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Hydrogel Fiber Evaporator with Vertical Channels Integrated with Dual Heat Supply/Insulation Model for Continuous Solar Desalination 垂直通道水凝胶纤维蒸发器集成双供热/保温模式连续太阳能脱盐。
IF 36.3 1区 材料科学 Q1 Engineering Pub Date : 2026-02-28 DOI: 10.1007/s40820-026-02120-z
Tian Wang, Shuai Gao, Yongli Yu, Zhigang Chen, Lili Wang, Xiansheng Zhang
AbstractSection Highlights
  • A versatile yet scalable “wet-spinning hydrogel fibers assisted with constrained alignment (HFCA)” strategy is proposed to achieve a highly vertical hydrogel fiber aggregate with multiscale pore structure.

  • The dual “heat supply/insulation model” transforms the conventional single cold evaporation into cold/hot evaporation on the side surface for the first time, maximizing energy utilization of 3D evaporator.

  • HFCA makes a breakthrough in verticalization of water transport channels and maximum utilization of energy, accompanied with superior salt tolerance, anti-oil fouling and self-cleaning ability.

基于水凝胶的蒸发器为海水淡化提供了独特的优势,但由于聚合物的随机排列,水输送通道的高度垂直化仍然受到很大的限制。本文提出了一种通用且可扩展的“湿纺水凝胶纤维辅助约束排列(HFCA)”策略,用于制造分层多孔水凝胶纤维蒸发器,实现相邻纤维之间的完美垂直、大尺度空间和水凝胶内部的小尺度孔隙。多尺度孔隙的协同作用显著增强了纤维间的虹吸效应和水分输送能力,同时改善了热局部化、光吸收和盐通量。此外,在三维蒸发器中首次引入了双重“供热/保温模型”,而不是采用流行的“隔热模型”,其中一个新的加热层向散装水提供额外的热量,以及一个最大限度地减少热量损失的保温层。这些组件共同创造了一个正的净能量平衡,将单一的冷转化为侧面表面的冷/热组合蒸发方式。利用该模型,HFCA蒸发器在已有的水凝胶蒸发器中具有较高的蒸发速率(8.09 kg m-2 h- 1,1 KW m-2),并具有优异的室外蒸发量(64.74 kg m-2, 9 h),同时具有耐盐、抗油污和自清洁能力。
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引用次数: 0
Dual-Piezo-Charge Strategy in (1–0)–3 Single-Crystal Composite for Enhancing Underwater Acoustic Sensing (1-0)-3单晶复合材料中增强水声传感的双压电电荷策略。
IF 36.3 1区 材料科学 Q1 Engineering Pub Date : 2026-02-28 DOI: 10.1007/s40820-026-02102-1
Yu Lei, Xiaotian Li, Zewei Hou, Bing Wang, Shuguang Zheng, Yang Wei, Zhonghui Yu, Jiawang Hong, Shuxiang Dong

Highlights

  • (1–0)–3 single-crystal piezocomposite (SCPC) based on [011]-oriented relaxor PIN-PMN-PT crystal was fabricated via a modified method combining 3D printing-assisted dice-and-insert with dice-and-fill techniques.

  • The (1–0)–3 SCPC, characterized by ordered and poled microholes and incorporating a dual-piezo-charge mechanism, achieves an ultrahigh hydrostatic figure of merit dhgh of about 8089 × 10−15 m2 N−1.

  • The ultrasound transducer based on (1–0)–3 SCPC exhibits a ~ 70% enhancement in underwater acoustic sensitivity while maintaining a broad − 3 dB bandwidth of 130 kHz.

压电超声换能器(put)广泛应用于各种技术领域,但传统的1-3压电复合材料在声灵敏度和流体静力性能方面的进一步提高已经趋于稳定,其结构几十年来基本保持不变。本文报道了一种基于[011]取向Pb(In1/2Nb1/2)O3-Pb(Mg1/3Nb2/3)O3-PbTiO3 (PIN-PMN-PT)单晶的(1-0)-3单晶压电复合材料(SCPC),该材料具有压电和压电极体协同效应产生的双压电电荷(DPC)机制。在单相压电柱中有意引入具有排列偶极子的有序极性0相微孔,从而产生独特的低有效介电常数,降低声阻抗,以及传统scpc无法实现的DPC性能。仿真和实验均证实,这种DPC机制在(1-0)-3 SCPC中实现了~ 8089 × 10-15 m2 N-1的超高密度,比商用1-3 SCPC和1-3压电陶瓷复合材料分别提高了443.2%和890.6%。设计的微孔结构和DPC策略还可以显著提高水声灵敏度,同时保持130 kHz的宽3db带宽,这对海上安全和避碰至关重要。同时,长期试验进一步验证了PUT的运行稳定性。这种设计方法为下一代压电复合材料和PUT技术提供了一条有前途的途径。
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引用次数: 0
Novel Gradient p-Doping Strategy Enables Efficient Carbon-Based Hole Transport Layer-Free Perovskite Solar Cells 新型梯度p掺杂策略实现高效碳基空穴传输无层钙钛矿太阳能电池。
IF 36.3 1区 材料科学 Q1 Engineering Pub Date : 2026-02-23 DOI: 10.1007/s40820-026-02112-z
Junwei Xiang, Siqi Jiang, Yanjie Cheng, Weiting Du, Yuan Shi, Song Shen, Bolun Zhang, Qian Yue, Xinyi Xu, Anyi Mei, Yang Zhou, Yinhua Zhou, Hongwei Han

Highlights

  • A novel strategy of creating spontaneous formation of gradient p-doping in perovskite embedded in mesoporous oxide scaffold is developed.

  • The feasibility of implementing a gradient p-doping strategy in printable mesoscopic perovskite solar cells is demonstrated for the first time through combined device simulations and cross-sectional photoluminescence mapping.

  • The resulting carbon-based hole transport layer-free solar cell exhibits outstanding power conversion efficiency along with superior operational stability over 1500 h without UV filter at 55 °C.

碳基无空穴传输层(html -free)可打印介观钙钛矿太阳能电池(p-MPSCs)因其低成本和可扩展的制造工艺而具有很高的吸引力。然而,钙钛矿本质上的n型性质,加上缺乏HTL,严重阻碍了孔的提取,限制了设备的性能。在这项工作中,我们创新地引入了一种具有强吸电子能力的聚合物作为p-MPSCs的添加剂。由于其大分子尺寸,该聚合物在制造过程中自发地在介孔支架内形成从上到下的负梯度分布。这种分布在p-MPSCs中创造了有利的梯度p掺杂谱,促进了更有效的空穴传输,这一发现得到了组合器件模拟和截面光致发光映射的证实。因此,优化后的p-MPSCs在无UV滤光器的卤素灯模拟1太阳照射下,平均开路电压提高超过50 mV,稳态功率转换效率为21.56%,工作稳定性超过1500 h,温度为55°C。
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引用次数: 0
Engineering PtFe/LiO2 Frontier Orbital Interaction in Li–O2 Batteries 工程PtFe/LiO2前沿轨道相互作用在Li-O2电池。
IF 36.3 1区 材料科学 Q1 Engineering Pub Date : 2026-02-18 DOI: 10.1007/s40820-026-02085-z
Yin Zhou, Kun Yin, Tian Zhang, Dongyu Feng, Jiapei Li, Anquan Zhu, Dewu Lin, Pan Xue, Yu Liu, Yongyu Liu, Kai Liu, Kunlun Liu, Chuhao Luan, Huawei Yang, Hou Chen, Yagang Yao, Guo Hong

Highlights

  • PtFe catalyst was rationally designed based on frontier molecular orbital theory to investigate orbital-level interactions for enhanced oxygen evolution reaction activity in Li–O2 batteries.

  • The dz2dz2 orbital coupling between Fe and Pt leads to electron donation from Fe to Pt, increasing electron population in the Pt dz2 orbital.

  • Excess electrons from the Pt dz2 orbital occupy antibonding states with LiO2, weakening interaction strength and boosting oxygen evolution reaction kinetics.

在锂氧(Li-O2)电池中,在轨道水平上阐明催化活性位点的电子结构与析氧反应(OER)活性之间的构效关系至关重要,但也具有挑战性。本文采用前沿分子轨道理论,设计了Pt基催化剂作为模型阴极,研究了Pt dz2轨道与LiO2的5σ轨道之间的前沿轨道相互作用对OER活性的影响。具体来说,与纯Pt催化剂相比,PtFe催化剂中低电负性Fe和Pt之间的dz2-dz2轨道耦合导致主要电子从Fe转移到Pt的dz2前沿轨道。随着PtFe合金中Pt含量的逐渐增加(从Pt58Fe42、Pt67Fe33到Pt76Fe24), Pt 5dz2轨道的电子居数逐渐降低(Pt58Fe42为1.92,Pt67Fe33为1.85,Pt76Fe24为1.80)。这导致Pt dz2轨道与LiO2的前沿轨道之间的相互作用强度逐渐增强,从而导致OER催化活性逐渐下降。建立dz2前沿轨道上的电子居数与OER活性之间的关系,为设计高效的锂氧电池电催化剂提供了一个描述符。
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引用次数: 0
Adhesion Reinforcement of Electrode–Electrolyte Interface in Flexible Electrochemical Energy Storage Devices 柔性电化学储能装置中电极-电解质界面的粘结增强
IF 36.3 1区 材料科学 Q1 Engineering Pub Date : 2026-02-17 DOI: 10.1007/s40820-026-02084-0
Xian Xie, Qiuhong Wang, Faheem Mushtaq, Kelong Ao, Hong Zhao, Walid A. Daoud

Wearable and deformable electronics are becoming increasingly essential components of modern healthcare and daily life. To power such devices, flexible electrochemical energy storage (FEES) plays a critical role. The practical performance of FEES is dominated by charge and mass transfer at the electrode-electrolyte interface, similar to many rigid battery technologies. However, a unique challenge for FEES is the durability of this interface under deformation. Herein, we present the first comprehensive review of the interface physics, unveiling the crucial role of interface adhesion in the mechanical endurance of FEES. By bridging adhesion physics, material chemistry, and device mechanics, adhesion reinforcement strategies are comprehensively discussed and quantitatively compared, providing multi-scale mechanisms for optimizing FFES interface - from nanoscale bond engineering to microscale surface topology, mechanical interlocking, and macroscale device design. Further, inspired by the synergetic effect of adhesion mechanisms, we propose potential research directions for durable electrode-electrolyte interfaces under dynamic deformation. We also revisit the evaluation of flexibility and electrochemical performance, proposing an application-driven bending index for device assessment. These insights on electrode-electrolyte interface physics of FEES will facilitate the flourishing future of flexible devices.

可穿戴和可变形的电子产品正在成为现代医疗保健和日常生活中越来越重要的组成部分。为了给这种装置供电,柔性电化学储能(FEES)起着至关重要的作用。与许多刚性电池技术类似,FEES的实际性能主要取决于电极-电解质界面的电荷和质量传递。然而,对于FEES来说,一个独特的挑战是这种接口在变形下的耐久性。在此,我们首次全面回顾了界面物理,揭示了界面粘附在FEES机械耐久性中的关键作用。通过连接粘附物理、材料化学和器件力学,全面讨论和定量比较粘附增强策略,为优化FFES界面提供多尺度机制-从纳米尺度的键合工程到微尺度的表面拓扑、机械联锁和宏观尺度的器件设计。此外,受粘附机制协同作用的启发,我们提出了动态变形下持久电极-电解质界面的潜在研究方向。我们还重新审视了柔性和电化学性能的评估,提出了一个应用驱动的弯曲指数用于设备评估。这些关于FEES电极-电解质界面物理的见解将促进柔性器件的蓬勃发展。
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引用次数: 0
Probing Electrode–Electrolyte Synergy and Bottleneck Breakthrough of Zinc-Ion Capacitors from Two Key Configurations 从两种关键结构探讨锌离子电容器的电极-电解质协同与瓶颈突破
IF 36.3 1区 材料科学 Q1 Engineering Pub Date : 2026-02-17 DOI: 10.1007/s40820-025-02063-x
Yudan Zhang, Hengyuan Hu, Yufeng Yan, Yuankai Huang, Yongbiao Mu, Zhiyu Zou, Kunxiong Zheng, Zhaoyang Yi, Yang Zhao, Miao Zhang, Lin Zeng, Meisheng Han

Highlights

  • This review provides a comprehensive discussion of the energy storage mechanisms, electrode materials, and electrolyte-related challenges in two key configurations: zinc metal anode//capacitive cathode zinc-ion capacitors (ZC-ZICs) and capacitive anode//battery-type cathode ZICs (CB-ZICs).

  • This review provides comprehensive and effective solutions to the core bottleneck issues in the two key configurations.

  • This review proposes forward-looking development roadmap of the ZICs, including pulse voltage activation on carbon electrodes, application of high-entropy materials as electrodes, and the development of stable and multifunctional electrolytes.

为了应对下一代储能系统对高能量密度、高功率密度和超长循环寿命的苛刻要求,学术界继续关注结合电池级能量和电容器级功率特性的耦合器件。锌离子电容器(ZICs)由于其高能量/功率特性、优异的本质安全性和显著的成本优势,已成为储能技术中最有前途的战略候选系统。本文从系统的角度综述了zic的最新研究进展。首先,根据器件结构将zic分为锌金属阳极/电容阴极zic (ZC-ZICs)和电容阳极/电池型阴极ZICs (CB-ZICs),并对其储能机理进行了深入分析。同时,针对ZC-ZICs和CB-ZICs两种构型及其电解质体系,针对问题逐一梳理出其中的关键难题和相应的解决方案。最后,在上述讨论的基础上,本文对zic的材料改性提出了前瞻性建议,包括脉冲电压活化、高熵材料的应用、稳定多功能电解质的开发等,旨在为高性能zic的实际应用提供科学指导,推动高性能zic研究的深入发展。
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引用次数: 0
Bioinspired Vascular Bundle Structured Nanocellulose/PVDF-HFP Composite Membranes for Efficient Ion Transport and Stable All-Solid-State Lithium Batteries 用于高效离子传输和稳定全固态锂电池的生物启发维管束结构纳米纤维素/PVDF-HFP复合膜。
IF 36.3 1区 材料科学 Q1 Engineering Pub Date : 2026-02-14 DOI: 10.1007/s40820-026-02092-0
Chenxiang Gao, Yijie Zhou, Yun Huang, Shuhui Wang, Xiaoyan Ma

Highlights

  • Bioinspired bundle-sheath structure improves electrochemical and thermal stability; nanocellulose composite membranes can be used as high-performance all-solid-state lithium batteries separators.

  • The FFP/ASSPE has a high ionic conductivity of 2.46 × 10−4 S cm−1 at 30 °C.

  • Li|FFP/ASSPE|LFP cells can maintain 77.48% capacity after 1000 cycles at 1 C, and Li|FFP/ASSPE|NCM811 cells maintain 83.94% capacity after 300 cycles of 0.1 C.

原位聚合固态聚合物电解质是实现全固态电池批量生产的一种很有前途的方法。然而,较差的离子电导率和隔膜渗透限制了实际应用。受植物中营养输送维管束的启发,设计并制备了一种由平行堆叠的纳米纤维素束包裹在PVDF-HFP鞘上的仿生氟化纳米纤维素/PVDF-HFP多孔复合膜。氟化纤维素纳米晶体和纤维素纳米纤维通过剪切诱导排列组装的纳米纤维素束形成了低曲率离子传输通道,而PVDF-HFP鞘有利于锂盐解离并增强结构稳定性。得益于这种束鞘结构,复合膜具有优异的离子导电性、稳定性和电解质润湿性。该复合膜制备的聚合物电解质具有较高的离子电导率(30°C)为2.46 × 10-4 S cm-1,电化学稳定窗口(5.3 V)和循环稳定性。因此,Li||LFP电池在1℃下循环1000次后可以保持77.48%的优良容量,Li||NCM811电池在0.1℃下循环300次后可以保持83.94%的容量。此外,袋状电池可以承受高达130℃的温度而不会热失控。这种仿生策略为高性能全固态电池的纤维素分离提供了一条有前途的途径。
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引用次数: 0
Beyond Conversion Chemistry: Unlocking a Cooperative Solid-Solution–Capacitive Sodium-Storage Mechanism in Nickel Phosphide 超越转化化学:解开磷化镍中固溶-电容性钠储存机制。
IF 36.3 1区 材料科学 Q1 Engineering Pub Date : 2026-02-13 DOI: 10.1007/s40820-026-02076-0
Jiaqin Liu, Tongzhen Wang, Jie Yang, Yulei Li, Zhaoqian Li, Jiewu Cui, Yan Yu, Yucheng Wu

Highlights

  • A cooperative dual-mode sodium-storage mechanism, combining interstitial solid-solution intercalation and surface pseudocapacitance, is identified, diverging from the conventional conversion-dominated chemistry of nickel phosphides.

  • In-situ/ex-situ analyses provide direct evidence of reversible Na+ insertion into lattice interstitials through (111)-oriented interplanar channels, enabling low-strain lattice breathing without phase transformation.

  • The freestanding Ni2P composite electrode achieves exceptional performance, including high reversible capacity (≈560 mAh g−1), remarkable rate capability (135 mAh g−1 at 10 A g−1), and long-term stability over 2000 cycles.

富镍磷化镍(Ni2P)由于具有较高的理论容量和固有的电子导电性而成为一种很有前途的钠离子电池负极,但其电荷存储化学仍然存在争议,并且通常被过度简化为转化反应。在此,我们设计了一种独立的Ni2P复合电极,该电极由超小型Ni2P纳米晶体嵌入磷掺杂的石墨烯类多孔碳基体中组成。综合原位和非原位分析明确地证明了一种间隙固溶机制,其中Na+离子通过(111)取向的面间通道可逆地占据晶格间隙,诱导可逆晶格呼吸而不发生相变。这种大块插入过程与大量的假电容贡献协同耦合,建立了协作双模存储机制。得益于这种固溶电容化学,电极提供了高可逆容量(≈560 mAh g-1),出色的倍率容量(10 a g-1时135 mAh g-1),以及出色的长期稳定性(2000次循环后263 mAh g-1)。当与Na3V2(PO4)3@C阴极配对时,整个电池达到245 Wh kg-1的高能密度。这项工作建立了固溶-电容耦合作为设计高倍率和耐用钠离子电池阳极的一般范例。
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引用次数: 0
Facilitated Polysulfide Redox Conversion by Delocalized Electrons in MBene Heterointerface for Highly Stable Lithium–Sulfur Batteries 高稳定锂硫电池MBene异质界面中离域电子促进多硫化物氧化还原转化
IF 36.3 1区 材料科学 Q1 Engineering Pub Date : 2026-02-11 DOI: 10.1007/s40820-026-02100-3
Guifen Wu, Yunmiao Fan, Jiatong Li, Zhaoxi Shen, Yuxiu Xie, Peixun Yang, Jun Pu

The shuttle effect of lithium polysulfides (LiPSs) and sluggish redox kinetics severely restrict the development of high-energy lithium–sulfur (Li–S) batteries. To alleviate this issue, this study adopts an in situ design strategy to construct tungsten carbide (WC) nanocrystals on the surface of two-dimensional (2D) tungsten boride (WB)-based MBene, creatively forming a WB@WC heterostructure to optimize the adsorption–migration–catalysis mechanism of LiPSs. The WB–WC heterointerface reduces the reaction energy barrier of LiPSs due to the electron delocalization effect and promotes the deposition/dissociation of Li2S and the transfer of charge. In situ Raman verified that WB@WC can effectively inhibit LiPSs shuttling. In situ X-ray absorption fine structure spectroscopy (XAFS) characterizations further explored the dynamic change of W valence state during LiPSs redox cycle. Encouragingly, the WB@WC-modified Li–S cell delivers an initial capacity of 1277 mAh g−1 at 0.2 C. It exhibits extremely stable cycling performance at 2 C, with a low-capacity decay rate of only ~ 0.024% per cycle. Even under sulfur loading of 7.92 mg cm−2, high capacity of 7.9 mAh cm−2 can still be achieved. This work provides an effective method for regulating the activity of MBene-based catalysts.

多硫化物锂(LiPSs)的穿梭效应和缓慢的氧化还原动力学严重制约了高能锂硫(li -硫)电池的发展。为了解决这一问题,本研究采用原位设计策略,在二维(2D)硼化钨(WB)基MBene表面构建碳化钨(WC)纳米晶,创造性地形成WB@WC异质结构,优化LiPSs的吸附-迁移-催化机制。WB-WC异质界面由于电子离域效应降低了LiPSs的反应能垒,促进了Li2S的沉积/解离和电荷的转移。原位拉曼实验证实WB@WC能有效抑制LiPSs的穿梭。原位x射线吸收精细结构光谱(XAFS)表征进一步探讨了LiPSs氧化还原循环过程中W价态的动态变化。令人鼓舞的是,WB@WC-modified Li-S电池在0.2 C时的初始容量为1277 mAh g-1,在2 C时表现出极其稳定的循环性能,每次循环的低容量衰减率仅为~ 0.024%。即使在7.92 mg cm-2的硫负荷下,仍然可以实现7.9 mAh cm-2的高容量。本研究为mbene基催化剂的活性调控提供了一种有效的方法。
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引用次数: 0
Enabling Highly Efficient and Stable Perovskite Photovoltaics via A Multidentate Molecular Anchor Additive 通过多齿分子锚定添加剂实现高效稳定的钙钛矿光伏。
IF 36.3 1区 材料科学 Q1 Engineering Pub Date : 2026-02-11 DOI: 10.1007/s40820-026-02098-8
Liangding Zheng, Tai Wu, Lei Yang, Yong Hua

Highlights

  • A novel multifunctional additive (ZL1) enables formamidinium loss suppression and perovskite stabilization via synergistic multisite interactions.

  • ZL1 demonstrates defect passivation, enhanced charge carrier extraction, and reduced charge recombination.

  • The optimized devices exhibit a high champion efficiency of 26.13%, combined with robust photothermal stability.

抑制甲脒(FA)的损失和钙钛矿相降解是实现高效、长期稳定的钙钛矿太阳能电池(PSCs)的关键。在此,我们设计并合成了一种新型多功能添加剂(ZL1),通过协同多位点相互作用来稳定α-FAPbI3钙钛矿相:它的F原子与FA+形成F··H-N氢键,(ii)它的苯基环与FA+参与阳离子-π相互作用,(iii) C=O和S基团通过刘易斯酸碱相互作用配位Pb2+, (iv) NH基团通过N-H··i氢键与i -阴离子结合。因此,ZL1分子可以有效抑制FA损失,优化钙钛矿结晶动力学,制备出晶粒尺寸增大、缺陷密度降低、质量稳定的α-FAPbI3钙钛矿薄膜。同时,ZL1处理促进激子解离,有利于钙钛矿层空穴提取到空穴输运层,减少器件中载流子的复合。zl1修饰器件的功率转换效率为26.13%,明显优于控制器件(24.20%)。在宽带隙psc中观察到类似的改善,经过ZL1处理后效率从18.44%提高到20.53%。值得注意的是,未封装的基于zl1的器件在照明和热条件下都表现出出色的操作稳定性。
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引用次数: 0
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Nano-Micro Letters
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