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Carbon Nanofiber/Polyaniline Composite Aerogel with Excellent Electromagnetic Interference Shielding, Low Thermal Conductivity, and Extremely Low Heat Release
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2024-12-02 DOI: 10.1007/s40820-024-01583-2
Mingyi Chen, Jian Zhu, Kai Zhang, Hongkang Zhou, Yufei Gao, Jie Fan, Rouxi Chen, Hsing-Lin Wang

Highlights

  • Using electrospun high-strength carbon nanofibers as the aerogel scaffold, high loading of polyaniline in the aerogel was achieved through seed polymerization, forming the core–shell structure fibers and simultaneously connecting the fibers as a stable conductive network.

  • Combining carbon-based materials with conductive polymers like polyaniline significantly improves shielding performance, achieving electromagnetic interference shielding efficiency of up to 84.5 dB and SE d−1 values greater than 791.2 dB cm3 g⁻1. Flame retardancy reduces PHRR by 65.8%, and thermal insulation with low thermal conductivity of 0.104 W m⁻1 K⁻1.

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引用次数: 0
RGB Color-Discriminable Photonic Synapse for Neuromorphic Vision System 用于神经形态视觉系统的 RGB 色彩可分辨光子突触
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2024-11-29 DOI: 10.1007/s40820-024-01579-y
Bum Ho Jeong, Jaewon Lee, Miju Ku, Jongmin Lee, Dohyung Kim, Seokhyun Ham, Kyu-Tae Lee, Young-Beom Kim, Hui Joon Park

To emulate the functionality of the human retina and achieve a neuromorphic visual system, the development of a photonic synapse capable of multispectral color discrimination is of paramount importance. However, attaining robust color discrimination across a wide intensity range, even irrespective of medium limitations in the channel layer, poses a significant challenge. Here, we propose an approach that can bestow the color-discriminating synaptic functionality upon a three-terminal transistor flash memory even with enhanced discriminating capabilities. By incorporating the strong induced dipole moment effect at the excitation, modulated by the wavelength of the incident light, into the floating gate, we achieve outstanding RGB color-discriminating synaptic functionality within a remarkable intensity range spanning from 0.05 to 40 mW cm−2. This approach is not restricted to a specific medium in the channel layer, thereby enhancing its applicability. The effectiveness of this color-discriminating synaptic functionality is demonstrated through visual pre-processing of a photonic synapse array, involving the differentiation of RGB channels and the enhancement of image contrast with noise reduction. Consequently, a convolutional neural network can achieve an impressive inference accuracy of over 94% for Canadian-Institute-For-Advanced-Research-10 colorful image recognition task after the pre-processing. Our proposed approach offers a promising solution for achieving robust and versatile RGB color discrimination in photonic synapses, enabling significant advancements in artificial visual systems.

为了模拟人类视网膜的功能并实现神经形态视觉系统,开发一种能够进行多光谱颜色分辨的光子突触至关重要。然而,即使不考虑通道层的介质限制,要在很宽的强度范围内实现强大的色彩分辨能力也是一个巨大的挑战。在这里,我们提出了一种方法,它能赋予三端晶体管闪存以色彩分辨突触功能,甚至增强分辨能力。通过将激发时的强诱导偶极矩效应(受入射光波长调制)纳入浮动栅极,我们在 0.05 至 40 mW cm-2 的显著强度范围内实现了出色的 RGB 色彩分辨突触功能。这种方法并不局限于通道层中的特定介质,因此增强了其适用性。通过对光子突触阵列进行视觉预处理,包括区分 RGB 通道和通过降噪增强图像对比度,证明了这种色彩分辨突触功能的有效性。因此,经过预处理后,卷积神经网络在加拿大高级研究学院-10 彩色图像识别任务中的推理准确率达到了令人印象深刻的 94% 以上。我们提出的方法为在光子突触中实现稳健、多用途的 RGB 颜色识别提供了一种前景广阔的解决方案,使人工视觉系统取得了重大进展。
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引用次数: 0
Ultrahigh Energy and Power Density in Ni–Zn Aqueous Battery via Superoxide-Activated Three-Electron Transfer 通过超氧化物激活三电子转移实现镍锌水电池的超高能量和功率密度
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2024-11-29 DOI: 10.1007/s40820-024-01586-z
Yixue Duan, Bolong Li, Kai Yang, Zheng Gong, Xuqiao Peng, Liang He, Derek Ho

Highlights

  • Efficient activation of Ni electrode employs chronopotentiostatic superoxidation.

  • Novel superoxide activation mechanism realizes the redox reaction with three-electron transfer (Ni ↔ Ni3+).

  • As-prepared CPS-Ni||Zn batteries exhibit simultaneously ultrahigh energy and power densities.

亮点 利用计时恒电位超氧化作用高效活化镍电极。 新颖的超氧化物活化机制实现了三电子转移(Ni ↔ Ni3+)的氧化还原反应。 制备的 CPS-Ni|||Zn 电池同时表现出超高的能量密度和功率密度。
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引用次数: 0
Ligand Engineering Achieves Suppression of Temperature Quenching in Pure Green Perovskite Nanocrystals for Efficient and Thermostable Electroluminescence 配体工程抑制了纯绿色过氧化物纳米晶体的温度淬灭,实现了高效、恒温电致发光
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2024-11-28 DOI: 10.1007/s40820-024-01564-5
Kaiwang Chen, Qing Du, Qiufen Cao, Chao Du, Shangwei Feng, Yutong Pan, Yue Liang, Lei Wang, Jiangshan Chen, Dongge Ma

Highlights

  • The innovative synthesis of pure green FAPbBr3 nanocrystals at room temperature was exploited by employing aromatic amine ligands to refine the perovskite nanocrystals with high quality and excellent optoelectronic properties.

  • The proposed ligand engineering strategy firstly realized the suppression of emission thermal quenching effect in the organic-inorganic hybrid FAPbBr3 nanocrystals.

  • It was demonstrated that the FAPbBr3 based light-emitting diodes achieved a room temperature external quantum efficiency (EQE) of 21.9% at the luminance of 1580 cd m-2, and only presented less than 10% loss in EQE at a higher temperature of 343 K.

亮点 通过使用芳香胺配体,创新性地在室温下合成了纯绿色的 FAPbBr3 纳米晶体,使其具有高质量和优异的光电特性。 所提出的配体工程策略首先抑制了有机-无机杂化 FAPbBr3 纳米晶体的发射热淬效应。 结果表明,基于 FAPbBr3 的发光二极管在室温下亮度为 1580 cd m-2 时的外部量子效率(EQE)达到了 21.9%,而在较高的 343 K 温度下,EQE 的损失仅小于 10%。
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引用次数: 0
Advances in the Development of Gradient Scaffolds Made of Nano-Micromaterials for Musculoskeletal Tissue Regeneration 用于肌肉骨骼组织再生的纳米微材料梯度支架的开发进展
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2024-11-27 DOI: 10.1007/s40820-024-01581-4
Lei Fang, Xiaoqi Lin, Ruian Xu, Lu Liu, Yu Zhang, Feng Tian, Jiao Jiao Li, Jiajia Xue

Highlights

  • This review highlights the gradient variations in the structural composition of musculoskeletal tissues and comprehensively examines recent progress in the fabrication and application of biomimetic gradient scaffolds for musculoskeletal repair.

  • The challenges and prospects of gradient scaffolds for clinical application are discussed.

亮点 本综述强调了肌肉骨骼组织结构组成的梯度变化,并全面研究了用于肌肉骨骼修复的生物仿生梯度支架的制造和应用方面的最新进展。 文章还讨论了梯度支架在临床应用中面临的挑战和前景。
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引用次数: 0
A Multifunctional Hydrogel with Multimodal Self-Powered Sensing Capability and Stable Direct Current Output for Outdoor Plant Monitoring Systems 一种具有多模式自供电传感能力和稳定直流输出的多功能水凝胶,适用于室外植物监测系统
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2024-11-27 DOI: 10.1007/s40820-024-01587-y
Xinge Guo, Luwei Wang, Zhenyang Jin, Chengkuo Lee

Highlights

  • A simple and scalable fabricated hydrogel with multiple functionalities to realize self-sustainable outdoor monitoring solely by it for large-scale applications in precision agriculture.

  • Stable direct-current output without requirement on stochastic or temporal environmental energies, achieving an energy density of 1.36 × 107 J m–3 with continuous operation of 56.25 days in normal outdoor environment.

  • Self-powered noninvasive leaf relative water content monitoring and environmental sensing to evaluate plant health status with high durability and self-recoverability in severe environments.

亮点 一种简单且可扩展的水凝胶,具有多种功能,仅靠它就能实现可自我维持的户外监测,可大规模应用于精准农业。 稳定的直流电输出,无需随机或时间性环境能量,在正常室外环境中连续工作 56.25 天,能量密度达到 1.36 × 107 J m-3。 自供电无创叶片相对含水量监测和环境传感,可评估植物健康状况,在恶劣环境下具有高耐用性和自恢复能力。
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引用次数: 0
Dual-Donor-Induced Crystallinity Modulation Enables 19.23% Efficiency Organic Solar Cells 双供体诱导结晶度调制可实现 19.23% 效率的有机太阳能电池
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2024-11-27 DOI: 10.1007/s40820-024-01576-1
Anhai Liang, Yuqing Sun, Sein Chung, Jiyeong Shin, Kangbo Sun, Chaofeng Zhu, Jingjing Zhao, Zhenmin Zhao, Yufei Zhong, Guangye Zhang, Kilwon Cho, Zhipeng Kan

Article Highlights

  • By modulating the crystalline properties of the active layer with dual donors, the efficiency of organic solar cells reaches 19.23%.

  • The introduction of PTzBI-dF suppresses the accumulation of traps and charge recombination, allowing ternary devices to maintain 82% of their initial power conversion efficiency (PCE) after illumination for 800 h.

  • The dual-donor strategy for modulating the crystallinity of the active layer is applicable to a variety of Y6 derivatives, and the increase in PCE exceeds 1%.

文章亮点 通过使用双供体调节活性层的晶体特性,有机太阳能电池的效率达到了 19.23%。 PTzBI-dF 的引入抑制了陷阱的积累和电荷的重组,使三元器件在光照 800 小时后仍能保持其初始功率转换效率(PCE)的 82%。双供体调节活性层结晶度的策略适用于多种 Y6 衍生物,且 PCE 的提高幅度超过 1%。
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引用次数: 0
Efficient and Stable Photoassisted Lithium-Ion Battery Enabled by Photocathode with Synergistically Boosted Carriers Dynamics 具有协同增效载流子动力学的光电阴极可驱动高效稳定的光助锂离子电池
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2024-11-27 DOI: 10.1007/s40820-024-01570-7
Zelin Ma, Shiyao Wang, Zhuangzhuang Ma, Juan Li, Luomeng Zhao, Zhihuan Li, Shiyuan Wang, Yazhou Shuang, Jiulong Wang, Fang Wang, Weiwei Xia, Jie Jian, Yibo He, Junjie Wang, Pengfei Guo, Hongqiang Wang

Highlights

  • Developing a universal bulk heterojunction strategy to create oxygen vacancies by embedding laser-manufactured metal nanocrystals into the TiO2 matrix.

  • Proposing a new mechanism based on plasmonic-induced hot electron injection and enhanced conductivity from Schottky contact-derived oxygen vacancies.

  • Establishing several benchmark values for the performance of TiO2-based photocathodes in photoassisted lithium-ion batteries.

亮点 通过在二氧化钛基体中嵌入激光制造的金属纳米晶体,开发出一种通用的体异质结策略来产生氧空位。 提出一种基于等离子体诱导热电子注入和肖特基接触衍生氧空位增强导电性的新机制。 为基于二氧化钛的光电阴极在光助锂离子电池中的性能建立几个基准值。
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引用次数: 0
Recent Strategies and Advances in Hydrogel-Based Delivery Platforms for Bone Regeneration 基于水凝胶的骨再生传输平台的最新战略和进展
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2024-11-27 DOI: 10.1007/s40820-024-01557-4
Xiao Wang, Jia Zeng, Donglin Gan, Kun Ling, Mingfang He, Jianshu Li, Yongping Lu

Highlights

  • Recent advances in the combined delivery platform that integrate nano-/microscale carriers and with 3D hydrogel network for bone regeneration are summarized.

  • The strategies for bioactive molecules delivery involving nanoparticles, nanosheets, and microspheres, along with extra stimuli such as near-infrared light, temperature changes, ultrasonication, and inflammatory conditions, are introduced.

  • The prospects and challenges for the clinical translation and the development of nano-/microscale incorporated hydrogel-based delivery platform are discussed.

亮点概述 整合纳米/微米级载体和三维水凝胶网络的联合递送平台在骨再生方面的最新进展。 介绍了涉及纳米颗粒、纳米片和微球的生物活性分子递送策略,以及额外刺激(如近红外线、温度变化、超声波和炎症条件)。 此外,还讨论了基于纳米/微尺度水凝胶的递送平台的临床转化和发展前景与挑战。
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引用次数: 0
Deciphering Water Oxidation Catalysts: The Dominant Role of Surface Chemistry over Reconstruction Degree in Activity Promotion 解密水氧化催化剂:表面化学在促进活性方面的主导作用大于重构程度
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2024-11-26 DOI: 10.1007/s40820-024-01562-7
Li An, Jianyi Li, Yuanmiao Sun, Jiamin Zhu, Justin Zhu Yeow Seow, Hong Zhang, Nan Zhang, Pinxian Xi, Zhichuan J. Xu, Chun-Hua Yan

Highlights

  • Demonstrate that the key factor to determine the activity of reconstructed surfaces is the surface chemistry, instead of reconstruction degree using the popular perovskite LaNi1-xFexO3 oxides as model materials.

  • Fe content can influence both the surface reconstruction degree, the activation degree, and the activity of reconstructed surfaces.

  • The oxygen evolution reaction activity of reconstructed catalysts is primarily governed by the chemistry of the reconstructed surface species.

以常用的过氧化物 LaNi1-xFexO3 氧化物为模型材料,证明决定重构表面活性的关键因素是表面化学,而不是重构程度。
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引用次数: 0
期刊
Nano-Micro Letters
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