{"title":"Biomaterials and Structural Materials","authors":"Alan Kin Tak Lau, A. D. Pramata","doi":"10.4028/b-qt3ohm","DOIUrl":"https://doi.org/10.4028/b-qt3ohm","url":null,"abstract":"","PeriodicalId":7271,"journal":{"name":"Advanced Materials Research","volume":"468 ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-01-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140471305","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Cheng Wei Liu, En Wei Qin, Guo Xing Chen, Shao Chong Wei, Yang Zou, Lin Ye, Shu Hui Wu
As a post treatment, thermal remelting is an effective method to eliminate pores and establish a metallurgical bonding for thermal sprayed coatings. However, it is rather difficult to obtain simultaneously high corrosion and wear resistance, since additional energy input usually leads to more homogeneous microstructure in coatings, which deteriorates mechanical hardness. In this work, flame remelting has been imposed to high velocity oxygen-fuel sprayed self-flux NiCrBSi coatings. The remelting effects on microstructure were characterized in terms of porosity and phase analysis. The microhardness, wear resistance and corrosive behaviors were compared among substrate steel, as-sprayed and as-remelted coatings. Results show that the lamellar boundaries and internal defects in the as-sprayed coatings have been eliminated by remelting. The coating porosity has substantially reduced from 7.36% to 0.75%, and a metallurgical bonding at the coating/substrate interface has been formed. Comparing with the as-sprayed coatings, the microhardness of the remelted coatings increases about 21% and the wear weight loss reduces about 42%. By flame remelting, the wear mechanism changes from furrow and abrasive wear to micro-cutting and local fracture. The remelted coatings have also exhibited better corrosion resistance by means of salt spraying and potentiodynamic tests.
{"title":"Effect of Flame Remelting on the Microstructure, Wear and Corrosion Resistance of HVOF Sprayed NiCrBSi Coatings","authors":"Cheng Wei Liu, En Wei Qin, Guo Xing Chen, Shao Chong Wei, Yang Zou, Lin Ye, Shu Hui Wu","doi":"10.4028/p-v2xcol","DOIUrl":"https://doi.org/10.4028/p-v2xcol","url":null,"abstract":"As a post treatment, thermal remelting is an effective method to eliminate pores and establish a metallurgical bonding for thermal sprayed coatings. However, it is rather difficult to obtain simultaneously high corrosion and wear resistance, since additional energy input usually leads to more homogeneous microstructure in coatings, which deteriorates mechanical hardness. In this work, flame remelting has been imposed to high velocity oxygen-fuel sprayed self-flux NiCrBSi coatings. The remelting effects on microstructure were characterized in terms of porosity and phase analysis. The microhardness, wear resistance and corrosive behaviors were compared among substrate steel, as-sprayed and as-remelted coatings. Results show that the lamellar boundaries and internal defects in the as-sprayed coatings have been eliminated by remelting. The coating porosity has substantially reduced from 7.36% to 0.75%, and a metallurgical bonding at the coating/substrate interface has been formed. Comparing with the as-sprayed coatings, the microhardness of the remelted coatings increases about 21% and the wear weight loss reduces about 42%. By flame remelting, the wear mechanism changes from furrow and abrasive wear to micro-cutting and local fracture. The remelted coatings have also exhibited better corrosion resistance by means of salt spraying and potentiodynamic tests.","PeriodicalId":7271,"journal":{"name":"Advanced Materials Research","volume":"271 2","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-01-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140471890","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Biodiesel tends to oxidation during the time of storage due to chemical structure, makes deterioration of fuel quality. Hence, the presence in feed stock required to gain standard quality for biodiesel commercialization. Natural antioxidant, mainly oryzanol found in rice bran feed stock, have been worked in biodiesel oxidation synergistic without any additional of synthetic antioxidant. In this work, the potential natural antioxidant has been evaluated by the oxidation stability. The biodiesel exhibited oxidation stability gained the induction period at 3 h by Rancimat method. It was found that the concentration of oryzanol above 300 ppm keep the biodiesel from oxidation. Even though very small amount 3 ppm oryzanol was obtained but contribute as cost implication due to antioxidants are costly chemicals. Otherwise adding synthetic antioxidant making high cost on biodiesel storage and utilization.
{"title":"Sinergy of Biodiesel and its Natural Antioxidant from Rice Bran Feedstock","authors":"Ghusrina Prihandini, Dhyna Analyses, Tifa Paramita, Rony Pasonang Sihombing","doi":"10.4028/p-0zmhd9","DOIUrl":"https://doi.org/10.4028/p-0zmhd9","url":null,"abstract":"Biodiesel tends to oxidation during the time of storage due to chemical structure, makes deterioration of fuel quality. Hence, the presence in feed stock required to gain standard quality for biodiesel commercialization. Natural antioxidant, mainly oryzanol found in rice bran feed stock, have been worked in biodiesel oxidation synergistic without any additional of synthetic antioxidant. In this work, the potential natural antioxidant has been evaluated by the oxidation stability. The biodiesel exhibited oxidation stability gained the induction period at 3 h by Rancimat method. It was found that the concentration of oryzanol above 300 ppm keep the biodiesel from oxidation. Even though very small amount 3 ppm oryzanol was obtained but contribute as cost implication due to antioxidants are costly chemicals. Otherwise adding synthetic antioxidant making high cost on biodiesel storage and utilization.","PeriodicalId":7271,"journal":{"name":"Advanced Materials Research","volume":"6 9","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-01-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140477392","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
F. Ayodele, T. Ajijola, Ohunene Usman, Jonathan Segun Adekanmi
This study investigates the influence of cow bone powder (CBP) on consistency and compaction characteristics of lime-stabilized soil. Twelve soil samples were collected from four routes connecting Ado-Ekiti. Index and compaction tests were performed on the natural and stabilized samples. The soil samples were classified according to AASHTO groups and eventually restructured into four (4) groups: A-6, A-7-6, A-4, and A-7-5. They were named samples A, B, C, and D respectively. The oxide compositions of the samples were determined. Lime was blended with soils at proportions of 0, 2, 4, 6, 8,10 %, and the optimal lime content (LimeOpt) was obtained. The LimeOpt + soil mixture was mixed with 2, 4, 6, 8,10 % of CBP. The Soil + LimeOpt + CBP mixtures were subjected to consistency limits and compaction tests. Plasticity index (PI) of soils A, B, C, and D was 14.19, 21.06, 11.64, and 14.19 % respectively, while the MDD was 1640, 1730, 1630, and 1631 kg/m3. Soil A, B, C, and D + LimeOpt all had reduced PIs of 7.68, 16.40, 5.04, and 12.05%, respectively. For the MDD of soil + LimeOpt mixtures, 1789, 1920, 1906, and 1898 kg/m3 were also found for Samples A, B, C, and D. Soil + LimeOpt + CBP showed that both the PI (from 0.6 to 81.7%) and MDD (from 0.1 to 14.6%) improved. On the other hand, the addition of lime to soils A, B, C, and D showed that 8% lime content offered the optimal CBR performance. Further addition of CBP to the soil + LimeOpt mixtures equally improved both the soaked and unsoaked CBR of soils A, B, C, and D predominantly with 6% CBP addition offering the peak performance. This suggests that CBP is viable and can save cost, mitigate environmental hazards, and complement lime. Strength and durability evaluation of the ternary mixture is however recommended.
{"title":"Influence of Cow Bone Powder on Selected Engineering Properties of Lime-Stabilized Soil","authors":"F. Ayodele, T. Ajijola, Ohunene Usman, Jonathan Segun Adekanmi","doi":"10.4028/p-v0qpkz","DOIUrl":"https://doi.org/10.4028/p-v0qpkz","url":null,"abstract":"This study investigates the influence of cow bone powder (CBP) on consistency and compaction characteristics of lime-stabilized soil. Twelve soil samples were collected from four routes connecting Ado-Ekiti. Index and compaction tests were performed on the natural and stabilized samples. The soil samples were classified according to AASHTO groups and eventually restructured into four (4) groups: A-6, A-7-6, A-4, and A-7-5. They were named samples A, B, C, and D respectively. The oxide compositions of the samples were determined. Lime was blended with soils at proportions of 0, 2, 4, 6, 8,10 %, and the optimal lime content (LimeOpt) was obtained. The LimeOpt + soil mixture was mixed with 2, 4, 6, 8,10 % of CBP. The Soil + LimeOpt + CBP mixtures were subjected to consistency limits and compaction tests. Plasticity index (PI) of soils A, B, C, and D was 14.19, 21.06, 11.64, and 14.19 % respectively, while the MDD was 1640, 1730, 1630, and 1631 kg/m3. Soil A, B, C, and D + LimeOpt all had reduced PIs of 7.68, 16.40, 5.04, and 12.05%, respectively. For the MDD of soil + LimeOpt mixtures, 1789, 1920, 1906, and 1898 kg/m3 were also found for Samples A, B, C, and D. Soil + LimeOpt + CBP showed that both the PI (from 0.6 to 81.7%) and MDD (from 0.1 to 14.6%) improved. On the other hand, the addition of lime to soils A, B, C, and D showed that 8% lime content offered the optimal CBR performance. Further addition of CBP to the soil + LimeOpt mixtures equally improved both the soaked and unsoaked CBR of soils A, B, C, and D predominantly with 6% CBP addition offering the peak performance. This suggests that CBP is viable and can save cost, mitigate environmental hazards, and complement lime. Strength and durability evaluation of the ternary mixture is however recommended.","PeriodicalId":7271,"journal":{"name":"Advanced Materials Research","volume":"353 2","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-01-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140473197","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
R. Narzary, Tani Chekke, S. Ngadong, Biswarup Satpati, S. Bayan, Upamanyu Das
We report on an approach for the in-situ synthesis (chemical method based) of SnO-SnO2 nanocomposites followed by characterisation (including morphological, chemical, structural and optical) and investigation of the electrical properties of the nanocomposites with reference to the as-synthesized SnO2 nanoparticles. Compared to spherical SnO2 particles, the SnO phase is found existing in the form of sheet like morphology. It has been found that through controlling of the Sn:OH precursor ratio is effective for the achievement of SnO phase. Compared to the pristine SnO2 nanoparticles, the current-voltage (I-V) characteristics of the nanocomposites show the p-n junction characteristics. The observation of rectification ratio 2.05 indicates the excellent rectifying property of the nanocomposites due to the presence of p-type SnO phase. Further, exploration of the I-V characteristics has revealed the dominance of space-charge limited current transport mechanism for the nanocomposites sample. The lattice defects are discovered to be the cause of the transport mechanism in the nanocomposites sample.
{"title":"SnO-SnO2 Nanocomposites Based pn Diode: In Situ Synthesis, Characterization and Fabrication of Device for pn Diode Applicability","authors":"R. Narzary, Tani Chekke, S. Ngadong, Biswarup Satpati, S. Bayan, Upamanyu Das","doi":"10.4028/p-6v9m01","DOIUrl":"https://doi.org/10.4028/p-6v9m01","url":null,"abstract":"We report on an approach for the in-situ synthesis (chemical method based) of SnO-SnO2 nanocomposites followed by characterisation (including morphological, chemical, structural and optical) and investigation of the electrical properties of the nanocomposites with reference to the as-synthesized SnO2 nanoparticles. Compared to spherical SnO2 particles, the SnO phase is found existing in the form of sheet like morphology. It has been found that through controlling of the Sn:OH precursor ratio is effective for the achievement of SnO phase. Compared to the pristine SnO2 nanoparticles, the current-voltage (I-V) characteristics of the nanocomposites show the p-n junction characteristics. The observation of rectification ratio 2.05 indicates the excellent rectifying property of the nanocomposites due to the presence of p-type SnO phase. Further, exploration of the I-V characteristics has revealed the dominance of space-charge limited current transport mechanism for the nanocomposites sample. The lattice defects are discovered to be the cause of the transport mechanism in the nanocomposites sample.","PeriodicalId":7271,"journal":{"name":"Advanced Materials Research","volume":"531 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-01-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140479573","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Salman Khan, Zainab Ali, Khadija Rehman, Massab Junaid
Solid-state diffusion bonding effectively joins dissimilar materials, even with varying metallurgical properties and melting points. In this study, a Cu/Ni joint was produced at a bonding temperature of 950°C for 60 minutes under a vacuum. The microstructural and mechanical properties of the bonding interface were evaluated using scanning electron microscopy (SEM) equipped with energy-dispersive spectroscopy (EDS), microhardness tests, and X-ray diffraction (XRD). It was found that the EDS point scan analysis revealed the formation of a solid solution of Cu-Ni at the bonding interface. Since Cu-Ni exhibit complete solubility with each other, no intermetallic compounds (IMCs) were formed. The microhardness indicated that the bonding interface had a microhardness of 20% and 54% higher than the base metals (BM) of Ni and Cu, respectively.
{"title":"Mechanical and Microstructural Characterization of Diffusion-Bonded Copper-Nickel Joint Interface","authors":"Salman Khan, Zainab Ali, Khadija Rehman, Massab Junaid","doi":"10.4028/p-k8wuuo","DOIUrl":"https://doi.org/10.4028/p-k8wuuo","url":null,"abstract":"Solid-state diffusion bonding effectively joins dissimilar materials, even with varying metallurgical properties and melting points. In this study, a Cu/Ni joint was produced at a bonding temperature of 950°C for 60 minutes under a vacuum. The microstructural and mechanical properties of the bonding interface were evaluated using scanning electron microscopy (SEM) equipped with energy-dispersive spectroscopy (EDS), microhardness tests, and X-ray diffraction (XRD). It was found that the EDS point scan analysis revealed the formation of a solid solution of Cu-Ni at the bonding interface. Since Cu-Ni exhibit complete solubility with each other, no intermetallic compounds (IMCs) were formed. The microhardness indicated that the bonding interface had a microhardness of 20% and 54% higher than the base metals (BM) of Ni and Cu, respectively.","PeriodicalId":7271,"journal":{"name":"Advanced Materials Research","volume":"281 ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-01-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140474934","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
R. M. Bulatao, P. Eugenio, John Paulo A. Samin, J. R. Salazar, J. Monserate
Nanoencapsulation technology has been used in food and pharmaceutical applications to increase bioactive chemical functioning and stability against external influences. To develop a cost-effective encapsulating procedure, additional optimization is required. This study employed response surface methodology (RSM) to optimize the encapsulation of anthocyanin-rich extract from black rice bran. The extract was encapsulated through pre-gelation and polyelectrolyte complex formation processes. Box-Behnken design was employed to determine the optimum conditions for the encapsulation process with the following process variables: chitosan concentration, pH, and CaCl2 concentration. Chemical characteristics, surface morphology, and particle size were used to describe the resultant capsules, which were then subjected to phytochemical analysis. The optimal encapsulation conditions for anthocyanin were 6.30 mg/mL chitosan, pH 5.5, and 36 mM CaCl2, with a 51.20 % encapsulation efficiency. The developed anthocyanin-loaded nanocapsule has a high TPC (3.87 mg GAE/g) and potent antioxidant activity (5.69 mg TE/g). SEM images revealed a smooth surface area and spherical particles that clumped together, with an average particle size of 94.70 nm. FTIR analysis corroborates the well-incorporation of anthocyanin into the nanocapsules. The encapsulation process of anthocyanin-rich extract from black rice bran was successfully optimized via RSM.
{"title":"Response Surface Methodology: An Optimization of Process Variables for the Nanoencapsulation of Anthocyanins from Black Rice Bran","authors":"R. M. Bulatao, P. Eugenio, John Paulo A. Samin, J. R. Salazar, J. Monserate","doi":"10.4028/p-rv054a","DOIUrl":"https://doi.org/10.4028/p-rv054a","url":null,"abstract":"Nanoencapsulation technology has been used in food and pharmaceutical applications to increase bioactive chemical functioning and stability against external influences. To develop a cost-effective encapsulating procedure, additional optimization is required. This study employed response surface methodology (RSM) to optimize the encapsulation of anthocyanin-rich extract from black rice bran. The extract was encapsulated through pre-gelation and polyelectrolyte complex formation processes. Box-Behnken design was employed to determine the optimum conditions for the encapsulation process with the following process variables: chitosan concentration, pH, and CaCl2 concentration. Chemical characteristics, surface morphology, and particle size were used to describe the resultant capsules, which were then subjected to phytochemical analysis. The optimal encapsulation conditions for anthocyanin were 6.30 mg/mL chitosan, pH 5.5, and 36 mM CaCl2, with a 51.20 % encapsulation efficiency. The developed anthocyanin-loaded nanocapsule has a high TPC (3.87 mg GAE/g) and potent antioxidant activity (5.69 mg TE/g). SEM images revealed a smooth surface area and spherical particles that clumped together, with an average particle size of 94.70 nm. FTIR analysis corroborates the well-incorporation of anthocyanin into the nanocapsules. The encapsulation process of anthocyanin-rich extract from black rice bran was successfully optimized via RSM.","PeriodicalId":7271,"journal":{"name":"Advanced Materials Research","volume":"803 ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-01-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140476437","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Bone tissue engineering has been used in the biomedical field to treat bone defects by implanting scaffolds into bone tissue. However, the currently developed scaffold still needs to be developed to obtain scaffold building materials with good compatible properties and can regenerate damaged bone cells. This study combines PVA/Chitosan polymer with CHA of tuna bone using the porogen leaching method at a calcination temperature of 100°C for 12 hours. The purpose of this study was to determine the physicochemical properties by characterizing XRD, SEM-EDX, FTIR, and the porosity of the scaffold. The results obtained from the results of the PVA/Chitosan/CHA XRD patterns are the formation of the PVA/Chitosan phase at 2θ(°)=19.68, the IR spectrum of the 43−group band and 2 stretching, the ratio mol Ca/P is 1.98, the pore diameter is 1.561 ± 0.07 μm and the porosity is 55.04%. These results indicate that the PVA/Chitosan/CHA scaffold is an amorphous calcium phosphate (ACP) that has the potential for bone tissue engineering.
{"title":"Characterization of PVA/Chitosan and Tuna Fish Bones CHA Scaffold for Bone Tissue Engineering","authors":"Sulistiyani Hayu Pratiwi, M. Sari, Yusril Yusuf","doi":"10.4028/p-blfv8p","DOIUrl":"https://doi.org/10.4028/p-blfv8p","url":null,"abstract":"Bone tissue engineering has been used in the biomedical field to treat bone defects by implanting scaffolds into bone tissue. However, the currently developed scaffold still needs to be developed to obtain scaffold building materials with good compatible properties and can regenerate damaged bone cells. This study combines PVA/Chitosan polymer with CHA of tuna bone using the porogen leaching method at a calcination temperature of 100°C for 12 hours. The purpose of this study was to determine the physicochemical properties by characterizing XRD, SEM-EDX, FTIR, and the porosity of the scaffold. The results obtained from the results of the PVA/Chitosan/CHA XRD patterns are the formation of the PVA/Chitosan phase at 2θ(°)=19.68, the IR spectrum of the 43−group band and 2 stretching, the ratio mol Ca/P is 1.98, the pore diameter is 1.561 ± 0.07 μm and the porosity is 55.04%. These results indicate that the PVA/Chitosan/CHA scaffold is an amorphous calcium phosphate (ACP) that has the potential for bone tissue engineering.","PeriodicalId":7271,"journal":{"name":"Advanced Materials Research","volume":"52 6","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-01-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140478487","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Microwave heating was used with a gas foaming method for fabricating limestone carbonated hydroxyapatite scaffold (SCHA). Carbonated hydroxyapatite (CHA) was produced from limestone as a calcium source using the co-precipitation method. For further treatment, 0.6 gr CHA powder was mixed in 1 ml H2O2 solution as a blowing agent. The slurry-foam-like CHA was heated in a microwave with different levels of heating power from 180 W to 720 W. The SCHA samples were characterized using X-ray diffraction (XRD), Fourier-transform infrared (FTIR), and Scanning electron microscope (SEM). The crystallinity and crystallite size were affected due to different rates of heating power in the microwave-assisted method. The increasing temperature decreased the crystallite size from 37.49 to 33.97(nm). However, other crystallinity trends were observed at 180 W because the lower power heating needed a longer time to be formed SCHA. The different power rates have an insignificant contribution to the morphology of the scaffolds.
利用微波加热和气体发泡法制造石灰石碳化羟基磷灰石支架（SCHA）。碳化羟基磷灰石（CHA）以石灰石为钙源，采用共沉淀法制备而成。为了进一步处理，将 0.6 克 CHA 粉末混合在 1 毫升 H2O2 溶液中作为发泡剂。用 X 射线衍射（XRD）、傅立叶变换红外（FTIR）和扫描电子显微镜（SEM）对 SCHA 样品进行了表征。在微波辅助方法中，不同的加热功率会影响结晶度和晶粒尺寸。随着温度的升高，结晶尺寸从 37.49nm 减小到 33.97nm。然而，在 180 W 下观察到了其他的结晶趋势，因为低功率加热需要更长的时间才能形成 SCHA。不同的功率对支架的形态影响不大。
{"title":"The Effect of Power Rate Microwave Heating on Limestone Carbonated Hydroxyapatite Scaffold Using Gas Foaming Method","authors":"Dyah Aris Widyastuti, Yusril Yusuf","doi":"10.4028/p-6gy5gl","DOIUrl":"https://doi.org/10.4028/p-6gy5gl","url":null,"abstract":"Microwave heating was used with a gas foaming method for fabricating limestone carbonated hydroxyapatite scaffold (SCHA). Carbonated hydroxyapatite (CHA) was produced from limestone as a calcium source using the co-precipitation method. For further treatment, 0.6 gr CHA powder was mixed in 1 ml H2O2 solution as a blowing agent. The slurry-foam-like CHA was heated in a microwave with different levels of heating power from 180 W to 720 W. The SCHA samples were characterized using X-ray diffraction (XRD), Fourier-transform infrared (FTIR), and Scanning electron microscope (SEM). The crystallinity and crystallite size were affected due to different rates of heating power in the microwave-assisted method. The increasing temperature decreased the crystallite size from 37.49 to 33.97(nm). However, other crystallinity trends were observed at 180 W because the lower power heating needed a longer time to be formed SCHA. The different power rates have an insignificant contribution to the morphology of the scaffolds.","PeriodicalId":7271,"journal":{"name":"Advanced Materials Research","volume":"27 ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-01-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140478828","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ketankumar G. Chitte, J. Narkhede, Ravindra G. Puri, Tushar Deshpande, Mahendra Bari, Ujwal Patil
To increase cohesiveness, toughness, impermeability, and adhesion strength in cementitious materials like mortars and concrete, vinyl acetate ethylene (VAE) copolymer redispersible powder (RDP) is used. However, due to numerous variety of material, choosing an original performing RDP is challenging. The goal of this study is to assess the bond strength to concrete surfaces of various redispersible polymer-modified cementitious coatings under various accelerated settings. The outcomes showed that the RDP backbone composition has a significant influence on the coatings' adhesion strength. Methyl methacrylate (MMA) and Vinyl chloride (VC) present as comonomers in RDP exhibit outstanding thermal stability and boost tensile adhesion strength by 41% and 21%, respectively, in comparison to other RDPs. According to SEM studies, the VC- RDP stimulates the formation of fibrous ettringite, producing a uniform and cohesive microstructure.
{"title":"Cementitious Coatings for Concrete Surfaces: Effects of Curing Conditions on Performance Measure","authors":"Ketankumar G. Chitte, J. Narkhede, Ravindra G. Puri, Tushar Deshpande, Mahendra Bari, Ujwal Patil","doi":"10.4028/p-ro4ybi","DOIUrl":"https://doi.org/10.4028/p-ro4ybi","url":null,"abstract":"To increase cohesiveness, toughness, impermeability, and adhesion strength in cementitious materials like mortars and concrete, vinyl acetate ethylene (VAE) copolymer redispersible powder (RDP) is used. However, due to numerous variety of material, choosing an original performing RDP is challenging. The goal of this study is to assess the bond strength to concrete surfaces of various redispersible polymer-modified cementitious coatings under various accelerated settings. The outcomes showed that the RDP backbone composition has a significant influence on the coatings' adhesion strength. Methyl methacrylate (MMA) and Vinyl chloride (VC) present as comonomers in RDP exhibit outstanding thermal stability and boost tensile adhesion strength by 41% and 21%, respectively, in comparison to other RDPs. According to SEM studies, the VC- RDP stimulates the formation of fibrous ettringite, producing a uniform and cohesive microstructure.","PeriodicalId":7271,"journal":{"name":"Advanced Materials Research","volume":"77 ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-01-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140475656","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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