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Full-Photolithographic High-Density Skin-Like Transistor Arrays for All-Organic Active-Matrix Displays 用于全有机有源矩阵显示的全光刻高密度类皮肤晶体管阵列。
IF 36.3 1区 材料科学 Q1 Engineering Pub Date : 2026-03-04 DOI: 10.1007/s40820-026-02107-w
Peng Xue, Juntong Li, Xiaoli Zhao, Yanping Ni, Hongyan Yu, Xianghui Liu, Bowen Xiang, Yao Fu, Junru Zhang, Baoying Sun, Pengbo Xi, Xiang Song, Yijun Shi, Guodong Zhao, Mingxin Zhang, Yanhong Tong, Qingxin Tang, Yichun Liu

Organic thin-film transistors (OTFTs) are widely recognized as promising building blocks for next-generation flexible and wearable electronics. However, scalable fabrication of high-density OTFT arrays for active-matrix applications remains highly challenging, primarily due to the incompatibility of conventional photolithography with organic semiconductors. Here, we report an all-photolithographic strategy that enables the scalable fabrication of flexible OTFT arrays with both high device density and superior charge transport characteristics. By combining synergistic interfacial modulation and dual-protection photolithography strategy of organic semiconductors, we successfully fabricated transistor arrays exhibiting an average mobility above 1.0 cm2 V−1 s−1 and on/off ratios of ~ 105. This scalable method further enables an integration density of 6.25 × 104 cm−2, which is one of the highest densities reported to date for full-photolithographic OTFT active-matrix arrays. Moreover, we demonstrate seamless integration of OTFT active-matrix arrays with organic light-emitting diodes (OLEDs), yielding all-organic active-matrix OLED (AMOLED) arrays. These devices exhibit stable electroluminescence, ultralight weight (~ 24.3 g m−2), excellent flexibility, and skin-like display functionality with reliable pixel-level addressing. This work establishes a universal and scalable route toward high-density organic electronic systems, opening new opportunities for flexible displays, electronic skin, and next-generation wearable technologies.

有机薄膜晶体管(OTFTs)被广泛认为是下一代柔性和可穿戴电子产品的重要组成部分。然而,用于有源矩阵应用的高密度OTFT阵列的可扩展制造仍然具有很高的挑战性,主要是由于传统光刻技术与有机半导体不兼容。在这里,我们报告了一种全光刻策略,该策略可以实现柔性OTFT阵列的可扩展制造,具有高器件密度和优越的电荷传输特性。通过结合有机半导体的协同界面调制和双保护光刻策略,我们成功地制造出了平均迁移率高于1.0 cm2 V-1 s-1和通/关比为~ 105的晶体管阵列。这种可扩展的方法进一步实现了6.25 × 104 cm-2的集成密度,这是迄今为止报道的全光刻OTFT有源矩阵阵列的最高密度之一。此外,我们展示了OTFT有源矩阵阵列与有机发光二极管(OLED)的无缝集成,产生了全有机有源矩阵OLED (AMOLED)阵列。这些器件具有稳定的电致发光,超轻(~ 24.3 g m-2),出色的灵活性和具有可靠像素级寻址的皮肤显示功能。这项工作为高密度有机电子系统建立了一条通用和可扩展的路线,为柔性显示器、电子皮肤和下一代可穿戴技术开辟了新的机会。
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引用次数: 0
Chemo-Strain Valence Engineering for Boosting Photovoltaic Response in Double Perovskite Epitaxial Films 提高双钙钛矿外延薄膜光电响应的化学应变价工程。
IF 36.3 1区 材料科学 Q1 Engineering Pub Date : 2026-03-04 DOI: 10.1007/s40820-026-02105-y
Yonghui Wu, Jie Tu, Jing Xia, Xudong Liu, Longyuan Shi, Hangren Li, Menglin Li, Peng Chen, Qianqian Yang, Siyuan Du, Pengfei Song, Haiying Li, Qian Zhan, Xiaolong Li, Jianjun Tian, Linxing Zhang

Highlights

  • A simple inequivalent substitution strategy modulates lattice distortion andelement valence states, realizing a remarkable boost in ferroelectric photovoltaicperformance under white light (|JSC| = 320 μA cm−2 after negative poling).

  • Synergistic integration of chemical strain and defect engineering yields high performance ferroelectric photovoltaic in double perovskite thin films.

  • Oxygen vacancies enable electric-field modulation of photovoltaic response inferroelectric thin films by tuning the band gap and engineering the Schottkybarrier.

由于其结构的可调性,双钙钛矿薄膜为多铁和铁电光伏提供了巨大的潜力。本研究采用了一种价取代策略,将Bi2FeMnO6 (BFMO)中的Bi部分替换为Pb,在保持宿主晶格的同时破坏电荷平衡和局部极化。铅的掺入同时调节了所有组成元素的化学状态,引起明显的晶格畸变和正向的化学应变。非极性Pb-BFMO薄膜在80 mW cm-2光照下表现出优异的光伏性能,短路电流密度(|JSC|)为192 μA cm-2,开路电压(|VOC|)为0.525 V。这表示与纯BFMO相比,内在JSC增加了109倍,VOC增加了4倍。|JSC|通过极化开关表现出电场可调性,在负极化下达到320 μA cm-2,是白光下报道的亚100 nm单层铁电薄膜的最高JSC。高分辨率高角度环形暗场扫描透射电子显微镜,基于同步加速器的互反空间映射和x射线吸收光谱分析共同证实了晶体畸变,化学应变和价态变化的耦合。化学应变和离子价态之间的协同作用有效地设计了带隙并增强了光伏响应,这为钙钛矿材料在光存储器件和可持续能源系统中的应用开辟了新的途径。
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引用次数: 0
Eco-Friendly, Multi-Mode Processable Highly Moldable Wood Enabled by the Reconstruction of Hydrogen-Bonding Domain 生态友好,可多模式加工的高度可塑木材通过氢键域的重建。
IF 36.3 1区 材料科学 Q1 Engineering Pub Date : 2026-03-04 DOI: 10.1007/s40820-026-02121-y
Rui Yang, Linghui Qi, Xiaoli Wu, Zhipeng Liu, Huiyang Bian, Changlei Xia, Changtong Mei, Shuaicheng Jiang, Meng Yao, Jianzhang Li

Highlights

  • A hydrogen-bond reconstruction strategy creates a moldable wood with greatly improved dimensional stability (≈ 80% lower moisture absorption) and plasticity for precision 3D shaping.

  • We develop a moldable wood that combines high plasticity with exceptional water resistance, enabling the creation of complex, precise 3D structures like mechanical metamaterials.

  • This moldable wood bridges sustainable materials and precision engineering, offering an energy-efficient alternative to synthetic composites in demanding fields like aviation.

先进的3D工程材料的生产依赖于金属和塑料等能源密集型可成型材料,难以应对日益严重的全球能源危机。木材作为一种可持续材料,可以通过水热处理成型,但有限的可塑性阻碍了其制造精密设备的能力。本文将氢键结构域重组工艺应用于高可塑性木材的制造,以提高木材的可塑性,保证纤维素结构的稳定性。木材细胞壁的天然氢键网络被破坏,并通过脱木质素释放纤维素原纤维基质。随后的环氧化大豆油丙烯酸酯(AESO)塑化使塑性显著增强。纤维间的氢键域通过水分变化重建。同时,AESO在纤维表面形成一层保护层,防止过多的水分进入而导致纤维框架的坍塌。这个过程允许材料形成复杂的3D几何形状,包括折纸鹤或蜂窝,通过低能量的水热处理。该策略解决了与木质复合材料相关的尺寸稳定性挑战和环境不稳定性,并为航空和运输中的功能化结构提供了一种环保的替代方案。
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引用次数: 0
Electrolyte Engineering in Redox-Enhanced Electrochemical Capacitors with Zn Anodes: The Role of Colorimetric Indicators 锌阳极氧化还原增强电化学电容器的电解质工程:比色指示剂的作用。
IF 36.3 1区 材料科学 Q1 Engineering Pub Date : 2026-03-02 DOI: 10.1007/s40820-026-02116-9
Ming Chen, Qinglong Luo, Xiaolei Wang, Kaiyuan Shi

Highlights

  • Triphenylmethane dyes as colorimetric indicators were developed for fabricating functional electrolytes in redox-enhanced zinc-ion hybrid capacitors (RZICs), integrating pH buffering, electrochromic response, and redox activity.

  • The colorimetric indicators exhibit proton-electron transfer behavior, where proton transfer enables health state diagnostics and electron transfer facilitates reversible redox reactions.

  • The dye-containing electrolytes provide a wider voltage window, high capacity, and long cycling stability for high-performance RZIC devices.

  • Incorporating colorimetric indicators extends the cycling lifespan of Zn||Zn cells to 4,000 h, allowing RZICs to deliver a capacity of 152.4 mAh g−1 within a 0.2-1.6 V voltage window, with 87.7% capacity retention after 20,000 cycles.

对高性能能源设备日益增长的需求促使人们探索用于水储能的先进电解解决方案。氧化还原增强锌离子电容器(rzic)通过将氧化还原活性分子集成到电解质中,克服了传统电化学电容器的局限性,从而实现了更高的能量密度和更大的电压窗。在这项研究中,我们开发了基于有机染料的比色指示剂,用于在rzic中制备功能电解质。这些染料的结构响应性由电致变色动力学的质子-电子转移驱动,可以实时监测和优化rzic。比色指示剂的酸碱平衡支持pH缓冲,导致Zn||锌电池寿命延长至4,000 h。指示剂的共轭芳香结构增强了它们在活性炭上的吸附,从而最大限度地减少了rzic中的自放电。此外,在优化的0.2-1.6 V电压窗口内,苯酚-醌转化将rzic的容量提高到152.4 mAh g-1,同时促进电化学动力学并抑制阳极降解。研究结果促进了超电容储能用比色氧化还原电解质的设计和定制。
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引用次数: 0
An Integrated Flexible Bioelectrical and Biochemical Monitoring System Based on Spindle-Structured Directional Sweat-Pumping Nanomesh 一种基于纺锤结构定向排汗纳米网的柔性集成生物电生化监测系统。
IF 36.3 1区 材料科学 Q1 Engineering Pub Date : 2026-03-02 DOI: 10.1007/s40820-026-02115-w
Jingzhi Wu, Rongkuan Han, Jianfeng Ma, Jinyi Gong, Tianxin Guan, Peiyan Dong, Hao Tang, Haidong Liu, Jinan Luo, Chang Liu, Yuanfang Li, Degong Zeng, Chuting Liu, Zhikang Deng, Xinyi Qu, Lvjie Chen, Tian-Ling Ren, Jianhua Zhou, Yancong Qiao

Highlights

  • Built via controlled electrospinning, the nanomesh integrates wettability and structural gradients, enabling ultrafast unidirectional liquid transport at speeds up to 4.00 mL min−1 cm−2.

  • An Au nanomesh electrode with high breathability and moisture permeability is designed, offering superior conformability and stretchability for stable on-skin monitoring during motion, along with excellent skin compatibility.

  • The system enables wireless and continuous electrochemical and electrophysiological monitoring, combining sweat biomarkers and electrocardiogram signals for comprehensive health analysis.

可穿戴表皮监测在健康评估中具有重要意义。然而,目前的电子皮肤受到汗液堆积导致的一致性差、低透气性带来的不适以及信号单一的限制,使得长期、稳定、高通量的信号记录变得非常困难。本研究采用静电纺丝技术制备了一种纺锤结构定向吸汗纳米网(SDSN)。通过结合多种不对称性,包括润湿性、孔径和纺锤结结构,SDSN建立了协同力,使液体单向输送的速度比人类运动时的排汗速度快1000倍以上。为了体现流体导向的优势,构建了双结构、双视角的比较模型框架。引入Au nanomesh作为电极允许Au nanomesh电极同时监测电化学和电生理信号,同时保持良好的皮肤顺应性和运动稳定性。此外,还研制了一种纳米网格封装柔性电路,实现了连续无线监测。该系统显示了代谢能量输出与心血管反应相关性分析的潜力,使其成为高强度体力劳动和运动期间健康管理的理想工具。
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引用次数: 0
Design Concept of Metal Sulfide Photocatalyst for Efficient Photocatalytic Hydrogen Evolution 高效光催化析氢的金属硫化物光催化剂设计构想。
IF 36.3 1区 材料科学 Q1 Engineering Pub Date : 2026-03-02 DOI: 10.1007/s40820-026-02111-0
Qizhi Gao, Xinlong Zheng, Jiaxin Lin, Jiadi Zhai, Fan Yang, Xinjie Chen, Minghui Wang, Miaomiao Yang, Jing Li, Xiaodong Shi, Yonghao Xiao, Xinlong Tian, Yuhao Liu

Highlights

  • Highlighting the essential 3D electronic dimensionality, isotropic orbital hybridization is shown to enhance charge carrier mobility in metal sulfide (MS) photocatalysts, overcoming structural dimensionality limits.

  • A controllable-photocorrosion approach is developed to functionally harness corrosion, in situ generating catalytically active sulfur species that boost photocatalytic hydrogen evolution and structural durability.

  • The intrinsic sulfur-coordination directionality synthesis method suppresses MS photocorrosion, offering a scalable stability enhancement, proved for CdS and ZnCdS systems.

金属硫化物(MS)光催化剂具有窄带隙范围、高光吸收系数和合适的能带结构等特点,为通过水裂解实现高效可见光光催化析氢(PHE)提供了巨大的潜力。然而,传统的质谱光催化剂的低电子维数通常会降低光生载流子的转移和迁移效率。此外,严重的内在光腐蚀问题也严重降低了PHE的光稳定性,阻碍了PHE的大规模实际应用。在这方面,以高电子维数构建和高效光腐蚀抑制为重点的MS光催化剂的先进设计理念具有重要意义。本文首先介绍了PHE的基本机制,然后深入讨论了结构维度和电子维度之间的基本区别,强调了三维电子连接在实现各向同性电荷迁移和浅缺陷态方面的优势。随后,系统总结了具有3D电子维度的质谱光催化剂和光腐蚀的解决方案,特别强调了新兴的先进“可控光腐蚀”范式,该范式战略性地利用腐蚀过程来产生活性位点,而不仅仅是抑制它。最后,对目前质谱光催化剂尚未解决的问题进行了全面的讨论。
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引用次数: 0
Graphene-Skinned Fiber with Fine-Tunable Electrical Resistance via Radical and Substrate Engineering for Electromagnetic-Thermal Fabric 基于基板和基板工程的电阻可调石墨烯包覆纤维。
IF 36.3 1区 材料科学 Q1 Engineering Pub Date : 2026-03-02 DOI: 10.1007/s40820-026-02117-8
Jie Liang, Zhaochen Li, Fang Ye, Yuchen Cao, Yi An, Xiaomeng Fan, Qiang Song

Highlights

  • The composition of C1/C2/C6 radicals is strategically regulated by temperature, dictating the growth of either defective or highly textured graphene microstructures.

  • A synergistic strategy involving radical manipulation and substrate effect via methanol- chemical vapor deposition enables precise control of graphene microstructure, allowing fine tuning of sheet resistance from 26 to 150 Ω sq−1.

  • Laser-patterned band-pass frequency selective surface and a sandwich structure synergistically achieve excellent broadband wave transmission (7.29 GHz) and effective Joule heating (72 °C).

本研究展示了一种利用甲醇前驱体通过低压化学气相沉积方法合成石墨烯(Gr)包皮SiO2织物的自由基操纵策略。控制高温热解,调节C1/C2/C6自由基比,实现微观结构工程。底物效应支配着双分子层的演化。与Gr相比,SiO2具有较低的C1吸附能和较高的自由基扩散势垒,促进了地下g1型Gr层的边缘缺陷,而衬底约束的减少有助于在g1型Gr之上生长低缺陷的g2型Gr。气相动力学和衬底动力学的协同控制实现了可调的薄片电阻(26-150 Ω sq-1),使Gr包皮纤维成为集成电磁热管理系统的多功能平台。为满足电磁通信和电热除冰的需要,制备了激光刻蚀带通频率选择的gr皮织物表面结构,在保持焦耳加热能力的同时实现电磁波透射。通过将gr -skin织物与EMW透明片层压制成三明治结构,具有电压相关的透光率,同时保持宽带传输和有效加热。这项工作展示了一种策略,通过多尺度工程,协调微观结构调节和宏观图案,缓解gr功能化纤维中长期存在的电导率- emw透明度权衡,从而解锁用于5G/6G可穿戴设备、航空航天天线罩等的下一代智能复合材料。
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引用次数: 0
Quantitative Defect–Property Correlations in Ti3C2Tx MXenes via Precursor-Controlled Defect Engineering 基于前驱体控制缺陷工程的Ti3C2Tx MXenes中缺陷与性能的定量关联。
IF 36.3 1区 材料科学 Q1 Engineering Pub Date : 2026-03-02 DOI: 10.1007/s40820-026-02106-x
Tufail Hassan, Doyeon Lee, Shabbir Madad Naqvi, Myungjae Kim, Jung-Min Oh, Sang Woon Park, Aamir Iqbal, Soo Yeong Cho, Zhiwang Hao, Noushad Hussain, Zubair Khalid, Shakir Zaman, Xiangmeng Kong, Ki-Min Roh, Hanjung Kwon, Chong Min Koo

Highlights

  • Titanium vacancies (VTi), carbon vacancies (VC), and substitutional oxygen (SO) defects were precisely tuned in TiC and Ti3AlC2 MAX phases by adjusting C and Al feed ratios, yielding Ti3C2Tx MXenes with systematically varied defect densities.

  • Defect minimization resulted in excellent multifunctional performance, including electrical conductivity of 26,000 S cm−1, thermal conductivity of 57 W m−1 K−1, infrared emissivity of 0.05, EMI shielding of 90.5 dB (at 10 µm), Joule heating of 263 °C (at 1.5 V), and activation energy of 72 kJ mol−1.

  • The defect-minimized MXene exhibited excellent oxidation stability, retaining ~90% optical absorption after 4 months in dilute dispersion (0.02 mg mL−1).

  • This study establishes a comprehensive quantitative framework linking precursor-derived defect structures to electrical, thermal, optical, and environmental stability of MXenes.

缺陷工程为定制MXenes的多功能特性带来了巨大的希望。然而,由于缺乏精确控制缺陷密度的可靠策略,缺陷和材料性能之间的定量相关性在很大程度上仍未被探索。本文研究表明,通过调整TiC前驱体合成过程中的碳化学计量和Ti3AlC2 MAX形成过程中的铝含量,可以精确地控制Ti3C2Tx mxines的缺陷密度(包括钛和碳空位、取代氧缺陷和相关的晶格应变)。缺陷密度从前驱体传播到最终的MXenes,使得制造一系列具有系统控制缺陷密度的Ti3C2Tx MXenes成为可能。这使得缺陷密度和多功能特性(包括电导率和导热率、红外发射率、电磁屏蔽效率、焦耳加热性能和氧化稳定性)之间的定量关联成为可能。缺陷最小化的Ti3C2Tx MXene表现出优异的性能,电导率为26,000 S cm-1,导热系数为57 W m-1 K-1, 10µm时电磁屏蔽效率为90.5 dB, 1.5 V时焦耳加热性能为263°C,超低红外发射率为0.05,具有优异的抗氧化性能(活化能为72 kJ mol-1)。此外,这项工作建立了一个综合的定量框架,将缺陷结构与多功能性能和稳定性联系起来。
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引用次数: 0
Mid-Infrared Transparent Materials: from Mechanisms to Cutting-Edge Applications 中红外透明材料:从机制到前沿应用。
IF 36.3 1区 材料科学 Q1 Engineering Pub Date : 2026-02-28 DOI: 10.1007/s40820-026-02113-y
Hanyuan Zhang, Zhenhui Huang, Changyuan Chen, Yi Long, Weilin Xu, Zhengui Zhou, Jun Wan

Highlights

  • Establishes a structure–property–function paradigm linking band structure, phonons, and architecture to mid-infrared (MIR) transmittance.

  • Provides a rigorous taxonomy spanning intrinsic and engineered materials with clarified transparency mechanisms.

  • Derives design rules enabling low-loss MIR transport for advanced thermal and photonic systems.

中红外(MIR)光谱窗口,通常跨越波长从2.5到20 μm(或波数500-4000 cm-1),构成了电磁波谱的关键领域,其中分子振动和旋转跃迁实现了精确的光谱识别和可调谐的热辐射调制。对这一光谱范围的掌握支撑了广泛且不断增长的技术套件,包括高分辨率MIR成像和光谱气体传感,通过辐射冷却/加热和动态发射率控制的先进热管理,具有低损耗光学窗口和波导的集成光子平台,以及利用宽带透明度进行高效频率转换和光束传输的MIR激光系统。因此,高MIR透射率(TMIR)对于推动MIR光子创新至关重要,可以实现高效的光子传输、调制和有针对性的热控制。然而,材料结构、光子/电子行为和MIR光学性能之间的基本相互作用仍未得到充分探讨。本文综合评价了高TMIR材料,重点介绍了它们的光学机制、结构属性、合成途径和性能基准。通过阐明MIR透明材料的结构-性能关系和设计策略,本综述为开发用于先进热管理、红外光学和下一代光子系统的高性能MIR透明材料提供了路线图。
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引用次数: 0
High-Performance Differential Imaging via Reconfigurable Black Phosphorus p–n Homojunction Optoelectronics 基于可重构黑磷p-n同结光电子学的高性能差分成像。
IF 36.3 1区 材料科学 Q1 Engineering Pub Date : 2026-02-28 DOI: 10.1007/s40820-026-02104-z
Rui Hao, Lili Luo, Lu Yang, Xue Yang, Fengsong Gao, Meijie Zhu, Yingtao Li, Qingliang Feng, Zemin Zhang

Highlights

  • Ferroelectric BiFeO3 gating dynamically switches the black phosphorus (BP) homojunction between p–n and n–p states, enabling non-volatile reconfiguration.

  • BP/BiFeO3 heterostructure achieves broadband self-powered photodetection from 365 to 1550 nm, with responsivity ranging from 44 mA W–1 (808 nm) to 1.6 A W−1 (425 nm) and specific detectivity up to 1.8×1012 Jones.

  • Differential imaging leverages reversible p–n/n–p polarity switching to cancel common-mode static noise and enhance edge detection in near-infrared imaging.

差分成像和自适应机器视觉的进步需要能够动态调制信号的硬件,而传统的光电探测器受到静态掺杂轮廓和固定结极性的限制。为了克服这一瓶颈,我们提出了一种可重构的黑磷(BP) p-n同质结光电探测器,通过原位铁电畴规划设计。通过利用铋铁氧体衬底的非易失性铁电场,我们实现了BP带结构的精确、无损调制,允许在单个器件通道内在p-n和n-p构型之间可逆切换。这种铁电掺杂策略有效地消除了与离子注入相关的界面损伤,同时实现了可编程整流行为。在零偏置条件下,该器件在808 nm处的响应率为44 mA W-1。至关重要的是,我们展示了一个单像素成像原型,其中可重构的结极性可以实现可调的边缘清晰度和高保真图像重建。这项工作为铁电可编程2D器件建立了一个范例,为差分成像和对比度增强光电应用提供了一个通用平台。
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引用次数: 0
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Nano-Micro Letters
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