制备的55%固体含量的聚（甲基丙烯酸甲酯-丙烯酸丁酯-甲基丙烯酸）P（MMA-BA-MAA）单分散乳胶（接近理论极限：59%）。坚固的米级PDRC涂料通过各种工业模式在不同的表面上构建，解决了外观暗淡、成本高、效率低和施工难等瓶颈。值得注意的是，所设计的PDRC涂层在太阳辐射下的太阳反射率、长波红外发射率和计算的理论冷却功率分别达到~ 0.94、~ 0.97和~ 95.5 W m-2，可使南京夏季白天亚环境温度平均下降5.3℃。与最先进的设计相比，PDRC涂层的冷却性能、水垢制备和成本效益已处于领先地位。这项工作为减少碳排放和能源消耗，促进全球可持续发展提供了有希望的途径。
{"title":"Scalable-Designed Photonic Metamaterial for Color-Regulating Passive Daytime Radiative Cooling.","authors":"Xiao-Qing Yu,Fucheng Li,Jiawei Wang,Nianxiang Zhang,Guo-Xing Li,Yan Song,Qing Li,Su Chen","doi":"10.1007/s40820-025-01975-y","DOIUrl":"https://doi.org/10.1007/s40820-025-01975-y","url":null,"abstract":"Methods allowing passive daytime radiative cooling (PDRC) to be carried out in an energy-efficient and scalable way are potentially important for various disciplines. Here, we report a sustainable strategy for scalable-designed and color-regulating PDRC coating based on high-crystallinity photonic metamaterial (crystallinity: 71.5%; enhanced assembly efficiency: 72%), that is derived from the as-prepared 55 wt% solid content poly(methyl methacrylate-butyl acrylate-methacrylic acid) P(MMA-BA-MAA) monodispersed latexes (approaching theoretical limit: 59 wt%). Robust meter-scale PDRC coatings are constructed by various industrial modes onto diverse surfaces, addressing bottlenecks like dull appearance, high cost, low efficiency, and hard construction. Notably, the solar reflectance, long-wave infrared emittance, and calculated theoretical cooling power of the designed PDRC coating, respectively, reach ~ 0.94, ~ 0.97, and ~ 95.5 W m-2 under solar radiation, which can achieve an average 5.3 °C sub-ambient daytime temperature drop in the summer in Nanjing. The cooling performance, scale preparation, and cost-effectiveness of the PDRC coating have extended into leading position compared with those of state-of-the-art designs. This work provides promising route to reduce carbon emissions and energy consumption for global sustainability.","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"6 1","pages":"153"},"PeriodicalIF":26.6,"publicationDate":"2026-01-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145949751","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-01-12DOI: 10.1007/s40820-025-01981-0
Yan Dong,Boxi Tian,Cunhai Wang,Guoliang Zhang,Fengjiao Hua,Weifeng Meng,Chunzhe Li,Yuying Yan,Ziming Cheng,Fuqiang Wang
As an emerging thermal management strategy, dynamic radiative cooling (DRC) technology enables dynamic modulation of spectral radiation properties under varying environmental conditions through the directional design of material spectral characteristics. However, a comprehensive review of the basic physical mechanisms of radiative heat transfer in DRC materials and various design principles involved in dynamic radiative thermal regulation is still lacking. This review systematically summarizes recent advances in this field, spanning from fundamental physical principles to intrinsic molecular and electronic mechanisms, and further to representative material systems and multi-band regulation strategies, highlighting the interdisciplinary research achievements and technological innovations. This work outlines the core mechanisms governing the regulation of different spectral bands during radiative heat transfer processes. Then, the main categories of DRC materials are systematically reviewed, including actively responsive structures, passively responsive structures, and multi-stimuli-responsive materials. Furthermore, the challenges faced by current DRC technology and future development trends are summarized and discussed, providing valuable reference and guidance for further research in this field. Although DRC technologies still face significant challenges in material stability, manufacturing processes, and system integration, the continuous advances in related areas and multifunctional materials are expected to broaden the application prospects of DRC in the future.
{"title":"Dynamic Radiative Cooling: Mechanisms, Strategies, and Applications for Smart Thermal Management.","authors":"Yan Dong,Boxi Tian,Cunhai Wang,Guoliang Zhang,Fengjiao Hua,Weifeng Meng,Chunzhe Li,Yuying Yan,Ziming Cheng,Fuqiang Wang","doi":"10.1007/s40820-025-01981-0","DOIUrl":"https://doi.org/10.1007/s40820-025-01981-0","url":null,"abstract":"As an emerging thermal management strategy, dynamic radiative cooling (DRC) technology enables dynamic modulation of spectral radiation properties under varying environmental conditions through the directional design of material spectral characteristics. However, a comprehensive review of the basic physical mechanisms of radiative heat transfer in DRC materials and various design principles involved in dynamic radiative thermal regulation is still lacking. This review systematically summarizes recent advances in this field, spanning from fundamental physical principles to intrinsic molecular and electronic mechanisms, and further to representative material systems and multi-band regulation strategies, highlighting the interdisciplinary research achievements and technological innovations. This work outlines the core mechanisms governing the regulation of different spectral bands during radiative heat transfer processes. Then, the main categories of DRC materials are systematically reviewed, including actively responsive structures, passively responsive structures, and multi-stimuli-responsive materials. Furthermore, the challenges faced by current DRC technology and future development trends are summarized and discussed, providing valuable reference and guidance for further research in this field. Although DRC technologies still face significant challenges in material stability, manufacturing processes, and system integration, the continuous advances in related areas and multifunctional materials are expected to broaden the application prospects of DRC in the future.","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"30 1","pages":"146"},"PeriodicalIF":26.6,"publicationDate":"2026-01-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145949600","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The development of gradient lubrication materials is critical for numerous biomedical applications, particularly in magnifying mechanical properties and service longevity. Herein, we present an innovative approach to fabricate biomimetic gradient lubrication hydrogel through the synergistic integration of three-dimensional (3D) printed metal-organic frameworks (MOFs) nanoparticle network hydrogel skeletons with bio-inspired lubrication design. Specifically, robust hydrogel skeletons were engineered through single or multi-material 3D printing, followed by the in situ growth of MOFs nanoparticles within this hydrogel network to create a reinforced, load-bearing architecture. Subsequently, biomimetic lubrication capability was enabled by mechanically coupling another lubricating hydrogel within 3D-printed MOFs nanoparticle network hydrogel skeleton. The superficial layer is highly lubricious to ensure low coefficient of friction (~ 0.1141) and wear resistance (40,000 cycles), while the deeper layer is stiffer to afford the obligatory mechanical support (fracture strength ~ 2.50 MPa). Furthermore, the gradient architecture stiffness of the hydrogel can be modulated by manipulating the spatial distribution of MOFs within the 3D-printed hydrogel skeleton. As a proof-of-concept, biomimetic gradient hydrogel meniscus structures with C- and O-shaped configurations were constructed by leveraging multi-material 3D printing, demonstrating exceptional lubrication performance. This innovative biomimetic design opens new avenues for creating implantable biomedical gradient lubricating materials with reinforced mechanical and lubrication performance.
{"title":"Biomimetic Gradient Lubrication Hydrogel Contrived by Self-Reinforced MOFs Nanoparticle Network.","authors":"Desheng Liu,Yixian Wang,Changcheng Bai,Danli Hu,Xingxing Yang,Yaozhong Lu,Tao Wu,Fei Zhai,Pan Jiang,Xiaolong Wang,Weimin Liu","doi":"10.1007/s40820-025-02001-x","DOIUrl":"https://doi.org/10.1007/s40820-025-02001-x","url":null,"abstract":"The development of gradient lubrication materials is critical for numerous biomedical applications, particularly in magnifying mechanical properties and service longevity. Herein, we present an innovative approach to fabricate biomimetic gradient lubrication hydrogel through the synergistic integration of three-dimensional (3D) printed metal-organic frameworks (MOFs) nanoparticle network hydrogel skeletons with bio-inspired lubrication design. Specifically, robust hydrogel skeletons were engineered through single or multi-material 3D printing, followed by the in situ growth of MOFs nanoparticles within this hydrogel network to create a reinforced, load-bearing architecture. Subsequently, biomimetic lubrication capability was enabled by mechanically coupling another lubricating hydrogel within 3D-printed MOFs nanoparticle network hydrogel skeleton. The superficial layer is highly lubricious to ensure low coefficient of friction (~ 0.1141) and wear resistance (40,000 cycles), while the deeper layer is stiffer to afford the obligatory mechanical support (fracture strength ~ 2.50 MPa). Furthermore, the gradient architecture stiffness of the hydrogel can be modulated by manipulating the spatial distribution of MOFs within the 3D-printed hydrogel skeleton. As a proof-of-concept, biomimetic gradient hydrogel meniscus structures with C- and O-shaped configurations were constructed by leveraging multi-material 3D printing, demonstrating exceptional lubrication performance. This innovative biomimetic design opens new avenues for creating implantable biomedical gradient lubricating materials with reinforced mechanical and lubrication performance.","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"30 1","pages":"150"},"PeriodicalIF":26.6,"publicationDate":"2026-01-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145949756","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The lack of macro-continuity and mechanical strength of covalent organic frameworks (COFs) has significantly limited their practical applications. Here, we propose an "alcohol-triggered defect cleavage" strategy to precisely regulate the growth and stacking of COF grains through a moderate reversed Schiff base reaction, realizing the direct synthesis of COF nanofibers (CNFs) with high aspect ratio (L/D = 103.05) and long length (> 20 μm). An individual CNF exhibits a biomimetic scale-like architecture, achieving superior flexibility and fatigue resistance under dynamic bending via a multiscale stress dissipation mechanism. Taking advantages of these structural features, we engineer CNF aerogels (CNF-As) with programmable porous structures (e.g., honeycomb, lamellar, isotropic) via directional ice-template methodology. CNF-As demonstrate 100% COF content, high specific surface area (396.15 m2 g-1) and superelasticity (~ 0% elastic deformation after 500 compression cycles at 50% strain), outperforming most COF-based counterparts. Compared with the conventional COF aerogels, the unique structural features of CNF-A enable it to perform outstandingly in uranium extraction, with an 11.72-fold increment in adsorption capacity (920.12 mg g-1) and adsorption rate (89.9%), and a 2.48-fold improvement in selectivity (U/V = 2.31). This study provides a direct strategy for the development of next-generation COF materials with outstanding functionality and structural robustness.
{"title":"Flexible High-Aspect-Ratio COF Nanofibers: Defect-Engineered Synthesis, Superelastic Aerogels, and Uranium Extraction Applications.","authors":"Binbin Fan,Jianyong Yu,Xueli Wang,Yang Si,Peixin Tang","doi":"10.1007/s40820-025-01984-x","DOIUrl":"https://doi.org/10.1007/s40820-025-01984-x","url":null,"abstract":"The lack of macro-continuity and mechanical strength of covalent organic frameworks (COFs) has significantly limited their practical applications. Here, we propose an \"alcohol-triggered defect cleavage\" strategy to precisely regulate the growth and stacking of COF grains through a moderate reversed Schiff base reaction, realizing the direct synthesis of COF nanofibers (CNFs) with high aspect ratio (L/D = 103.05) and long length (> 20 μm). An individual CNF exhibits a biomimetic scale-like architecture, achieving superior flexibility and fatigue resistance under dynamic bending via a multiscale stress dissipation mechanism. Taking advantages of these structural features, we engineer CNF aerogels (CNF-As) with programmable porous structures (e.g., honeycomb, lamellar, isotropic) via directional ice-template methodology. CNF-As demonstrate 100% COF content, high specific surface area (396.15 m2 g-1) and superelasticity (~ 0% elastic deformation after 500 compression cycles at 50% strain), outperforming most COF-based counterparts. Compared with the conventional COF aerogels, the unique structural features of CNF-A enable it to perform outstandingly in uranium extraction, with an 11.72-fold increment in adsorption capacity (920.12 mg g-1) and adsorption rate (89.9%), and a 2.48-fold improvement in selectivity (U/V = 2.31). This study provides a direct strategy for the development of next-generation COF materials with outstanding functionality and structural robustness.","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"1 1","pages":"142"},"PeriodicalIF":26.6,"publicationDate":"2026-01-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145949759","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Photocatalytic H2O2 Production over Ultrathin Layered Double Hydroxide with 3.92% Solar-to-H2O2 Efficiency","authors":"Yamin Xi, Zechun Lu, Tong Bao, Yingying Zou, Chaoqi Zhang, Chunhong Xia, Guangfeng Wei, Chengzhong Yu, Chao Liu","doi":"10.1007/s40820-025-02044-0","DOIUrl":"10.1007/s40820-025-02044-0","url":null,"abstract":"<div><h2>Highlights</h2><div>\u0000 \u0000 <ul>\u0000 <li>\u0000 <p>The use of layered double hydroxides for photocatalytic for H<sub>2</sub>O<sub>2</sub> production is innovatively demonstrated.</p>\u0000 </li>\u0000 <li>\u0000 <p>Facet-dependent spatial charge separation enables maximized carrier utilization efficiency.</p>\u0000 </li>\u0000 <li>\u0000 <p>The unique role of intercalated nitrate in promoting electron-hole separation and facilitating intermolecular electron transfer is unveiled.</p>\u0000 </li>\u0000 <li>\u0000 <p>A record-high H<sub>2</sub>O<sub>2</sub> production rate of 28.7 mmol g<sup>-1</sup> h<sup>-1</sup> with 3.92% solar-to-chemical efficiency is achieved.</p>\u0000 </li>\u0000 </ul>\u0000 </div></div>","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"18 1","pages":""},"PeriodicalIF":36.3,"publicationDate":"2026-01-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40820-025-02044-0.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145949568","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-01-12DOI: 10.1007/s40820-025-01994-9
Zefang Yang,Qi Zhang,Chao Hu,Yougen Tang,Jinchi Li,Qi Wang,Wanhai Zhou,Dongliang Chao,Haiyan Wang
Electrolytic Zn-MnO2 batteries are promising candidates for safe and sustainable energy storage owing to their high voltage, environmental benignity, and cost-effectiveness. However, practical applications are hindered by the poor conductivity and the irreversible dissolution of conventional ε-MnO2 deposits. Herein, we report a scalable semisolid slurry electrode architecture that enables stable MnO2 deposition/dissolution using a three-dimensional percolating network of carbon nanotubes (CNTs) as both conductive matrix and deposition host. The slurry system promotes the formation of highly conductive γ-MnO2 owing to enhanced charge transfer kinetics, enabling overall dissolution rather than the localized separation typically seen in traditional electrodes. The Zn-MnO2 slurry cell exhibits a reversible areal capacity approaching 60 mAh cm-2. Moreover, the flowable nature of the slurry allows electrochemically inactive MnO2 formed during dissolution to be reconnected and reactivated by CNTs in the rheological network, ensuring deep utilization and cycling stability. This work establishes a slurry electrode strategy to improve electrolytic MnO2 reactions and offers a viable pathway toward renewable aqueous batteries for grid-scale applications.
电解锌-二氧化锰电池因其高电压、环保和成本效益而成为安全和可持续能源储存的有希望的候选者。然而，常规的ε-MnO2沉积层的导电性差和不可逆溶解阻碍了其实际应用。在此，我们报告了一种可扩展的半固态浆料电极结构，该结构使用碳纳米管（CNTs）作为导电基质和沉积宿主的三维渗透网络，能够稳定地沉积/溶解MnO2。由于电荷转移动力学的增强，浆液体系促进了高导电性γ-MnO2的形成，实现了整体溶解，而不是传统电极中常见的局部分离。锌- mno2浆料电池的可逆面积容量接近60 mAh cm-2。此外，浆料的流动性使得溶解过程中形成的电化学活性MnO2可以在流变网络中被CNTs重新连接和激活，从而确保深度利用和循环稳定性。这项工作建立了一种浆液电极策略，以改善电解MnO2反应，并为电网规模应用的可再生水电池提供了一条可行的途径。
{"title":"Unlocking Reversible Mn2+/MnO2 Chemistry in Semisolid Slurry Electrodes for High-Performance Aqueous Zn-Mn Batteries.","authors":"Zefang Yang,Qi Zhang,Chao Hu,Yougen Tang,Jinchi Li,Qi Wang,Wanhai Zhou,Dongliang Chao,Haiyan Wang","doi":"10.1007/s40820-025-01994-9","DOIUrl":"https://doi.org/10.1007/s40820-025-01994-9","url":null,"abstract":"Electrolytic Zn-MnO2 batteries are promising candidates for safe and sustainable energy storage owing to their high voltage, environmental benignity, and cost-effectiveness. However, practical applications are hindered by the poor conductivity and the irreversible dissolution of conventional ε-MnO2 deposits. Herein, we report a scalable semisolid slurry electrode architecture that enables stable MnO2 deposition/dissolution using a three-dimensional percolating network of carbon nanotubes (CNTs) as both conductive matrix and deposition host. The slurry system promotes the formation of highly conductive γ-MnO2 owing to enhanced charge transfer kinetics, enabling overall dissolution rather than the localized separation typically seen in traditional electrodes. The Zn-MnO2 slurry cell exhibits a reversible areal capacity approaching 60 mAh cm-2. Moreover, the flowable nature of the slurry allows electrochemically inactive MnO2 formed during dissolution to be reconnected and reactivated by CNTs in the rheological network, ensuring deep utilization and cycling stability. This work establishes a slurry electrode strategy to improve electrolytic MnO2 reactions and offers a viable pathway toward renewable aqueous batteries for grid-scale applications.","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"81 1","pages":"148"},"PeriodicalIF":26.6,"publicationDate":"2026-01-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145949752","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
SRMs integrate intrinsic diode-like rectification, enabling sneak path suppression in crossbar arrays without external selectors, simplifying design, and enhancing energy efficiency for high-density in-memory computing.
Key metrics such as rectification ratio, nonlinearity, and CMOS compatibility are systematically reviewed, highlighting progress in 3D integration and scalable array.
Applications span in-memory computing, neuromorphic networks, and hardware security, with emerging potentials in in-sensor computing and self-supervised learning, positioning SRMs as pivotal beyond-CMOS building blocks.
Organic-inorganic metal halides (OIMHs) have emerged as highly promising novel multifunctional optoelectronic materials, owing to their easily adjustable properties from a variety of combinations of different components. But it is still difficult and rare to realize highly tunable multicolor luminescence within the same material. In this work, we successfully incorporated three adjustable emission centers in OIMHs to synthesize a novel OIMH (NEA)2MnBr4, with each emission center capable of emitting one of the primary colors-red, green, and blue. The green and red emissions originate from the tetrahedron and octahedron structures in the Mn-based frame, while the blue can be attributed to the contribution of organic components. Additionally, to achieve comparable emission intensity among the three primary colors, we enhanced the blue emission performance by optimizing the ratio of organic structure components and incorporating chirality in the OIMHs. The resulting high-quality films can be obtained by spin-coating method with a photoluminescence quantum yields of up to 96%. More interestingly, by the dual manipulation of excitation wavelength and temperature, the sample can be emitted at least seven distinct colors including a standard white luminescence at (0.33, 0.33), opening up promising prospects for multicolor luminescence applications such as high-end anti-counterfeiting technology, light-emitting diodes, X-ray imaging, latent fingerprints, humidity detection, and so on. Therefore, based on application scenarios and requirements, our research on this highly tunable luminescent OIMH material lays a solid foundation for further development of various functional properties of related materials.
{"title":"Modulation of Trichromatic Emission Centers in Organic-Inorganic Hybrids for Optoelectronic Applications.","authors":"Weidong Cai,Chongyuan Li,Qiang Guo,Fuxiang Ji,Muyi Zhang,Yiqiang Zhan","doi":"10.1007/s40820-025-01965-0","DOIUrl":"https://doi.org/10.1007/s40820-025-01965-0","url":null,"abstract":"Organic-inorganic metal halides (OIMHs) have emerged as highly promising novel multifunctional optoelectronic materials, owing to their easily adjustable properties from a variety of combinations of different components. But it is still difficult and rare to realize highly tunable multicolor luminescence within the same material. In this work, we successfully incorporated three adjustable emission centers in OIMHs to synthesize a novel OIMH (NEA)2MnBr4, with each emission center capable of emitting one of the primary colors-red, green, and blue. The green and red emissions originate from the tetrahedron and octahedron structures in the Mn-based frame, while the blue can be attributed to the contribution of organic components. Additionally, to achieve comparable emission intensity among the three primary colors, we enhanced the blue emission performance by optimizing the ratio of organic structure components and incorporating chirality in the OIMHs. The resulting high-quality films can be obtained by spin-coating method with a photoluminescence quantum yields of up to 96%. More interestingly, by the dual manipulation of excitation wavelength and temperature, the sample can be emitted at least seven distinct colors including a standard white luminescence at (0.33, 0.33), opening up promising prospects for multicolor luminescence applications such as high-end anti-counterfeiting technology, light-emitting diodes, X-ray imaging, latent fingerprints, humidity detection, and so on. Therefore, based on application scenarios and requirements, our research on this highly tunable luminescent OIMH material lays a solid foundation for further development of various functional properties of related materials.","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"8 1","pages":"140"},"PeriodicalIF":26.6,"publicationDate":"2026-01-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145949603","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Conventional treatments for non-small cell lung cancer (NSCLC) suffer from low remission rates, high drug resistance, and severe adverse effects. To leverage the therapeutic potential of reactive oxygen species (ROS), nanocatalytic medicine utilizes nanomaterials to generate ROS specifically within tumor sites, enabling efficient and targeted cancer treatment. In this study, hyaluronic acid (HA)-modified copper-N,N-dimethyl-N-phenylsulfonylbisamine (DMSA)-assembled nanoparticles (Cu-DMSA-HA NPs) are developed with tumor-targeting capability and efficiently catalyze ROS production via coordination chemistry. Targeted delivery is facilitated by HA surface modification through recognition of overexpressed cluster of differentiation 44 receptors on cancer cells, which enhances nanoparticle uptake. Once internalized, intracellular glutathione is depleted by the NPs, followed by a Fenton-like reaction that sustains ROS production. Both in vitro and in vivo studies demonstrate that this catalytic strategy effectively inhibits DNA replication, prevents cell cycle progression, downregulates glutathione peroxidase 4 expression, induces ferroptosis, and ultimately suppresses NSCLC progression. Overall, the readily prepared Cu-DMSA-HA NPs exhibit robust catalytic activity and tumor specificity, highlighting their strong potential for clinical translation in nanocatalytic cancer therapy.
非小细胞肺癌（NSCLC）的常规治疗存在缓解率低、耐药高、不良反应严重等问题。为了利用活性氧（ROS）的治疗潜力，纳米催化医学利用纳米材料在肿瘤部位特异性地产生ROS，从而实现高效和靶向的癌症治疗。在本研究中，透明质酸（HA）修饰的铜- n， n -二甲基- n -苯基磺酰基双胺（DMSA）组装纳米粒子（Cu-DMSA-HA NPs）具有肿瘤靶向能力，并通过配位化学有效催化ROS的产生。通过识别癌细胞上过度表达的分化44受体簇，透明质酸表面修饰促进了靶向递送，从而增强了纳米颗粒的摄取。一旦内化，细胞内谷胱甘肽被NPs耗尽，随后是维持ROS产生的芬顿样反应。体外和体内研究均表明，该催化策略可有效抑制DNA复制，阻止细胞周期进展，下调谷胱甘肽过氧化物酶4表达，诱导铁凋亡，最终抑制NSCLC进展。总的来说，制备的Cu-DMSA-HA NPs表现出强大的催化活性和肿瘤特异性，突出了它们在纳米催化癌症治疗中的临床翻译潜力。
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