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Reversible Metamorphosis of a Conjugated Polymer Induced by Photoexcitation 光激发诱导共轭聚合物的可逆变态
IF 3.9 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-03-07 DOI: 10.1002/adpr.202500311
Solomon L. Joseph, Anmol Arya, Günter Reiter

Optoelectronic properties of materials are frequently examined through spectroscopic tools based on the absorption and emission of (visible) photons. Typically, one assumes that these transient characterization processes do not cause observable change of these properties because of the low power of the employed light sources. However, for flexible conjugated polymers in a medium of low viscosity, it is decidedly unclear whether photoexcitation of electrons on the backbone of a long polymer chain has an influence on macromolecular conformations and the corresponding intermolecular interactions. Here, we provide clear experimental evidence that continuous absorption of photons progressively causes persistent changes in the spectroscopic properties of conjugated polymers, accompanied by microscopically observable changes in their spatial distribution within a low-viscosity matrix. By contrast, all these changes were completely absent in nonilluminated parts of the same sample. Quantitative spectral analysis allowed to identify the fraction of molecules that underwent such metamorphosis, which increased with the dose of photoexcitation, that is, with the number of absorbed photons. Complementary experiments revealed the reversibility of this behavior and so demonstrated the integrity of the polymers. Our results depict new pathways for tailoring properties of conjugated polymers and widening their spectrum of advanced engineering applications.

材料的光电特性通常通过基于(可见)光子的吸收和发射的光谱工具来检测。通常,人们假设这些瞬态表征过程不会引起这些特性的可观察到的变化,因为所使用的光源功率低。然而,对于低粘度介质中的柔性共轭聚合物,长聚合物链主链上电子的光激发是否会影响大分子构象和相应的分子间相互作用,目前还不清楚。在这里,我们提供了清晰的实验证据,证明光子的连续吸收逐渐导致共轭聚合物光谱特性的持续变化,伴随着显微镜下可观察到的低粘度矩阵内空间分布的变化。相比之下,所有这些变化在同一样品的未照明部分完全不存在。定量光谱分析可以确定发生这种变形的分子的比例,这种变形随光激发剂量的增加而增加,即随吸收光子的数量而增加。补充实验揭示了这种行为的可逆性,从而证明了聚合物的完整性。我们的研究结果描绘了定制共轭聚合物性能和扩大其先进工程应用范围的新途径。
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引用次数: 0
Modeling and Optimization of Frequency-Doubled Radio-Over-Fiber Link Based on Deep Learning Technique 基于深度学习技术的倍频光纤无线链路建模与优化
IF 3.9 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-03-07 DOI: 10.1002/adpr.70167
Difei Shi, Xiangyan Meng, Hanxin Chen, Wei Li

Deep learning (DL) technology has shown extensive potential for modeling radio-over-fiber (RoF) systems. Meanwhile, frequency multiplication technology serves as an effective approach to reduce the bandwidth requirements of core components in RoF links. However, the introduction of harmonic interference, nonlinear distortion, and phase noise in frequency-doubled RoF systems poses additional challenges to DL-based modeling and optimization. A DL-based frequency doubled RoF link end-to-end (E2E) modeling and optimization method is proposed. The DL model consist of three models: a signal preprocessing model for symbol mapping and signal generation, a fiber channel model for transmission link modeling in addition with a receiver model for demodulation. Numerical analysis is carried out based on 16QAM RoF signal with a bit rate of 2 Gbit/s, which indicates that the DL model is capable of modeling the frequency doubled RoF link which incorporates harmonic and nonlinear distortion effects. Moreover, geometry shaping and probabilistic shaping are performed based on E2E framework to further enhance the performance of the system. The results show that the optimized link has better bit error rate performances, indicating that our approach holds potential applications in nonlinear RoF link modeling and could valuable insights for advanced communication systems.

深度学习(DL)技术在光纤无线电(RoF)系统建模方面显示出了广泛的潜力。同时,乘频技术是降低RoF链路中核心器件带宽需求的有效途径。然而,倍频RoF系统中谐波干扰、非线性失真和相位噪声的引入给基于dl的建模和优化带来了额外的挑战。提出一种基于dl的倍频RoF链路端到端(E2E)建模与优化方法。DL模型由三个模型组成:一个用于符号映射和信号生成的信号预处理模型,一个用于传输链路建模的光纤通道模型以及一个用于解调的接收器模型。以比特率为2 Gbit/s的16QAM RoF信号为例进行了数值分析,结果表明DL模型能够对包含谐波和非线性失真效应的倍频RoF链路进行建模。此外,基于端到端框架进行几何整形和概率整形,进一步提高了系统的性能。结果表明,优化后的链路具有更好的误码率性能,表明我们的方法在非线性RoF链路建模中具有潜在的应用前景,并为先进的通信系统提供了有价值的见解。
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引用次数: 0
Reversible Metamorphosis of a Conjugated Polymer Induced by Photoexcitation 光激发诱导共轭聚合物的可逆变态
IF 3.9 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-03-07 DOI: 10.1002/adpr.202500311
Solomon L. Joseph, Anmol Arya, Günter Reiter

Optoelectronic properties of materials are frequently examined through spectroscopic tools based on the absorption and emission of (visible) photons. Typically, one assumes that these transient characterization processes do not cause observable change of these properties because of the low power of the employed light sources. However, for flexible conjugated polymers in a medium of low viscosity, it is decidedly unclear whether photoexcitation of electrons on the backbone of a long polymer chain has an influence on macromolecular conformations and the corresponding intermolecular interactions. Here, we provide clear experimental evidence that continuous absorption of photons progressively causes persistent changes in the spectroscopic properties of conjugated polymers, accompanied by microscopically observable changes in their spatial distribution within a low-viscosity matrix. By contrast, all these changes were completely absent in nonilluminated parts of the same sample. Quantitative spectral analysis allowed to identify the fraction of molecules that underwent such metamorphosis, which increased with the dose of photoexcitation, that is, with the number of absorbed photons. Complementary experiments revealed the reversibility of this behavior and so demonstrated the integrity of the polymers. Our results depict new pathways for tailoring properties of conjugated polymers and widening their spectrum of advanced engineering applications.

材料的光电特性通常通过基于(可见)光子的吸收和发射的光谱工具来检测。通常,人们假设这些瞬态表征过程不会引起这些特性的可观察到的变化,因为所使用的光源功率低。然而,对于低粘度介质中的柔性共轭聚合物,长聚合物链主链上电子的光激发是否会影响大分子构象和相应的分子间相互作用,目前还不清楚。在这里,我们提供了清晰的实验证据,证明光子的连续吸收逐渐导致共轭聚合物光谱特性的持续变化,伴随着显微镜下可观察到的低粘度矩阵内空间分布的变化。相比之下,所有这些变化在同一样品的未照明部分完全不存在。定量光谱分析可以确定发生这种变形的分子的比例,这种变形随光激发剂量的增加而增加,即随吸收光子的数量而增加。补充实验揭示了这种行为的可逆性,从而证明了聚合物的完整性。我们的研究结果描绘了定制共轭聚合物性能和扩大其先进工程应用范围的新途径。
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引用次数: 0
Modeling and Optimization of Frequency-Doubled Radio-Over-Fiber Link Based on Deep Learning Technique 基于深度学习技术的倍频光纤无线链路建模与优化
IF 3.9 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-03-07 DOI: 10.1002/adpr.70167
Difei Shi, Xiangyan Meng, Hanxin Chen, Wei Li

Deep learning (DL) technology has shown extensive potential for modeling radio-over-fiber (RoF) systems. Meanwhile, frequency multiplication technology serves as an effective approach to reduce the bandwidth requirements of core components in RoF links. However, the introduction of harmonic interference, nonlinear distortion, and phase noise in frequency-doubled RoF systems poses additional challenges to DL-based modeling and optimization. A DL-based frequency doubled RoF link end-to-end (E2E) modeling and optimization method is proposed. The DL model consist of three models: a signal preprocessing model for symbol mapping and signal generation, a fiber channel model for transmission link modeling in addition with a receiver model for demodulation. Numerical analysis is carried out based on 16QAM RoF signal with a bit rate of 2 Gbit/s, which indicates that the DL model is capable of modeling the frequency doubled RoF link which incorporates harmonic and nonlinear distortion effects. Moreover, geometry shaping and probabilistic shaping are performed based on E2E framework to further enhance the performance of the system. The results show that the optimized link has better bit error rate performances, indicating that our approach holds potential applications in nonlinear RoF link modeling and could valuable insights for advanced communication systems.

深度学习(DL)技术在光纤无线电(RoF)系统建模方面显示出了广泛的潜力。同时,乘频技术是降低RoF链路中核心器件带宽需求的有效途径。然而,倍频RoF系统中谐波干扰、非线性失真和相位噪声的引入给基于dl的建模和优化带来了额外的挑战。提出一种基于dl的倍频RoF链路端到端(E2E)建模与优化方法。DL模型由三个模型组成:一个用于符号映射和信号生成的信号预处理模型,一个用于传输链路建模的光纤通道模型以及一个用于解调的接收器模型。以比特率为2 Gbit/s的16QAM RoF信号为例进行了数值分析,结果表明DL模型能够对包含谐波和非线性失真效应的倍频RoF链路进行建模。此外,基于端到端框架进行几何整形和概率整形,进一步提高了系统的性能。结果表明,优化后的链路具有更好的误码率性能,表明我们的方法在非线性RoF链路建模中具有潜在的应用前景,并为先进的通信系统提供了有价值的见解。
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引用次数: 0
Diffractive Neural Networks for High-Throughput Classification of Objects in Microfluidic Systems 微流体系统中高通量物体分类的衍射神经网络
IF 3.9 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-03-06 DOI: 10.1002/adpr.202500272
Jingli Li, Steffen Schoenhardt, Jeffrey Harmon, Jochen Guck, Min Gu, Elena Goi

The integration of optical imaging and machine learning on microfluidic platforms makes it possible to achieve high-content, minimally invasive characterization of a population of samples on a single chip. As the analysis of this high-content information is typically conducted in the electronic domain, optoelectronic conversion speeds and the bandwidth available for data processing put a limitation on the throughput of these methods. In this work, we present an analysis system based on diffractive neural networks with the potential for integration in microfluidic systems for high-content classification of objects with high sampling rates. We show that such a system can distinguish objects by size through passive optical inference with a numerical test accuracy of 98.2% and an experimental test accuracy of 83.4%, in an environment compatible with a microfluidic chamber. This development paves the way for novel approaches in high-speed phenotyping of large cell populations based on all-optical or hybrid optoelectronic neuromorphic information processing.

在微流控平台上集成光学成像和机器学习,可以在单个芯片上实现高含量,微创的样本群表征。由于这种高含量信息的分析通常在电子领域进行,因此光电转换速度和可用于数据处理的带宽限制了这些方法的吞吐量。在这项工作中,我们提出了一个基于衍射神经网络的分析系统,该系统具有集成在微流体系统中的潜力,用于高采样率的高含量物体分类。实验结果表明,该系统在微流控室环境下,通过被动光学推断可以区分物体的大小,数值测试精度为98.2%,实验测试精度为83.4%。这一发展为基于全光或混合光电神经形态信息处理的大细胞群高速表型分析的新方法铺平了道路。
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引用次数: 0
Diffractive Neural Networks for High-Throughput Classification of Objects in Microfluidic Systems 微流体系统中高通量物体分类的衍射神经网络
IF 3.9 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-03-06 DOI: 10.1002/adpr.202500272
Jingli Li, Steffen Schoenhardt, Jeffrey Harmon, Jochen Guck, Min Gu, Elena Goi

The integration of optical imaging and machine learning on microfluidic platforms makes it possible to achieve high-content, minimally invasive characterization of a population of samples on a single chip. As the analysis of this high-content information is typically conducted in the electronic domain, optoelectronic conversion speeds and the bandwidth available for data processing put a limitation on the throughput of these methods. In this work, we present an analysis system based on diffractive neural networks with the potential for integration in microfluidic systems for high-content classification of objects with high sampling rates. We show that such a system can distinguish objects by size through passive optical inference with a numerical test accuracy of 98.2% and an experimental test accuracy of 83.4%, in an environment compatible with a microfluidic chamber. This development paves the way for novel approaches in high-speed phenotyping of large cell populations based on all-optical or hybrid optoelectronic neuromorphic information processing.

在微流控平台上集成光学成像和机器学习,可以在单个芯片上实现高含量,微创的样本群表征。由于这种高含量信息的分析通常在电子领域进行,因此光电转换速度和可用于数据处理的带宽限制了这些方法的吞吐量。在这项工作中,我们提出了一个基于衍射神经网络的分析系统,该系统具有集成在微流体系统中的潜力,用于高采样率的高含量物体分类。实验结果表明,该系统在微流控室环境下,通过被动光学推断可以区分物体的大小,数值测试精度为98.2%,实验测试精度为83.4%。这一发展为基于全光或混合光电神经形态信息处理的大细胞群高速表型分析的新方法铺平了道路。
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引用次数: 0
Experimental Demonstration of Unified Kerr Nonlinear Effective Lengths for Gallium Phosphide-On-Insulator Photonic Devices 绝缘体上磷化镓光子器件统一Kerr非线性有效长度的实验论证
IF 3.9 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-03-05 DOI: 10.1002/adpr.70166
Weiren Cheng, Ning Ding, Xucheng Zhang, Yifan Wang, Yatao Yang, Zhenyu Liu, Xingyu Tang, Mingjian You, Yi Li, Xingchen Ji, Qiancheng Zhao

Field enhancement (FE) plays a pivotal role in boosting the four-wave mixing conversion efficiency (FWM CE)in photonic resonant cavities. While previous studies typically attributed this enhancement to intracavity power buildup, fewer have linked it to the effective nonlinear interaction length. In this work, we propose a different perspective that FE can be interpreted as an elongation of effective length. Moreover, we establish a unified framework that bridges nonresonant waveguides and resonant cavities through this generalized effective length concept. We validate the model experimentally using direct-bonded gallium phosphide-on-insulator waveguides and microresonators. We achieve an intrinsic quality (Q) factor of 2.8 × 104 for the TM00 resonance at 1546.15 nm wavelength. The TM00 mode FWM CE is −37.12 dB in a 25 µm-radius microresonator, 18 dB higher than that in a 4.8 mm-long waveguide of identical cross section and polarization under the same on-chip power of 10 dBm. The FWM CEs of both the waveguides and the microresonators exhibit a well-correlated relation versus their effective lengths, confirming the unified theoretical framework. These experimentally validated findings offer a fresh perspective on Kerr nonlinearity and pave the way toward advancing the development of highly efficient nonlinear photonic devices and products.

场增强在提高光子谐振腔的四波混频转换效率方面起着至关重要的作用。虽然以前的研究通常将这种增强归因于腔内功率的积累,但很少将其与有效非线性相互作用长度联系起来。在这项工作中,我们提出了一个不同的观点,即FE可以解释为有效长度的延伸。此外,我们建立了一个统一的框架,通过这个广义有效长度的概念,桥接非谐振波导和谐振腔。我们用直接键合的绝缘体上磷化镓波导和微谐振器对模型进行了实验验证。我们在1546.15 nm波长处实现了TM00共振的内在质量因子(Q)为2.8 × 104。在半径为25 μ m的微谐振腔中,TM00模式FWM的等效等效系数为−37.12 dB,比相同截面和极化的4.8 mm长波导在相同片上功率为10 dBm时的等效等效等效系数高18 dB。波导和微谐振腔的FWM ce与其有效长度均表现出良好的相关关系,证实了统一的理论框架。这些实验验证的发现为克尔非线性提供了一个新的视角,并为推进高效非线性光子器件和产品的开发铺平了道路。
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引用次数: 0
Experimental Demonstration of Unified Kerr Nonlinear Effective Lengths for Gallium Phosphide-On-Insulator Photonic Devices 绝缘体上磷化镓光子器件统一Kerr非线性有效长度的实验论证
IF 3.9 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-03-05 DOI: 10.1002/adpr.70166
Weiren Cheng, Ning Ding, Xucheng Zhang, Yifan Wang, Yatao Yang, Zhenyu Liu, Xingyu Tang, Mingjian You, Yi Li, Xingchen Ji, Qiancheng Zhao

Field enhancement (FE) plays a pivotal role in boosting the four-wave mixing conversion efficiency (FWM CE)in photonic resonant cavities. While previous studies typically attributed this enhancement to intracavity power buildup, fewer have linked it to the effective nonlinear interaction length. In this work, we propose a different perspective that FE can be interpreted as an elongation of effective length. Moreover, we establish a unified framework that bridges nonresonant waveguides and resonant cavities through this generalized effective length concept. We validate the model experimentally using direct-bonded gallium phosphide-on-insulator waveguides and microresonators. We achieve an intrinsic quality (Q) factor of 2.8 × 104 for the TM00 resonance at 1546.15 nm wavelength. The TM00 mode FWM CE is −37.12 dB in a 25 µm-radius microresonator, 18 dB higher than that in a 4.8 mm-long waveguide of identical cross section and polarization under the same on-chip power of 10 dBm. The FWM CEs of both the waveguides and the microresonators exhibit a well-correlated relation versus their effective lengths, confirming the unified theoretical framework. These experimentally validated findings offer a fresh perspective on Kerr nonlinearity and pave the way toward advancing the development of highly efficient nonlinear photonic devices and products.

场增强在提高光子谐振腔的四波混频转换效率方面起着至关重要的作用。虽然以前的研究通常将这种增强归因于腔内功率的积累,但很少将其与有效非线性相互作用长度联系起来。在这项工作中,我们提出了一个不同的观点,即FE可以解释为有效长度的延伸。此外,我们建立了一个统一的框架,通过这个广义有效长度的概念,桥接非谐振波导和谐振腔。我们用直接键合的绝缘体上磷化镓波导和微谐振器对模型进行了实验验证。我们在1546.15 nm波长处实现了TM00共振的内在质量因子(Q)为2.8 × 104。在半径为25 μ m的微谐振腔中,TM00模式FWM的等效等效系数为−37.12 dB,比相同截面和极化的4.8 mm长波导在相同片上功率为10 dBm时的等效等效等效系数高18 dB。波导和微谐振腔的FWM ce与其有效长度均表现出良好的相关关系,证实了统一的理论框架。这些实验验证的发现为克尔非线性提供了一个新的视角,并为推进高效非线性光子器件和产品的开发铺平了道路。
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引用次数: 0
Front Cover: Nonreciprocal Terahertz Propagation via InSb Topological Photonic Crystals (Adv. Photonics Res. 3/2026) 封面:通过InSb拓扑光子晶体的非互易太赫兹传播(ad . Photonics Res. 3/2026)
IF 3.9 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-03-02 DOI: 10.1002/adpr.70165
Chun-Yu Li, Yong-Jun Xie, Pei-Yu Wu, Sai Chen

Low-Field Non-Reciprocal Terahertz Devices

Indium antimonide (InSb) rod arrays enable robust unidirectional propagation at terahertz frequencies under low magnetic fields (0.1 T). By exploiting the Voigt effect and dispersive scaling, this work realizes magnetic-field-controlled non-reciprocal devices that exhibit topological immunity to defects and sharp bends. More information can be found in the Research Article by Sai Chen and co-workers (10.1002/adpr.202500253).

低场非互易太赫兹器件锑化铟(InSb)棒阵列在低磁场(0.1 T)下实现了太赫兹频率下的鲁棒单向传播。通过利用Voigt效应和色散缩放,本工作实现了磁场控制的非互易器件,该器件对缺陷和急剧弯曲具有拓扑免疫。更多信息可以在Sai Chen及其同事的研究文章(10.1002/adpr.202500253)中找到。
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引用次数: 0
Front Cover: Nonreciprocal Terahertz Propagation via InSb Topological Photonic Crystals (Adv. Photonics Res. 3/2026) 封面:通过InSb拓扑光子晶体的非互易太赫兹传播(ad . Photonics Res. 3/2026)
IF 3.9 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-03-02 DOI: 10.1002/adpr.70165
Chun-Yu Li, Yong-Jun Xie, Pei-Yu Wu, Sai Chen

Low-Field Non-Reciprocal Terahertz Devices

Indium antimonide (InSb) rod arrays enable robust unidirectional propagation at terahertz frequencies under low magnetic fields (0.1 T). By exploiting the Voigt effect and dispersive scaling, this work realizes magnetic-field-controlled non-reciprocal devices that exhibit topological immunity to defects and sharp bends. More information can be found in the Research Article by Sai Chen and co-workers (10.1002/adpr.202500253).

低场非互易太赫兹器件锑化铟(InSb)棒阵列在低磁场(0.1 T)下实现了太赫兹频率下的鲁棒单向传播。通过利用Voigt效应和色散缩放,本工作实现了磁场控制的非互易器件,该器件对缺陷和急剧弯曲具有拓扑免疫。更多信息可以在Sai Chen及其同事的研究文章(10.1002/adpr.202500253)中找到。
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引用次数: 0
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Advanced Photonics Research
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